971 resultados para Jillson, Willard Rouse, 1890-
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针对大规模计算机网络的脆弱性评估,提出了一种基于贝叶斯网络近似推理的评估方法,对网络各组件和影响网络安全的因素进行建模,采用模型检测工具生成攻击状态转移图,描述网络脆弱性的利用过程,通过采用随机采样的方法对网络的攻击状态转移图进行近似推理,经过对采样样本的统计分析得到网络脆弱性评估的量化结果,为提升网络的安全性能提供理论依据。
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本论文应用应力应变和动态力学方法,系统地表征了L_n-PIR的粘弹行为及其对聚合物链结构、分子量和分子量分布的依赖性,建立了有关力学量与分子量和分子量之间的相互作用规律的数学模式。结果表明,聚合物的粘弹力学量可以用有效分子量的概念来描述:P=K{(M-bar)_ηexp[(M-bar)_w/(M-bar)_n-1]}~(-α) <1>不同类型的分子量的K_D值是不同的,其K_D大小顺序为:(M-bar)_n > (M-bar)_w > (M-bar)_k > (M-bar)_z。弹性物理量对分子量分布的依赖性较粘性物理量为小。分子量和分子量分布对屈服行为的影响,可以归结为分子链缠结行为的作用。L_n-PIR的屈服强度与链缠结点数(m-1)之间的关系满足如下指数方程λ_yσ_y=5.99*10~5(m-1)~(0.47),达因·厘米~(-2) <2>聚合物的屈服活化能与解链缠结活化能等值等效,均是为使分子链开始解缠结,克服缠结间链段的分子间作用力所做的功,是链缠结分子量的函数。对L_n-PIR,ΔEy与Me之间的关系为 ΔEy=-148.0+40.0 logMe,千焦/摩尔 <3>在M-bar=Mc时,ΔEy达最大值,为其流动活化能。L_n-PIR的屈服破坏能等效于解分子链缠结能,是为使缠结点解脱,克服缠结点的单体单元之间的范德华力所做的功。ΔEd是缠结点数(m-1)的函数ΔEd.=1.38*10~4(m-1),焦耳·摩尔~(-1) <4>单个链缠结点对ΔEd的贡献是相同的,约为0.143er,相当于相互缠结的两分子链段的链节单元之间的距离接近于范德华平衡半径re=2.84A的分子间作用力。另由于L_n-PIR聚合物本体内存在的紧密的分子链缠结结构,导致非牛顿效应,其流变行为和应力松弛行为偏离牛顿线性流动规律。L_n-PIR的本体粘度与分子量和分子量分布的关系为η_0~(100)=8.91*10~(-19) (M-bar)_η~(4.25)exp[-0.30*4.25((M-bar)_w/(M-bar)_n-1)],达因·厘米~(-2)·秒 <5>正应力系数与分子量和分子量分布之关系为ξ_0~(100)=1.43*10~(-32) (M-bar)_η~(6.86)exp[-1.10((M-bar)_w/(M-bar)_n-1)],达因·厘米~(-2)·秒<6>由于分子链的热运动状况不同,回复柔量对分子链结构和分子结构的依赖性是随温度而变化的。L_n-PIR在25 ℃和100 ℃时,回复柔量与分子量和分子量分布的关系为25 ℃: Je-o=0.158(M-bar)_η~(-0.75)exp[+0.298((M-bar)_w/(M-bar)_n-1)],达因~(-1)·厘米~2 <7> 100 ℃: Je-o=1.32*10~6(M-bar)_η~(-1.81)exp[0.704((M-bar)_w/(M-bar)_n-1)]达因~(-1)·厘米~2 <8>最大松弛时间与(M-bar)_η、MWD之关系为Jm=1.19*10~(-6)(M-bar)_η~(1.72)exp[-0.282((M-bar)_w/(M-bar)_n-1)],秒<9> Rouse松弛时间与(M-bar)_η、MWD之关系为Jr=1.79*10~(-14)(M-bar)_η~(3.46)exp[-0.567((M-bar)_w/(M-bar)_n-1)],秒 <10>。
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采用热丝化学气相沉积技术制备了一系列处于不同生长阶段的薄膜样品,用原子力显微镜系统地研究生长在单晶硅衬底和玻璃衬底上薄膜表面形貌的演化.按照分形理论分析得到:在玻璃衬底上的硅薄膜以零扩散随机生长模式生长;而在单晶硅衬底上,薄膜早期以有限扩散生长模式生长,当膜厚超过某一临界厚度时转变为零扩散随机生长模式.岛面密度与膜厚的依赖关系表明,在临界厚度时硅衬底和玻璃衬底上的岛面密度均出现了极大值.Raman谱的测量证实,玻璃衬底上薄膜临界厚度与非晶/微晶相变之间存在密切的关系.不同的衬底材料直接影响反应基元的表面扩散能力,从而造成薄膜早期生长模式的差异.
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在历史旱涝记载资料可靠性检验的基础上,重建了湖北省3个区域近500年来的干湿气候变化序列,并比较分析了各区域干湿气候变化的趋势特征、准周期性及跃变现象。结果表明:在3个区域中,鄂东区1570~1770、1890~1950年两个时段偏湿,1470~1520、1790~1830年则偏干;鄂北区偏湿时期主要在1470~1530、1710~1750、1850~1910年三个时段,1470~1530、1770~1830年则偏干;鄂西南区有1550~1610、1650~1710、1830~1890、1930~1990
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The biosensing application of single-walled carbon nanohorns (SWCNHs) was demonstrated through fabrication of an amperometric glucose biosensor. The biosensor was constructed by encapsulating glucose oxidase in the Nafion-SWCNHs composite film. The cyclic voltammograms for glucose oxidase immobilized on the composite film displayed a pair of well-defined and nearly symmetric redox peaks with a formal potential of -0.453V. The biosensor had good electrocatalytic activity toward oxidation of glucose.
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Ti45Zr35Ni13Pd7 alloys are prepared by melt spinning at different cooling rates (v). The phase structure and electrochemical hydrogen storage performance are investigated. When U is 10 m/s, the alloy consists of icosahedral quasicrystalline phase (I-phase), C14 Laves phase and a little amorphous phase. When v increases to 20 or 30 m/s, a mixed structure of I-phase and amorphous phase is formed. Maximum discharge capacity of alloy electrode decreases from 156 mAh/g (v = 10 m/s) to 139 mAh/g (v = 30 m/s) with increasing v. High-rate discharge ability at the discharge current density of 240 mA/g decreases monotonically from 61.2% (v = 10 m/s) to 56.8% (v = 30 m/s).
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The mechanical and thermal properties of glass bead-filled nylon-6 were studied by dynamic mechanical analysis (DMA), tensile testing, Izod impact, thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC) tests. DMA results showed that the incorporation of glass beads could lead to a substantial increase of the glass-transition temperature (T-g) of the blend, indicating that there existed strong interaction between glass beads and the nylon-6 matrix. Results of further calculation revealed that the average interaction between glass beads and the nylon-6 matrix deceased with increasing glass bead content as a result of the coalescence of glass beads. This conclusion was supported by SEM observations. Impact testing revealed that the notch Izod impact strength of nylon-6/glass bead blends substantially decreased with increasing glass bead content. Moreover, static tensile measurements implied that the Young's modulus of the nylon-6/glass bead blends increased considerably, whereas the tensile strength clearly decreased with increasing glass bead content.
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Gradient colloidal crystals with a thickness gradient were prepared by the vertical deposition technique with vertically graded concentration suspensions. The thickness of the gradient colloidal crystal gradually changes at different positions along the specific gradient direction of the crystal. The thickness gradient was determined by the concentration gradient, depending on the initial colloidal concentration and the settling time. The optical transmission intensity at the dip wavelength can be tuned by changing the thickness of the colloidal crystals. The gradient colloidal crystals lead to a gradient of optical intensity at the dip in transmission light. The gradient of optical intensity at the dip increases as the thickness gradient of the colloidal crystal increases.
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The present paper reports 8 pontoniine shrimp species, from Anambas and Natuna, Indonesia, i. e., Anchistus miersi (De Man, 1888), Conchodytes meleagrinae Peters, 1852, Hamodacotylus boschmai Holthuis, 1952, Jocaste japonica (Ortmann, 1890), Palaemonella pottsi (Borradaile, 1915), Periclimenes andamanensis Kemp, 1922, Periclimenes attenuatus Bruce, 1971, and Periclimenes grandis (Stimpson, 1860).
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建立并检测印度獐牙菜和川西獐牙菜中獐牙菜苦苷、龙胆苦苷、芒果苷、异荭草苷4种苷类成分含量的反相高效液相色谱分析方法.结果表明,该方法简单,准确,快速,可作为獐牙菜类药材的质量控制依据.
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In this paper, we studied the secular variations of the main geomagnetic field during 1900-2000 in details. Emphasis is put on three aspects of the secular variations, i.e. westward drifts and intensity variations of non-dipole part, the decay of the dipole field. Firstly, we introduced the method of correlation analysis of moving random pattern into Geomagnetism in order to overcome the weakness of available methods on westward drift studies. We had committed testing and modifying the method, and analyzed the westward drifts and intensity variations of the non-dipole parts of geomagnetic field and 6 planetary-scale geomagnetic anomalies by this way. The globe and area characters of the westward drifts and intensity variations were discussed in detail. Second, the lat-dependence and dispersion of drift velocities were examined carefully. The results showed the velocities of the different wavelengths (from m = 1 to m = 10) geomagnetic potential were changing with the latitude. The lat-dependence of drift velocities is related to the latitude distributing of the geomagnetic potential. There was a negative dispersion in the westward drift, namely, the components of long wavelength drift faster than that of short wavelengths. Finally, we calculated the moments of the geomagnetic dipole, and found that the intensity of the dipole fields has been decreasing. Linking to the results in paleomagnetism, we draw a conclusion that the geomagnetic polarities may be reversed in 700 years.
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了解过去是认识现在和预测未来的基础。晚全新世是PAGES研究的目标时段之一。寻找和解译最近2000年连续、高分辨率自然记录是古气候研究的热点与难点。本项研究有针对性地选择程海、草海和青海湖开展湖泊沉积物环境记录的精细研究,结合14C、210Pb和137Cs定年,系统探讨了碳酸盐碳氧同位素、纤维素碳氧同位素、有机质碳同位素以及介形虫壳体Li/Ca比值指标的古环境指示意义。 通过研究,本论文取得了如下成果和新的认识: 1. 建立了一套有效的四阶段湖泊沉积物有机质纤维素提取方法(5%NaOH碱洗、5%HCl酸洗、亚氯酸钠和冰醋酸混合溶液漂白以及17.5%NaOH碱洗),红外光谱鉴定提取物为纯的α-纤维素,表明该实验方法是可行的,为今后广泛开展湖泊沉积物纤维素稳定同位素研究打下了坚实基础。 2. 多指标综合辨识了程海和草海沉积物碳酸盐主要是自生碳酸盐。程海和草海沉积物有机质C/N比值结合有机质碳同位素结果表明两湖的有机质分别源于水生植物藻类和大型水草。程海和草海沉积物碳酸盐含量主要反映了湖区温度的变化。 3. 程海、草海沉积物碳酸盐与青海湖沉积物介形虫壳体氧同位素组成均反映了湖区降水/蒸发比。降水/蒸发比大的湿润期,碳酸盐δ18O值小;降水/蒸发比小的干旱期,碳酸盐δ18O值大。程海沉积物碳酸盐碳同位素组成影响因素复杂,除了受大气与湖水之间的CO2交换影响外,还受水生植物光合/吸收作用的影响;草海沉积物碳酸盐碳同位素组成更大的变化范围,反映了湖区水生植物光合/吸收作用的影响,其异常的正值可能指示了湖区细菌参与有机质碳同位素分馏过程。 4. 利用草海沉积物有机质纤维素氧同位素定量恢复了湖水氧同位素组成变化。在此基础上,结合碳酸盐氧同位素组成初步恢复了草海地区过去500年来温度变化历史:草海地区在过去500年明显存在四个冷期,包括1550-1610年,1670-1730年,1770-1870年和1890-1920年冷期,其中前三个发生在传统意义上的现代小冰期时段。与其它记录研究结果的一致性表明纤维素氧同位素结合碳酸盐氧同位素是恢复古温度变化的最有效途径之一,同时也为现代小冰期在中国西南地区的存在提供了湖泊沉积学方面的证据。 5. 不同类型水生植物湖泊,湖泊沉积物有机质δ13C值对湖泊初级生产力变化的响应过程不同。大型水草为主的湖泊(草海),其沉积物有机质δ13C值随湖泊生产力的增大呈现增加的变化趋势;藻类为主的湖泊(程海),其沉积物有机质δ13C随湖泊生产力的增大呈现减小的变化趋势,藻类易降解是导致δ13C值随湖泊生产力的增大呈现减小变化趋势的主要原因。 6. 程海沉积物碳酸盐和有机质碳同位素组成的正相关变化以及草海沉积物碳酸盐和有机质碳同位素组成的负相关变化.表明湖泊生产力变化并不是导致碳酸盐和有机质碳同位素正相关变化的主要原因,湖泊水生植物类型以及湖泊大小均起着重要作用。湖泊沉积物碳酸盐与有机质之间的碳同位素分馏(△δ13C)是一种有效的湖泊生产力指示剂,即使是在有微生物参与有机质碳同位素分馏过程的草海,△δ13C值也反映了湖泊生产力的变化过程。 7. 青海湖沉积物单一种属介形虫壳体胖真星介(Eucypris inflata)Li/Ca比值与气象记录以及邻近地区都兰和祁连山树轮宽度指数恢复的古温度变化序列的对比研究揭示,介形虫壳体Li/Ca比值与温度呈明显的负相关变化(Li/Ca比值高,温度低;Li/Ca比值低,温度高),表明介形虫壳体Li/Ca比值是一种有效的古温度代用指标。 8. 青海湖沉积物单一种属介形虫壳体胖真星介(Eucypris inflata)Li/Ca比值、氧同位素与反映太阳活动的大气14C含量和冰芯10Be含量的一致性变化表明青海湖地区温度和降雨量的同步变化主要受太阳活动控制。