Identificação de adulteração de biocombustível por adição de óleo residual ao diesel por espectrofluorimetria total 3D e análise das componentes principais

Total spectrofluorimetry associated to Principal Components Analysis (PCA) were used to classify into different groups the samples of diesel oil, biodiesel, vegetal oil and residual oil, as well as, to identify addition of non-transesterified residual vegetable oil, instead of biodiesel, to the diesel oil. Using this method, the samples of diesel oil, mixtures of biodiesel in diesel and mixtures of residual oil in diesel were separated into well-defined groups.

Estudo espectroscópico de compósito obtido da reação no estado sólido entre um complexo mononuclear de vanádio(IV) e caulinita

The use of probes, such as paramagnetic species diluted in diamagnetic materials in EPR spectroscopy, and mathematical tools such, as the Kubelka-Munk function in DRUV-VIS spectroscopy are strategies in the analysis of complex mixtures of solid materials. The results obtained here show that the solid state reaction between the complex, [VO(acac)(BMIMAPY)] [ClO4], BMIMAPY = [(bis(1-methylimidazole-2-yl)methyl)(2-(pyridyl-2-yl)ethyl) amine] and acac = acetilacetonate, with kaolinite turns possible to obtain anisotropic EPR spectrum of the complex with a reasonable level of resolution. The study by DRUV-VIS using the method of second derivative mode of the Kubelka-Munk function revealed new complex structural arrangements, a solid hitherto unknown.

O sistema globalmente harmonizado de classificação e rotulagem de produtos químicos (GHS): uma introdução para sua aplicação em laboratórios de ensino e pesquisa acadêmica

The present article provides an overview of the Globally Harmonised System of Classification, Labelling and Packaging of Chemicals (GHS) and its implementation in Brazil. Although Classification and Packaging is beyond the scope of the responsibility of academic chemists, labelling of chemicals used in academic laboratories will be required by the competent authorities to ensure the safety of students and staff. Therefore, academic teachers and researchers responsible should be familiarised with the GHS principles outlined here and at least be able to label, by applying these principles, mixtures of substances previously classified by the competent authorities.

Avaliação da mineralização de arroz em sistema de refluxo para a determinação de Cu, Fe, Mn e Zn por FAAS

This paper describes the evaluation of a new method of sample preparation using a cold finger system with continuous water flow for rice analysis by flame atomic absorption spectrometry. The limits of detection for Cu, Fe, Mn and Zn for the proposed method were 0.36, 1.84, 2.12 and 0.16 mg kg-1, respectively. The RSDs were lower than 6.0% for all elements and the CRM analyzed showed values with 95% agreement. The proposed method is simple and safe for the proposed objective and does not require the use of mixtures of acid or special equipment for sample preparation.

Otimização da etapa de extração do ácido clavulânico presente no caldo de fermentação utilizando misturas de solventes

The purpose of this work was to study four different solvent mixtures intended to increase the yield of the extraction stage of clavulanic acid (CA), which is one of the steps in the purification process. Four central composite rotatable designs (CCRD) were utilized to optimize the solvent mixtures. The variables selected for the factorial design were solvent mixture ratio (mL/mL) and temperature (ºC). The results showed that the yield of CA extracted from fermentation broth with the solvent mixtures of methyl-ethyl-ketone and ethyl acetate, and methyl-isobutyl-ketone and ethyl acetate (44.7 and 50.0%, respectively) was higher than that of the individual ethyl acetate alone (36.5%).

Pyörivien sähkökoneiden kotelointia koskevat standardit ja aksiaalivuokoneen jäähdytyksen kehittäminen

Tämä diplomityö on osa Lappeenrannan teknillisen yliopiston ja Visedo Oy:n yhteistyöprojektia. Työssä selvitetään pyörivien sähkökoneiden kotelointeja koskevia standardeja ja niiden vaikutukset koneiden suunnittelulle ja valmistukselle. Lisäksi työssä käsitellään aksiaalivuokoneen jäähdytykseen liittyviä ongelmia, kehitetään koneen nykyisiä jäähdytysratkaisuja ja ideoidaan käytettävissä olevia uusia jäähdytysmenetelmiä. Kehitysideoiden rajoitteena toimii koneelta vaadittu kotelointiluokka IP 64 – IP 68 sekä koneelle määritetty kestomagnetoitu aksiaalivuorakenne. Sähkökoneiden kotelointeja koskevien standardien asettamien vaatimusten määrittäminen tapahtui suurilta osin kirjallisuusselvityksenä. Standardien vaikutukset koneiden suunnittelulle ja valmistettavuudelle on selvitetty standardien kotelointien rakenteelle asettamien vaatimusten perusteella. Aksiaalivuokoneen jäähdytysongelmien selvittäminen, käytössä olevien jääh-dytysratkaisujen kehittäminen ja uusien menetelmien ideointi suoritettiin projektiluontoisesti yhdessä eri alojen asiantuntijoista koostuvan jäähdytystyöryhmän kanssa. Työn tuloksena laadittiin Visedo Oy:lle standardikäsikirja, jonka avulla Visedon sähkökoneiden tuoteperheeseen kuuluvien koneiden suunnitteluvaiheessa voidaan varmistaa koneiden standardienmukaisuus. Käsikirjassa on myös esitetty huomioita eri kotelointiluokkien asettamista vaatimuksista koneiden valmistukselle. Aksiaalivuokoneiden jäähdytykseen liittyen tavoitteena oli ratkaista aksiaalivuokoneisiin liittyviä jäähdytysongelmia. Työn tuloksena saa-tiin selville aksiaalivuokoneissa jäähdytyksen kehittämistä vaativat kohteet, laadittiin nykyisten jäähdytysratkaisujen parannusehdotuksia ja kehitettiin täysin uusia jäähdytysmenetelmiä.

Taajuusmuuttajan hyödyntämismahdollisuudet kompressorijärjestelmien elinkaarikustannusten optimoimisessa

Paineilmaa on kutsuttu neljänneksi perushyödykkeeksi veden, sähkön ja kaasun lisäksi. Paineilman kuluttaja on usein myös sen tuottaja. EU:n alueen teollisuudessa keskimää-rin 16 % kulutetusta kokonaissähkötehosta kuluu ilmakompressoreiden käyttöön. Taa-juusmuuttajan käyttö on viime vuosikymmeninä lisääntynyt merkittävästi, kun on pyrit-ty energiatehokkaisiin ratkaisuihin esimerkiksi pumppaus- ja puhallinjärjestelmissä. Kompressorijärjestelmissä taajuusmuuttajien käyttö ei ole vielä yhtä yleistä kuin esi-merkiksi pumppukäytöissä, vaikka taajuusmuuttajan käytöllä saavutetaan useimmissa tapauksissa huomattavia etuja. Tässä työssä tutkitaan taajuusmuuttajan hyödyntämismahdollisuuksia kompressorijär-jestelmien käytönaikaisten elinkaarikustannusten optimoimisessa. Työssä selvitetään säästöpotentiaalia, ja pohditaan pyörimisnopeussäädöllä saavutettavia etuja eri komp-ressorityypeillä. Lopuksi muodostetaan elinkaarikustannusanalyysit kahdelle todelliselle teollisuuden kompressorikohteelle. Tutkimusmenetelminä ovat kirjallisuustyö sekä asi-antuntijahaastattelut teollisuudesta. Työn tavoitteena on kartoittaa taajuusmuuttajan hyödyntämispotentiaalia kompressorijärjestelmissä ja luoda pohjaa mahdolliselle jatko-tutkimukselle.

China's 'Assertive’ South China Sea Policy And Rhetoric: Proactive, Reactive Or Myth?

In March 2010, Chinese State Councillor, Dai Bingguo, in a private meeting with US Deputy Secretary of State, James Steinberg, allegedly referred to the South China Sea (SCS) as one of the country’s ‘core interests’, a term normally only used to refer to regions like Taiwan, Tibet and Xinjiang upon whose sovereignty Beijing will make no compromises. This alleged wording by Mr Dai caused a strong global reaction, with many countries around the world expressing a fear that China, on the back of its rise to the status of the world's second largest economic power, was now about to implement a more assertive foreign policy more in keeping with its new status of global superpower. As the use of the term ‘core interest’ took place in a private meeting and appears to have been subsequently leaked, it is impossible to prove what was said or meant, yet in 2011, with China and the US continuing to eye each other with suspicion, the adverse repercussions of people trying to deduce what was meant are undeniable. By analysing the views of experts and the evolution or otherwise of Chinese rhetoric and policy towards the SCS, this thesis will show how the alleged use of a term in a private meeting can have consequences that far exceed what was originally intended. It will also show that it is highly unlikely that China’s maritime policy is becoming more assertive as, at China's present stage of social and economic development, it simply cannot afford the ill will and adverse consequences that would result from an act of international aggression. It will show how easy it seems to be for a country like the US to project a misleading image of another country’s intentions, which can in turn serve partially to mask its own intentions. Finally, it will show that the China’s stance on the SCS is starting to be seen by the world as a litmus test for the assertiveness of overall Chinese foreign policy.

Sosiaalinen rekrytointikanava - tykkääjien kokemukset yrityksen Facebook-sivusta, case Rekrytointipalvelu Sihti Oy

Pro gradu –tutkielman tavoitteena oli tutkia Facebook-tykkääjien ja Oma Sihti –palveluun kirjautuneiden työnhakijoiden sosiaalisen pääoman rakentumista ja hyödyntämistä. Case-yrityksen toimialana oli henkilöstönvuokraus ja asiantuntijarekrytoinnit. Työn tavoitteena oli lisäksi selvittää kuinka vastavuoroista kommunikointi online-yhteisöissä on, miten aktiivisia ja sitoutuneita yhteisön jäsenet ovat ja kuinka hyvin tykkääjät tuntevat toisensa. Empiirisen tutkimuksen tavoitteena oli tuoda teoria käytännön tasolle ja sosiaalista pääomaa, sen rakentumista ja hyödyntämistä tutkittiin erityisesti vuorovaikutuksen kautta. Tutkimus toteutettiin kvantitatiivisena tapaustutkimuksena. Tutkimusaineisto kerättiin verkkokyselyinä yrityksen Facebook-sivuilla sekä Oma Sihti –palvelussa. Tutkimukseen poimittiin sosiaalisen pääoman alueelta online-yhteisöön liittyvät olennaiset asiat ja tutkittiin niiden näkymistä verkkopalveluissa. Tutkimuksen tulokset tukivat teoriaa. Online-yhteisössä voidaan nähdä olevan sosiaalista pääomaa ja se rakentuu ja sitä hyödynnetään yhteisön jäsenten kesken.

Weed control in young coffee plantations through post emergence herbicide application onto total area

This study was carried out to investigate the efficiency of several herbicides under field conditions, by post-emergence application onto the entire area, their effect on the control of weeds in young coffee plantations and commercial coffee and bean intercropping system, as well as on both crops. Seedlings of Coffea arabica cv. Red Catuaí with four to six leaf pairs were transplanted to the field and treated according to conventional agronomic practices. A bean and coffee intercropping system was established by sowing three lines of beans in the coffee inter-rows. At the time the herbicides were sprayed, the coffee plants had six to ten leaf pairs; the bean plants, three leaflets; and the weeds were at an early development stage. Fluazifop-p-butyl and clethodim were selective for coffee plants and controlled only Brachiaria plantaginea and Digitaria horizontalis efficiently. Broad-leaved weeds (Amaranthus retroflexus, Bidens pilosa, Coronopus didymus, Emilia sonchifolia, Galinsoga parviflora, Ipomoea grandifolia, Lepidium virginicum, and Raphanus raphanistrum) were controlled with high efficiency by sole applications of fomesafen, flazasulfuron, and oxyfluorfen, except B. pilosa, C. didymus, and R. raphanistrum for oxyfluorfen. Sequential applications in seven-day intervals of fomesafen + fluazifop-p-butyl, or clethodim, and two commercial mixtures of fomesafen + fluazifop-p-butyl simultaneously controlled both types of weed. Cyperus rotundus was only controlled by flazasulfuron. Except for fluazifop-p-butyl and clethodim, all herbicide treatments caused only slight injuries on younger coffee leaves. However, further plant growth was not impaired and coffee plant height and stem diameter were therefore similar in the treatments, as evaluated four months later. Fomesafen, fluazifop-p-butyl, and clethodim, at sole or sequential application, and the commercial mixtures of fomesafen + fluazifop-p-butyl were also highly selective for bean crop; thus at doses recommended for bean crop, these herbicides may be applied to control weeds in coffee and bean intercropping systems by spraying the entire area.

Social entrepreneurship – Believe in it or not!

The practice of social entrepreneurship already exists for a long time but the concept is quite new and has more recently raised a growing interest among academics. However, the majority of researches and considerations about the subject have taken a strong positive concern by omitting some sort of a critical reflection. The idea of this study is to consider the gap between the very optimistic and the more precautious concerns about social entrepreneurship. It means presenting the advantages and downsides connected to the topic in the business, public and third sector. The aim is to help the reader building his/her own belief on social entrepreneurship by considering the positive and negative sides of social entrepreneurship. Hence, the research is intended to take a critical step and aims to answer to the following research questions:  Shall we believe in social entrepreneurship?  What are the reasons for believing or not in social entrepreneurship taking into account the advantages and possible risks of it in the business, public, and third sector? The theoretical framework consists of the comparison between the promising and precautious sides about social entrepreneurship for private, public and non-governmental organizations including the actors or participants inside these sectors. The empirical part is conducted using a qualitative method. Personal interviews of experts in the fields of business, public and third sectors were handled. The purpose of this approach is to compare the critics in theory with the experience of persons dealing with social entrepreneurship. The results from the interviews revealed that in general, reasons for believing in social entrepreneurship prevail over critics about the subject. Social entrepreneurship may not yet represent a full performing business. Concerns for weakening the public power and putting aside the interests of communities in need may exist too. Furthermore, naïve and extra liberal ways of thinking or doing can lead to practices going in opposition with initial social objectives. Nevertheless, problems about social entrepreneurship would be mainly due to the young age of the movement. Time and experience would give better foundations and results to social entrepreneurs. Critics about social entrepreneurship could also easily be done to any sorts of business. Overall, the positive considerations of social entrepreneurship with skillful, motivated and responsible actors could represent some useful tools for enterprises, governments and charities. Some tools among many other possibilities to help people in need.

Not Going it Alone: The US National Agenda for Digital Stewardship and Repositories

Presentation at Open Repositories 2014, Helsinki, Finland, June 9-13, 2014

Mating system in Myracrodruon urundeuva (Anarcadiaceae): implications for conservation genetics

The aims of this study were to investigate the mating system of a fragmented population of the dioecious tropical tree Myracrodruon urundeuva Allemão, using five microsatellite loci and the mixed mating and correlated mating models. The study was conducted in the Estação Ecológica de Paulo de Farias (436 ha), where the population occupies about 142 ha. The mating system was estimated using 514 open-pollinated offspring, collected from 30 seed-trees. Estimates of the multilocus outcrossing rate confirm that the species is dioecious (t m = 1.0). Low levels of mating among relatives were detected in the population (1 - t s = 0.020). The estimate of paternity correlation (r p(m)) indicated that offsprings were composed of mixtures of half-sibs and full-sibs, with the latter occurring at a low frequency (average of 0.148). The estimated coancestry coefficient within families (Θ = 0.147) was larger and the effective population size (Ne(v)) was lower (Ne(v) = 2.98) than expected in progenies from panmictic populations (Θ = 0.125, Ne(v) = 4, respectively). In terms of conservation, the results indicate that to retain an effective population size of 150, is necessary to collect seeds from at least 50 seed-trees.

Efficacy, safety, quality control, marketing and regulatory guidelines for herbal medicines (phytotherapeutic agents)

This review highlights the current advances in knowledge about the safety, efficacy, quality control, marketing and regulatory aspects of botanical medicines. Phytotherapeutic agents are standardized herbal preparations consisting of complex mixtures of one or more plants which contain as active ingredients plant parts or plant material in the crude or processed state. A marked growth in the worldwide phytotherapeutic market has occurred over the last 15 years. For the European and USA markets alone, this will reach about $7 billion and $5 billion per annum, respectively, in 1999, and has thus attracted the interest of most large pharmaceutical companies. Insufficient data exist for most plants to guarantee their quality, efficacy and safety. The idea that herbal drugs are safe and free from side effects is false. Plants contain hundreds of constituents and some of them are very toxic, such as the most cytotoxic anti-cancer plant-derived drugs, digitalis and the pyrrolizidine alkaloids, etc. However, the adverse effects of phytotherapeutic agents are less frequent compared with synthetic drugs, but well-controlled clinical trials have now confirmed that such effects really exist. Several regulatory models for herbal medicines are currently available including prescription drugs, over-the-counter substances, traditional medicines and dietary supplements. Harmonization and improvement in the processes of regulation is needed, and the general tendency is to perpetuate the German Commission E experience, which combines scientific studies and traditional knowledge (monographs). Finally, the trend in the domestication, production and biotechnological studies and genetic improvement of medicinal plants, instead of the use of plants harvested in the wild, will offer great advantages, since it will be possible to obtain uniform and high quality raw materials which are fundamental to the efficacy and safety of herbal drugs.

Julkishallinnon verkostojohtaminen - Case: Helsingin kaupungin ympäristöjohtaminen

Tämän pro gradu -tutkielman tavoitteena oli tutkia millainen on hyvä ympäristö-johtamisen verkostomalli kunnalle. Lisäksi työssä tarkasteltiin mitä hyötyjä haittoja on kunnan verkostomaisesti organisoidussa ympäristöjohtamisessa verrattuna ei-verkostomaiseen toteutukseen. Työssä selvitettiin myös millaiset verkostojohtamisen mallit ovat tehokkaita ja mitkä ovat verkoston osapuolten odotukset kunnan ympäristöjohtamisen verkostolle. Tutkielman lopputuloksena oli ympäristöjohtamisen verkostomalli kunnalle. Tutkielman teoreettisen viitekehyksen muodostivat julkishallinnon verkoston hallintamalli, verkostojohtaminen, ympäristöjohtaminen ja tehokkuus. Nämä kolme käsitettä muodostivat työn verkostomallin. Tutkimusmenetelmänä työssä käytettiin laadullista tapaustutkimusta, ja tutkimuksen kohteena oli kuntaorganisaation ympäristöjohtamisen verkosto, joka käsitti ympäristöjohtamisen asiantuntijatyöryhmän. Tutkimusaineisto kerättiin teemahaastatteluin ja tutkimuksessa haastateltiin kolmetoista asiantuntijatyöryhmän jäsentä yksilö-, pari- ja ryhmähaastatteluin.