Um experimento com propostas múltiplas para um laboratório de química geral

This article suggests a sequence of experiments on the preparation, analysis and some photochemical aspects of potassium tris (oxalato) ferrate(III) trihydrate. The sequence of experiments could be carried out in four or five 4-hour laboratory periods. The new part of this article is related to the kinetics studies involving the ambient illumination as well as the use of the cellophane paper of different colors as light filters. The aspects such as quantum yield, light absorption and photochemical reactions are explored in order to illustrate the relationships between the exposure time, light intensity and wavelength range on the photochemical reactions.

Experimentos simples usando fotometria de chama para ensino de princípios de espectrometria atômica em cursos de química analítica

The purpose of this paper is the development of simple strategies to teach basic concepts of atomic spectrometry. Metals present in samples found in the daily lives of students are determined by flame atomic emission spectrometry (FAES). FAES is an accurate, precise, and inexpensive analytical method often used for determining sodium, potassium, lithium, and calcium. Historical aspects and their contextualization for students are also presented and experiments with samples that do not require pre-treatment are described.

Analysis of the tensile modulus of polypropylene composites reinforced with stone groundwood fibers

One of the most relevant properties of composite materials to be considered is stiffness. Fiberglass has been used traditionally as a fibrous reinforcing element when stiff materials are required. However, natural fibers are been exploited as replacements for synthetic fibers to satisfy environmental concerns. Among the different natural fibers, wood fibers show the combination of relatively high aspect ratio, good specific stiffness and strength, low density, low cost, and less variability than other natural fibers of such those from annual crops. In this work, composites from polypropylene and stone groundwood fibers from softwood were prepared and mechanically characterized under tensile loads. The Young’s moduli of the ensuing composites were analyzed and their micromechanics aspects evaluated. The reinforcing effect of stone groundwood fibers was compared to that of conventional reinforcement such fiberglass. The Halpin-Tsai model with the modification proposed by Tsai-Pagano accounted fairly for the behavior of PP composites reinforced with stone groundwood fibers. It was also demonstrated that the aspect ratio of the reinforcement plays a role in the Young’s modulus of injection molded specimens

A three dimensional study of heat transfer in a supercritical circulating fluidized bed combustor

From the boiler design point of view, it is imperative to know and understand the operation of the boiler. Since comprehensive measurement of a large furnace is impossible, the furnace can be modeled in order to study its behavior and phenomena. This requires the used model to be validated to correspond with the physical furnace behavior. In this thesis, a three dimensional furnace model is validated to match a bituminous coal utilizing, supercritical once-through circulating fluidized bed combustor based on measurement data. The validated model is used for analyzing the furnace heat transfer. Other heat transfer analysis methods are energy balance method based on tube surface temperature measurements and a method based on measured temperature difference between the tube crest and the fin. The latter method was developed in the thesis using Fluent-software. In the theory part, literature is reviewed and the fundamental aspects of circulating fluidized bed are discussed. These aspects are solid particle behavior in fluidization known as hydrodynamics, behavior of fuel and combustion and heat transfer. Fundamental aspects of modeling are also presented.

Comunicar la ciudad desde el paisaje: hacia una teoría del landscape branding

The need to decode landscape meanings, the society- landscape interaction (intra- and inter-personal communication) and, more recently, the uses of landscape as a territorial sight linked to advertising communication, citymarketing or place branding (mass communication) highlights the study of landscape persuasion, which includes clear emotional, symbolic and, therefore, communicative aspects. The landscape, as a territory image or face, gathers the essence of the implicit message in the space, thus working as a great metaphor for city communication. Regarding the foregoing, specific communication research with intangible landscapes —together with the recent emergence of emotional geographies— suggests a new territorial message theory based on the union of geographical, landscape, emotional and communicational variables. Landscape has historically been studied by geographers, architects, historians or sociologists, among others researchers, but it has not been analysed from communicational viewpoints. In this sense, the proliferation of analyses highlighting the role played by the territory as a communication mediator in the interaction process between society and its spaces (cognition and/or perception) is also remarkable. Current sales of territorial identities lead to increases in the production of territory brands, which have gathered a noticeable relevance within the last years.

Gestão integrada de resíduos químicos em instituições de ensino superior

Since chemical residues management must be seriously considered at institutions of higher education and due to the relevance of this subject for students, this work proposes the involvement of the scientific community in the establishment of a program for management of chemical residues at universities, starting with a committee, to coordinate the process. The program should integrate the entire scientific community in an organized effort. The program involves legislative, educational and environmental management aspects, with environmental education as an important tool to integrate all the administrative areas of a chemistry department.

Óleo da castanha de caju: oportunidades e desafios no contexto do desenvolvimento e sustentabilidade industrial

The new millennium is marked by a growing search for renewable fuels and alternative raw materials from biomass in the petrochemicals industry. However, there are many challenges to overcome regarding technological and human resources aspects. In this scenario, cashew nut oil, which is rich in natural phenols, is considered to be very promising for the development of synthetic and functional products and as a feedstock for production of fine chemicals and a wide variety of new materials.

Vaneritehtaan energianäkökohtien tarkastelu ja seuranta

Diplomityön tavoitteena oli tunnistaa ja analysoida vaneritehtaan energianäkökohdat. Lisäksi tavoitteena oli luoda työkalu, joka mahdollistaisi energianäkökohtien seurannan ja vertailun sekä tehtaan energiankäytön jatkuvan kehittämisen. Teoriaosuudessa käsiteltiin energiatehokkuutta sekä energian käyttöä, hankintaa ja tuotantoa. Lisäksi tarkasteltiin vanerin valmistusprosessia. Tarkoituksena oli luoda pohja vaneritehtaan energiankäytön hahmottamiselle ja sen energianäkökohtien analysoinnille. Energian käytön kartoittaminen tehtiin osaksi hyödyntämällä olemassa olevaa tietokantaa ja osaksi prosessoimalla kerättyjä mittaustuloksia. Kartoituksen perusteella tunnistettiin vaneritehtaan osastokohtaiset energianäkökohdat. Näkökohtien analysoinnilla selvitettiin niiden vaikutusta energiankulutukseen ja tuotannon tehokkuuteen. Tämän pohjalta luotiin seurantatyökalu, johon energianäkökohdat ja niihin vaikuttavat tekijät koottiin osastoittain. Energiatehokkuuteen vaikuttavien tekijöiden merkittävyyttä tarkasteltiin pisteyttämällä toiminnan osa-alueita. Analysoinnin yhteydessä työssä esitettiin myös yksittäisiä toiminnan tehokkuuteen liittyviä kehitysesimerkkejä.

Commercializing technology in transitional economies. Case: Nanotechnology in Russia

The aim of the study is to find out “What are the challenges to overcome for the successful nanotechnology commercialization in Russia?” Working closely with the case country was definitely an advantage when it comes to the understanding of the research subject. The thesis is divided to two parts: first part examines the concept of technology commercialization and identifies unique aspects of the process in context of nanotechnology. Second part is dedicated to an empirical research, investigating current status of nanotechnology commercialization in Russia. For the purpose of this study, Russian and international scientists, researchers, entrepreneurs, industry and government representatives were interviewed systematically during 2007 – 2009. Based on the research done it can be concluded that immense public funding provides necessary support for the development of Russian nanotechnology industry. However, investments alone do not address important structural shortcomings of a national innovation system, which in turn slow down the progress. Taking into consideration gap between science and business and challenging IPR legislation, expected significant economic impact in Russia may be overestimated. Nevertheless it should be noted that development of nanotechnology is advancing rapidly and therefore, the state of commercialization is changing accordingly, even while this lines are written.

Management of interdependency in project portfolio

Project management has evolved in recent decades. Project portfolio management, together with multi project management, is an emerging area in the project management field in practice, and correspondingly in academic research and forums. In multi project management, projects cannot be handled isolated from each other, as they often have interdependencies that have to be taken into account. If the interdependencies between projects are evaluated during the selection process, the success rate of the project portfolio is increased. Interdependencies can be human resources, technological, and/or market based. Despite of the fact that interdependency as a phenomenon has roots in the 1960s and is related to famous management theories, it has not been much studied, although in practice most companies use it to great extent. There exists some research on interdependency, but prior publications have not emphasized the phenomenon per se, because a practical orientation practitioner techniques prevails in the literature. This research applies the method triangulation, electronic surveys and multiple case study. The research concentrates on small to large companies in Estonia and Finland, mainly in construction, engineering, ICT, and machinery industries. The literature review reveals that interdependencies are deeply involved in R&D and innovation. Survey analysis shows that companies are aware of interdependency issues in general, but they i have lack of detailed knowledge to use it thoroughly. Empirical evidence also indicates that interdependency techniques influence the success rate and other efficiency aspects to different extents. There are a lot of similarities in interdependency related managerial issues in companies of varying sizes and countries in Northern Europe. Differences found in the study are for instance the fact that smaller companies face more difficulties in implementing and evaluating interdependency procedures. Country differences between Estonia and Finland stem from working solutions to manage interdependencies on a daily basis.historical and cultural reasons, such as the special features of a transition country compared to a mature country. An overview of the dominant problems, best practices, and commonly used techniques associated with interdependency is provided in the study. Empirical findings show that many interdependency techniques are not used in practice. A multiple case study was performed in the study to find out how interdependencies are managed in real life on a daily basis. The results show that interdependencies are mostly managed in an informal manner. A description of managing the interdependencies and implementation procedures is given. Interdependency procedures are hard to implement, especially in smaller companies. Companies have difficulties in implementing interdependency procedures and evaluating them. The study contains detailed results on how companies have implemented working solutions to manage interdependencies on a daily basis

Under ytan, vid ytan och ovanför ytan : analys av tanken bakom tre läromedel i slöjd

This thesis is based on the personal experience gained related to the planning and production of three web-based teaching materials for the teaching subject knownas sloyd at the comprehensive school in Finland. After the teaching materials had been produced and published on the Internet at the Finnish textile teachers' website KässäBoxi, the idea for this thesis emanated from the questions: Why do the three teaching materials look the way they do and why do other textile teachers comment that they are different? In earlier sloyd educational research it has been stated that a scientific paradigm affects the individual ideology of a sloyd teacher. The aimfor my doctoral thesis is to continue on the topic. As the area of interest comprises the thought behind three teaching materials in sloyd, the aim of the thesis is to show how teaching and educational ideologies in sloyd appear in the teaching materials at hand. The research approach has parallels to research about another, tangible phenomena, namely the iceberg. In a similar way as an iceberg, a teaching material has a profound base, but the base is not always completely visible to the user of the teaching material. In this thesis I strive to show what there is under the surface, on the surface and above the surface of three teaching materials in sloyd. The research approach is defined as qualitative and phenomenologic-hermeneutic. The analysis results in knowledge about how the producer of a teaching material affects the character of a teaching material by choices concerning for example the form, structure, language and illustrations of the teaching material. The analysis also shows how the producers' individual educational and teaching ideologies within the teaching subject at hand appear by means of traces concerning the view on the pupil and the teacher, and the view on planning and conducting teaching in sloyd. The thesis also results in knowledge about how sloyd educational scientific theories and demands from society, as they are stated in the national core curriculum, appear in the three teaching materials. The application of the sloyd educational scientific theory of individual sloyd activity as a holistic educative system is also widened in the thesis. This thesis contributes to future research on producing teaching materials by information about what aspects a producer of teaching materials needs to consider and how the aspects become visible in the teaching materials. This kind of knowledge is valuable to teacher students in sloyd, to teachers in sloyd who intend to plan and produce teaching materials and to teachers who tutor the planning and production of teaching materials.

Aurinkopaneeleihin liitettävien vaihtosuuntaajien testaussuunnitelman laadinta ja toteutus

Aurinkoenergia on yksi monista uusiutuvan energian muodoista, joiden suosio on viimeisten vuosien aikana kasvanut fossiilisten polttoaineiden kallistumisen sekä ilmaston lämpenemisen vuoksi. Auringon säteilyn energiaa voidaan muuttaa sähköenergiaksi mm. aurinkopaneeleiden avulla. Aurinkopaneeleihin liitetään usein vaihtosuuntaaja, jolla tuotettu teho voidaan muokata sähköverkkoon tai kotitalouden sähköjärjestelmään sopivaksi. Tässä työssä on esitelty aurinkopaneelilla tuotettavan sähköenergian perusperiaatteet sekä tehoa tuottavan järjestelmän reunaehdot. Tutkimuksessa on perehdytty keskeisiin, aurinkopaneeleihin liitettäville vaihtosuuntaajille laadittuihin standardeihin, hyötysuhteen mittaamisen sekä sähkön laadun näkökulmista. Selvityksen avulla järjestelmän hyötysuhteen sekä lähtötehon laadun määrittämiseksi voidaan laatia standardien mukainen mittaussuunnitelma vaihtosuuntaajan nimellistehosta riippumatta. Standardien avulla on laadittu mittaussuunnitelma Global Inversonne, 100 kW - verkkovaihtosuuntaajayksikölle. Suunnitelman mukaisissa mittauksissa on tutkittu yksikön muunnoshyötysuhdetta sekä lähtöjännitteen- ja virran laatua. Lisäksi työssä on analysoitu mittaustulosten mittausepävarmuuksia ja niitä aiheuttavia tekijöitä.

PYRENE MORPHOLOGY OF THREE SPECIES OF Byrsonima Rich. ex Kunth (Malpighiaceae)1

ABSTRACT The species of the genus Byrsonima Rich. ex Kunth are of great medicinal and economic importance, but they are still poorly studied with respect to their propagules. This study describes, illustrates and comparse morphological aspects of the pyrenes of Byrsonima crassifolia (L.) Kunth, Byrsonima verbascifolia (L.) DC. and Byrsonima coccolobifolia Kunth occurring in areas of savannah of Boa Vista, Roraima. The pyrenes are globoid, obovoid to ovoid, with endocarp dark brown in color, with a corrugated and reticulate surface and corneous consistency. They possess distinctly septate locules with or without seeds, the outer wall of which are dark brown in color with corneous consistency and thin black inner walls also with corneous consistency. The number of locules and seeds per pyrene among the species varies. The seeds are exalbuminous, globoid, obovoid to ovoid, with a thin, smooth integument and are light-brown in color. They have radicular lobes and hypostasis. The embryo is continuous and axial with cylindrical spirally rolled cotyledons. The diameter of pyrenes of Byrsonima crassifolia is greater than in the other two species. The pyrenes of B. coccolobifolia are longer and heavier, while those of B. verbascifolia are lighter and the seeds have greater lengths, widths and thickness compared to the other two species studied. The three species have similar morphologies, differing in the size and weight of pyrenes and seeds.

Väsymiskestävyyden määritys murtumismekaanisilla särönmallinnusohjelmilla

Tässä työssä tutkitaan Wärtsilä Oyj:n moottorin ja ABB Oy:n generaattorin muodostaman aggregaatin väsymiskestävyyttä lineaarisen murtumismekaniikan avulla. Työn tavoitteena on selvittää ABAQUS/XFEM- ja FRANC3D-ohjelman soveltuvuus kuormitukseltaan ja geometrialtaan vaativan generaattorirungon suunnittelutyökaluksi. Generaattorirungon kuormitukset aiheutuvat aggregaatin käynnin sekä käynnistys- ja sammutusvaiheen aikai-sista syntyvistä värähtelyistä. Tutkimuksessa tarkastellaan generaattorirungon väsymistä käynninaikaisella kuormituksella. Työssä mallinnettiin generaattorirungosta valittu hitsausdetalji alimallinnustekniikalla, jolloin alimallin reunaehdot voitiin määrittää aggregaatille tehdyn vastelaskennan perus-teella. Alimallista tutkittiin kahta erilaista hitsiliitostyyppiä, joihin mallinnettiin XFEM- ja FRANC3D-ohjelmilla erikokoisia säröjä hitsiliitosten rajaviivalle sekä juuren puolelle. Tutkittavilla ohjelmilla saatujen jännitysintensiteettikertoimien avulla säröille voitiin las-kea ekvivalentti jännitysintensiteettikerroin, jota verrattiin kokeellisesti saatuun jännitysin-tensiteettikertoimen kynnysarvoon. XFEM- ja FRANC3D-ohjelmia vertailtiin käytön helppouden, tulosten tarkkuuden sekä laskenta-aikojen perusteella. Käytettävyyden ja laskenta-aikojen perusteella XFEM-ohjelma soveltui paremmin käytettäväksi teollisuudessa suunnittelu- ja kehitystyön apu-työkaluna. FRANC3D taas antoi XFEM-ohjelmaa luotettavampia tuloksia, mutta laskenta-ajat olivat moninkertaiset.

Collaborative information behaviour : a case study of two research groups

The aim of the licentiate thesis is to examine researchers' information practices in research groups. The researchers were involved with study communication and media related issues within Social Sciences and Humanities Faculties. The theoretical framework of the study comprises the new holistic models of information seeking (for example: Meho and Tibbo, 2003; Seldén, 1999) and the collective aspects of information behaviour (Prekop, 2002 ; Talja, 2002; Talja and Hansen, 2006). The research questions are: 1. How do scholars seek information in research groups? 2 What kind of collaborative information behaviour occurs in the research groups? The research data was gathered by interviews and observations. Three meetings of a research group at the University of Tampere were observed during the autumn of 2004. The group members and the group leader of the research group were interviewed in the spring of 2005. The research group members and the group leader of a research group at the University of Jyväskylä were interviewed in the autumn of 2005. Altogether, two research group leaders and eight researchers were interviewed. The significance of the research group for information seeking is more important in closeknit research groups than in rather loose research groups. The significance of the research group for information seeking can be at least threefold. First, research group members can inform the group about relevant information resources and potential library or other information services. Second, the research group can to some extent compensate for the information seeking systems of libraries by distributing material and information resources. Third, information seeking can be carried out in collaboration in research groups. The significance of the research group was found to be most important in informing about new information services and marketing library systems. Recommendations from colleagues were often needed to mobilize researchers into using new library services. The significance of colleagues in informing about library services is in line with earlier studies. The present study showed that sometimes information from colleagues was regarded as more important than information distributed directly by the local library. A culture of information sharing, including mutual trust, seemed mainly to be reflected in collaboration and collaborative information seeking in the research groups studied. The timing of the onset of individual research seemed to be related to the information sharing culture and social networks in research groups. The simultaneous onset of the research work by group members seemed to promote the growth of unbiased collaboration, also in information seeking.