961 resultados para 2,4-pentanedione Schiff Base Derived From N-methyldithiocarbazate
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A planar monopole antenna suitable for broadband wireless communication is designed and developed. With the use of a truncated ground plane, the proposed printed monopole antenna offers nearly 60% 2:1 VSWR bandwidth and good radiation characteristics for the frequencies across the operating band. A parametric study of the antenna is performed based on the optimized design, and a prototype of the antenna suitable for 2.4-GHz WLAN application is presented. The antenna can be easily integrated into wireless circuitry and is convenient for application in laptop computers.
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Various modern nucleon-nucleon (NN) potentials yield a very accurate fit to the nucleon-nucleon scattering phase shifts. The differences between these interactions in describing properties of nuclear matter are investigated. Various contributions to the total energy are evaluated employing the Hellmann-Feynman theorem. Special attention is paid to the two-nucleon correlation functions derived from these interactions. Differences in the predictions of the various interactions can be traced back to the inclusion of nonlocal terms.
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Thiosemicarbazones have emerged as an important class of ligands over a period of time, for a variety of reasons, such as variable donor properties, structural diversity and biological applications. Interesting as the coordination chemistry may be, the driving force for the study of these ligands has undoubtedly been their biological properties and the majority of the 3000 or so publications on thiosemicarbazones since 2000 have alluded to this feature. Thiosemicarbazones with potential donor atoms in their structural skeleton fascinate coordination chemists with their versatile chelating behavior. The thiosemicarbazones of aromatic aldehydes and ketones form stable chelates with transition metal cations by utilizing both their sulfur and azomethine nitrogen as donor atoms. They have been shown to possess a diverse range of biological activities including anticancer, antitumor, antibacterial, antiviral, antimalarial and antifungal properties owing to their ability to diffuse through the semipermeable membrane of the cell lines. The enhanced effect may be attributed to the increased lipophilicity of the metal complexes compared to the ligand alone.
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The title compound, C21H19N3O2S, exists in the thione form. The configuration about the C N bond is E. The hydrazinecarbothioamide unit adopts an almost planar arrangement, with maximum deviations of 0.016 (3) and 0.016 (2) A ° for the two thiourea N atoms. An intramolecular O—H N hydrogen bond occurs. Weak intermolecular N— H S, C—H O and C—H interactions are observed in the crystal structure
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Resumen en inglés
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Experiencia orientada a mejorar y acondicionar el espacio exterior del centro para lograr que el patio de recreo ayude en la labor educativa de la escuela infantil. Plantea los siguientes objetivos: potenciar las posibilidades de juego; crear un espacio específico para los niños de cero a dos años en el que se tengan en cuanto la seguridad y las necesidades de desarrollo de esta etapa; y conseguir una mejor distribución y aprovechamiento de los espacios dentro del conjunto de la escuela. El espacio se estructura en diferentes zonas: arenero, zona de tierra dura y césped para realizar actividades de acercamiento a la naturaleza y al entorno; zona de intercambio, para juegos en los que interviene la comunicación; zona de movimiento, con diversos elementos como toboganes, balancines, etc., para realizar actividades en las que interviene la acción, el equilibrio, el movimiento, etc.; y, finalmente, una zona para guardar los juguetes. La evaluación de los alumnos es continua mediante la observación directa y la redacción de informes sobre las actividades realizadas en el nuevo espacio, en los que hace se referencia al cumplimiento o no de los objetivos y a la actitud de los alumnos.
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Resumen basado en el de la publicación
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D'entre els defectes organolèptics associats al vi, en destaca l'anomenat "gust de suro" habitualment vinculat a la presència de cloroanisoles, els quals són productes de l'activitat microbiana formats a partir dels corresponents clorofenols. La present tesi doctoral recull, en primer lloc, metodologies analítiques adreçades principalment a la determinació dels compostos clorofenòlics (2,4,6-triclorofenol, 2,3,4,6-tetraclorofenol i pentaclorofenol) en el control de qualitat dels taps suro, emprant dissolucions hidroalcohòliques com a medi de maceració o d'extracció i utilitzant les tècniques d'extracció en fase sòlida (SPE) i microextracció en fase sòlida (SPME) acoblades a la cromatografia de gasos (GC). En segon lloc, per tal de dur a terme l'anàlisi de cloroanisoles juntament amb els seus precursors en matrius de suro s'ha avaluat un mètode basat en l'extracció amb dissolvent orgànic, el qual ha estat aplicat per a l'estudi de diferents sistemes d'eliminació d'aquests anàlits en la matriu citada. En darrer lloc, s'han proposat metodologies per l'anàlisi de mostres de vi, en les quals d'una banda s'han determinat els compostos clorofenòlics utilitzant la SPME i de l'altra el 2,4,6-tricloroanisole i el 2,4,6-tribromoanisole mitjançant l'acoblament de la SPE i la injecció de grans volums (LVI) en el sistema cromatogràfic.
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We show that small quantities of 1,3:2,4-di(4-chlorobenzylidene) sorbitol dispersed in poly(epsilon-caprolactone) provide a very effective self-assembling nanoscale framework which, with a flow field, yields extremely high levels of polymer crystal orientation. During modest shear flow of the polymer melt, the additive forms highly extended nano-particles which adopt a preferred alignment with respect to the flow field. On cooling, polymer crystallisation is directed by these particles. This chloro substituted dibenzylidene sorbitol is considerably more effective at directing the crystal growth of poly(epsilon-caprolactone) than the unsubstituted compound.
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Although accuracy of digital elevation models (DEMs) can be quantified and measured in different ways, each is influenced by three main factors: terrain character, sampling strategy and interpolation method. These parameters, and their interaction, are discussed. The generation of DEMs from digitised contours is emphasised because this is the major source of DEMs, particularly within member countries of OEEPE. Such DEMs often exhibit unwelcome artifacts, depending on the interpolation method employed. The origin and magnitude of these effects and how they can be reduced to improve the accuracy of the DEMs are also discussed.