Sr2CeO4: Electronic and structural properties

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Emergetic ternary diagrams: five examples for application in environmental accounting for decision-making

In a recent paper, "A combined tool for environmental scientists and decision makers: ternary diagrams and emergy accounting." [Giannettti BF, Barrella FA, Almeida CMVB. A combined tool for environment scientists and decision makers: ternary diagrams and emergy accounting. J Clean Prod, in press http://dx.doi.org/10.1016/j.jclepro.2004.09.002] Ternary diagrams were proposed as a graphical tool to assist emergy analysis. The graphical representation of the emergy accounting data makes it possible to compare processes and systems with and without ecosystem services, to evaluate improvements and to follow the system performance over time. The graphic tool is versatile and adaptable to represent products, processes, systems, countries, and different periods of time.The use and the versatility of ternary diagrams for assisting in performing emergy analyses are illustrated by means of five examples taken from the literature, which are presented and discussed. It is shown that emergetic ternary diagram's properties assist the assessment of the system of the system efficiency, its dependance upon renewable and non-renewable inputs and the environmental support for dilution and abatement of process emissions. With the aid of ternary diagrams, details such as the interaction between systems and between systems and the environment are recognized and evaluated. Such a tool for graphical analysis allows a transparent presentation of the results and can serve as an interface between emergy scientists and decision makers, provided the meaning of each line in the diagram is carefully explained and understood. (c) 2005 Elsevier Ltd. All rights reserved.

Preparation of TiO2/SnO2 Thin Films by Sol-Gel Method and Periodic B3LYP Simulations

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Adsorption of pH-responsive polyelectrolyte chains onto spherical macroions

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Circulação atmosférica e precipitação pluviométrica na Bacia do Itajaí - SC: um estudo climatológico aplicado

The work is guided by the detailing of the Itajaí river basin, SC, rainfall dynamics at the annual, seasonal and monthly levels, allowing us to identify different responses that each location gives to the regional atmospheric circulation, particularly the rainfall. In this sense, we are aiming at approaching the concept of rhythm, which must be obtained at the daily level. The analysis at different climate scales was possible through isohyetal maps, trend lines, and Schroeder pluviographs. Moreover, we established the flow rate of the air masses by means of the Venn diagram. This data made it possible to assess the behavior of rains on that site and the reason why it is the stage of major flooding, as occurred in November 2008. The relatively mountainous topography combined with the frequent invasions of the Atlantic Polar Front, which often stop over the region, generate events of that magnitude, with high volumes accumulated in short periods of time. Such extreme events reinforce the idea of the search for the succession of types of weather to the detriment of averages that tend to abstract the reality

Lean six sigma como estratégia para o aumento de eficiência em laminação de alumínio

This study aims to assess the implementation of Lean Six Sigma in the preparation of plates and hot lamination process for a company of aluminum rolled products, to improve the quality, productivity and process efficiency. As a basis for achieving these goals, the DMAIC methodology and various quality tools such as Cause Effect Diagram, Process Flow, SIPOC, Pareto, FMEA and Control Chart were used, trying to propose improvements to processes and increase their efficiency. The results were significant and were the basis for the continuation of a continuous improvement project throughout the factory

Aplicação do lean six sigma na linha de produção de turbinas industriais a vapor

This work evaluates the implementation of Lean Six Sigma into the Steam Turbine’s Blades Manufacturing Process, aiming to improve productivity, quality and operational efficiency. Therefore, several tools have been applied, such as VSM, Spaghetti Diagram, Ishikawa, Pareto, DMAIC, Benchmarking and Control Charts, seeking to propose process improvements, as well as Quality Indicators creation. It was obtained a significant waste reduction throughout the process, achieving a lead time reduction of 42% and 83,41% in transport. Also, were introduced the Lean Thinking concepts, such as pull production and Continuous material flow. At the same time, it was possible to calculate the process capability and the sigma level, evaluating and proposing some improvements

Análise do conforto térmico da cidade de Mirandópolis/SP em seus espaços abertos

Mirandópolis/SP appeared in 1934 from the railroad “the Brazil Northwest”, that there it served one of the points of its stretch that had as main function to drain the agricultural production northwestern native of São Paulo of that time. The installation of the town happened absent of concerns with initial urbanístico planning, thus modifying its natural landscape and modifying characteristic ambient without compensatory measures aiming at a future expansion of the urban mesh. Fact this that still causes today consequences the quality of life of the people and also the observed thermal comfort later. Ahead of this, the present work had for objective to identify through measurements of temperature and relative humidity of the city of Mirandópolis/SP the differences that in the fabric urban they corroborate for a comfort situation or thermal discomfort to the outdoors in accordance with the Diagram Bioclimático de Olgyay the collection of data was made throughout the month of July of 2011 involving the attainment of information of Temperature and relative humidity of air and questionnaire applied to the passer-bys in the act of the measurements. Also approaching the different thermal dynamic of the zones of housing in relation to the Urban Cannyon that develops the commerce as predominant activity. This research sample that, although a city to be small, the quality of life of its inhabitants is not only guaranteed by the transport or that its thermal comfort reveals inside homogeneous of the urban perimeter, but that it has yes heterogeneidade in the scope of the urban climate in these spaces

Análise doprojeto de expansãode um armazém por meio da elaboração de um layout e análise de investimento: estudo de caso em uma fábrica do setor alimentício

The proper management of materials storage is essential to supply the needs of production and reduce the inventory costs. Moreover, an effective layout contributes to improve the productivity and reduce the operational costs of a warehouse. This way, the purpose of this study was: to propose an expansion project to the warehouse of a factory in the food sector, suggesting a layout that best fit their needs and to verify its economic feasibility. To achieve this goal, it was applied methods such as ABC curve, spaghetti diagram and concepts of economics engineering to the analysis of investment in the project. The results showed that the second layout model was better than the first, supporting the storage capacity required by the company and presenting an internal movement more efficient. However, with the investment analysis, it was found that it was not feasible, given the conditions of the company, investing in the expansion of the warehouse

Estudo da tratabilidade de água pluvial utilizando coagulante natural a base de tanino visando fins não potáveis

This paper aimed to study the treatability of rainwater collected in Rio Claro, SP, using natural coagulant tannin based. The tannin was compared with other too primary coagulants, namely ferric chloride and corn starch. Assays were performed in laboratory scale using equipment known as Jarteste and aimed to study the conditions most suitable dosage and coagulation pH. First tests were conducted to compare the coagulating and determination of the conditions to be used in the following tests, taking as a criterion the greatest efficiency for water treatment. Also performed were performed tests to construct the tannin coagulation diagram, using the optimal concentration found in the previous phase, by varying the dosage of coagulant and the pH of clotting in order to determine the isoefficiency regions for apparent color and turbidity. Finally, tests were performed cyclically filtration with filter paper. Preliminary tests indicated that the vegetable tannin concentration 3% (m/m) from the commercial solution was presented the best set of results (84.3% removal of apparent color and 82.51% removal of turbidity) compared to ferric chloride (66.25% removal efficiency and apparent color of turbidity 67.82%) and starch (73.68% removal efficiency apparent color and turbidity to 67.19%). The coagulation diagrams indicate that the best region to work with vegetable tannin 3% is where the coagulant dosage ranges from 15 mg/L to about 37.5 mg/L and coagulation pH ranging from about 6.5 to 7.5. The cyclic filtration showed to be not efficient for the best dosage of coagulant, due to the process of clogging of the filter paper, but proved to be efficient for other dosages. Thus, for the waters studied, the results indicate that the natural coagulant based tannin is an alternative to conventional coagulants, possessing benefits of technical and environmental

Análise da confiabilidade de equipamentos em uma indústria química com aplicações de ferramentas da melhoria contínua

The constant search for improvements and the survival of organizations makes the strategic guidelines are deployed and executed at the operational levels. This work is the approach to critical analysis of the equipment of a chemical industry through a case study based on the classification of each equipment manufactures through qualitative and quantitative analysis on the pillars of maintenance costs, loss of production, MTBF, contribution margin, Health Safety and Environment (SHE). From this study and future data collection, along with the flow diagram show the main equipment that should be special attention. To this can be prepared an action plan with deadlines and responsible. With the results one can measure the maintenance costs, loss of production and technical availability of the plant, with future gains

Método de Taguchi aplicado a um processo de corte por fusão de um tecido sintético

A company must have full knowledge and control of its operations so as to meet the market requirements and meet their production goals. Thus this paper uses the Taguchi method to extend the operational control of a cutting process by fusion of a synthetic fabric in the longitudinal direction. For process analysis and tracking of possible causes of the problem techniques of Production Engineering as the cause and effect diagram, also known as Ishikawa diagram, and design of experiments were used, the last one was applied to the design techniques of Taguchi. Finally the preparation method of understanding and design of experiment was due to the use of the software MINITAB v15 ®, which showed that the speed of rolling the fabric after cutting is crucial for controlling the entire operation

Estudo de caso: aplicação do método DMAIC-White Belt- na redução de latas amassadas em uma produção de leite em pó

This work consists of the implementation of the steps Define, Measure , Analyze , Improve and Control ( DMAIC ) to develop a Six Sigma project in an industry the food industry. The objective was to demonstrate a potential for reducing the occurrence of crushed cans in potting milk powder industry in a White Belt project. The food industry accounts for about 9 % of Brazil's gross domestic product ( GDP ), generating thousands of jobs . Among the major sectors of the food industry is the manufacturing sector of milk , occupies approximately 10 % of the total turnover of the food industry . Brazil is considered today one of the eight largest producers of milk powder in the world. The milk powder is packed , mostly for aluminum cans that are lined internally with varnishes and other materials to protect the milk of metals from aluminum. When the cans are dented food protection is compromised and may lead ingestion causing dis-eases such as botulism. Aiming to solve the problem of dented cans methodology was used as a case study with a quantitative approach through the DMAIC method. Some quality tools used in each step of the project as brainstorming , cause and effect diagram , flowchart , ef-fort and impact matrix, 5W1H , among other Pareto diagram is presented . A survey about the disposal of cans in the company verifying a mean loss and, from this histor-ical , a goal loss was calculated was performed . With the target set we calculated the annual saving design . During application of DMAIC was found that the highest rate of loss occurred in transportation between the factory and the factory that fills cans milk . Several actions were taken to resolve problems that resulted in dented cans and the first two months of phase control it was found that the smaller losses calculated target resulting in a saving for the company. The short time of implementa-tion of the Improve phase did not allow a more detailed a ...

Radioatividade e hidroquímica em águas subterrâneas do município de Botucatu (SP)

The main objective of this study is to determine the activity of Po-210, Pb-210 and gross alpha/beta radioactivity in groundwater collected in Botucatu, municipality of the São Paulo state, Brazil. Samples were collected in wells to perform the radiochemical analysis. Most wells are registered in DAEE, Sabesp or CPRM. The activity of polonium was obtained by the method of alpha spectrometry, held in LABIDRO at UNESP, Rio Claro. All samples showed radioactivity values below the maximum allowed by WHO, that are: gross alpha radioactivity = 0,5 Bq/L, gross beta radioactivity = 1,0 Bq/L, Po210 = 0,2 Bq/L and Pb210 = 0,1 Bq/L. The results of hydrochemical analysis were compared with the 1469 Ordinance of the Health Ministry, and all values are bellow the maximum allowed. The data also allowed obtain the samples classification using the Piper diagram. The samples AAB, Quinta do Manacás, Faz. Quatro Irmãs, Sesi, Sitio São José and ITE are classified as calcic bicarbonate; the samples Staroup and Caio are potassic; the samples Banespa and BTC are bicarbonate and mixed interms of dissolved cations; Sitio das Palmeiras sample is sodium bicarbonate; the sample Faz. São Paulo is chlorinated calcic; the sample Sítio Btu-Pardinho chlorinated and mixed interms of dissolved cations

Proposta de melhoria do layout de um armazém de vidros automotivos

This work was based on a case study of improvement of the warehouse layout of a multinational automotive glass sector, located in the State of Sao Paulo. The aim was to propose a layout template to be more effective and besides optimizing production would also promote an increase in warehouse packaging capacity for metal containers containing glasses, thus reducing operating costs. To achieve the desired purpose, it was developed two layout proposals and to this end inventory management tools have been used, such as ABC curve and the Spaghetti Diagram, and other concepts of Packaging Engineering and Logistics. By the end of this work, it was obtained as a result, a project in which it was possible to rearrange the packages according the demand, and the developed changes became the most efficient layout both in storage capacity as well as in the internal drive