909 resultados para High pressure system
Resumo:
This dissertation discusses current status of high temperature and high pressure and focuses on analyzing systematically the solubility of heavy metals in the silicate magma in HTHP experiments. The high temperature study on the content of heavy metal molybdenum in the silicate melts in this dissertation, which is granted, based on the geology mineralization model and the theory of HTHP experiments and combined with mineralization grade and geochemical nature of Mo, discusses the difference of mineralization between mantle plume and aqueous fluids and comes to the conclusions, which are as follows: (1) The content of Mo in the silicate melts is much greater than Mo mineralization grade. The molybdenum ore has the exploitation value when the industrial grade is higher than 0.06%. Mo content in different silicate melts varies because of the concentration of SiO2, that is, Mo content in the granodiorite is greater. (2) The content of Mo, which varies with reaction time, arises first and drops down in the alkali basalt melts, while variation is not too obvious in the granodiorite melts on the whole. (3) According to the picture of sample, the conclusion is not reached very well on some issues, such as the volatility and characteristic of molybdenum oxide and dependence on the geology environment.
Resumo:
The determination of the composition and structure of the Earth’s inner core has long been the major subject in the study of the Earth’s deep interior. It’s widely believed that the Earth’s core is formed by iron with a fraction of nickel. However, light elements must exist in the inner core because the earth core is less dense than pure iron-nickel alloy (~2-3% in the solid inner core and ~6-7% in the liquid outer core). The questions are what and how much light element is there in the iron-nickel alloy. Besides the composition, the crystal structure of the iron with or without light element is also not well known. According to the seismological observations, the sound waves propagate 3-4% faster along the spin axis than in the equatorial plane. That means the inner core is anisotropic. The densest structure of iron-nickel alloy should be h.c.p structure under the very high pressures. However, the h,c,p structure does not propagate waves anisotropic ally. Then what is the structure of the iron-nickel alloy or the iron-nickle-light element alloy. In this study, we tried to predict the composition and the structure of the inner core through ab initio calculation of the Gibbs free energy, which is a function of internal energy, density and entropy. We conclude that the h.c.p structure is more stable than the b.c.c structure under high pressure and 0 K, but with the increase of temperature, the free energy of the b.c.c structure is decreasing much faster than the h.c.p structure caused by the vibration of the atomics, so the b.c.c structure is more stable at high temperatures. With the addition of light elements (S or Si or both), the free energy of b.c.c. decreases even faster, about 3at% of Si not only explains why the inner core is about 2-3 % lighter than the iron-nickle alloy, but also reasons why the inner core is anisotropic, since the b.c.c. structure becomes more stable than the h.c.p structure at 5500-6000K and b.c.c. is anisotropic in propagating seismic waves. Therefore, we infer that the inner core of the earth is formed by b.c.c iron and a fraction of nickel plus ~3at.% Si, with a temperature higher than 5500K, which is consistent with the studies from other approaches.
Resumo:
The petrology and geochemistry of peridotites entrained in Beiyan Cenozoic alkaline basalts within the middle segment of Tan-Lu fault zone and clinopyroxene megacrysts in the late Mesozoic and Cenozoic alkaline basaltic rocks from the North China Craton, have been systematically investigated. The main conclusions are obtained as follows. The peridotites entrained in alkaline basalts at Beiyan, Shandong Province, China are comprised of dominantly spinel lherzolites and spinel wehrlites with porphyroclastic, granuloblastic textures to resorption textures. The xenoliths are fertile in major element compositions (High CaO, TiO2, Low MgO, Cr2O3). The olivine Fo (= 100×Mg / (Mg+Fe) possesses a low and very large range of 81.0 to 91.0. The peridotites contain high percentages (Lherzolites: 10 - 19% in volume; Wehrlites: 24 - 28% in volume) of clinopyroxene with spongy textures. The Sr and Nd isotopic ratios of clinopyroxene separates from peridotites and pyroxenite xenoliths have a depleted and small range fall within the area of MORB, similar to newly-accreted lithospheric mantle. However, the appearance of many wehrlites and highly enriched LREE pattern suggest that this newly-accreted lithospheric mantle was considerably modified and reconstructed recently through the peridotite-asthenospheric melt interaction. The upwelling of asthenosphere from late Cretaceous to Eogene and upper mantle shearing of the Tan-Lu fault played an important role in the modification and reconstruction of the newly-accreted lithospheric mantle. The clinopyroxene megacrysts in the late Mesozoic and Cenozoic alkaline basaltic rocks from the eatern North China Craton are different in aspects of major elements, trace elements and isotopic composition. The characteristics of texture, mineral compositions and geochemistry as well as the Fe-Mg partitioning between the crystal and the melt indicates that the Al-augites in the Cenozoic basalts represent high-pressure crystallization products of alkaline basaltic melts. Thus, both of clinopyroxene megacrysts and host basalts could be derived from a same primitive magma. However, the Al-augites in the late Mesozoic basaltic rocks represent accidentally-included xenocrysts of basaltic components which had crystallized in the depth from a previously melting episode. The more depleted Sr-Nd isotopic compositions of Cenozoic megacrysts compared with those of host alkaline basalts and tholeiites demonstrate that even the alkali basalts could not completely represent primitive magma initiating in asthenosphere. That is to say, the Cenozoic alkaline basalts were more or less modified by some enriched Sr-Nd isotopic components during their eruption. Meanwhile, the tholeiites were not the products formed only by fractional crystallization of alkaline basaltic magma or different degrees of partial melting. It may result from the contribution of lithospheric mantle materials or crust contamination in magma chamber to alkali basaltic magmas.
Resumo:
Atmospheric dust as an important factor for climate feedbacks is mainly derived from and drove by the aeolian activities of the semi-arid regions in Asia. Therefore, reconstructing the history of aeolian activities in this region has a great significance in understanding the dynamics of past and future climate changes. This paper made a systematical sedimentology, geochemisty and high-resolution chronology analysis on the sediments from the Xiarinao Lake, which located in Hunshandake Desert, Inner Mongolia, and compared with the meteorological records for identifying the indicator of aeolian activities and climate changes. Based on above work, the evolution history of the aeolian activities and climate changes since 11,000 a BP was reconstructed and the dynamics of the aeolian activities and climate changes in the Hunshandake Desert was discussed. The indicator of aeolian activities was established through the comparison of the clastic and chemical records with the meteorological registers in recent 50 years: 1. The sediments of Xiarinao Lake are mainly derived from eaolian clastic materials and composed of two major components: one is the sand fraction (<4 ) similar to the composition of sand dunes, the other is the silt fraction (>4 ) similar to the atmospheric dust. The sand content and the median grain size, particularly the sand content, show a close association with the intensity of wind, indicating that the particle-size composition of the sediments reflect the variations of the aeolian activities. 2. The proportion of soluble salts relative to the total carbonates in the sediments was correlated to the arid degree registered in meteorological records, suggesting that arid degree might be associated with changes of wind speed and the relative proportion of soluble salts to the total carbonate could be used as the indicator of aridity. 3. The δ18O of authigenic calcite in the Xiarinao Lake show a well correlation with both the atmosphere precipitation and variation of the moisture indicated by the concentrations of soluble salts, suggesting that δ18O of anthigenic calcite is a reliable indicator of humidity. Based on above studies, the evolution history of the aeolian activities and climate changes since 11,000 a BP was reconstructed. At the same time, their association and underlying dynamics was discussed: 1. The evolution history of the eaolian activity was reconstructed by the sand content and median grain size. The result showed that aeolian activities had experienced several different climate periods in the Holocene: the aeolian activities fluctuated with a 500-year cycles during the interval from 10,900 to 8200 a BP; no significant aeolian activities had been developed from 8200 to 6300 a BP; during the interval of 6300 to 2600 a BP, sand content and media grain size had increased gradually, the sand content increased from about 5% to 25%, indicating the intensity of aeolian activity increased in the Hunshandake Desert; since 2600 a BP, intensity of aeolian activity has become stronger and activated the sand dunes. 2. The relative arid degree indicated by the proportion of soluble salts relative to the total carbonate show that both the wind speed and dry degree had being increased since 11,000 a BP. During the interval of 10900 to 6300 a BP, no detectable soluble salt was found in the sediments, indicating the humidity condition; the proportion increased to 20% from 6300 to 4200 a BP, showing the climate became drier; the little change of proportion (20%) suggest that the climate was relative stable during the interval of 4200 to 2600 a BP; after 2600 a BP, the proportion increased, showing the climate became further dry. 3. The δ18O evolution of the lake water was established through analysis of authigenetic calcite δ18O for revealing the variations of relative effective humidity in the Hunshandake Desert. δ18O maintained around -6 ‰ during the interval of 10900 to 8200 a BP, showing the climate was a little dry relative to that of the whole Holocnene; in the period of 8200 to 6300 a BP, δ18O had the most negative values, indicating that it was the most humid interval in Holocene; from 6300 to 4200 a BP, δ18O increased from about -7.5 ‰ to about -3 ‰ gradually, suggesting increased aridity; since 4200 a BP, the climate has become stable and dry. On the whole, the records in this study show that the variation of the relative humidity and aridity is consistent with that of summer monsoon in the Hunshandake Desert. The relationships among the grain size, soluble salts relative content, and the authigenic calcite δ18O indicate aeolian activities is controlled by the aridity in the studied area, and the increased aeolian activities is closely associated with the temperature changes under the relative dry condition. The high wind speed under the low temperature leads to the increased aeolian activity, and the temperature change associated with the aeolian activities might be related with the perturbations of the Siberian High Pressure.
Resumo:
In Dongpu depression, there are obviously overpressure phenomena below 2000-3200m. Research to the relationship between sedimentation-diagenesis and overpressure of reservoirs is in great need. In this paper, after analyzing and simulating the overpressure in Wendong, Qiaokou and Baimiao regions, we draw a conclusion that the fast sedimentation since Low Tertiary is one of the most important mechanisms for the formation of overpressure in Dongpu Depression. The gypsum in northern part of Dongpu Depression is the good seal for the development of overpressure. On the base of detailed work to the distribution and magnitude of overpressure in Wen-qiao-Bai regions, we selected several wells that have different overpressure to find the sedimentary and diagenetic differences of these wells. We find that compaction is obviously inhibited in overpressured reservoirs, which results in the linear relation between physical properties of reservoirs and sedimentary parameters, such as sorting coefficient, the content of matrix, etc. Reservoirs with great magnitude of overpressure have undergone more extensive erosion than the ones with low magnitude of overpressure, which probably is the result of the great solubility of CO_2 under high pressure. The great burial depth, the high content of matrix and the extensively developed cement of carbonate are the most important factors that influence the physical properties of reservoirs in Dongpu depression. Overpressure plays a constructive role in the physical properties of reservoirs. the overpressured reservoirs of Es_3~3 subsection in Wendong region are probably the ones that have good physical properties. From homogenetic temperatures that obtained form the fluid inclusions in quartz overgrowth, we find that there were 4 episodes of fluid flows in Dongpu depression. In conjunction with the analysis of the burial history of overpressured reservoirs, we draw conclusions that the first, second and third episodes of fluid flows took place in the extensive rifting stage of Dongpu Depression, the burial depth when the first episode of fluid flow took place was about 1500m, the age was about 36 my; the burial depth of the second and third episodes of fluid flow was between 1800-3000m at that time, the age was between 35-28my. The fluid flows of the second, third, and fourth episodes were in close relation to the overpressure and maybe were the results of the episodic hydrofracturing of overpressured mudstones and shales. The episodic fluid flow of overpressured mudstones and shales probably facilitates the cementation of carbonate, which decreases the physical properties of overpressured reservoirs. The dolomites and ferrodolomites maybe the products of the episodic hydrofracturing of overpressured mudstones and shales.
Resumo:
The Study on rheology of the lithosphere and the environments of the seismogenic layer is currently the basic project of the international earthquake research. Yunnan is the ideal place for studying this project. Through the multi-disciplinary comprehensive study of petrology, geophysics, seismo-geology, rock mechanics, etc., the depth-strength profiles of the lithosphere have been firstly constructed, and the seismogenic layer and its geophysical and tectonic environments in Yunnan have been systematically expounded in this paper. The related results achieved are of the important significances for further understanding the mechanism of strong earthquake generation, dividing the potential foci and exposing recent geodynamical processes in Yunnan. Through the comprehensive contrast of the metamorphic rocks in early and middle Proterozoic outcropping on the surface, DSS data and experimental data of rock seismic velocity under high temperature and high pressure, the petrological structure of the crust and upper mantle has been studied on Yunnan: the upper, middle and lower crust is composed of the metamorphic rocks of greenschist, amphibolite and granulite facies, respectively or granitoids, diorites and gabbros, respectively, and the upper mantle composed of the peridotites. Through the contrast studies of the heat flow and epicenters of the strong earthquakes, the distribution of the geotemperature and the data of focal depth, the relationship of between seismicity and geothermal structure of the lithosphere in Yunnan has been studied: the strong earthquakes with magnitude M ≥ 6.0 mainly take place at the geothermal gradient zone, and the seismic foci densely distribute between 200~500 ℃ isogeotherms. On the basis of studies of the rock properties and constituents of the crust and upper mantle and geothermal structure of the lithosphere, the structure of the rheological stratification of the lithosphere has been studied, and the corresponding depth-strength profiles have been constructed in Yunnan. The lithosphere in majority region of Yunnan has the structure of the rheological stratification, i.e. the brittle regime in the upper crust or upper part of the upper crust, ductile regime in the middle crust or lower part of the upper crust to middle crust, ductile regime in the lower crust and ductile regime in the subcrustal lithosphere. The rheological stratification has the quite marked lateral variations in the various tectonic units. The distributions of the seismogenic layer have been determined by using the high accurate data of focal depth. Through the contrast of the petrological structure, the structure of seismic velocity, electric structure, geotemperature structure, and rheological structure and the study of the focal mechanism in the seismogenic layer, the geophysical environments of the seismogenic layer in Yunnan have been studied. The seismogenic layer in Yunnan is located at the depths of 3 ~ 20 km; the rocks in the seismogenic layer are composed of the metamorphic rocks of greenschist to amphibolite facies (or granites to diorites); the seismogenic layer and its internal focal regions of strong earthquakes have the structure of medium properties with the relatively high seismic velocity, high density and high resistivity; there exists the intracrustal low seismic velocity and high conductivity layer bellow the seismogenic layer, the geotemperature is generally 100~500 ℃ in the depth range in which the seismogenic layer is located. The horizontal stress field predominates in the seismogenic layer, the seismogenic layer corresponds to the brittle regime of the upper crust or brittle regime of the upper crust to semibrittle regime of the middle crust. The formation of the seismogenic layer, preparedness and occurrence of the strong earthquakes is the result of the comprehensive actions of the source fault, rock constituent, structure of the medium properties, distribution of the geotemperature, rheological structure of the seismogenic layer and its external environments. Through the study of the structure, active nature, slip rate, segmentation of the active faults, and seismogenic faults, the tectonic environments of the seismogenic layer in Yunnan have been studied. The source faults of the seismogenic layer in Yunnan are mainly A-type ones and embody mainly the strike slip faults with high dip angle. the source faults are the right-lateral strike slip ones with NW-NNW trend and left-lateral strike slip ones with NE-NEE trend in Southwestern Yunnan, the right-lateral strike slip ones with NNW trend and left-lateral strike slip ones with NNE trend (partially normal ones) in Northwestern Yunnan, the right-lateral strike slip ones with NWW trend in Central Yunnan and left-lateral strike slip ones with NW-NNW trend in Eastern Yunnan. Taking Lijiang earthquake with Ms = 7.0 for example. The generating environments of the strong earthquake and seismogenic mechanical mechanism have been studied: the source region of the strong earthquake has the media structure with the relatively high seismic velocity and high resistivity, there exists the intracrustal low velocity and high conductivity layer bellow it and the strong earthquakes occur near the transitional zone of the crustal brittle to ductile deformation. These characteristics are the generality of the generating environments of strong earthquakes. However, the specific seismogenic tectonic environments and action of the stress field of the seismic source in the various regions, correspondingly constrains the dislocation and rupture mechanical mechanism of source fault of strong earthquake.
Resumo:
As powerful tools to study the lithosphere dynamics, the effective elastic thickness (Te) as well as the envelope of yielding stress of lithosphere have been attracted great attention of geoscientists in the past thirty years. The oceanic lithosphere, contrary to the continental lithosphere, has more fruits for its simple structures and evolution process. In continent, the lithosphere commonly is complex and variable in the rheological, thermal structures, and has a complicated history. Therefore, the application of the effective elastic thickness in continent is still a subject to learn in a long time. Te, with the definition of the thickness of an elastic plate in theory flexured by the equal benging of the real stress in the lithosphere plate (Turcotte, 1982), marks the depth of transition between elastic and fluid behaviors of rocks subjected to stress exceeding 100 MPa over the geological timescales (McNutt, 1990). There are three methods often adapted: admittance or isostatic response function, coherence and forwarding. In principle, the models of Te consist of thermal-rheological, non-linear Maxwell, non-linear work hardening and rheological layered models. There is a tentative knowledge of Te that it is affected by the following factors: crustal thickness, crust-mantle decoupling, plate bending, boundary conditions of plate (end forces and bending moments), stress state, sedimentary layer, faulting effect, variation in the mountain belts' strike, foreland basin, inheritance of tectonic evolution, convection of mantle, seismic depth and lithosphere strength. In this thesis, the author introduces the geological sketch of the Dabie collisional orogenic belt and the Hefei Basin. The Dabie Mts. is famous for the ultra-high pressure metamorphism. The crustal materials subducted down to the depth of at least 100 km and exhumed. So that the front subjects arise such as the deeply subduction of continent, and the post-collisional crust-mantle interaction. In a geological journey at June of 1999, the author found the rarely variolitic basaltic andesite in the Dabie Mts. It occurs in Susong Group, near Zhifenghe Countryside, Susong County, Anhui Province. It is just to the south of the boundary between the high-grade Susong melange and the ultra-high grade South Dabie melange. It has a noticeable knobby or pitted appearance in the surface. The size of the varioles is about 1-4 mm. In hand-specimen and under microscope, there are distinct contacts between the varioles and the matrice. The mineralogy of the varioles is primarily radiate plagioclase, with little pyroxene, hornblende and quartz. The pyroxene, hornblende and quartz are in the interstices between plagioclase. The matrix is consisted of glass, and micro-crystals of chlorite, epidote and zoisite. It is clearly subjected and extensive alteration. The andesite has an uncommon chemical composition. The SiO_2 content is about 56.8%, TiO_2 = 0.9%, MgO = 6.4%, (Fe_2O_3)_(Total) = 6.7% ~ 7.6%, 100 Mg/(Mg+Fe) = 64.1 ~ 66.2. Mg# is significantly high. The andesite has higher abundances of large-lithophile trace elements (e.g. K, Ba, Sr, LREE), e.g. La/Nd = 5.56-6.07, low abundances of high-strength-field elements (HFSE, e.g. Ta, Nb, P, Ti), particularly Ta and Nb strongly depleted. These are consistent with the characteristics of subducted-related magmas (Pearcce, 1982; Sun and McDonaugh, 1989). In the spider diagram of trace elements, from Ce to right hand, the abundances of elements decrease quickly, showing a characteristic of the continental margins (Pearce, 1982). There has a strongly enrichment of light-rare-earth elements, with a significant diffraction of REEs (the mean value of (La/Yb)_N is 32.84). No Eu anomaly, but there are anomaly high (La/Yb)_N = 28.63-36.74, (La/Y)_N = 70.33 - 82.84. The elements Y and Yb depleted greatly, Y < 20 ppm, Y_N = 2.74-2.84, Yb_N = 2.18 - 2.35. From the La-(La/Sm) diagram, the andesite is derived from partial melting. But the epsilone value of Nd is -18.7 ~ -19.2, so that the material source may be the mantle materials affected by the crustal materials. The Nd model age is 1.9 Ga indicating that the basaltic andesite was resulted from the post-collisional crust-mantle interaction between the subducted Yangze carton and the mantle of Sino-Korea carton. To obtain the Te of the lithosphere beneath the Dabie Mts. and the Hefei Basin, the author applies the coherence method in this thesis. The author makes two topography-gravity profiles (profiles 7~(th) and 9~(th)) across the Dabie Mts. and the Hefei Basin, and calculates the auto-coherence, across coherence, power spectrum, across power spectrum of the topography and gravity of the two profiles. From the relationships between the coherence and the wave-number of profiles. From the relationships between the coherence and the wave-number of profiles 7~(th) and 9~(th), it is obtained that the characteristic wavelengths respectively are 157 km and 126 km. Consequently the values of effective elastic thickness are 6.5 km and 4.8 km, respectively. However, the Te values merely are the minimum value of the lithosphere because the coherencemethod in a relative small region will generate a systemic underestimation. Why there is a so low Te value? In order to check the strength of the lithosphere beneath the Dabie Mts., the authore tries to outline the yielding-stress envelope of the lithosphere. It is suggested that the elastic layers in the crust and upper mantle are 18 km and 35 km, respectively. Since there exist a low viscosity layer about 3-5 km thickness, so it is reasonable that the decoupling between the crust and mantle occurred. So the effective thickness of the lithosphere can be estimated from the two elastic layers. Te is about 34 km. This is the maximum strength of the lithosphere. We can make an approximately estimation about the strength of the lithosphere beneath the Dabie Mts.: Te is about 20-30 km. The author believes that the following factors should be responsible for the low Te value: (1) the Dabie Mts. has elevated strongly since K_3-J_1. The north part of the Dabie Mts. elevates faster than the south part today; (2) there occur large active striking faults in this area. And in the east, the huge Tan-Lu striking fault anyway tends to decrease the lithosphere strength; (3) the lithosphere beneath the Dabie Mts. is heter-homogeneous in spatio-temporal; (4) the study area just locates in the adjacent region between the eastern China where the lithosphere thickness is significantly reduced and the normal western China. These factors will decrease the lithosphere strength.
Resumo:
The South continent of China lies to southeast of Eurasia block. It is an active area from the view of crust growth and continent spread and is a transition zone between continental crust and oceanic crust. The compressional wave velocities and anisotropies of typical crustal metamorphic rocks were determined at high temperature (up to 1000 ℃) and high pressure(up to 800MPa). The experimental results show that the velocities generally increase with pressure, and is unaffected by temperature up to around 550 ℃. But the velocities of all experimental samples start to drop above a temperature point. For an example, this greatly reduce the speed of wave propagation in amphibolite and serpentinite above 760 ℃ and above 550 ℃ respectively, which may be due to dehydrate of amphibole and serpentine. P-wave anisotropy coefficients of those rocks range from 2% to 10% at 800MPa and 500 ℃. The anisotropies decrease with increasing pressure at room temperature, but hardly change as function of temperature at constant 800MPa or 600MPa pressure. The average velocity of the six crustal rocks is 6.28km/s under the condition of 800MPa and 550 ℃, which is consistent with the result of deep seismic sounding data. Based on this experimental result, we deduce there may exist a lot of felsic granulites and amphibolites at the depth of 15-25km underground. With increasing temperature and pressure, the deformation behavior of the rocks undergoes from localized brittle fracture, semi-brittle deformation (cataclastic flow or semi-brittle faulting, semi-brittle flow) to homogeneous crystal-plastic flow. This transition is associated with mechanical behavior and micro-mechanism. It is very important to understanding earthquake source mechanics, the strength of the lithosphere and the style of deformation. The experiments were conducted at temperature of 600-1000 ℃, confining pressure of 500MPa, and stain rates of 10~(-4)-10~(-6) S~(-1). For fine-grained natural amphibolite, the results of experiments show that brittle faulting is major failure mode at temperature <600 ℃, but crystal-plastic deformation is dominate at temperature >800 ℃, and there is a transition with increasing temperature from sembrittle faulting to cataclastic flow and sembrittle flow at temperature of 670-750 ℃. For medium-grained natural Felsic granulite, the results of experiments show that brittle faulting is major failure mode at temperature <500 ℃, but crystal-plastic deformation is dominate at temperature >700 ℃, and there is a transition with increasing temperature from semibrittle faulting to cataclastic flow and sembrittle flow at temperature of 500-600 ℃.
Resumo:
Based on the study of fluvial sandstone reservoir in upper of Guantao group in Gudao and Gudong oilfields, this paper first introduces A.D.Miall's(1996a) architectural-element analysis method that was summarized from ground outcrop scale into the reservoir formation research of the study area, more subtly divides sedimentary microfacies and establishes sedimentary model of research area.on this base, this paper summarizes the laws of residual oil distribution of fluvial formation and the control effect of sedimentary microfacies to residual oil distribution, and reveals residual oil formation mechanism. These results have been applied to residual oil production, and the economic effect is good. This paper will be useful for residual oil research and production and enhancement of oil recovery in similar reservoir. The major conclusions of this paper are as follows. 1. Using the architectural-element analysis method to the core data, a interfacial division scheme of the first to the dixth scale is established for the studied fluvial formation. 2.Seven architectural-elements are divided in upper of Guantao group of study area. The sandstone group 5~1+2 of Neogene upper Gutao group belongs to high sinuous fine grain meandering river, and the sandstone group 6 is sandy braided river. 3. Inter layer, the residual oil saturation of "non-main layer" is higher than "main layer", but the residual recoverable reserve of former is larger. Therefore, "main layer" is the main body of residual oil distribution. The upper and middle part of inner layer has lower permeability and strong seeping resistance. Addition to gravity effect in process of driving, its driving efficiency is low; residual oil saturation is high. Because of controlling of inside non-permeable interlayer or sedimentary construction, the residual oil saturation of non-driving or lower driving efficiency position also is high. On plane, the position of high residual oil saturation mostly is at element LV, CS, CH (FF), FF etc, Which has lower porosity and permeability, as well as lens sand-body and sand-body edge that is not controlled by well-net, non-perfect area of injection and production, lower press difference resort area of inter-well diffiuent-line and shelter from fault, local high position of small structure. 4.Microscopic residual oil mainly includes the non-moved oil in the structure of fine pore network, oil in fine pore and path, oil segment in pore and path vertical to flow direction, oil spot or oil film in big pore, residual oil in non-connective pore. 5.The most essential and internal controlling factor of fluvial formation residual oil distribution is sedimentary microfacies. Status of injection and production is the exterior controlling factor of residual oil distribution. 6. The controlling effect of formation sedimentary microfacies to residual oil distribution indicates inter-layer vertical sedimentary facies change in scale of injection and production layer-series, planar sedimentary face change and inner-layer vertical sedimentary rhythm and interbed in single layer to residual oil distribution. 7. It is difficult to clear up the inter-layer difference in scale of injection and production layer-series. The using status of minor layer is not good and its residual oil saturation is high relatively. It is obvious that inter-layer vertical sedimentary facies changes control inter-layer residual oil distribution at the same or similar conditions of injection and production. For fluvial formation, this vertical sedimentary facies change mainly is positive
gyration. Namely, from down to top, channel sediment (element CHL, LA) changes into over-bank sediment (element LV, CR, CS).
8. In water-injection developing process of transverse connecting fluvial sandstone oil formation, injection water always comes into channel nearby, and breaks through along
channel and orientation of high pressure gradient, does not expand into side of channel until pressure gradient of channel orientation changes into low. It brings about that water-driving status of over-bank sedimentary element formation (LV, CR, CS) is not good, residual oil saturation is high. In non-connective abandoned channel element (CH
Resumo:
Mudstone reservoir is a subtle reservoir with extremely inhomogeneous, whose formation is greatly related to the existence of fracture. For this kind of reservoir, mudstone is oil source rock, cover rock and reservoir strata, reservoir type is various, attitude of oil layer changes greatly, and the distribution of oil and gas is different from igneous or clastic rock reservoir as well as from carbonate reservoir of self-producing and self-containing of oil and gas. No mature experience has been obtained in the description, exploration and development of the reservoir by far. Taking Zhanhua depression as an example, we studied in this thesis the tectonic evolution, deposit characteristics, diagenesis, hydrocarbon formation, abnormal formation pressure, forming of fissure in mudstone reservoir, etc. on the basis of core analysis, physical simulation, numerical simulation, integrated study of well logging and geophysical data, and systematically analyzed the developing and distributing of mudstone fissure reservoir and set up a geological model for the formation of mudstone fissure reservoir, and predicted possible fractural zone in studied area. Mudstone reservoir mainly distributed on the thrown side of sedimentary fault along the sloping area of the petroleum generatiion depression in Zhanhua depression. Growing fault controlled subsidence and sedimentation. Both the rate of subsidence and thickness of mudstone are great on the thrown side of growing fault, which result in the formation of surpressure in the area. The unlocking of fault which leads to the pressure discharges and the upward conduct of below stratum, also makes for the surpressure in mudstone. In Zhanhua depression, mudstone reservior mainly developed in sub-compacted stratum in the third segment of Shahejie formation, which is the best oil source rock because of its wide spread in distribution, great in thickness, and rich in organic matter, and rock types of which are oil source mudstone and shale of deep water or semi-deep water sediment in lacustrine facies. It revealed from core analysis that the stratum is rich in limestone, and consists of lamina of dark mudstone and that of light grey limestone alternately, such rock assemblage is in favor of high pressure and fracture in the process of hydrocarbon generation. Fracture of mudstone in the third segment of Shahejie formation was divided into structure fracture, hydrocarbon generation fracture and compound fracture and six secondary types of fracture for the fist time according to the cause of their formation in the thesis. Structural fracture is formed by tectonic movement such as fold or fault, which develops mainly near the faults, especially in the protrude area and the edge of faults, such fracture has obvious directivity, and tend to have more width and extension in length and obvious direction, and was developed periodically, discontinuously in time and successively as the result of multi-tectonic movement in studied area. Hydrocarbon generation fracture was formed in the process of hydrocarbon generation, the fracture is numerous in number and extensively in distribution, but the scale of it is always small and belongs to microfracture. The compound fracture is the result of both tectonic movement and hydrocarbon forming process. The combination of above fractures in time and space forms the three dimension reservoir space network of mudstone, which satellites with abnormal pressure zone in plane distribution and relates to sedimentary faces, rock combination, organic content, structural evolution, and high pressure, etc.. In Zhanhua depression, the mudstone of third segment in shahejie formation corresponds with a set of seismic reflection with better continuous. When mudstone containing oil and gas of abnormal high pressure, the seismic waveform would change as a result of absorb of oil and gas to the high-frequency composition of seismic reflection, and decrease of seismic reflection frequency resulted from the breakage of mudstone structure. The author solved the problem of mudstone reservoir predicting to some degree through the use of coherent data analysis in Zhanhua depression. Numerical modeling of basin has been used to simulate the ancient liquid pressure field in Zhanhua depression, to quantitative analysis the main controlling factor (such as uncompaction, tectonic movement, hydrocarbon generation) to surpressure in mudstone. Combined with factual geologic information and references, we analyzed the characteristic of basin evolution and factors influence the pressure field, and employed numerical modeling of liquid pressure evolution in 1-D and 2-D section, modeled and analyzed the forming and evolution of pressure in plane for main position in different periods, and made a conclusion that the main factors for surpressure in studied area are tectonic movement, uncompaction and hydrocarbon generation process. In Zhanhua depression, the valid fracture zone in mudstone was mainly formed in the last stage of Dongying movement, the mudstone in the third segment of Shahejie formation turn into fastigium for oil generation and migration in Guantao stage, and oil and gas were preserved since the end of the stage. Tectonic movement was weak after oil and gas to be preserved, and such made for the preserve of oil and gas. The forming of fractured mudstone reservoir can be divided into four different stages, i.e. deposition of muddy oil source rock, draining off water by compacting to producing hydrocarbon, forming of valid fracture and collecting of oil, forming of fracture reservoir. Combined with other regional geologic information, we predicted four prior mudstone fracture reservoirs, which measured 18km2 in area and 1200 X 104t in geological reserves.
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Based on the study of sequence stratigraphy, modern sedimentary, basin analysis, and petroleum system in abrupt slop of depression, this paper builds sedimentary system and model, sandy bodies distribution, and pool-forming mechanism of subtle trap. There are some conclusions and views as follows. By a lot of well logging and seismic analysis, the author founded up the sequence stratigraphic of the abrupt slope, systematically illustrated the abrupt slope constructive framework, and pointed out that there was a special characteristics which was that south-north could be divided to several fault block and east-west could be carved up groove and the bridge in studying area. Based all these, the author divided the studying area to 3 fault block zone in which because of the groove became the basement rock channel down which ancient rivers breathed into the lake, the alluvial fan or fan delta were formed. In the paper, the author illustrated the depositional system and depositional model of abrupt slope zone, and distinguished 16 kinds of lithofacies and 3 kinds of depositional systems which were the alluvial fan and fan-delta system, lake system and the turbidite fan or turbidity current deposition. It is first time to expound completely the genetic pattern and distributing rule of the abrupt slope sandy-conglomeratic fan bodies. The abrupt slope sandy-conglomeratic fan bodies distribute around the heaves showing itself circularity shape. In studying area, the sandy-conglomeratic fan bodies mainly distribute up the southern slope of Binxian heave and Chenjiazhuang heave. There mainly are these sandy-conglomeratic fan body colony which distributes at a wide rage including the alluvial fan, sub-water fluvial and the turbidite fan or the other turbidity current deposition in the I fault block of the Wangzhuang area. In the II fault block there are fan-delta front and sub-water fluvial. And in the Binnan area, there mainly are those the alluvial fan (down the basement rock channel) and the sandy-conglomeratic fan body which formed as narrowband sub-water fluvial (the position of bridge of a nose) in the I fault block, the fan-delta front sandy-conglomeratic fan body in the H fault block and the fan-delta front and the turbidity current deposition sandy-conglomeratic fan body in the m fault block. Based on the reservoir outstanding characteristics of complex classic composition and the low texture maturity, the author comparted the reservoir micro-structure of the Sha-III and Sha-IV member to 4 types including the viscous crude cementation type, the pad cementation type, the calcite pore-funds type and the complex filling type, and hereby synthetically evaluated 4 types sandy- conglomeratic fan body reservoir. In the west-north abrupt slope zone of Dongying Depression, the crude oil source is belonging to the Sha-III and Sha-IV member, the deep oil of Lijin oilfield respectively come from the Sha-III and Sha-IV member, which belongs to the autogeny and original deposition type; and the more crude oil producing by Sha-IV member was migrated to the Wangzhuan area and Zhengjia area. The crude oil of Binnan oil-field and Shanjiasi oil-field belongs to mixed genetic. It is the first time to illustrate systematically the genetic of the viscous crude that largely being in the studying area, which are that the dissipation of the light component after pool-forming, the biological gradation action and the bath-oxidation action, these oil accumulation belonging to the secondary viscous crude accumulation. It is also the first time to compart the studying area to 5 pool-forming dynamical system that have the characteristic including the common pressure and abnormal pressure system, the self-fountain and other-fountain system and the closing and half-closing system etc. The 5 dynamical systems reciprocally interconnected via the disappearance or merger of the Ethology and the fluid pressure compartment zone, the fault and the unconformity surface, hereby formed duplicated pattern oil-gas collecting zone. Three oil-gas pool-forming pattern were founded, which included the self-fountain side-direction migrated collecting pattern, the self-fountain side-direction ladder-shape pool-forming pattern and the other-fountain pressure releasing zone migrated collecting pattern. A series of systemic sandy-conglomeratic fan bodies oil-gas predicting theory and method was founded, based on the groove-fan corresponding relation to confirm the favorable aim area, according as the characteristic of seismic-facies to identify qualitatively the sandy-conglomeratic fan bodies or its scale, used the temporal and frequency analysis technique to score the interior structure of the sandy- conglomeratic fan bodies, applied for coherent-data system analysis technology to describe the boundary of the sandy-conglomeratic fan bodies, and utilized the well logging restriction inversion technique to trace quantificational and forecast the sandy-conglomeratic fan bodies. Applied this technique, totally 15 beneficial sandy-conglomeratic fan bodies were predicted, in studying area the exploration was preferably guided, and the larger economic benefit and social benefit was acquired.
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Dabie shan lies between Northchina crust and Yangzi crust, which is the result of the collisional orogenen in Triassic period. The biggest area of UHP metamorphic zone have been found in Dabie Shan, which have been verified formed during the course of collision and extrusion after orogenic activity. The Dabie shan is divisioned into four parts, which are North Huaiyang metamorphic zone, North Dabie complex zone, South Dabie ultra-high pressure metamorphic zone and Susong metamorphic zone. Extension structure of late Mesozoic is the key to explain the intrusion and outcrop of UHP metamorphic rocks in Dabie Shan. During the course of structure evolution of the Dabie shan in late Mesozoic period, Luotian dome was formed with the old gneiss lifting from the core of the Dabie shan. There are four enormous ductile zone circled Luotian dorm. Xiaotian-mozitan shear zone is the limit of North Huaiyang metamorphic zone and North Dabie complex zone; Shuihou-wuhe shear zone is the limit of North Dabie complex zone and South Dabie ultra-high pressure metamorphic zone; Taihu-mamiao shears zone is the limit of South Dabie ultra-high pressure metamorphic zone and Susong metamorphic zone and Susong-Qingshuihe shear zone is the south limit of Susong metamorphic zone; the old stress at Dabie shan in late Mesozoic was about 90MPa through the experiment of transmission electricity microscope. The main four ductile shear zone of Dabie shan all have the characteristic of detachment, Xiaotian-mozitan shear zone detached to NNE, the detachment direction of Shuihou-wuhe shear zone and Taihu-mamiao shears zone is SSE, and Susong-Qingshuihe shear zone is SW. The finite strain measurement show that Xiaotian-mozitan shear zone have experienced detachment which was more than 50km, and the detachment of Susong-Qingshuihe shear zone was more than 12km in late Mesozoic; the Flin parameter of Shuihou-wuhe shear zone is much smaller than 1(0.01-0.1), which show that this shear zone was squeezed when it was formed and the initiative function of Luotian granite intrusion during the course of detachment. The Flin parameter of Taihu-mamiao shears zone is above 1(1.1) and Susong-Qingshuihe shear zone is much more than 1(7.6), which show that they are formed in the state of extension at the beginning. These all Flin parameter imply a transition from pure shear to simple shear of the south three shear zone circling Luotian dome from north to south. The rock group analysis show that the rocks inside shear zone encountered middle or high temperature metamorphic activity. The single mineral ~(40)Ar/~(39)Ar age of the main shear zone at Dabie shan show that the three shear zone north to Luotian dome were formed about 190Ma.Taihu-mamiao shear zone was the earliest, Susong shear zone was later than former, and Shuihou-wuhe sheanaone was the latest. They were all the chanel of returning of UHP metamorphic rocks, so they all representative the returning age of UHP metamorphic rocks. The final outcrop of these UHP metamorphic rocks was due to the detachment aroused by the enormous magma intrusion. The biotite age of deformed rocks in Susong-Qingshuihe shear zone is in average 126Ma, and the age of Xiaotian-mozitan is about 125Ma, which is in the same time or a little later than magma intrusion of Luotian dome, and imply that granite intrusion of late Mesozoic in Dabie orogenen is the reason of the detachment.
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With the development of petroleum exploration, subtle reservoir has become the main exploration object in Dongying Depression, which requires some new technologies and methods to further reveal the geological characteristics in step with the mature exploration stage. In this paper, on the references to the studies of petroleum system and multiple oil-gas accumulation belt with flexible maneuverability, and the application of systematic theory, the concept of reservoir assemblage is initially defined as "the association of active source rock(s) and hydrocarbon reservoir(s) that are genetically related, with the bridge of pathway system in an oil and gas bearing basin". Compared with the theories of petroleum system and multiple oil-gas accumulation belts, it emphasizes on the processes of petroleum migration and accumulation and the correlation among active source rock, trapped hydrocarbon and migration pathway, and has been confirmed to be more suitably applied to high maturely explored basin. In the first study of this paper, sequence stratigraphy and subtle analytical technology of source rock have been employed to find that two categories of source rock with their characteristic types of organic matter and substantial states occurred in Dongying Depression. The first category, consisting of the oil shales within the third-order sequences of lacustrine expanding system tracts in the upper interval of the fourth Member of Shahejie Formation and both in the middle and lower intervals of the third Member of Shahejie Formation, is featured with the highest abundance of total organic matter (TOC) and the strongest abilities of hydrocarbon generation and expulsion, which is classified into the standard of good hydrocarbon source rock. Exploration assessment confirmed that about 70-80% of hydrocarbon in Dongying Depression came from this set of source rock for which the low sedimentary rate and strong oxygen-free environment would play the key role during its generation. The second category, composed of organic matter of dark mudstone in high stand system tracts in the upper and middle intervals of the third Member of Shahejie Formation, has been characterized by low content of total organic matter which mostly dispersedly distributes, and formed in the pre-delta to delta front environments. In classification, it belongs to the ordinary standard of source rocks. In the second research part, through the studies of high frequency sequence stratigraphy, fault geometry and active history combining with geochemistry of fluid inclusion and nitrogen compound and simulation test of hydrocarbon migration and accumulation, the faults have been thought to be the principal conduits, and the sandy bodies and unconformities might played the complementary pathways for hydrocarbon migration and accumulation in Dongying Depression of the continental faulted basin. Therefore, the fault activities may mainly constrain on the development of hydrocarbon pathways in space and time. Even more, using homogenization temperatures of fluid inclusion in digenetic minerals, three critical moments for hydrocarbon accumulation have been determined as well in Dongying Depression, which happened during the late stage of Dongying Formation (Ed), the early stage of Guantao Formation (Nig) and the early stage of Minghuazhen Formation (Nim), respectively. Comparatively, the last stage is looked as the main forming-reservoir period, which has also been supported by the results of geochemical analysis and simulation experiments of hydrocarbon generation and expulsion. Clearly, the times of hydrocarbon migration and accumulation are consistent with those of the fault activities in Dongying Depression, which indicate that tectonic activities would control the forming-reservoir. A conceptual model of faulting-episodic expulsion coupled with episodic forming-reservoir has then been established in this study. In the third part of this paper, some focusing areas were selected for the fine descriptions of pathway distribution and forming-reservoir, which has given four types of reservoir assemblage in terms of the main pathway and its correlation with the reservoir and trap: (1) mainly consisted of sandy bodies; (2) mainly consisted of faults; (3) mainly consisted of unconformities; and (4) their complex with two or three types of pathways. This classified criteria has also been applied to access the risk of some prospected traps in Dongying Depression. Finally, through the application of reservoir assemblage integrated with pathway distribution to all the prospective targets in Dongying Depression, the new favorably hydrocarbon accumulated belts have been figured out, and more subtle reservoirs have also been found. For examples, during 2000 and 2002, in the mature exploration areas, such as Liangjialou and Shengtuo structural closures etc., newly proved reserves were 2274 * 104t, and forecasted oil reserves 5660-5860xl04t; and in the predicted favorable areas, newly additional controlled oil reserves was 3355xl04t. Besides those, many other favorable exploration areas need to be further appraised.
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As far as the architecture of the south Dabie metamorphic terrain is concerned, there have been lots of different opinions for a long time. Wang et al. (1990, 1992) thought of it was a continuous terrain. Okay (1993) held that it consistes of two different tectonic terrains: the 'hot' and 'cold' eclogite belt. Liu and Wang (1998) held that it is composed of different metamorphic blocks through 'melange' in depth. For this reason, we have choiced Hualiangting reservoir of Taihu county as the study area treat eclogite as the investigated objection in this thesis, and employ the detailed 1 :10000 geological mapping, methods of Petrography and electonic probe anaylsis to probe into the architecture of the south Dabie metamorphic terrains. In the light of the eclogite occurrenc in the field, the analysis of Petrography, the research on metamoiphic P-T path and condition of the peak metamorphic P-T condition, the eclogite in the Taihu area of Dabieshan have been classified into three types eclogite from the south to the north: The zhujiachong type eclogite; The Daba type eclogite; (3) The Jinheqiao type eclogite, their mineral composition, structure, and mineral component vary continuously. These eclogites have the same rnetamoiphic stages, P-T evolution pattern, and their peak P-T condition varies continuously. The zhujiachong type eclogite is formed in the high pressure metamoiphic environment. The Jinheqiao type eclogite is formed in the typical ultra-high pressure environment. The Daba type eclogite is formed in the transformed metamorphic environment between high pressure and ultra-high pressure metamorphism. All these evidences show that the south Dabie metamorphic terrain is a continuous metamorphic block and no large fault ever existed.
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With the development of oil and gas exploration, the exploration of the continental oil and gas turns into the exploration of the subtle oil and gas reservoirs from the structural oil and gas reservoirs in China. The reserves of the found subtle oil and gas reservoirs account for more than 60 percent of the in the discovered oil and gas reserves. Exploration of the subtle oil and gas reservoirs is becoming more and more important and can be taken as the main orientation for the increase of the oil and gas reserves. The characteristics of the continental sedimentary facies determine the complexities of the lithological exploration. Most of the continental rift basins in East China have entered exploration stages of medium and high maturity. Although the quality of the seismic data is relatively good, this areas have the characteristics of the thin sand thickness, small faults, small range of the stratum. It requests that the seismic data have high resolution. It is a important task how to improve the signal/noise ratio of the high frequency of seismic data. In West China, there are the complex landforms, the deep embedding the targets of the prospecting, the complex geological constructs, many ruptures, small range of the traps, the low rock properties, many high pressure stratums and difficulties of boring well. Those represent low signal/noise ratio and complex kinds of noise in the seismic records. This needs to develop the method and technique of the noise attenuation in the data acquisition and processing. So that, oil and gas explorations need the high resolution technique of the geophysics in order to solve the implementation of the oil resources strategy for keep oil production and reserves stable in Ease China and developing the crude production and reserves in West China. High signal/noise ratio of seismic data is the basis. It is impossible to realize for the high resolution and high fidelity without the high signal/noise ratio. We play emphasis on many researches based on the structure analysis for improving signal/noise ratio of the complex areas. Several methods are put forward for noise attenuation to truly reflect the geological features. Those can reflect the geological structures, keep the edges of geological construction and improve the identifications of the oil and gas traps. The ideas of emphasize the foundation, give prominence to innovate, and pay attention to application runs through the paper. The dip-scanning method as the center of the scanned point inevitably blurs the edges of geological features, such as fault and fractures. We develop the new dip scanning method in the shap of end with two sides scanning to solve this problem. We bring forward the methods of signal estimation with the coherence, seismic wave characteristc with coherence, the most homogeneous dip-sanning for the noise attenuation using the new dip-scanning method. They can keep the geological characters, suppress the random noise and improve the s/n ratio and resolution. The rutine dip-scanning is in the time-space domain. Anew method of dip-scanning in the frequency-wavenumber domain for the noise attenuation is put forward. It use the quality of distinguishing between different dip events of the reflection in f-k domain. It can reduce the noise and gain the dip information. We describe a methodology for studying and developing filtering methods based on differential equations. It transforms the filtering equations in the frequency domain or the f-k domain into time or time-space domains, and uses a finite-difference algorithm to solve these equations. This method does not require that seismic data be stationary, so their parameters can vary at every temporal and spatial point. That enhances the adaptability of the filter. It is computationally efficient. We put forward a method of matching pursuits for the noise suppression. This method decomposes any signal into a linear expansion of waveforms that are selected from a redundant dictionary of functions. These waveforms are chosen in order to best match the signal structures. It can extract the effective signal from the noisy signal and reduce the noise. We introduce the beamforming filtering method for the noise elimination. Real seismic data processing shows that it is effective in attenuating multiples and internal multiples. The s/n ratio and resolution are improved. The effective signals have the high fidelity. Through calculating in the theoretic model and applying it to the real seismic data processing, it is proved that the methods in this paper can effectively suppress the random noise, eliminate the cohence noise, and improve the resolution of the seismic data. Their practicability is very better. And the effect is very obvious.