Alvará de Ley, porque V. Magestade ha por bem tomar debaixo da sua Real Protecção o Contrato dos Diamantes do Brasil, e fazer exclusivo o comercio das referidas pedras, na forma, que nelle se declara : para V. Magestade ver

Nota de Conteúdo : Lei do Contrato dos Diamantes do Brasil, de 11 de agosto de 1753.

Discrepancias en el seno de la burguesía guipuzcoana en torno a la libertad de comercio y el traslado de aduanas durante los siglos XVIII y XIX

[ES] El objetivo del presente artículo es demostrar y analizar las discrepancias que hubo en el seno de la burguesía guipuzcoana durante los siglos XVIII y XIX en torno a la habilitación de los puertos guipuzcoanos para el comercio directo con América y el traslado de aduanas desde el interior a la costa. Para ello, se acude a la extensa historiografía que se ha ocupado del tema y se hace un análisis crítico de cierto número de representaciones enviadas por el grupo de comerciantes disidentes, con el fin de llevar a cabo un reco- rrido por el debate en torno a ambas cuestiones, que se prolongó desde el advenimiento de la dinastía borbónica hasta los decretos de 1841. A pesar de la visión unívoca que se ha dado del mencionado debate, según la cual parti- ciparon dos bloques perfectamente diferenciados, la documentación muestra una mayor heterogeneidad en las posturas, de manera que en el seno de la burguesía comercial se perciben ciertas divisiones y discrepancias. Si bien es cierto que en un principio los bloques parecen tener un discurso claramente beligerante, aunque también existen todavía puntos de coincidencia, a medi- da que transcurre el tiempo, las posturas se van radicalizando y diversifi- cando, creando una mayor heterogeneidad.

Sistema de comercio electrónico para el sector textil: generar maniquíes 3D a partir de imágenes del sensor Kinect

Este proyecto consiste en analizar la viabilidad técnica un sistema de información para mejorar el comercio electrónico de compra –venta de ropa. El nuevo sistema de comercio electrónico ayudará al usuario a escoger el tamaño de la prenda con más precisión. El sistema consiste en calcular las medidas esenciales del cuerpo del cliente utilizando el dispositivo Kinect. Posteriormente, estas medidas se introducen en el programa Makehuman que genera un maniquí en 3D. Con la idea de que en el futuro se puede utilizar el maniquí para probar virtualmente prendas de vestir, se ha ideado un método, utilizando el programa Blender, que genera ropa en 3D con fotografías de prendas. Se generan dos ejemplos (pantalón y camiseta) para ilustrarlo.

Hacia un ética universal para la profesión contable: análisis de las restricciones socioeconómicas y culturales en la convergencia del código de ética internacional

Máster en Dirección Empresarial desde la Innovación y la Internacionalización. Curso 2011/2012

Developing and characterizing bulk metallic glasses for extreme applications

Metallic glasses have typically been treated as a “one size fits all” type of material. Every alloy is considered to have high strength, high hardness, large elastic limits, corrosion resistance, etc. However, similar to traditional crystalline materials, properties are strongly dependent upon the constituent elements, how it was processed, and the conditions under which it will be used. An important distinction which can be made is between metallic glasses and their composites. Charpy impact toughness measurements are performed to determine the effect processing and microstructure have on bulk metallic glass matrix composites (BMGMCs). Samples are suction cast, machined from commercial plates, and semi-solidly forged (SSF). The SSF specimens have been found to have the highest impact toughness due to the coarsening of the dendrites, which occurs during the semi-solid processing stages. Ductile to brittle transition (DTBT) temperatures are measured for a BMGMC. While at room temperature the BMGMC is highly toughened compared to a fully glassy alloy, it undergoes a DTBT by 250 K. At this point, its impact toughness mirrors that of the constituent glassy matrix. In the following chapter, BMGMCs are shown to have the capability of being capacitively welded to form single, monolithic structures. Shear measurements are performed across welded samples, and, at sufficient weld energies, are found to retain the strength of the parent alloy. Cross-sections are inspected via SEM and no visible crystallization of the matrix occurs.

Next, metallic glasses and BMGMCs are formed into sheets and eggbox structures are tested in hypervelocity impacts. Metallic glasses are ideal candidates for protection against micrometeorite orbital debris due to their high hardness and relatively low density. A flat single layer, flat BMG is compared to a BMGMC eggbox and the latter creates a more diffuse projectile cloud after penetration. A three tiered eggbox structure is also tested by firing a 3.17 mm aluminum sphere at 2.7 km/s at it. The projectile penetrates the first two layers, but is successfully contained by the third.

A large series of metallic glass alloys are created and their wear loss is measured in a pin on disk test. Wear is found to vary dramatically among different metallic glasses, with some considerably outperforming the current state-of-the-art crystalline material (most notably Cu₄₃Zr₄₃Al₇Be₇). Others, on the other hand, suffered extensive wear loss. Commercially available Vitreloy 1 lost nearly three times as much mass in wear as alloy prepared in a laboratory setting. No conclusive correlations can be found between any set of mechanical properties (hardness, density, elastic, bulk, or shear modulus, Poisson’s ratio, frictional force, and run in time) and wear loss. Heat treatments are performed on Vitreloy 1 and Cu₄₃Zr₄₃Al₇Be₇. Anneals near the glass transition temperature are found to increase hardness slightly, but decrease wear loss significantly. Crystallization of both alloys leads to dramatic increases in wear resistance. Finally, wear tests under vacuum are performed on the two alloys above. Vitreloy 1 experiences a dramatic decrease in wear loss, while Cu₄₃Zr₄₃Al₇Be₇ has a moderate increase. Meanwhile, gears are fabricated through three techniques: electrical discharge machining of 1 cm by 3 mm cylinders, semisolid forging, and copper mold suction casting. Initial testing finds the pin on disk test to be an accurate predictor of wear performance in gears.

The final chapter explores an exciting technique in the field of additive manufacturing. Laser engineered net shaping (LENS) is a method whereby small amounts of metallic powders are melted by a laser such that shapes and designs can be built layer by layer into a final part. The technique is extended to mixing different powders during melting, so that compositional gradients can be created across a manufactured part. Two compositional gradients are fabricated and characterized. Ti 6Al¬ 4V to pure vanadium was chosen for its combination of high strength and light weight on one end, and high melting point on the other. It was inspected by cross-sectional x-ray diffraction, and only the anticipated phases were present. 304L stainless steel to Invar 36 was created in both pillar and as a radial gradient. It combines strength and weldability along with a zero coefficient of thermal expansion material. Only the austenite phase is found to be present via x-ray diffraction. Coefficient of thermal expansion is measured for four compositions, and it is found to be tunable depending on composition.

The Art of Madness

The nineteenth century was not an entirely kind time for the female artist. Coming of age as the 1800’s bridged into its latter half, literary artists Elizabeth Stuart Phelps Ward, Charlotte Perkins Gilman, and Kate Chopin were all well aware of their uncharitable culture. Equipped with firm feminist bents and creative visions, each of three women produced a seminal work – The Story of Avis, “The Yellow Wallpaper,” and The Awakening, respectively – taking that atmosphere to task. In these stories, each of the three women produces a female protagonist who struggles for having been born simultaneously an artist and a woman. The writers pit their women’s desires against the restrictive latitude of their time and show how such conditions drive women to madness, as a result of which they are forced to either escape into the blind mind of insanity or deal daily with their pain and inescapable societal condemnation. In an age where “hysteria” was a frequent hit in the vernacular, Phelps, Gilman and Chopin use art and literature as mediums to show that, indeed, there is a method behind the madness.

Validación de un código basado en método de paneles para flujos alrededor de perfiles aerodinámicos

[ES]El proyecto a realizar consiste en un estudio de la validez de un código basado en el método de los paneles. El objetivo es acotar el rango de aplicación del código.

Kinetic investigations of heterogeneously catalyzed reactions on the Ru(001) and Pt(110)-(1x2) surfaces

The initial probabilities of activated, dissociative chemisorption of methane and ethane on Pt(110)-(1 x 2) have been measured. The surface temperature was varied from 450 to 900 K with the reactant gas temperature constant at 300 K. Under these conditions, we probe the kinetics of dissociation via trapping-mediated (as opposed to 'direct') mechanism. It was found that the probabilities of dissociation of both methane and ethane were strong functions of the surface temperature with an apparent activation energies of 14.4 kcal/mol for methane and 2.8 kcal/mol for ethane, which implys that the methane and ethane molecules have fully accommodated to the surface temperature. Kinetic isotope effects were observed for both reactions, indicating that the C-H bond cleavage was involved in the rate-limiting step. A mechanistic model based on the trapping-mediated mechanism is used to explain the observed kinetic behavior. The activation energies for C-H bond dissociation of the thermally accommodated methane and ethane on the surface extracted from the model are 18.4 and 10.3 kcal/mol, respectively.

The studies of the catalytic decomposition of formic acid on the Ru(001) surface with thermal desorption mass spectrometry following the adsorption of DCOOH and HCOOH on the surface at 130 and 310 K are described. Formic acid (DCOOH) chemisorbs dissociatively on the surface via both the cleavage of its O-H bond to form a formate and a hydrogen adatom, and the cleavage of its C-O bond to form a carbon monoxide, a deuterium adatom and an hydroxyl (OH). The former is the predominant reaction. The rate of desorption of carbon dioxide is a direct measure of the kinetics of decomposition of the surface formate. It is characterized by a kinetic isotope effect, an increasingly narrow FWHM, and an upward shift in peak temperature with Ɵ_T, the coverage of the dissociatively adsorbed formic acid. The FWHM and the peak temperature change from 18 K and 326 K at Ɵ_T = 0.04 to 8 K and 395 K at Ɵ_T = 0.89. The increase in the apparent activation energy of the C-D bond cleavage is largely a result of self-poisoning by the formate, the presence of which on the surface alters the electronic properties of the surface such that the activation energy of the decomposition of formate is increased. The variation of the activation energy for carbon dioxide formation with Ɵ_T accounts for the observed sharp carbon dioxide peak. The coverage of surface formate can be adjusted over a relatively wide range so that the activation energy for C-D bond cleavage in the case of DCOOH can be adjusted to be below, approximately equal to, or well above the activation energy for the recombinative desorption of the deuterium adatoms. Accordingly, the desorption of deuterium was observed to be governed completely by the desorption kinetics of the deuterium adatoms at low Ɵ_T, jointly by the kinetics of deuterium desorption and C-D bond cleavage at intermediate Ɵ_T, and solely by the kinetics of C-D bond cleavage at high Ɵ_T. The overall branching ratio of the formate to carbon dioxide and carbon monoxide is approximately unity, regardless the initial coverage Ɵ_T, even though the activation energy for the production of carbon dioxide varies with Ɵ_T. The desorption of water, which implies C-O bond cleavage of the formate, appears at approximately the same temperature as that of carbon dioxide. These observations suggest that the cleavage of the C-D bond and that of the C-O bond of two surface formates are coupled, possibly via the formation of a short-lived surface complex that is the precursor to to the decomposition.

The measurement of steady-state rate is demonstrated here to be valuable in determining kinetics associated with short-lived, molecularly adsorbed precursor to further reactions on the surface, by determining the kinetic parameters of the molecular precursor of formaldehyde to its dissociation on the Pt(110)-(1 x 2) surface.

Overlayers of nitrogen adatoms on Ru(001) have been characterized both by thermal desorption mass spectrometry and low-energy electron diffraction, as well as chemically via the postadsorption and desorption of ammonia and carbon monoxide.

The nitrogen-adatom overlayer was prepared by decomposing ammonia thermally on the surface at a pressure of 2.8 x 10^(-6) Torr and a temperature of 480 K. The saturated overlayer prepared under these conditions has associated with it a (√247/10 x √247/10)R22.7° LEED pattern, has two peaks in its thermal desorption spectrum, and has a fractional surface coverage of 0.40. Annealing the overlayer to approximately 535 K results in a rather sharp (√3 x √3)R30° LEED pattern with an associated fractional surface coverage of one-third. Annealing the overlayer further to 620 K results in the disappearance of the low-temperature thermal desorption peak and the appearance of a rather fuzzy p(2x2) LEED pattern with an associated fractional surface coverage of approximately one-fourth. In the low coverage limit, the presence of the (√3 x √3)R30° N overlayer alters the surface in such a way that the binding energy of ammonia is increased by 20% relative to the clean surface, whereas that of carbon monoxide is reduced by 15%.

A general methodology for the indirect relative determination of the absolute fractional surface coverages has been developed and was utilized to determine the saturation fractional coverage of hydrogen on Ru(001). Formaldehyde was employed as a bridge to lead us from the known reference point of the saturation fractional coverage of carbon monoxide to unknown reference point of the fractional coverage of hydrogen on Ru(001), which is then used to determine accurately the saturation fractional coverage of hydrogen. We find that ƟSAT/H = 1.02 (±0.05), i.e., the surface stoichiometry is Ru : H = 1 : 1. The relative nature of the method, which cancels systematic errors, together with the utilization of a glass envelope around the mass spectrometer, which reduces spurious contributions in the thermal desorption spectra, results in high accuracy in the determination of absolute fractional coverages.

Análisis del comercio minorista vasco, y estrategias para impulsar el comercio urbano

Este documento recoge un análisis de la situación del sector del comercio minorista en el País Vasco y su evolución en los últimos años, en los que la crisis ha marcado significativamente la actividad económica. En él se abordan también las tendencias previsibles a corto plazo y los cambios que estas pueden suponer. Todo ello con el objetivo de proponer ideas que ayuden al comercio minorista a impulsar su dinamismo, considerando que el contexto competitivo es nuevo con un protagonismo evidente del mundo digital. He tratado de recoger propuestas lo más innovadoras posibles, sin olvidar que se trata de un reto complicado ya que un gran número de especialistas han trabajado a fondo en ese sentido desde hace tiempo. Sin embargo, entiendo que contar con nuevas ideas es siempre positivo y a ello se dirige mi contribución.

Análisis del comercio minorista vasco, y estrategias para impulsar el comercio urbano

Este documento recoge un análisis de la situación del sector del comercio minorista en el País Vasco y su evolución en los últimos años, en los que la crisis ha marcado significativamente la actividad económica. En él se abordan también las tendencias previsibles a corto plazo y los cambios que estas pueden suponer. Todo ello con el objetivo de proponer ideas que ayuden al comercio minorista a impulsar su dinamismo, considerando que el contexto competitivo es nuevo con un protagonismo evidente del mundo digital. He tratado de recoger propuestas lo más innovadoras posibles, sin olvidar que se trata de un reto complicado ya que un gran número de especialistas han trabajado a fondo en ese sentido desde hace tiempo. Sin embargo, entiendo que contar con nuevas ideas es siempre positivo y a ello se dirige mi contribución.

Análisis económico-financiero de las empresas del sector de comercio al por menor en el Pais Vasco

El trabajo consiste en realizar un análisis económico-financiero de las empresas del sector del comercio al por menor en establecimientos no especializados, con predominio en productos alimenticios establecidas en el País Vasco, centrándose especialmente en el diagnóstico de su situación actual y la evolución reciente de su liquidez, riesgo y rentabilidad. The work consists of carry out an economic and financial analysis of companies in the retail trade in non-specialized sector, stores with food products based in the Basque Country, especially focusing on the diagnosis of the current situation and recent developments their liquidity, risk and profitability.

Análisis económico-financiero de las empresas del sector de comercio al por menor en el País Vasco

Con las herramientas adecuadas, hemos explicado las características económico-financieras esenciales del sector del comercio al por menor en el País Vasco, su comparación con respecto a España, la influencia de Eroski en él y cómo ha sido la evolución del sector respecto a 1994. Hemos querido conocer el estado de salud de este grupo de empresas, para así poder conocer qué tipo de medidas deben tomar estas empresas y cuál es su futuro. La caída de la rentabilidad que surge con el inicio de la crisis en 2008 y unos fondos propios elevados, son los puntos más destacados en nuestro informe.

Evolución y situación actual del comercio internacional de alimentos

Análisis de la evolución del comercio internacional de alimentos y de las implicaciones económicas, sociales y políticas del sistema comercial actual.

Investigations into the structure and function of the exocrine pancreas of lampreys. [Translation from: Morph.Jb. 110 245-269, 1967.]

As representatives of the most primitive of recent vertebrate groups, lampreys show fundamental differences in different features of organisation to the species of the remaining classes of vertebrates. The topical distinction between exocrine and endocrine pancreas is also considered among the morphological peculiarities of Petromyzontida. This study aims to contribute to a further explanation of this phenomenon. 50 brook lampreys were histologically examined.