Dinoflagellates of multicorer surface sediments

Only very few studies focus on recent calcareous dinoflagellate cyst diversity, geographic distribution and ecology, so that information on the distribution patterns and environmental affinities of individual cyst species is extremely limited. This information is, however, essential if we want to use calcareous dinoflagellate cysts for palaeoenvironmental reconstruction. Surface sediment samples from the generally oligotrophic western equatorial Atlantic Ocean, offshore northeast Brazil, were therefore quantitatively analysed for their calcareous dinoflagellate cyst content, including the calcareous vegetative coccoid Thoracosphaera heimii. Seven calcareous dinoflagellate cyst species/morphotypes and T. heimii were encountered in high concentrations throughout the area. Substantial differences in the distribution patterns were observed. The highest concentrations of cysts are found in sediments of the more oligotrophic, oceanic regions, beyond the influence of Amazon River discharge waters. Dinoflagellates producing calcareous cysts thus appear to be capable of surviving low nutrient concentrations and produce large numbers of cysts in relatively stable and predictable environments affected by minimal seasonality. To test for the environmental affinities of individual species, distribution patterns in surface sediments were compared with temperature, salinity, density and stratification gradients within the upper water column (0-100 m) over different times of the year, using principal components analysis and redundancy analysis. T. heimii and four of the seven encountered cyst species (Sphaerodinella? albatrosiana, two morphotypes of Sphaerodinella? tuberosa and Scrippsiella regalis) relate to these parameters significantly and the variations in the cyst associations appear to be associated with the different surface water currents characterising the area. The results imply that calcareous dinoflagellate cyst distributions can potentially be used to distinguish between different open oceanic environments and they could, therefore, be useful in tracing water mass movements throughout the late Quaternary.

Hints to emigrants : in a series of letters from Upper Canada /

Map: Perth, Lanark & Richmond Settlements, district of Bathurst, Upper Canada with part of the adjacent county; Plans: [1]. Township of Drummond, ten miles square. This sketch shows how a township is divided into concessions & lots; [2]. Perth.

The Impact of Tropical Teleconnections on Antarctic Sea Ice and Climate

Thesis (Master's)--University of Washington, 2016-06

A refined solution to Earth's hidden niobium: implications for evolution of continental crust and mode of core formation

New high-precision niobium (Nb) and tantalum (Ta) concentration data are presented for early Archaean metabasalts, metabasaltic komatiites and their erosion products (mafic metapelites) from SW Greenland and the Acasta gneiss complex, Canada. Individual datasets consistently show sub-chondritic Nb/Ta ratios averaging 15.1+/-11.6. This finding is discussed with regard to two competing models for the solution of the Nb-deficit that characterises the accessible Earth. Firstly, we test whether Nb could have sequestered into the core due to its slightly siderophile (or chalcophile) character under very reducing conditions, as recently proposed from experimental evidence. We demonstrate that troilite inclusions of the Canyon Diablo iron meteorite have Nb and V concentrations in excess of typical chondrites but that the metal phase of the Grant, Toluca and Canyon Diablo iron meteorites do not have significant concentrations of these lithophile elements. We find that if the entire accessible Earth Nb-deficit were explained by Nb in the core, only ca. 17% of the mantle could be depleted and that by 3.7 Ga, continental crust would have already achieved ca. 50% of its present mass. Nb/Ta systematics of late Archaean metabasalts compiled from the literature would further require that by 2.5 Ga, 90% of the present mass of continental crust was already in existence. As an alternative to this explanation, we propose that the average Nb/Ta ratio (15.1+/-11.6) of Earth's oldest mafic rocks is a valid approximation for bulk silicate Earth. This would require that ca. 13% of the terrestrial Nb resided in the Ta-free core. Since the partitioning of Nb between silicate and metal melts depends largely on oxygen fugacity and pressure, this finding could mean that metal/silicate segregation did not occur at the base of a deep magma ocean or that the early mantle was slightly less reducing than generally assumed. A bulk silicate Earth Nb/Ta ratio of 15.1 allows for depletion of up to 40% of the total mantle. This could indicate that in addition to the upper mantle, a portion of the lower mantle is depleted also, or if only the upper mantle were depleted, an additional hidden high Nb/Ta reservoir must exist. Comparison of Nb/Ta systematics between early and late Archaean metabasalts supports the latter idea and indicates deeply subducted high Nb/Ta eclogite slabs could reside in the mantle transition zone or the lower mantle. Accumulation of such slabs appears to have commenced between 2.5 and 2.0 Ga. Regardless of these complexities of terrestrial Nb/Ta systematics, it is shown that the depleted mantle Nb/Th ratio is a very robust proxy for the amount of extracted continental crust, because the temporal evolution of this ratio is dominated by Th-loss to the continents and not Nb-retention in the mantle. We present a new parameterisation of the continental crust volume versus age curve that specifically explores the possibility of lithophile element loss to the core and storage of eclogite slabs in the transition zone. (C) 2003 Elsevier Science B.V. All rights reserved.

Compilation of planktonic foraminiferal census counts from the Southern Hemisphere Oceans

We present an improved database of planktonic foraminiferal census counts from the Southern Hemisphere Oceans (SHO) from 15°S to 64°S. The SHO database combines 3 existing databases. Using this SHO database, we investigated dissolution biases that might affect faunal census counts. We suggest a depth/[DCO3]2- threshold of ~3800 m/[DCO3]2- = ~-10 to -5 µmol/kg for the Pacific and Indian Oceans, and ~4000 m/[DCO3]2- = ~0 to 10 µmol/kg for the Atlantic Ocean, under which core-top assemblages can be affected by dissolution and are less reliable for paleo-sea surface temperature (SST) reconstructions. We removed all core-tops beyond these thresholds from the SHO database. This database has 598 core-tops and is able to reconstruct past SST variations from 2° to 25.5°C, with a root mean square error of 1.00°C, for annual temperatures. To inspect dissolution affects SST reconstruction quality, we tested the data base with two "leave-one-out" tests, with and without the deep core-tops. We used this database to reconstruct Summer SST (SSST) over the last 20 ka, using the Modern Analog Technique method, on the Southeast Pacific core MD07-3100. This was compared to the SSST reconstructed using the 3 databases used to compile the SHO database. Thus showing that the reconstruction using the SHO database is more reliable, as its dissimilarity values are the lowest. The most important aspect here is the importance of a bias-free, geographic-rich, database. We leave this dataset open-ended to future additions; the new core-tops must be carefully selected, with their chronological frameworks, and evidence of dissolution assessed.

Description of manganese deposits collected by R/V Nothwind during the 1963 expedition in the Laptev sea

The 400-km-wide, low gradient Laptev Sea continental shelf consists of flat terrace-like features at regular depth intervals from 10 to 40 m below present sea level. The five large submarine valleys traversing the shelf do not continuously grade seaward, but contain elongated, closed basins. These terraces and closed basins plus deltaic sediments associated with the submarine valleys quite possibly mark sea level Stillstands, and enable reconstruction of the paleogeography of the Laptev Sea shore line at five periods during post-Wisconsin (Holocene) time. Radiocarbon dates on the silty-clay to clayey-silt sediments from cores of the northeastern Laptev Sea indicate average sedimentation intensity of 2 to 15 mg/cm2/yr. The presence of manganese nodules and crusts in surface samples from less than 55 m depths and a general decrease in total foraminiferal abundances with depth in the cores suggest that the present deposition rate is less than when sea level was lower. The main components of the shelf deposits are near- shore sediments which were spread over the shelf as Holocene sea level fluctuated and marine currents distributed modern fine sediment. Rare silty-sand layers and the coarser nuclei of the manganese crusts and nodules indicate ice rafting. However, this mechanism is probably only locally important as a significant transporting agent.

Data compilation on the biological response to ocean acidification: environmental and experimental context of data sets and related literature

The exponential growth of studies on the biological response to ocean acidification over the last few decades has generated a large amount of data. To facilitate data comparison, a data compilation hosted at the data publisher PANGAEA was initiated in 2008 and is updated on a regular basis (doi:10.1594/PANGAEA.149999). By January 2015, a total of 581 data sets (over 4 000 000 data points) from 539 papers had been archived. Here we present the developments of this data compilation five years since its first description by Nisumaa et al. (2010). Most of study sites from which data archived are still in the Northern Hemisphere and the number of archived data from studies from the Southern Hemisphere and polar oceans are still relatively low. Data from 60 studies that investigated the response of a mix of organisms or natural communities were all added after 2010, indicating a welcomed shift from the study of individual organisms to communities and ecosystems. The initial imbalance of considerably more data archived on calcification and primary production than on other processes has improved. There is also a clear tendency towards more data archived from multifactorial studies after 2010. For easier and more effective access to ocean acidification data, the ocean acidification community is strongly encouraged to contribute to the data archiving effort, and help develop standard vocabularies describing the variables and define best practices for archiving ocean acidification data.

Physical oceanography during POLARSTERN cruise ANT-V/3

The work carried out by the physical oceanography group on POLARSTERN Leg ANT-V/3 concentrated on four major topics: A. A large scale survey of the eastern boundary between the Weddell gyre and the open ocean. On the way to the coastal polynya in early October 12 CTD stations were carried out between 54°30'S, 6°E and 70°30'S 8°W. Another set of 16 stations was obtained in early December on the way back north. During this transsect three current meter moorings were recovered at Maud Rise. The path between the current meter arrays was used to run an additional section to the NNE across the top of Maud Rise. B. A large scale survey of the Antarctic Coastal Current along the eastern shelf area. To obtain the water mass characteristics along the eastern Weddell shelf 36 CTD stations were carried out between Atka Bay and the Filchner Trench. Most of the stations were located on the shelf. Cross shelf sections were obtained both near Drescher Inlet and off Halley Bay, in the divergence area of the Coastal Current where the continental slope turns to the west and south of Vestkapp at Neptune's Point. A longshore section over 120 km was run north of Vestkapp. C. A mesoscale survey of the Antarctic Coastal Current off Drescher Inlet. The experimental work consisted of 37 CTD-stations and direct current measurements. The CTD-profiles were grouped into seven sections perpendicular to the coast line off Drescher Inlet extending once over 70 km but normally over 35 km. The profile depth ranged from 300 m on one section to the complete water column at two sections. Most sections consist of five stations providing highest resolution over the upper continental slope with offshore increasing spacing. The stations were chosen to represent the shelf (450 m), the shelf break (800 m), the upper slope (1600 m), the lower slope (2400 m) and the transition to the abyssal plain (3400 m). Rough topography and difficult ice conditions made it impossible to meet those requirements in all cases. D. A small scale survey of the hydrographic conditions under the sea ice. The motivation for these studies arose during the cruise. Consequently a suitable Instrumentation had to be developed at sea. This was done with a NB-Smart CTD which was inserted on an L-shaped lever through a hole in the ice. However, various water intrusions into the instrument resulted in the failure of this technique. In consequence a special lever system was built to position a NB Mark 3b weighing about 40 kg below the ice. Twenty four profiles were obtained reaching from the bottom of the ice down to 2 m below the ice surface with a maximum distance of 1 m from the entry hole. As the conductivity sensor was influenced by nearby ice platelets, salinity samples where drawn to check the sensor.

Accumulation rates of bulk sediment and opal in surface sediments of the South Atlantic

A set of 114 samples from the sediment surface of the Atlantic, eastern Pacific and western Indian sectors of the Southern Ocean has been analyzed for 230Th and biogenic silica. Maps of opal content, Th-normalized mass flux, and Th-normalized biogenic opal flux into the sediment have been derived. Significant differences in sedimentation patterns between the regions can be detected. The mean bulk vertical fluxes integrated into the sediment in the open Southern Ocean are found in a narrow range from 2.9 g/m**2 yr (Eastern Weddell Gyre) to 15.8 g/m**2 yr (Indian sector), setting upper and lower limits to the vertically received fraction of open ocean sediments. The silica flux to sediments of the Atlantic sector of the Southern Ocean is found to be 4.2 ± 1.4 * 10**11 mol/yr, just one half of the last estimate. This adjustment represents 6% of the output term in the global marine silica budget.

Documentation and sedimentology of core PS1021-1 from the Antarctic continental margin off Kap Norvegia

Sedimentological analyses concerning ice rafted debris, grain size distribution, biogenous components, and clay mineral composition of four sediment cores from the Antarctic continental margin off Kapp Norvegia reveal a cyclical pattern of three different sediment facies. These are classified into warm and cold types representing warm and cold climatic periods and a short transition period from cold to warm events. The sedimentological parameters reflect the variations within the cryosphere and the hydrosphere, which are directly influenced by the climatic fluctuations. The unusually high content of carbonaceous planktonic and benthonic foraminifera in these polar sediments, as well as the interfingering of terrigeneous and biogeneous-rich sediments with increasing distance from the continent, might reflect the influence of the Weddell Sea Polynya and the oscillations of polynya, pack-ice and ice shelf extent during the late Pleistocene.

(Table 3) Age determination of sediment cores from the SW Pacific Ocean

Eight- to ten-point depth profiles (from 1200 to 4800 m water depth) of oxygen and carbon isotopic values derived from benthic foraminifera, averaged over selected times in the past 160 ka, are presented. The data are from 10 sediment cores off eastern New Zealand, mainly North Chatham Rise. This lies under the Deep Western Boundary Current in the Southwest Pacific and is the main point of entry for several water masses into the Pacific Ocean. The benthic isotopic profiles are related to the structure of water masses at present and inferred for the past. These have retained a constant structure of Lower Circumpolar Deep Water-Upper Circumpolar Deep Water/North Pacific Deep Water-Antarctic Intermediate Water with no apparent changes in the depths of water mass boundaries between glacial and interglacial states. Sortable silt particle size data for four cores are also examined to show that the vigour of the inflow to the Pacific, while variable, appears to have remained fairly constant on average. Among the lowest Last Glacial Maximum values of benthic d13C in the world ocean (-1.03 per mil based on Cibicidoides wüllerstorfi) occurs here at ~2200 m. Comparable values occur in the Atlantic sector of the Southern Ocean, while those from the rest of the Pacific are distinctly higher, confirming that the Southern Ocean was the source for the unventilated/nutrient-enriched water seen here. Oxygen and carbon isotopic data are compatible with a glacial cold deep water mass of high salinity, but lower nutrient content (or better ventilated), below ~3500 m depth. This contrasts with the South Atlantic where unventilated/nutrient-enriched water extends all the way to the sea bed. Comparison with previous studies also suggests that the deeper reaches of the Antarctic Circumpolar Current below ~3500 m are not homogeneous all around the Southern Ocean, with the Kerguelen Plateau and/or the Macquarie-Balleny Ridges posing barriers to the eastward spread of the deepest low-d13C water out of the South Atlantic in glacials. These barriers, combined with inferred high density of bottom waters, restricted inter-basin exchange and allow three glacial domains dominated by bottom waters from Weddell Sea, Adelie Coast and Ross Sea to be defined. We suggest that the Ross Sea was the main source of the deep water entering the Pacific below ~3500 m.

Epibenthic foraminiferal d13C in the Recent deep Arctic Ocean

Low planktic and benthic d18O and d13C values in sediments from the Nordic seas of cold stadials of the last glaciation have been attributed to brines, formed similar to modern ones in the Arctic Ocean. To expand on the carbon isotopes of this hypothesis I investigated benthic d13C from the modern Arctic Ocean. I show that mean d13C values of live epibenthic foraminifera from the deep Arctic basins are higher than mean d13C values of upper slope epibenthic foraminifera. This agrees with mean high d13C values of dissolved inorganic carbon (DIC) in Arctic Bottom Water (ABW), which are higher than mean d13CDIC values from shallower water masses of mainly Atlantic origin. However, adjustments for oceanic 13C-Suess depletion raise subsurface and intermediate water d13CDIC values over ABW d13CDIC ones. Accordingly, during preindustrial Holocene times, the d13CDIC of ABW was as high or higher than today, but lower than the d13CDIC of younger subsurface and intermediate water. If brine-enriched water significantly ventilated ABW, brines should have had high d13CDIC values. Analogously, high-d13CDIC brines may have been formed in the Nordic seas during warm interstadials. During cold stadials, when most of the Arctic Ocean was perennially sea-ice covered, a cessation of high-d13CDIC brine rejection may have lowered d13CDIC values of ABW, and ultimately the d13CDIC in Nordic seas intermediate and deep water. So, in contrast to the idea of enhanced brine formation during cold stadials, the results of this investigation imply that a cessation of brine rejection would be more likely.

LGM, planktic foraminifera (EPILOG version)

[1] We used planktic foraminiferal assemblages in 70 sediment cores from the tropical and subtropical South Atlantic Ocean (10°N-37°S) to estimate annual mean sea surface temperatures (SSTs) and seasonality for the Last Glacial Maximum with a modified version of the Imbrie-Kipp transfer function method (IKTF) that takes into account the abundance of rare but temperature sensitive species. In contrast to CLIMAP Project Members [1981], the reconstructed SSTs indicate cooler glacial SSTs in the entire tropical/subtropical South Atlantic with strongest cooling in the upwelling region off Namibia (7-10°C) and smallest cooling (1-2°C) in the western subtropical gyre. In the western Atlantic, our data support recent temperature estimates from other proxies. In the upwelling regions in the eastern Atlantic, our data conflict with SST reconstructions from alkenones, which may be due to an environmental preference of the alkenone-producing algae or to an underestimation of foraminiferal SSTs due to anomalous high abundances of N. pachyderma (sinistral).

Organic carbon accumulation in the South Atlantic Ocean

A compilation of 1118 surface sediment samples from the South Atlantic was used to map modern seafloor distribution of organic carbon content in this ocean basin. Using new data on Holocene sedimentation rates, we estimated the annual organic carbon accumulation in the pelagic realm (>3000 m water depth) to be approximately 1.8*10**12 g C/year. In the sediments underlying the divergence zone in the Eastern Equatorial Atlantic (EEA), only small amounts of organic carbon accumulate in spite of the high surface water productivity observed in that area. This implies that in the Eastern Equatorial Atlantic, organic carbon accumulation is strongly reduced by efficient degradation of organic matter prior to its burial. During the Last Glacial Maximum (LGM), accumulation of organic carbon was higher than during the mid-Holocene along the continental margins of Africa and South America (Brazil) as well as in the equatorial region. In the Eastern Equatorial Atlantic in particular, large relative differences between LGM and mid-Holocene accumulation rates are found. This is probably to a great extent due to better preservation of organic matter related to changes in bottom water circulation and not just a result of strongly enhanced export productivity during the glacial period. On average, a two- to three-fold increase in organic carbon accumulation during the LGM compared to mid-Holocene conditions can be deduced from our cores. However, for the deep-sea sediments this cannot be solely attributed to a glacial productivity increase, as changes in South Atlantic deep-water circulation seem to result in better organic carbon preservation during the LGM.

Age determination and clay layer frequencies of sediments of the Black and Red Sea

Paleoenvironmental proxy data for ocean properties, eolian sediment input, and continental rainfall based on high-resolution analyses of sediment cores from the southwestern Black Sea and the northernmost Gulf of Aqaba were used to infer hydroclimatic changes in northern Anatolia and the northern Red Sea region during the last ~7500 years. Pronounced and coherent multicentennial variations in these records reveal patterns that strongly resemble modern temperature and rainfall anomalies related to the Arctic Oscillation/North Atlantic Oscillation (AO/NAO). These patterns suggest a prominent role of AO/NAO-like atmospheric variability during the Holocene beyond interannual to interdecadal timescales, most likely originating from solar output changes.