942 resultados para erbium doping


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A novel double-slab Nd:YAG laser, which uses face-pumped slab medium cooled by liquid with different temperatures on both sides, is proposed. The thermal distortion of wavefront caused by the non-uniform temperature distribution in the laser gain media can be self-compensated. According to the method of operation, the models of the temperature distribution and stress are presented, and the analytic solutions for the model are derived. Furthermore, the numerical simulations with pulse pumping energy of 10 J and repetition frequencies of 500 and 1000 Hz are calculated respectively for Nd:YAG laser medium. The simulation results show that the temperature gradient remains the approximative linearity, and the heat stress is within the extreme range. Then the absorption coefficient is also discussed. The result indicates that the doping concentration cannot be too large for the high repetition frequency laser. It has been proved that the high repetition frequency, high laser beam quality, and high average output power of the order of kilowatt of Nd: YAG slab laser can be achieved in this structure.

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A high-power Ytterbium-doped fiber laser (YDFL) with homemade double clad fiber (DCF) is introduced in this paper. The output power characteristics of a linear cavity fiber laser have been studied theoretically by solving the rate equations and experimentally tested with single- and double-end-pumping configurations. When both ends of the fiber are pumped by two high-power laser diodes with a launched power of similar to 300 W each, a maximum CW output of 444 W is obtained with a slope efficiency of similar to 75%. (c) 2006 Elsevier Ltd. All rights reserved.

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研究了摩尔组分为70TeO2-(20-x)ZnO-xPbO-5La2O3-2.5K2O-2.5Na2O(x=0,5,10,15,20)的新型多元铅锌镧碲酸盐激光玻璃,外掺Yb2O3为玻璃摩尔组分的1%,测试了试样的物理性质及吸收光谱、荧光光谱和荧光寿命,计算了Yb^3+的吸收截面、受激发射截面、荧光有效线宽等光谱参数,结果表明:该系列玻璃都具有良好的热学稳定性((Tx-Tg)>195℃,高于TZN玻璃(118℃));当X=15时,样品具有较好的光谱性质:高的受激发射截面(1.25pm^2)、长的荧光寿命(

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测试了掺铒碲酸盐玻璃在不同掺杂浓度下的荧光特性.根据Dexter能量转移理论计算了Er^3+在碲酸盐玻璃中发生浓度猝灭的临界距离R0及Er^3+间相互作用参数CEr-Er,并与其他基质玻璃中CEr-Er数值进行了比较.最后建立了Er^3+基于OH^-作为猝灭中心下碲酸盐玻璃中的浓度猝灭模型.

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Ce3+ ions were introduced into the Er3+/Yb3+ -codoped TeO2-WO3-ZnO glasses, and the effect of Ce3+ on the emission properties at 1.5 mu m band and the upconversion luminescence of Er3+ in the glasses was investigated. With the increasing of Ce3+ concentration, the emission intensity of Er3+ at 1.5 mu m band increases firstly, and then decreases. The optimal doping concentration of Ce3+ is about 2.07 x 10(20)/cm(3). As for the Er3+ emission at 1.5-mu m band, the fluorescence lifetime decreases a little from 3.4ms to 3.0ms, while the full width at half maximum (FWHM) hardly changes with the increase of Cc 3+ concentration. Due to the effective cross relaxation between Ce3+ and Er3+ : Er3+ (I-4(11/2)) + Ce3+ (F-2(5/2)) -> Er3+ (I-4(13/2)) + Ce3+ (F-2(7/2)), the upconversion emission intensity of Er3+ is reduced greatly. But when Ce3+ -doping concentration is too high, the other cross relaxation between Ce3+ and Er3+ : Er3+ (4I(13/2)) + Ce3+ (F-2(5/2)) -> Er3+ (I-4(15/2)) + Ce3+ (F-2(7/2)) happens, which depopulates the I-4(13/2) level of Er3+ and results in the decrease of the emission intensity and fluorescence lifetime of Er3+ at 1.5 mu m band.

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制备了四种不同铒离子掺杂浓度的碲酸盐玻璃,通过测定吸收光谱计算了吸收谱线的振子强度,根据Judd-Ofelt理论计算了不同浓度下Er^3+离子发光光谱的强度参数Ω(i=2,4,6),计算了自发辐射电偶和磁偶跃迁概率、辐射寿命、荧光分支比等参数,讨论了Er^3+离子浓度变化对以上这些参数的影响。测试了Er^3+:^4I13/2→^4I15/2跃迁对应的荧光光谱和Er^3+:^4I13/2能级荧光寿命。最后应用McCumber理论计算了玻璃中Er^3+:^4I13/2→^4I15/2跃迁对应的受激发射截面大小

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探求新的具有优良的热学和光学性能的基质玻璃系统,是获得具有宽带宽和增益平坦的掺Er^3+光纤放大器(EDFA)的一种有效途径。制备了一种新型氧氟碲酸盐玻璃TeO2-BaF2-LaF3,并对其热学性能和光学性质进行了测试。应用乍得-奥菲尔特(Judd-Ofelt)理论计算了Er^3+离子的J-O理论参量和荧光寿命r。探讨了氟化物的引入对碲酸盐玻璃结构的改变的影响,并分析了其对玻璃的热学性质和光学性质的影响。实验发现,获得的氧氟碲酸盐玻璃具有优良的热学稳定性(△T=156.6C),宽的荧光半峰全宽(72nm)

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玻璃中稀土掺杂的离子的光谱性质受其周围的玻璃结构和在玻璃基质中的分布影响很大。利用熔融法制备了组分为9SiO2·26Al2O3·65CaO·1.0Er2O3·0.3Yb2O3和分别加入MgO以及La2O3的掺铒钙铝硅玻璃,并研究了其吸收边和光学带隙。计算得出离子填充比随玻璃的平均摩尔质量的增大而减小,同时利用Judd—Ofelt模型计算出该玻璃体系的Ω2,Ω4和Ω6参数,并进行了分析。随着MgO或La2O3的加入,吸收边向短波长移动,光学带隙增大,同时Ω2和Ω6值也增大。对ln(α)和hω的曲线进行线性拟

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制备了用于离子交换法制备光波导器件的掺铒碲-钨-钠玻璃基质。应用扎得-奥菲而特(Judd—Ofelt)理论计算了玻璃样品的三个强度参量,由强度参量计算了Er^3+离子的自发跃迁几率、荧光分支比等光谱参量;应用麦克库玻(McCumber)理论,计算了Er^3+离子在1.5μm的受激发射截面,荧光测试发现Er^3+离子的荧光半峰全宽可达65nm。比较了Er^3+离子在不同玻璃基质中的光谱特性。结果表明,Er^3+离子在碲-钨-钠玻璃中具有较高的受激发射截面和较宽的荧光半峰全宽,可以用于宽带光波导器件的制备。

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Nanocrystalline La0.8Pb0.2FeO3 has been prepared by the sol-gel method. XRD patterns show that the nanocrystalline La0.8Pb0.2FeO3 is a perovskite phase with the orthorhombic structure and its mean crystallite size is about 19 nm. The influence of Pb ions which replaced the La ions on A-sites can be directly observed from the electrical and sensing properties to H-2 gas. The conductance of La0.8Pb0.2FeO3-based sensor is considerably higher than that of LaFeO3-based sensor, and Pb-doping can enhance the sensitivity to H2 gas. An empirical relationship of R = KCH2alpha with alpha = 0.668 was obtained.

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测量了不同掺杂浓度下Er^3+离子在碲酸盐玻璃中的吸收光谱、发射光谱和Er^3+离子的荧光寿命,计算了Er^3+离子的发射截面σc,分析了Er^3+离子掺杂浓度对其发光强度和荧光寿命的影响.结果表明,Er^3+离子掺杂浓度较低时,对其荧光强度和荧光寿命没有显著的影响;掺杂浓度高时,出现了浓度猝灭效应,使Er^3+离子荧光光强度降低,荧光寿命下降.实验确定了掺杂浓度最优值,同时对浓度猝灭机制进行了分析.

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研究了Cr^3+,Yb^3+,Er^3+共掺磷酸盐铒玻璃转镜调Q激光性质.三种Er2O3掺杂浓度的激光实验结果表明,在Er2O3名义掺杂浓度为0.5wt%时,玻璃的综合激光性质最好,重复频率为0.1Hz时,它的激光阈值功率为14.5mJ,最大输出能量为9.6mJ,斜率效率为0.55%.在同种实验条件下,比较了Cr14和Kigre公司生产的QE-7S激光性质参数,实验表明,前者激光阈值功率稍低,而后者的斜率效率和最大输出功率略高.

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分析了掺Er^3+碲酸盐玻璃的热力学稳定性能,研究了掺Er^3+碲酸盐玻璃的吸收和荧光光谱性质;应用Judd-Ofelt理论计算了碲酸盐玻璃中Er^3+离子的强度参数Ω(Ω2=4.79×10^-20cm^2,Ω4=1.52×10^-20cm^2,Ω6=0.66×10^-20cm^2),计算了离子的自发跃迁几率,荧光分支比;应用McCumber理论计算了Er^3+的受激发射截面(σe=10.40×10^-21cm^2)、Er^3+离子^4I13/2→^4I15/2发射谱的荧光半高宽(FWHM=65.5nm)

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研究了一种新型掺Er^3+碲酸盐玻璃的光谱性质;应用Judd-Ofelt理论计算了碲酸盐玻璃中Er^3+离子的强度参数Ω(Ω2=4.79×10^-20cm^2,Ω4=1.52×10^-20cm^2,Ω6=0.66×10^-20cm^2),计算了离子的自发跃迁概率,荧光分支比;应用McCumber理论计算了Er^3+的受激发射截面(σe=10.40×10^-21cm^2),Er^3+离子^4I13/2→^4I15/2发射谱的荧光半高宽(FWHM=65.5nm)及各能级的荧光寿命(^4I13/2能级为τrad

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包边技术是提高大尺寸激光玻璃饱和增益系数的关键。为获得优质包边玻璃,以CuO和CuCl分别作为Cu2+的引入物质,采用传统的玻璃熔制方法,研究了Cu2+掺杂量和不同引入物质对P2O5-ZnO-Na2O体系玻璃形成区、析晶稳定性、物化性能以及吸收系数的影响。研究结果表明,CuO和CuCl都能增大P2O5-ZnO-Na2O体系的玻璃形成区、提高玻璃样品的析晶稳定性。玻璃样品的吸收系数随Cu2+掺杂浓度的增加而明显增大,当Cu2+掺杂摩尔分数达到6%时,样品在1053 nm处的吸收系数为59.46 cm-1,基