Development of the gas chromatograph – mass spectrometer to investigate volatile species in the lunar soil for the Luna-Resurs mission

Since the analysis of the lunar rocks and soil samples, brought to Earth by the Apollo missions, it is believed that the Moon has a waterless nature and also other volatile species are strongly depleted. Advancement in analysis techniques helped to identify water and other volatile species in lunar volcanic glasses. Additionally, recent lunar space missions detected water and volatile organic compounds in the region of the lunar poles where permanently shadowed craters are existing. All known lunar soil samples available on Earth come from the lunar near side, close to the equator. To verify the most recent measurement results and to enhance the knowledge of the geological history of the Moon it is of high interest to perform in situ measurements on the lunar poles. For this reason the Russian space agency, Roskosmos, developed aprogram for the scientific exploration of the lunar poles. The Gas Analysis Package (GAP) is part of the selected scientific payload aboard the Luna-Resurs Lander. This instrument uses pyrolytic cells and will apply laser spectroscopy, gas chromatography and mass spectrometry to detect and analyze volatile components trapped in the lunar soil. An existing ion optical design of a compact reflectron type time-of-flight mass spectrometer, originally built for the MEAP/P-BACE balloon mission, was chosen as a part of the GAP instrument. The scope of this thesis is the development of the interface between gas chromatography (GC) and this Neutral Gas Mass Spectrometer (NGMS) to perform coupled GC-MS measurements. In the first part of this thesis the interfacing concept was developed and verified by coupling the NGMS prototype to gas chromatography. The second part of this thesis is devoted to the development of the NGMS flight version.

Aspectos fisiologicos do umbuzeiro.

Realizou-se um estudo objetivando avaliar a resistencia estomatica, transpiracao e temperatura da folha do umbuzeiro (Spondias tuberosa Arr. Cam.), no seu habitat natural, no final da estacao seca e apos as primeiras chuvas. A resistencia estomatica comecou a aumentar em torno das 7 horas nos dois periodos, porem de forma mais brusca durante a seca, resultando em baixa transpiracao. Apos as primeiras chuvas, a resistencia estomatica comecou a aumentar em torno de 13 horas, quando as condicoes ambientais ainda eram favoraveis a uma grande demanda evapotranspiratoria. Estes resultados sugeram uma acentuada economia de agua pelo umbuzeiro. Nao se observaram diferencas na temperatura das folhas relativas aos dois periodos.

Desarrollo de un modelo de negocio para la empresa Agroindustrias Villalonso S.A.S. y su proyecto de reforestación comercial de caucho natural

El caucho natural y su proceso de transformación industrial es una cadena que presenta grandes potencialidades agroecológicas en el país, genera empleo rural productivo, construye capital y contribuye con el medio ambiente, razones que motivaron al autor a investigar los aspectos técnicos que el inversionista debe tener presente al momento de emprender un proyecto de reforestación comercial de caucho -- El caso de estudio se desarrolló para la microempresa Agroindustrias Villalonso, ubicada en la región heveícola del Magdalena Medio Santandereano, con el objetivo principal de analizar y abordar cada una de las etapas que constituyen un modelo de negocio, y proponerle a la microempresa, y demás interesados, cuáles son las mejores alternativas que deben desarrollarse para que un proyecto de este tipo tenga un resultado financiero positivo y por consiguiente un retorno favorable de la inversión -- La descripción y análisis de alternativas de todas las etapas que constituyen un modelo de negocio fueron desarrolladas con base en la metodología de Osterwalder & Pigneur, en el lienzo del modelo de negocio; esta metodología fue escogida como la más completa para este proyecto -- Del desarrollo de la investigación se evidenció que aunque el proyecto presenta características técnicas favorables, las condiciones macroeconómicas actuales, el entorno del mercado nacional y extranjero y los sistemas de explotación convencionales que elevan especialmente los costos en mano de obra, podrían poner en riesgo la viabilidad del mismo, a menos que la propuesta de valor se desarrolle a partir de los criterios y alternativas planteados en este trabajo

A relevância geoestratégica da Turquia para a segurança energética da União Europeia : o caso do gás natural

Nos próximos anos a União Europeia terá crescentes necessidades de importação de gás natural, existindo uma preocupação com os riscos inerentes à dependência face ao gás russo, especialmente nos países do centro e leste europeu. Esses riscos foram evidenciados pelas crises e conflitos que opuseram a Rússia à Ucrânia e à Geórgia e mostraram à União Europeia a necessidade de encontrar alternativas que diminuíssem a sua vulnerabilidade. As alternativas possíveis passam por incrementar a produção de shale gas, aumentar a importação do Gás Natural Liquefeito e diversificar os fornecedores. A União Europeia tem apostado num corredor meridional de gás, cujo objetivo é obter fornecimento do Médio Oriente, do Cáucaso do Sul e da Ásia Central. Esta opção europeia faz ressurgir a importância geoestratégica da Turquia. No artigo propomo-nos discutir a estratégia europeia para diminuir a sua vulnerabilidade energética no abastecimento de gás natural e as vantagens que poderão resultar do reforço da relação com a Turquia nesta área.

Avaliação Pós-Ocupação da iluminação natural das salas dos setores de aulas teóricas da Universidade Federal do Rio Grande do Norte

The objective of this study is to assess the natural light of the classrooms sectors, at Universidade Federal do Rio Grande do Norte. It was applied the Post-Occupation Evaluation technique, by using questionnaires and brightness levels measurements inside the classrooms. In order to check the users satisfaction degree, it was initially done a general approach on the related aspects to natural light: their characteristics, availability, sources, opening systems and evaluating tools. It was also determined the necessary brightness levels for the activities development in the classroom and the Post-Occupation Evaluation technique used in the search analyses. Then, it was made the UFRN Campus` characterization; the models` definition which formed the data collection basis; the detailing of the procedures used in the research, the processing description and the data analysis. Subsequently, the results that clarify the issues raised were shown through quantitative and / or qualitative data analyses. This research notes a high level of satisfaction by the users, despite some problems such as the reflections occurrence on the board, the lack of uniformity and, occasionally, the brightness low levels

Contribuição para a valorização, geoconservação e gestão da jazida fossilífera de Cacela (Parque Natural da Ria Formosa, Algarve, Portugal)

Dissertação de mest. em Gestão e Conservação da Natureza, Faculdade de Ciências do Mar e do Ambiente, Univ. do Algarve, 2004

Estudo da molhabilidade de tecidos 100% poliéster tratados em plasma N2/O2 em função do seu envelhecimento natural

This work reports the influence of the poly (ethylene terephthalate) textile surface modification by plasmas of O2 and mixtures (N2 + O2), on their physical and chemical properties. The treatment was carried out in a vacuum chamber. Some parameters remained constant during all treatment, such as: Voltage 470 V; Pressure 1,250 Mbar; Current: 0, 10 A and gas flow: 10 cm3/min. Other parameters, such as working gas composition and treatment time, were modified as the following: to the O2 plasma modified samples only the treatment time was changed (10, 20, 30, 40, 50 and 60 minutes). To the plasma with O2 and N2 only the chemical concentrations were changed. Through Capillary tests (vertical) an increase in textile wettability was observed as well as its influence on aging time and its consequence on wettability. The surface functional groups created after plasma treatments were investigated using X-ray Photoelectron Spectroscopy (XPS). The surface topography was examined by scanning electron microscope (SEM)

Estudo e implementação de algoritmos inteligentes para detecção e classificação de falhas na medição de gás natural

This master dissertation presents the study and implementation of inteligent algorithms to monitor the measurement of sensors involved in natural gas custody transfer processes. To create these algoritmhs Artificial Neural Networks are investigated because they have some particular properties, such as: learning, adaptation, prediction. A neural predictor is developed to reproduce the sensor output dynamic behavior, in such a way that its output is compared to the real sensor output. A recurrent neural network is used for this purpose, because of its ability to deal with dynamic information. The real sensor output and the estimated predictor output work as the basis for the creation of possible sensor fault detection and diagnosis strategies. Two competitive neural network architectures are investigated and their capabilities are used to classify different kinds of faults. The prediction algorithm and the fault detection classification strategies, as well as the obtained results, are presented

Dissipation of triadimefon on the solid/gas interface

The dissipation or triadimefon, as pure solid and in the Bayleton 5 commercial formulation, was studied under controlled and natural conditions. Volatilization and photodegradation were shown to be the main dissipation processes. The volatilization results can be described by an empirical model assuming exponential decay of the volatilization rate. The filler of the commercial formulation is determinant for the volatilization but has little effect on the photodegradation rates. The main photoproducts were identified and a reaction mechanism proposed. (C) 2001 Elsevier Science Ltd. All rights reserved.

Evaluación financiera del uso de gas licuado de petróleo (GLP) en empresas dedicadas al transporte de carga terrestre.

Las empresas de transporte de carga terrestre del país son parte de uno de los sectores productivos más importantes, que contribuyen en la economía y en el producto interno bruto (PIB), a través de las operaciones requeridas para su actividad. Así mismo, influye en los costos de los bienes que se movilizan desde su lugar de embarque hacia su destino, mediante el cobro de la tarifa del servicio de transporte y/o logística. El origen de esta investigación radica en la incidencia del alza de los precios de los combustibles en los costos operativos de las empresas dedicadas al transporte de carga terrestre nacional, y la decisión de estas; entre incrementar el importe de la prestación, afectando el nivel de competitividad que se tiene en el mercado o absorber las variaciones provocando la disminución del margen de ganancias. El objetivo de este trabajo es brindar información referente al uso del recurso energético alternativo llamado gas licuado de petróleo (GLP) para automotores, que disminuya significativamente los costos de operación del sector de transporte de carga terrestre en el país y contribuya de esta manera en la competitividad brindando precios rentables sin sacrificar sus utilidades. Además, dar a conocer la legislación, los aspectos técnicos de instalación, mantenimiento, el análisis del ahorro generado y el valor de la inversión. Con el propósito que los empresarios de dicho sector puedan tomar la decisión, de invertir en el proyecto del uso del recurso energético alternativo GLP. El desarrollo de la investigación se enfocó en las empresas dedicadas al transporte de carga terrestre ubicadas en el departamento de San Salvador, municipio de San Salvador. Formando un universo de 66 empresas y de las que se tomó una muestra de 32. La encuesta fue la herramienta de investigación utilizada para entrevistar a los empresarios y/o responsables del área contable financiera, por medio de preguntas relevantes para la comprobación de la problemática y la ampliación del estudio, las cuales se encuentran tabuladas y con su correspondiente análisis. Los resultados obtenidos permitieron elaborar un diagnóstico, el cual determina que las empresas han visto afectados sus costos de operación de una forma representativa, principalmente por el incremento de los precios de los combustibles, este dato lo reportan por medio del análisis financiero que de forma periódica llevan a cabo. También los empresarios poseen información significativa de algunas opciones para el ahorro en los carburantes, y además se evidencia la necesidad de un documento completo que les brinde el conocimiento de una alternativa para enfrentar la problemática mencionada. En conclusión, al ejecutar el estudio y al realizar el análisis financiero de los ahorros generados a partir de la instalación del sistema de conversión combustión Diesel – Gas Licuado de Petróleo (GLP) en los equipos de transporte de carga terrestre, se observa una disminución sustancial de los costos operativos de la empresa permitiendo mayores ganancias y una mejor competitividad del negocio. Por lo tanto, se recomienda sean tomados en cuenta los resultados de esta investigación por parte de los empresarios de dicho sector para que les sirva de apoyo en la evaluación y toma de mejores decisiones.

Análise da recuperação em reservatório de gás com baixa permeabilidade (TIGHT GAS) através do fraturamento hidráulico

With the increasing of energetic consumption in the worldwile, conventional reservoirs, known by their easy exploration and exploitation, are not being enough to satisfy this demand, what has made necessary exploring unconventional reservoirs. This kind of exploration demands developing more advanced technologies to make possible to exploit those hydrocarbons. Tight gas is an example of this kind of unconventional reservoir. It refers to sandstone fields with low porosity, around 8%, and permeabilities between 0.1 and 0.0001 mD, which accumulates considerable amounts of natural gas. That natural gas can only be extracted by applying hydraulic fracturing, aiming at stimulating the reservoir, by creating a preferential way through the reservoir to the well, changing and making easier the flow of fluids, thus increasing the productivity of those reservoirs. Therefore, the objective of this thesis is analyzing the recovery factor of a reservoir by applying hydraulic fracturing. All the studies were performed through simulations using the IMEX software, by CMG (Computer Modelling Group), in it 2012.10 version

Sistemas de medição de desempenho para projetos de PD&I no Setor de Petróleo e Gás Natural

Organizations are seeking new ideas, tools and methods aiming to improve management process and performance. On the other hand, system performance measurement needs to portray organizational changes and provide managers with a set of true and more appropriate information for the decision-making process. This work aims to propose a performance measurement system in the academic field regarding Research, Development and Innovation (RDI) in the oil and gas industry. The research performed a bibliographic review in a descriptive exploratory manner. A field research was conducted with an expert focus group in order to gather new indicators. As for the validation of these indicators, a survey with experienced professional was also realized. The research surveyed four segments in and outside of the Federal University of Rio Grande do Norte-Brazil such as oil and gas project coordinators, staff at Academic Planning Offices, FUNPEC employees as well as coordinators from Petrobrás. The performance measuring system created from this study features three interrelated performance indicators pointed out as: process indicators, outcome indicators and global indicators. The proposal includes performance indicators that seek to establish more appropriate strategies for effective institution management. It might help policy making of university-industry interaction policies

An enforced cooperation : understanding scientific assessments in adversarial polities through Quebec shale gas policymaking, 2010-2014

Les biotechnologies, le réchauffement climatique, les ressources naturelles et la gestion des écosystèmes sont tous représentatifs de la “nouvelle politique de la nature” (Hajer 2003), un terme englobant les enjeux marqués par une grande incertitude scientifique et un encadrement réglementaire inadapté aux nouvelles réalités, suscitant de fait un conflit politique hors du commun. Dans l'espoir de diminuer ces tensions et de générer un savoir consensuel, de nombreux gouvernements se tournent vers des institutions scientifiques ad hoc pour documenter l'élaboration des politiques et répondre aux préoccupations des partie-prenantes. Mais ces évaluations scientifiques permettent-elles réellement de créer une compréhension commune partagée par ces acteurs politiques polarisés? Alors que l'on pourrait croire que celles-ci génèrent un climat d'apprentissage collectif rassembleur, un environnement politique conflictuel rend l'apprentissage entre opposant extrêmement improbable. Ainsi, cette recherche documente le potentiel conciliateur des évaluation scientifique en utilisant le cas des gaz de schiste québécois (2010-2014). Ce faisant, elle mobilise la littérature sur les dimensions politiques du savoir et de la science afin de conceptualiser le rôle des évaluations scientifiques au sein d'une théorie de la médiation scientifique (scientific brokerage). Une analyse de réseau (SNA) des 5751 références contenues dans les documents déposés par 268 organisations participant aux consultations publiques de 2010 et 2014 constitue le corps de la démonstration empirique. Précisément, il y est démontré comment un médiateur scientifique peut rediriger le flux d'information afin de contrer l'incompatibilité entre apprentissage collectif et conflit politique. L'argument mobilise les mécanismes cognitifs traditionnellement présents dans la théorie des médiateurs de politique (policy broker), mais introduit aussi les jeux de pouvoir fondamentaux à la circulation de la connaissance entre acteurs politiques.

Mercury in Gas Operations - Occupational Health Risk Assessment

The project goal was to determine plant operations and maintenance worker’s level of exposure to mercury during routine and non-routine (i.e. turnarounds and inspections) maintenance events in eight gas processing plants. The project team prepared sampling and analysis plans designed to each plant’s process design and scheduled maintenance events. Occupational exposure sampling and monitoring efforts were focused on the measurement of mercury vapor concentration in worker breathing zone air during specific maintenance events including: pipe scrapping, process filter replacement, and process vessel inspection. Similar exposure groups were identified and worker breathing zone and ambient air samples were collected and analyzed for total mercury. Occupational exposure measurement techniques included portable field monitoring instruments, standard passive and active monitoring methods and an emerging passive absorption technology. Process sampling campaigns were focused on inlet gas streams, mercury removal unit outlets, treated gas, acid gas and sales gas. The results were used to identify process areas with increased potential for mercury exposure during maintenance events. Sampling methods used for the determination of total mercury in gas phase streams were based on the USEPA Methods 30B and EPA 1631 and EPA 1669. The results of four six-week long sampling campaigns have been evaluated and some conclusions and recommendations have been made. The author’s role in this project included the direction of all field phases of the project and the development and implementation of the sampling strategy. Additionally, the author participated in the development and implementation of the Quality Assurance Project Plan, Data Quality Objectives, and Similar Exposure Groups identification. All field generated data was reviewed by the author along with laboratory reports in order to generate conclusions and recommendations.