Development of an Analytical Methodology for Quantification of Strong Acid in Diesel Oil

Many factors can affect the quality of diesel oil, in particular the degradation processes that are directly related to some organosulfur compounds. During the degradation process, these compounds are oxidized into their corresponding sulfonic acids, generating a strong acid content during the process. p-Toluene sulfonic acid analysis was performed using the linear sweep voltammetry technique with a platinum ultramicroelectrode in aqueous solution containing 3 mol L(-1) potassium chloride. An extraction step was introduced prior to the voltammetric detection in order to avoid the adsorption of organic molecules, which inhibit the electrochemical response. The extraction step promoted the transference of sulfonic acid from the diesel oil to an aqueous phase. The method was accurate and reproducible, with detection and quantification limits of 5 ppm and 15 ppm, respectively. Recovery of sulfonic acid was around 90%.

A combined X-ray and theoretical study of flavonoid compounds with anti-inflammatory activity

The structure of 7,4`-dimethoxy-3`-acetylflavone (tithonin-Ac) has been determined by X-ray diffraction and its geometry is compared with optimized geometrical parameters obtained by means of density functional theory at the B3LYP/6-311++G(d,p) level of calculation. in addition, vertical ionization potential (IPv) and acidity for tithonin-Ac and two derivatives have been also calculated. Calculations of spin densities were also performed for the radical formed by the electron abstraction of other flavones. The unpaired electron is located on C3 carbon atom (21-25%). (C) 2008 Elsevier B.V. All rights reserved.

Light-Induced Oxidation of Unsaturated Lipids as Sensitized by Flavins

Triplet-excited riboflavin ((3)RF*) was found by laser flash photolysis to be quenched by polyunsaturated fatty acid methyl esters in tert-butanol/water (7:3, v/v) in a second-order reaction with k similar to 3.0 x 10(5) L mol(-1) s(-1) at 25 degrees C for methyl linoleate and 3.1 x 10(6) L mol(-1) s(-1), with Delta H double dagger = 22.6 kJ mol(-1) and Delta S double dagger = -62.3 J K(-1) mol(-1), for methyl linolenate in acetonitrile/water (8:2, v/v). For methyl oleate, k was <10(4) L mol(-1) s(-1). For comparison, beta-casein was found to have a rate constant k similar to 4.9 x 10(8) L mol(-1) s(-1). Singlet-excited flavin was not quenched by the esters as evidenced by insensitivity of steady-state fluorescence to their presence. Density functional theory (DFT) calculations showed that electron transfer from unsaturated fatty acid esters to triplet-excited flavins is endergonic, while a formal hydrogen atom transfer is exergonic (Delta G(HAT)degrees = -114.3, -151.2, and -151.2 kJ mol(-1) for oleate, linoleate, and linolenate, respectively, in acetonitrile). The reaction is driven by acidity of the lipid cation radical for which a pK(a) similar to -0.12 was estimated by DFT calculations. Absence of electrochemical activity in acetonitrile during cyclic voltammetry up to 2.0 V versus NHE confirmed that Delta G(ET)degrees > 0 for electron transfer. Interaction of methyl esters with (3)RF* is considered as initiation of the radical chain, which is subsequently propagated by combination reactions with residual oxygen. In this respect, carbon-centered and alkoxyl radicals were detected using the spin trapping technique in combination with electron paramagnetic resonance spectroscopy. Moreover, quenching of 3RF* yields, directly or indirectly, radical species which are capable of initiating oxidation in unsaturated fatty acid methyl esters. Still, deactivation of triplet-excited flavins by lipid derivatives was slower than by proteins (factor up to 10(4)), which react preferentially by electron transfer. Depending on the reaction environment in biological systems (including food), protein radicals are expected to interfere in the mechanism of light-induced lipid oxidation.

Opting out of oppositionality : toward an informed and engaged "third wave" feminism

I begin by citing a definition of "third wave" from the glossary in Turbo Chicks: Talking Young Feminisms at length because it communicates several key issues that I develop in this project. The definition introduces a tension within "third wave" feminism of building and differentiating itself from second wave feminism, the newness of the term "third wave," its association with "young" women, complexity of contemporary feminisms, and attention to multiple identities and oppressions. Uncovering explanations of "third wave" feminism that go beyond, like this one, generational associations, is not an easy task. Authors consistently group new feminist voices together by age under the label "third wave" feminists without questioning the accuracy of the designation. Most explorations of "third wave" feminism overlook the complexities and distinctions that abound among "young" feminists ; not all young feminists espouse similar ideas, tactics, and actions; and for various reasons, not all young feminists identify with a "third wave" of feminism. Less than a year after I began to learn about feminism I discovered Barbara Findlen's Listen Up: Voices From the Next Feminist Generation. Although the collection nor its contributors declare association with "third wave" feminism, consequent reviews and citations in articles identify it, along with Rebecca Walker's To Be Real: Telling the Truth and Changing the Voice of Feminism, as a major text of "third wave" feminism. Re-reading Listen Up since beginning to research "third wave" feminism, I now understand its fundamental influence on my research questions as a starting point for assessing persistent exclusion in contemporary feminism, rather than as a revolutionary text (as it is claimed to be in many reviews). Findlen begins the introduction with the bold claim, "My feminism wasn't shaped by antiwar or civil rights activism ..." (xi). Framing the collection with a disavowal of the influence women of color's organizational efforts negates, for me, the project's proclaimed commitment to multivocality. Though several contributions examine persistent exclusion within contemporary feminist movement, the larger project seems to rely on these essays to reflect this commitment, suggesting that Listen Up does not go beyond the "add and stir" approach to "diversity." Interestingly, this statement does not appear in the new edition of Listen Up published in 2001. And the content has changed with this new edition, including several more Latina contributors and other "corrective" additions.

Assistência nutricional hospitalar : um estudo da satisfação dos clientes da Santa Casa de Porto Alegre

Esta dissertação apresenta um estudo que analisa o grau de satisfação de clientes, pacientes e acompanhantes, acerca da assistência nutricional hospitalar da ISCMPA, que utiliza o índice de satisfação de clientes como indicador de desempenho, demostrando a preocupação em elevar a qualidade do serviço a níveis de excelência. Foi aplicado um questionário, realizando entrevista pessoal com 215 clientes, resultando num estudo descritivo, de corte transversal, de perfil qualitativo e quantitativo. A análise de resultados foi apresentada em três blocos: características dos envolvidos na investigação, nível de satisfação e grau de importância por constructos. Aspectos como percepção dos clientes da imagem da Instituição, posição frente à comunidade, fatores que os levariam a trocar de Hospital e os sentimentos expressos pelos respondentes na ocasião da pesquisa, também foram abordados. O índice de 95 % de satisfação dos clientes, meta da Instituição, foi atingido em quatro dos seis contructos avaliados: Comportamento e Atuação de Funcionários, Comunicação com a Equipe por Telefone, Contato Inicial com a Equipe de Nutrição e Higiene de Material da Copa. Os constructos que não alcançaram a meta foram Refeições e Adequação de Material. O conhecimento do grau de satisfação dos clientes permitiu estabelecer um plano de intervenção, definindo ações corretivas e de melhorias para constructos que não alcançaram a meta e para pontos críticos identificados.

Padrão sazonal da produção industrial, exportações e importações: uma aplicação do X-12 ARIMA

Este trabalho tem por objetivo identificar os coeficientes sazonais de algumas variáveis econômicas (produção industrial, exportações e importações), isentos das mudanças estruturais registradas na economia. O estudo verifica se os planos de estabilização implementados pelo governo nos últimos quinze anos afetaram o padrão sazonal daquelas séries. Para tanto aplica-se o X-12-ARIMA, o novo método de dessazonalização de séries desenvolvido pelo U.S. Bureau of the Census. O uso desse método torna-se necessário, porque os demais métodos conhecidos impedem testar nossa hipótese, ao não permitirem o emprego de intervenções, não obtendo assim os melhores estimadores para os coeficientes sazonais. O estudo cobre o período que vai de 1980 a 1997 e os resultados confirmam a nossa hipótese de mudança no padrão sazonal no período. As nossas variáveis econômicas foram - de um ou de outro modo - atingidas pelos planos de estabilização implementados nos últimos quinze anos.

Os efeitos de sistema de registro de preço nas compras públicas: estudo de caso da Secretaria Municipal de Obras, Serviços Básicos e Habitação da cidade de Manaus

Public administration has been labeled as inefficient for decades, with society seen it as a great waste of public money with a low generation of results. Its services are notably classified as sluggish, bureaucratic, with a low productivity level and a high incidence of mistakes. In periods of crisis, public administration must be the first to give good examples of balance and parsimony in its expenditures, or it could lead to the failure of the government, in general, causing damages to the population. To reach this goal, some corrective measures must be done, in different directions, by selecting the expenditures and fostering the maximum economy for the exchequer. This is only possible through the application of correct planning techniques, a still far way reality from the culture of our public organisms. One way to this change is the adoption of the Price Registration System, that in the Federal scope was already adopted by the Decree nº 3.931/01, and in the scope of the municipality of Manaus was ordered by the Decree nº 8.270/06. The present study verifies the influence of the use of the Price Registration System in purchases and contracts undertaken by the Local Secretariat of Construction, Basic Services and Housing, in the city of Manaus concerning the economy obtained when compared to other methods of tenders.

Fatores da administração do sistema penitenciário do Rio de Janeiro que os impedem de cumprirem com sua missão de recuperação do detento?

Since some years ago, the penitentiany systen of Rio de Janeiro is going through the nuest sendus administrative crisis,leading more and more to chaotic situations, over imagined before by homan being. Nowadays all the factors and components of the existing models are still medievaIs, and even distant fron the human needs. The daily life ofthe condemned is a sway betuen lack of hygiene, disrespect to homan rigts, lack of modem corrective practices and also, lack of psychological support. How, then can me demand from the state ( Govemment) the rehabilitation of the imprisoned and their preparation to face society if they are treated manny times as victins of this same society? This society impose a life style enjoyed only by a privileged social class which forget about then when sent to the darkness. Many of then, join the penitentary systen because of minor crimes, and when they serve their tem, um for funately they go back to prison accused for move violent crimes. The penitentian models haven't developed the same way the society where they worked at has. There, the present brazilian penitentiary model has showed obsolete and inefficient alone its principal mission ofrehabilitation and re - education ofthe imprisoned. Our main objetive will be the construction and analysis of the penitential administrative model, as being able to fullfill the necesity of the penitentiary administrator (Manager). Analy zing on a specific reasoning which focus showld not be that of the theories and isolated projects of the topic, we will develop a progran far form religions, judiciary on political technics by building na administrtive penitentiary model strictly professional where we coul a have a deep analysis of the topic. We will try to approach the aspects of organization existing to day inorder to understand them and criate, a model wich will adjust betten to the necesitives of this thesis.

O orçamento do governo local sob condições de participação dos cidadãos: o caso da Prefeitura de Santos

Este trabalho trata de um estudo de caso sobre a participação direta dos cidadãos no orçamento público municipal. Discute-se a teoria democrática sustentando-se que a democracia representativa apresenta fàlhas que exigem mecanismos corretivos e que a participação direta dos cidadãos se apresenta como uma alternativa para corrigir esses desvios. A premissa básica que permeia toda a pesquisa é a da participação direta como meio eficiente de controle do cidadão sobre as ações do Estado - Governo Local. Por meio da análise do Programa de Governo do Partido e do Plano de Governo da Prefeitura de Santos~ procurou-se verificar quais os fundamentos teóricos da participação direta que orientam as ações do Governo Municipal Santista. A dimensão institucional da participação é explorada por meio da descrição e análise crítica das formas de participação direta~ previstas na legislação constitucional - Constituições Federal e Estadual de São Paulo e Lei Orgânica do Município de Santos. Busca-se identificar quais são os limites dos mecanismos de participação direta, previstos na legislação. quando aplicados ao orçamento municipal. A investigação sobre o processo decisório orçamentário visa a captar qual lógica subjaz no processo de alocação de recursos no orçamento público. Embora se tenha assinalados certos embaraços jurídicos e operacionais à participação direta dos cidadãos no orçamento~ esses entraves não invalidam a importância da experiência com orçamento participativo no Município de Santos. A proposta da Prefeitura Santista, por seu caráter inovador e educativo revela-se uma valiosa contribuição para a prática de uma gestão mais democrática e transparente no âmbito municipal.

Solução de conflitos: análise de dez casos.

A prática da negociação é tão antiga quanto a existência do ser humano. Segundo Shell (1999, p. 6, tradução nossa), “todos nós negociamos muitas vezes ao dia”. Negociam-se sobre infinitos assuntos com pessoas da mesma cultura ou de outra totalmente distinta, nos mais diversos ambientes. Na verdade, a negociação está tão presente que não se passa um dia sequer sem que se negocie algo, desde aumentos de salário até a construção de plantas industriais no exterior, em cenário de conflito político. O objetivo geral deste trabalho é levá-lo a compreender por que algumas dessas negociações são bem-sucedidas enquanto outras fracassam. Afim de que este objetivo seja atingido, é preciso inicialmente descrever o que se passa no momento em que a negociação está ocorrendo. Todavia, a descrição do processo em si tão somente não leva a maiores conquistas. É preciso também diagnosticar o que está acontecendo de errado para então prescrever soluções corretivas ou preventivas, conforme o caso. Em suma, os objetivos do presente trabalho visam responder às seguintes perguntas de pesquisa: 1. Qual é o perfil do negociador brasileiro? 2. O brasileiro negocia assuntos diferentes da mesma maneira? 3. Quando confrontado com outras culturas, como o brasileiro se comporta?O trabalho contempla um levantamento, pesquisa na forma de questionário, submetido com sucesso à apreciação de algumas centenas de brasileiros, com o intuito de saber como se comportam diante de dez situações reais em cenários diferentes, cuidadosamente escolhidos e que serão analisados ao longo do presente trabalho. Alguns resultados obtidos foram bastante curiosos. O leitor é convidado a explorar as conclusões sobre os desafios enfrentados pelos brasileiros nos dez cenários citados.

CAUC: orientações preventivas e corretivas acerca da regularidade dos municípios

O objetivo deste trabalho é orientar o gestor municipal, através de medidas preventivas e corretivas, no cumprimento dos requisitos fiscais elencados pelo Serviço Auxiliar de Informações para Transferências Voluntárias - CAUC, promovendo assim, a adimplência do Município e, consequentemente, a possibilidade de captação de recursos federais por transferências voluntárias. Desta forma, primeiramente, é realizada uma breve contextualização do tema, destacando sua relevância e as dificuldades enfrentadas pelos municípios no momento atual. No referencial teórico, a definição dos tipos de transferências de recursos, com destaque para as transferências voluntárias, a definição de convênios e a apresentação do CAUC, seus requisitos e funcionalidades, bem como a metodologia adotada no trabalho. Neste trabalho é apresentada pesquisa realizada no período de 2010 a 2013, com os municípios do Estado do Rio de Janeiro, apontando os requisitos recorrentes no CAUC que geram inadimplência e os principais aspectos observados. A partir dos dados coletados são elencadas medidas de caráter preventivo e corretivo, as principais ações e tipos de monitoramento, com o intuito de auxiliar os municípios na compreensão e no cumprimento das exigências.

Modified value stream mapping of airport check-in procedures

In June 2014 Brazil hosted the FIFA World Cup and in August 2016 Rio de Janeiro hosts the Summer Olympics. These two seminal sporting events will draw tens of thousands of air travelers through Brazil’s airports, airports that are currently in the midst of a national modernization program to address years of infrastructure neglect and insufficient capacity. Raising Brazil’s major airports up to the standards air travelers experience at major airports elsewhere in the world is more than just a case of building or remodeling facilities, processes must also be examined and reworked to enhance traveler experience and satisfaction. This research paper examines the key interface between airports and airline passengers—airport check-in procedures—according to how much value and waste there is associated with them. In particular, the paper makes use of a value stream mapping construct for services proposed by Martins, Cantanhede, and Jardim (2010). The uniqueness of this construct is that it attributes each activity with a certain percentage and magnitude of value or waste which can then be ordered and prioritized for improvement. Working against a fairly commonly expressed notion in Brazil that Brazil’s airports are inferior to the airports of economically advanced countries, the paper examines Rio’s two major airports, Galeão International and Santos Dumont in comparison to Washington D.C.’s Washington National and Dulles International airports. The paper seeks to accomplish three goals: - Determine whether there are differences in airport passenger check-in procedures between U.S. and Brazilian airports in terms of passenger value - Present options for Brazilian government or private sector authorities to consider adopting or implementing at Brazilian airports to maximize passenger value - Validate the Martins et al. construct for use in evaluating the airport check-in procedures Observations and analysis proved surprising in that all airports and service providers follow essentially the same check-in processes but execute them differently yet still result in similar overall performance in terms of value and waste. Although only a few activities are categorized as completely wasteful (and therefore removed in the revised value stream map of check-in activities), the weighting and categorization of individual activities according to their value (or waste) presents decision-makers a means to prioritize possible corrective actions. Various overall recommendations are presented based on this analysis. Most importantly, this paper demonstrates the viability of using the construct developed by Martins et al to examine airport operations, as well as its applicability to the study of other service industry processes.

Argilas modificadas como catalisadores ácidos sólidos

Important bentonitic deposits are present in Porto Santo Island, part of the Madeira Archipelago. Several locations were selected and samples were collected and characterised. The bentonite obtained at Serra de Dentro (SD) was selected for further laboratorial work. The fine fraction of SD bentonite was purified using several methods and the sodium homoionic form was prepared. This was the starting material used in the three generic types of modifications: metal exchange, acid activation and pillaring. These modifications produce materials with markedly different acidic (e.g. Brönsted and/or Lewis acidity), textural (e.g. increase of the surface area and active site accessibility) or structural (e.g. creation of permanent porous structures) properties. The wide range of materials obtained (including reference clays counterparts) was characterised in terms of chemical, structural, textural and catalytic properties. Limonene is an important raw material produced in Portugal, and its aromatisation reaction was chosen for the catalytic characterisation of the clay catalysts prepared.

Use of Fibres Obtained from the Cashew (Anacardium ocidentale, L) and Guava (Psidium guayava) Fruits for Enrichment of Food Products

OLIVEIRA, E. L. et al. Use of Fibres obtained from the Cashew (Anacardium ocidentale, L) and Guava (Psidium guayava) Fruits for Enrichment of Food Products. Brazilian Archives of Biology and Technology, Curitiba, PR, v. 48, p. 143-150, 2005.