938 resultados para Percutaneous Ethanol Injection


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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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The existence of organic and inorganic contaminants present in both fossil and biomass fuels and the fact that they can provide undesirable effects (environmental problems, corrosion processes, lead to storage instability, and others) implies a rigorous quality control of these fuels, although these contaminants make up a small part of the final fuel composition. Considering the rising importance of fuel ethanol in the worldwide panorama, this review aims at reporting the use of successful alternative analytical methods in the monitoring of organic and inorganic contaminants at trace levels, used to determine and to quantify these substances in fuel ethanol and also presenting all official norms for quality control of fuel ethanol employed by ABNT (Brazilian Association of Technical Norms), ASTM (American Society for Testing and Materials), and ECS (European Committee for Standardization).

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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A flow-injection (FI) spectrophotometric procedure exploiting merging zones is proposed for the determination of azithromycin in pharmaceutical formulations. The method is based on the reaction of azithromycin with tetrachloro-phenzoquinone (p-chloranil) accelerated by hydrogen peroxide and conducted in a methanol medium, producing a purple-red color compound (lambda(max) = 540 nm). The FI system and the experimental conditions were optimized using a multivariate method. Beer's law is obeyed in a concentration range of 50 - 1600 mu g mL(-1) with an excellent correlation coefficient (r = 0.9998). The detection limit and the quantification limit were 6.6 and 22.1 mu g mL(-1), respectively. No interference was observed from the common excipients, and the recoveries were within 98.6 to 100.4%. The procedure was applied to the determination of azithromycin in pharmaceuticals with a high sampling rate (65 samples h(-1)). The results obtained by the proposed method were in good agreement with those obtained by the comparative method at 95% confidence level.

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)