Efficiency of ethanol conversion induced by controlled modification of pore structure and acidic properties of alumina catalysts
Contribuinte(s) |
Universidade Estadual Paulista (UNESP) |
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Data(s) |
20/05/2014
20/05/2014
15/05/2011
|
Resumo |
Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) Bimodal porous alumina catalysts with both continuous macropores and mesopores were prepared using a dual soft template method. The addition of decahydronaphthalene as emulsifier agent successfully contributed to the formation of macropores. The effectiveness of macropore insertion was evaluated in the model reaction of ethanol dehydration at 300 degrees C. Judging from the results obtained by acidity measurements using temperature programmed desorption of ammonia and the performance of these catalysts in the ethanol dehydration, the introduction of macropores in the catalyst structure enhanced the ethanol conversion. (C) 2011 Elsevier B.V. All rights reserved. |
Formato |
59-65 |
Identificador |
http://dx.doi.org/10.1016/j.apcata.2011.03.014 Applied Catalysis A-general. Amsterdam: Elsevier B.V., v. 398, n. 1-2, p. 59-65, 2011. 0926-860X http://hdl.handle.net/11449/25327 10.1016/j.apcata.2011.03.014 WOS:000291118000007 |
Idioma(s) |
eng |
Publicador |
Elsevier B.V. |
Relação |
Applied Catalysis A: General |
Direitos |
closedAccess |
Palavras-Chave | #Macroporous materials #Mesoporous materials #Alumina #Emulsion #Ethanol dehydration |
Tipo |
info:eu-repo/semantics/article |