(Table DR1) Biogenic silica and chert in the Pacific Ocean, DSDP and ODP data

Evidence for the dissolution of biogenic silica at the base of pelagic sections supports the hypothesis that much of the chert formed in the Pacific derives from the dissolution and reprecipitation of this silica by hydrothermal waters. As ocean bottom waters flow into and through the crust, they become warmer. Initially they remain less saturated with respect to dissolved silica than pore water in the overlying sediments. With the diffusion of heat, dissolved ions, and to some extent the advection of water itself, biogenic silica in the basal part of the sedimentary section is dissolved. Upon conductively cooling, these pore waters precipitate chert layers. The most common thickness for the basal silica-free zone (20 m) lies below the most common height of the top of the chert interval above basement (50 m). This mode of chert formation explains the frequent occurrence of chert layers at very shallow subbottom depths in pelagic sections of the Pacific. It is also consistent with the common occurrence of cherts

Stable isotope record of sediment core MD98-2177

We present a reconstruction of El Niño Southern Oscillation (ENSO) variability spanning the Medieval Climate Anomaly (MCA, A.D. 800-1300) and the Little Ice Age (LIA, A.D. 1500-1850). Changes in ENSO are estimated by comparing the spread and symmetry of d18O values of individual specimens of the thermocline-dwelling planktonic foraminifer Pulleniatina obliquiloculata extracted from discrete time horizons of a sediment core collected in the Sulawesi Sea, at the edge of the western tropical Pacific warm pool. The spread of individual d18O values is interpreted to be a measure of the strength of both phases of ENSO while the symmetry of the d18O distributions is used to evaluate the relative strength/frequency of El Niño and La Niña events. In contrast to previous studies, we use robust and resistant statistics to quantify the spread and symmetry of the d18O distributions; an approach motivated by the relatively small sample size and the presence of outliers. Furthermore, we use a pseudo-proxy approach to investigate the effects of the different paleo-environmental factors on the statistics of the d18O distributions, which could bias the paleo-ENSO reconstruction. We find no systematic difference in the magnitude/strength of ENSO during the Northern Hemisphere MCA or LIA. However, our results suggest that ENSO during the MCA was skewed toward stronger/more frequent La Niña than El Niño, an observation consistent with the medieval megadroughts documented from sites in western North America.

Summary of physical properties on cores used for petrofabric analyses triaxial experiments at DSDP Leg 67 Holes

Deformation features within the cores are studied with a view towards elucidating the structure of the Middle America Trench along the transect drilled during Leg 67. Where possible, inferences are made as to the physical environment of deformation. Extensional tectonics prevails in the area of the seaward slope and trench. Fracturing and one well-preserved normal fault are found mostly within the lower Miocene chalks, at the base of the sedimentary section. These chalks have high porosities (40%-60%) and water content (30%-190%, based on % dry wt.). Experimental triaxial compression tests conducted on both dry and water-saturated samples of chalk from Holes 495 and 499B show that only in the saturated samples is more brittle behavior observed. Brittle failure of the chalks is greatly facilitated by pore fluid pressures that lead to low effective pressures. Additional embrittlement (weakening) can take place as a result of the imposed extensional stress resulting from bending of a subducting elastic oceanic plate. The chalks exhibit, in a landward direction, an increase in density and mechanical strength and a decrease in water content. These changes are attributed to mechanical compaction that may have resulted from tectonic horizontal compression. The structure of the landward slope is not well understood because the slope sites had to be abandoned due to the presence of gas hydrate. The relationship of the chaotic, brittle deformation (observed in the cores from Hole 494A) at the base of the landward slope to tectonic processes remains unclear. The deformation observed on the slope sites (Holes 496 and 497) is mostly fracturing and near-vertical sigmoidal veinlets. These are interpreted as being the result of gas/fluid overpressurization due to the decomposition of the gas hydrate, and not due to tectonic loading of accreted sediments. Aside from four small displacement (less than 1cm) reverse faults observed in the lower Miocene chalks (which may be the product of soft-sediment deformation), there is a noticeable absence of structures reflecting a dominance of horizontal (tectonic) compression along the transect drilled. The absence of such features, the lack of continuity of sediment types across the trench-landward slope, and the normal stratigraphic sequence in Hole 494A do not support any known accretionary model.

(Table 1) n-alkane distribution, and stable carbon and deuterium isotope ratios of DSDP Hole 10-94

Hydrology, source region, and timing of precipitation are important controls on the climate of the Great Plains of North America and the composition of terrestrial ecosystems. Moisture delivered to the Great Plains varies seasonally and predominately derives from the Gulf of Mexico/Atlantic Ocean with minor contributions from the Pacific Ocean and Arctic region. For this work, we evaluate long-term relationships for the past ~ 35 million years between North American hydrology, climate, and floral change, using isotopic records and average carbon chain lengths of higher plant n-alkanes from Gulf of Mexico sediments (DSDP Site 94). We find that carbon isotope values (d13C) of n-alkanes, corrected for variations in the d13C value of atmospheric CO2, provide minor evidence for contributions of C4 plants prior to the Middle Miocene. A sharp spike in C4 input is identified during the Middle Miocene Climatic Optimum, and the influence of C4 plants steadily increased during the Late Miocene into the Pleistocene - consistent with other North American records. Chain-length distributions of n-alkanes, indicative of the composition of higher plant communities, remained remarkably constant from 33 to 4 Ma. However, a trend toward longer chain lengths occurred during the past 4 million years, concurrent with an increase in d13C values, indicating increased C4 plant influence and potentially aridity. The hydrogen isotope values (dD) of n-alkanes are relatively invariant between 33 and 9 Ma, and then become substantially more negative (75 per mil) from 9 to 2 Ma. Changes in the plant community and temperature of precipitation can solely account for the observed variations in dD from 33 to 5 Ma, but cannot account for Plio-Pleistocene dD variations and imply substantial changes in the source region of precipitation and seasonality of moisture delivery. We posit that hydrological changes were linked to tectonic and oceanographic processes including the shoaling and closure of the Panamanian Seaway, amplification of North Atlantic Deep Water Production and an associated increase of meridional winds. The southerly movement of the Intertropical Convergence Zone near 4 Ma allowed for the development of a near-modern pressure/storm track system, driving increased aridity and changes in seasonality within the North American interior.

Geochemistry from DSDP Holes 67-497 and 67-496

Mineralogical identification, glass chemistry, and instrumental neutron activation analyses of Quaternary volcanic ash layers from Leg 67 Holes 496, 497, and 499 are used to correlate the drill holes and on-land sources. We have identified two units at Hole 496 that correspond to the 23,000-yr.-old Pinos Altos ash (Samples 496-3-4, 55-57 cm and 496-3-5, 74-76 cm); the 84,000-yr.-old Los Chocoyos ash corresponds with Sample 496-5-4, 134-146 cm, but this latter correlation is less certain.

Guidance in the diversity: a glance from Latin America

Guidance and Diversity, for the majority of the European countries and North America , are related to the attention to children and young people with special necessities, that are attend in an educative institution and for those who are elaborated educative programs directed to obtain one better adaptation to the prevailing social system. In most of the cases is considered that the problematic of the special necessities is imputable to genetic or personal factors that only respond to internal factors to the individuals that display them avoiding the external factors that in some cases can be more decisive determinants at the time of the conductual manifestation. In this work is pleaded because the professionals of the Guidance, as much private or public scenes of the European countries, make more specific considerations at the time of taking care of children, young people and adults, as immigrants, coming of Latin America . In an ample sense one sets out to make Guidance in the Diversity more than Guidance for the Diversity under the conception of a Guidance for All which implies the elimination of the expression "special necessities", whose connotation in our countries is not most appropriate, and than it includes the idea of an Ethnic Guidance. Perhaps the best way of boarding of these conceptions is promoting a process of Guidance from the School and not only in the School.

Paleomagnetic properties of igneous rocks from several DSDP and ODP sites, western Pacific

Oceanic basalts and other related igneous rocks are considered excellent recorders of the Earth's paleomagnetic field. Consequently, basalt core paleomagnetic data are valuable for the constraints they provide on plate tectonic motions, especially for oceanic plates such as the Pacific. Unfortunately, few Deep Sea Drilling Project (DSDP) and Ocean Drilling Program (ODP) boreholes have been cored very deeply into the ocean crust. The result is that there are only a few sites at which a large enough number of basalt flows have been cored to properly average secular variation (e.g., Kono, 1980, doi:10.2973/dsdp.proc.55.135.1980; Cox and Gordon, 1984, doi:10.1029/RG022i001p00047). Furthermore, there are a number of sites where basaltic core samples were retrieved but the cores were not measured. Often this occurs because leg scientists had more important sections to work on, or the section was ignored because it was too short to record enough time to average secular variation and obtain a reliable paleolatitude. Even though it may not be possible to determine a precise paleolatitude from such short sections, measurements from a small number of flows are important because they can be combined with other coeval paleomagnetic data from the same plate to calculate a paleomagnetic pole (Gordon and Cox, 1980, doi:10.1111/j.1365-246X.1980.tb02642.x; Cox and Gordon, 1984, doi:10.1029/RG022i001p00047). For this reason, I obtained samples for paleomagnetic measurements from eight Pacific sites (169, 170, 171, 581, 597, 800, 803, and 865), most of which have not been previously measured for paleomagnetism.

Guidance in the diversity: a glance from Latin America

Guidance and Diversity, for the majority of the European countries and North America , are related to the attention to children and young people with special necessities, that are attend in an educative institution and for those who are elaborated educative programs directed to obtain one better adaptation to the prevailing social system. In most of the cases is considered that the problematic of the special necessities is imputable to genetic or personal factors that only respond to internal factors to the individuals that display them avoiding the external factors that in some cases can be more decisive determinants at the time of the conductual manifestation. In this work is pleaded because the professionals of the Guidance, as much private or public scenes of the European countries, make more specific considerations at the time of taking care of children, young people and adults, as immigrants, coming of Latin America . In an ample sense one sets out to make Guidance in the Diversity more than Guidance for the Diversity under the conception of a Guidance for All which implies the elimination of the expression "special necessities", whose connotation in our countries is not most appropriate, and than it includes the idea of an Ethnic Guidance. Perhaps the best way of boarding of these conceptions is promoting a process of Guidance from the School and not only in the School.

Chemistry and accumulation rates of Jurassic to early Cretaceous sediments from the central equatorial Pacific

Sedimentation in the central Pacific during the Jurassic and Early Cretaceous was dominated by abundant biogenic silica. A synthesis of the stratigraphy, lithology, petrology, and geochemistry of the radiolarites in Sites 801 and 800 documents the sedimentation processes and trends in the equatorial central Pacific from the Middle Jurassic through the Early Cretaceous. Paleolatitude and paleodepth reconstructions enable comparisons with previous DSDP sites and identification of the general patterns of sedimentation over a wide region of the Pacific. Clayey radiolarites dominated sedimentation on Pacific oceanic crust within tropical paleolatitudes from at least the latest Bathonian through Tithonian. Radiolarian productivity rose to a peak within 5° of the paleoequator, where accumulation rates of biogenic silica exceeded 1000 g/cm**2/m.y. Wavy-bedded radiolarian cherts developed in the upper Tithonian at Site 801 coinciding with the proximity of this site to the paleoequator. Ribbon-bedding of some radiolarian cherts exposed on Pacific margins may have formed from silicification of radiolarite deposited near the equatorial high-productivity zone where radiolarian/clay ratios were high. Silicification processes in sediments extensively mixed by bioturbation or enriched in clay or carbonate generally resulted in discontinuous bands or nodules of porcellanite or chert, e.g., a "knobby" radiolarite. Ribbon-bedded cherts require primary alternations of radiolarian-rich and clay-rich layers as an initial structural template, coupled with abundant biogenic silica in both layers. During diagenesis, migration of silica from clay-rich layers leaves radiolarian "ghosts" or voids, and the precipitation in adjacent radiolarite layers results in silicification of the inter-radiolarian matrix and infilling of radiolarian tests. Alternations of claystone and clay-rich radiolarian grainstone were deposited during the Callovian at Site 801 and during the Berriasian-Valanginian at Site 800, but did not silicify to form bedded chert. Carbonate was not preserved on the Pacific oceanic floor or spreading ridges during the Jurassic, perhaps due to an elevated level of dissolved carbon dioxide. During the Berriasian through Hauterivian, the carbonate compensation depth (CCD) descended to approximately 3500 m, permitting the accumulation of siliceous limestones at near-ridge sites. Carbonate accumulation rates exceeded 1500 g/cm**2/m.y. at sites above the CCD, yet there is no evidence of an equatorial carbonate bulge during the Early Cretaceous. In the Barremian and Aptian, the CCD rose, coincident with the onset of mid-plate volcanic activity. Abundance of Fe and Mn and the associated formation of authigenic Fe-smectite clays was a function of proximity to the spreading ridges, with secondary enrichments occurring during episodes of spreading-center reorganizations. Callovian radiolarite at Site 801 is anomalously depleted in Mn, which resulted either from inhibited precipitation of Mn-oxides by lower pH of interstitial waters induced by high dissolved oceanic CO2 levels or from diagenetic mobilization of Mn. Influx of terrigenous (eolian) clay apparently changed with paleolatitude and geological age. Cyclic variations in productivity of radiolarians and of nannofossils and in the influx of terrigenous clay are attributed to Milankovitch climatic cycles of precession (20,000 yr) and eccentricity (100,000 yr). Diagenetic redistribution of biogenic silica and carbonate enhanced the expression of this cyclic sedimentation. Jurassic and Lower Cretaceous sediments were deposited under oxygenated bottom-water conditions at all depths, accompanied by bioturbation and pervasive oxidation of organic carbon and metals. Despite the more "equable" climate conditions of the Mesozoic, the super-ocean of the Pacific experienced adequate deep-water circulation to prevent stagnation. Efficient nutrient recycling may have been a factor in the abundance of radiolarians in this ocean basin.

Distribution models for mountain plant species: The value of elevation

The climatic conditions of mountain habitats are greatly influenced by topography. Large differences in microclimate occur with small changes in elevation, and this complex interaction is an important determinant of mountain plant distributions. In spite of this, elevation is not often considered as a relevant predictor in species distribution models (SDMs) for mountain plants. Here, we evaluated the importance of including elevation as a predictor in SDMs for mountain plant species. We generated two sets of SDMs for each of 73 plant species that occur in the Pacific Northwest of North America; one set of models included elevation as a predictor variable and the other set did not. AUC scores indicated that omitting elevation as a predictor resulted in a negligible reduction of model performance. However, further analysis revealed that the omission of elevation resulted in large over-predictions of species' niche breadths-this effect was most pronounced for species that occupy the highest elevations. In addition, the inclusion of elevation as a predictor constrained the effects of other predictors that superficially affected the outcome of the models generated without elevation. Our results demonstrate that the inclusion of elevation as a predictor variable improves the quality of SDMs for high-elevation plant species. Because of the negligible AUC score penalty for over-predicting niche breadth, our results support the notion that AUC scores alone should not be used as a measure of model quality. More generally, our results illustrate the importance of selecting biologically relevant predictor variables when constructing SDMs.

Age determination of sediments and biomarkers of ODP Hole 169-1034C

The radiocarbon contents of various biomarkers extracted from the varve-counted sediments of Saanich Inlet, Canada, were determined to assess their applicability for dating purposes. Calibrated ages obtained from the marine planktonic archaeal biomarker crenarchaeol compared favorably with varve-count ages. The same conclusion could be drawn for a more general archaeal biomarker (GDGT-0), although this biomarker proved to be less reliable due to its less-specific origin. The results also lend support to earlier indications that marine crenarchaeota use dissolved inorganic carbon (DIC) as their carbon source. The average reservoir age offset DR of 430 years, determined using the crenarchaeol radiocarbon ages, varied by ±110 years. This may be caused by natural variations in ocean-atmosphere mixing or upwelling at the NE Pacific coast but variability may also be due to an inconsistency in the marine calibration curve when used at sites with high reservoir ages.

Guidance in the diversity: a glance from Latin America

Guidance and Diversity, for the majority of the European countries and North America , are related to the attention to children and young people with special necessities, that are attend in an educative institution and for those who are elaborated educative programs directed to obtain one better adaptation to the prevailing social system. In most of the cases is considered that the problematic of the special necessities is imputable to genetic or personal factors that only respond to internal factors to the individuals that display them avoiding the external factors that in some cases can be more decisive determinants at the time of the conductual manifestation. In this work is pleaded because the professionals of the Guidance, as much private or public scenes of the European countries, make more specific considerations at the time of taking care of children, young people and adults, as immigrants, coming of Latin America . In an ample sense one sets out to make Guidance in the Diversity more than Guidance for the Diversity under the conception of a Guidance for All which implies the elimination of the expression "special necessities", whose connotation in our countries is not most appropriate, and than it includes the idea of an Ethnic Guidance. Perhaps the best way of boarding of these conceptions is promoting a process of Guidance from the School and not only in the School.

Tab. 1: Ar40/Ar39 results from Kuyul terrane, northeastern Russia

The Kamchatka Peninsula of northeastern Russia is located along the northwestern margin of the Bering Sea and consists of zones of complexly deformed accreted terranes. Along the northern portion of the peninsula, progressing from then orthwestem Bering Sea inland the Olyutorskiy, Ukelayat, and Koryak superterranes area acreted to the Okhotsk-Chukotsk volcanic-plutonic bell in northern-most Kamchatka. A sedimentary sequence of Albian to Maastrichtian age overlap terranes and units of the Koryak superterrane and constrains their accretion time with this region of the North America plate. Ophiolite complexes, widespread within the Koryak superterrane, are associated with serpentinite melanges and some of the ophiolite terranes include large portions of weakly serpentinized hyperbasites, layered gabbro, sheeted dikes, and pillow basalts outcropping as internally coherent blocks within a sheared melange matrix. Interpretation of magnetic anomalies allow the correlation of the Ukelayat with the West Kamchatka and Sredinny Range superterranes. The Olyutorskiy composite terrane may be correlated with the central and southern Kamchatka Peninsula Litke, Eastern Ranges and Vetlov composite terranes. The most "out-board" of the central and southern Kamchatka Peninsula terranes is the Kronotsky composite terrane, weil exposed along the Kamchatka, Kronotsky and Shipunsky Capes. Using regional geological constraints, paleomagnetism, and plate kinematic models for the Pacific basin a regional model can be proposed in which accretion of the Koryak composite terrane to the North America plate occurs during the Campanian-Maastrichtian, followed by the accretion of the Olyutorskiy composite terrane in the Middle Eocene, and the Late Oligocene-Early Miocene collision of the Kronotsky composite terrane. A revised age estimate of a key overlapping sedirnentary sequence of the Koryak superterrane, calibrated with new Ar40/Ar39 data, supports its Late Cretaceous accretion age.