Formulação de pasta de cimento flexível utilizando planejamento experimental

Steam injection is an oil recovery method accomplished by introducing steam directly into the oil well to the reservoir. The steam causes dilation of the casing, which, after reduction in temperature, tends to return to the initial dimensions: causing the formation of cracks in the cement and loss of hydraulic isolation.. In this context, the type of the SBR latex is used to improve the flexibility of the cement matrix by reducing the amount of fatigue failure. To prevent these failures, the mechanical resistance parameters should be carefully adjusted to well conditions. This work aims to study the mechanical behavior of cement slurry systems additivated with SBR latex for cementing oil wells subject to steam injection. Through the central composite factorial design was studied the behavior of the compressive strength by varying the density of the paste between 1.75 g /cm³ (14.6 lb/ Gal) and 1.89 g/cm³ (15,8lb / Gal), curing time between 4 days and 28 days and concentration of SBR Latex between 0 L / m³ and 534.722 L / m³ (0 gpc and 4 gpc). The results showed that increasing the concentration of SBR latex, within the given ranges, there was a decreased compression resistance and elastic modulus by increasing the elastic deformability of the slurry. From the results it can determine best slurries formulation conditions in oil well cementing operations subject to steam injection.

Formulação de pasta de cimento flexível utilizando planejamento experimental

Steam injection is an oil recovery method accomplished by introducing steam directly into the oil well to the reservoir. The steam causes dilation of the casing, which, after reduction in temperature, tends to return to the initial dimensions: causing the formation of cracks in the cement and loss of hydraulic isolation.. In this context, the type of the SBR latex is used to improve the flexibility of the cement matrix by reducing the amount of fatigue failure. To prevent these failures, the mechanical resistance parameters should be carefully adjusted to well conditions. This work aims to study the mechanical behavior of cement slurry systems additivated with SBR latex for cementing oil wells subject to steam injection. Through the central composite factorial design was studied the behavior of the compressive strength by varying the density of the paste between 1.75 g /cm³ (14.6 lb/ Gal) and 1.89 g/cm³ (15,8lb / Gal), curing time between 4 days and 28 days and concentration of SBR Latex between 0 L / m³ and 534.722 L / m³ (0 gpc and 4 gpc). The results showed that increasing the concentration of SBR latex, within the given ranges, there was a decreased compression resistance and elastic modulus by increasing the elastic deformability of the slurry. From the results it can determine best slurries formulation conditions in oil well cementing operations subject to steam injection.

Preparation of Polymer Nanoparticles by Ring Opening Metathesis Polymerization in Aqueous Dispersed Systems with Water-Soluble Ruthenium-based Catalyst

Ring opening metathesis polymerization (ROMP) is a variant of olefin metathesis used to polymerize strained cyclic olefins. Ruthenium-based Grubbs’ catalysts are widely used in ROMP to produce industrially important products. While highly efficient in organic solvents such as dichloromethane and toluene, these hydrophobic catalysts are not typically applied in aqueous systems. With the advancements in emulsion and miniemulsion polymerization, it is promising to conduct ROMP in an aqueous dispersed phase to generate well-defined latex nanoparticles while improving heat transfer and reducing the use of volatile organic solvents (VOCs). Herein I report the efforts made using a PEGylated ruthenium alkylidene as the catalyst to initiate ROMP in an oil-in-water miniemulsion. 1H NMR revealed that the synthesized PEGylated catalyst was stable and reactive in water. Using 1,5-cyclooctadiene (COD) as monomer, we showed the highly efficient catalyst yielded colloidally stable polymer latexes with ~ 100% conversion at room temperature. Kinetic studies demonstrated first-order kinetics with good livingness as confirmed by the shift of gel permeation chromatography (GPC) traces. Depending on the surfactants used, the particle sizes ranged from 100 to 300 nm with monomodal distributions. The more strained cyclic olefin norbornene (NB) could also be efficiently polymerized with a PEGylated ruthenium alkylidene in miniemulsion to full conversion and with minimal coagulum formation.

PVC Beret as part of Hats: An Anthology exhibition

Dip moulded plastic PVC beret. One of series starting from Jelly Beret 1997. This was made with the design company Inflate. This 2009 iteration of the PVC beret chosen for Stephen Jones Hat Anthology V&A, the first millinery exhibition of millinery design held at V&A. Whereas traditional millinery is known for its rather staid and bourgoise Stephen Jones selected chose this hat for its edgy sub cultural capital. This is reflected in the choices of materials and beret style with a reference to the Bohemien Parisienne avant garde revisited in 1960s London and made new for 21st century NY. "Jelly Beret" the very first prototype of a plastic millinery, reviewed in Elle 2000. This travelling exhibition went from London, New York, Sydney and exists at the V&A as a touring show. An accompanying catalogue by Oriole Cullen and Stephen Jones discusses the significance of innovative and original millinery design international design culture today.. " “House of Flora is noted for its sculptural and architecturally inspired hats made from technologically innovative materials such as latex,PVC and Perspex” Oriole Cullen

Revista de la Universidad de Cuenca. Anales

La promulgación del nuevo Reglamento Académico de la Universidad de Cuenca, aprobado por su Consejo Universitario en Agosto del 2008, sin duda constituye el hecho más relevante para el proceso de desarrollo de la ciencia y tecnología en nuestra Alma Mater. En efecto, este reglamento recoge una de las mayores aspiraciones de la comunidad universitaria, como es el reconocer la categoría de investigador, además de la de docente, dentro de su personal académico. El artículo 1, del capítulo 1, del referido reglamento académico reza textualmente: "el personal académico está constituido por los docentes e investigadores con nombramiento, en cualquier categoría o dedicación ..." La Dirección de Investigación de la Universidad de Cuenca (DIUC), por su parte, tiene un papel protagónico en este proceso, puesto que es el organismo responsable de la conformación y ejecución de los respectivos concursos de oposición y méritos para proceder al nombramiento de los futuros investiga-dores. De esta manera, durante el año 2008, cinco flamantes investigadores se han incorporado al personal académico de nuestra universidad mediante el respectivo concurso convocado de acuerdo al nuevo reglamento académico. La incorporación de nuevos investigadores a los diferentes programas y proyectos de investigación científica, que actualmente se hallan en ejecución en nuestra universidad constituye un irrefutable ejemplo de la política insti¬tucional instaurada por las actúalas autoridades universitarias, en el sentido de fortalecer e impulsar el desarrollo de la ciencia y tecnología, a fin de que nuestra universidad se convierta en la práctica en una universidad que en¬seña e investiga, acorde con las exigencias de la nueva época de la sociedad del conocimiento. En esta contexto, la DIUC lanza una nueva publicación de la Revista Anales de la Universidad de Cuenca, que contiene los resultados de los trabajos de investigación científica realizados por los profesores y estudiantes inves-tigadores de las diferentes unidades académicas, en una clara demostración que nuestra universidad genera nuevos conocimientos dirigidos a resolver los problemas sociales y económicos de la región y del país.

Effect of proteolytic enzyme and fiber of papaya fruit on human digestive health

The World Health Organization (WHO, 2005) recommends consumption of fruits and vegetables as part of a healthy diet with daily recommendation of 5 servings or at least 400 g per day. Fruits and vegetables are good sources of vitamins, minerals, antioxidants, and fiber. Papaya fruit is known for his high nutrient and fiber content, and with few exceptions, it is generally consumed ripe due to its characteristic flavor and aroma. Digestion improvement has been attributed to consumption of papaya; this we speculate is attributed to the fiber content and proteolytic enzymes associated with this highly nutritious fruit. However, research is lacking that evaluates the impact of papaya fruit on human digestion. Papain is a proteolytic enzyme generally extracted from the latex of unripe papaya. Previous research has focused on evaluating papain activity from the latex of different parts of the plant; however there are no reports about papain activity in papaya pulp through fruit maturation. The activity of papain through different stages of ripeness of papaya and its capacity of dislodging meat bolus in an in vitro model was addressed. The objective of this study was to investigate whether papain activity and fiber content are responsible for the digestive properties attributed to papaya and to find a processing method that preserves papaya health properties with minimal impact on flavor. Our results indicated that papain was active at all maturation stages of the fruit. Ripe papaya pulp displayed the highest enzyme activity and also presented the largest meat bolus displacement. The in vitro digestion study indicated that ripe papaya displayed the highest protein digestibility; this is associated with proteolytic enzymes still active at the acidity of the stomach. Results from the in vitro fermentation study indicated that ripe papaya produced the highest amount of Short Chain Fatty Acids SCFA of the three papaya substrates (unripe, ripe, and processed). SCFA are the most important product of fermentation and are used as indicators of the amount of substrate fermented by microorganisms in the colon. The combination of proteolytic enzymes and fiber content found in papaya make of this fruit not only a potential digestive aid, but also a good source of SCFA and their associated potential health benefits. Irradiation processing had minimal impact on flavor compounds of papaya nectar. However, processed papaya experienced the lowest protein digestibility and SCFA production among the papaya substrates. Future research needs to explore new processing methods for papaya that minimize the detrimental impact on enzyme activity and SCFA production.

Occupational contact urticaria: lessons from the French National Network for Occupational Disease Vigilance and Prevention (RNV3P)

International audience

Desenvolvimento de pastas de cimento flexíveis para poços de petróleo submetidos à injeção de vapor utilizando látex do tipo SBR

Novel cementing materials formulations containing flexible polymeric admixtures have been studied aiming at improving the mechanical behavior of oil well cement slurries submitted to steam injection. However, research activities in this sector are still under development. The steam injected directly into the well causes casing dilation, which after a reduction in temperature, tends to return to its original dimensions, resulting in crack formation and hydraulic isolation loss of the well, which will result in shortening of well life. In this scenario, the objective of the present study was to evaluate the mechanical behavior of Portland-based slurries containing SBR latex, applied in oil well cementing of wells submitted to steam injection. Were formulated slurries with densities of 1.797 g/cm3 (15.0 lb/Gal) and 1.869 g/cm3 (15.6 lb/Gal), containing admixtures with a latex concentration of 0; 66.88; 133.76; 200.64 and 267.52 L/m3 (0, 0.5, 1.0, 1.5 and 2.0 gpc). Tests including rheology, fluid loss control, thickening time, API compressive strength and splitting tensile strength, beyond steam injection simulation. Microstrutural characteristics of the slurries were also performed (XRD, TG, FTIR and SEM). The results showed that increasing the polymer concentration increased in the rheological properties and fluid loss, and a decrease in the elasticity modulus of the cement slurries. The results obtained showed that the slurries can be applied in cementing operations of oil wells submitted to steam injection.

Otimização e análise mecânica de pastas geopoliméricas para uso em poços sujeitos à injeção cíclica de vapor

Oil wells subjected to cyclic steam injection present important challenges for the development of well cementing systems, mainly due to tensile stresses caused by thermal gradients during its useful life. Cement sheath failures in wells using conventional high compressive strength systems lead to the use of cement systems that are more flexible and/or ductile, with emphasis on Portland cement systems with latex addition. Recent research efforts have presented geopolymeric systems as alternatives. These cementing systems are based on alkaline activation of amorphous aluminosilicates such as metakaolin or fly ash and display advantageous properties such as high compressive strength, fast setting and thermal stability. Basic geopolymeric formulations can be found in the literature, which meet basic oil industry specifications such as rheology, compressive strength and thickening time. In this work, new geopolymeric formulations were developed, based on metakaolin, potassium silicate, potassium hydroxide, silica fume and mineral fiber, using the state of the art in chemical composition, mixture modeling and additivation to optimize the most relevant properties for oil well cementing. Starting from molar ratios considered ideal in the literature (SiO2/Al2O3 = 3.8 e K2O/Al2O3 = 1.0), a study of dry mixtures was performed,based on the compressive packing model, resulting in an optimal volume of 6% for the added solid material. This material (silica fume and mineral fiber) works both as an additional silica source (in the case of silica fume) and as mechanical reinforcement, especially in the case of mineral fiber, which incremented the tensile strength. The first triaxial mechanical study of this class of materials was performed. For comparison, a mechanical study of conventional latex-based cementing systems was also carried out. Regardless of differences in the failure mode (brittle for geopolymers, ductile for latex-based systems), the superior uniaxial compressive strength (37 MPa for the geopolymeric slurry P5 versus 18 MPa for the conventional slurry P2), similar triaxial behavior (friction angle 21° for P5 and P2) and lower stifness (in the elastic region 5.1 GPa for P5 versus 6.8 GPa for P2) of the geopolymeric systems allowed them to withstand a similar amount of mechanical energy (155 kJ/m3 for P5 versus 208 kJ/m3 for P2), noting that geopolymers work in the elastic regime, without the microcracking present in the case of latex-based systems. Therefore, the geopolymers studied on this work must be designed for application in the elastic region to avoid brittle failure. Finally, the tensile strength of geopolymers is originally poor (1.3 MPa for the geopolymeric slurry P3) due to its brittle structure. However, after additivation with mineral fiber, the tensile strength became equivalent to that of latex-based systems (2.3 MPa for P5 and 2.1 MPa for P2). The technical viability of conventional and proposed formulations was evaluated for the whole well life, including stresses due to cyclic steam injection. This analysis was performed using finite element-based simulation software. It was verified that conventional slurries are viable up to 204ºF (400ºC) and geopolymeric slurries are viable above 500ºF (260ºC)

Aditivação de pastas geopoliméricas com tetraborato de sódio e látex não iônico para cimentação de Poços de Petróleo

The development of activities in the oil and gas sector has been promoting the search for materials more adequate to oilwell cementing operation. In the state of Rio Grande do Norte, the cement sheath integrity tend to fail during steam injection operation which is necessary to increase oil recovery in reservoir with heavy oil. Geopolymer is a material that can be used as alternative cement. It has been used in manufacturing of fireproof compounds, construction of structures and for controlling of toxic or radioactive waste. Latex is widely used in Portland cement slurries and its characteristic is the increase of compressive strength of cement slurries. Sodium Tetraborate is used in dental cement as a retarder. The addition of this additive aim to improve the geopolymeric slurries properties for oilwell cementing operation. The slurries studied are constituted of metakaolinite, potassium silicate, potassium hydroxide, non-ionic latex and sodium tetraborate. The properties evaluated were: viscosity, compressive strength, thickening time, density, fluid loss control, at ambient temperature (27 ºC) and at cement specification temperature. The tests were carried out in accordance to the practical recommendations of the norm API RP 10B. The slurries with sodium tetraborate did not change either their rheological properties or their mechanical properties or their density in relation the slurry with no additive. The increase of the concentration of sodium tetraborate increased the water loss at both temperatures studied. The best result obtained with the addition of sodium tetraborate was thickening time, which was tripled. The addition of latex in the slurries studied diminished their rheological properties and their density, however, at ambient temperature, it increased their compressive strength and it functioned as an accelerator. The increase of latex concentration increased the presence of water and then diminished the density of the slurries and increased the water loss. From the results obtained, it was concluded that sodium tetraborate and non-ionic latex are promising additives for geopolymer slurries to be used in oilwell cementing operation

Leaf anatomy of rubber-tree clones

A seringueira é uma planta de fácil reconhecimento por ser lenhosa, de porte mediano a grande, que apresenta um padrão característico de desfolha e reenfolhamento e, sobretudo, pela produção de látex. O objetivo do trabalho foi efetuar um estudo anatômico e morfológico foliar, comparando os clones RRIM 600 e GT 1 de seringueira &91;Hevea brasiliensis (Wild. ex Adr. de Juss.) Muell.- Arg&93;, desenvolvidos sob as mesmas condições edáficas e climáticas, para obtenção de informações que possam fornecer subsídios para correlações com dados fisiológicos e também diferenciar os clones em relação ao conteúdo de fibras, espessamento de tecidos do parênquima paliçádico e do parênquima lacunoso, caracterização anatômica do pecíolo, número e tamanho de estômatos e fornecer dados referentes a morfologia foliolar. Foram realizadas secções transversais na região do mesófilo, nervura central e pecíolo, seguindo-se os métodos usuais de preparação de lâminas permanentes. Foram realizadas análises biométricas de extensões de tecidos dos parênquimas paliçádico e lacunoso e contagem do número de células do parênquima lacunoso. Paralelamente foram realizadas análises biométricas para aferições de estômatos. Não houve diferenças para a altura das células epidérmicas, altura e número de camadas do parênquima lacunoso e para o comprimento e para a maior largura do limbo foliolar. Porém houve variação para a espessura das células do parênquima paliçádico, sendo que GT 1 apresentou maior espessura em relação a RRIM 600. GT1 apresentou maior número de estômatos em relação a RRIM 600, porém com menor tamanho. GT1 apresentou maior diâmetro da nervura central da folha e do pecíolo e maior quantidade de fibras de esclerênquima que RRIM 600.

Simulación de la capacidad de producción de las máquinas y áreas de trabajo que intervienen proceso productivo de fabricación de Guantes de Látex

42 p.

Uma Introdução à Sintaxe do C++: C++03 e C++11

A interacção dos humanos com os computadores envolve uma combinação das tarefas de programação e de utilização. Nem sempre é explícita a diferença entre as duas tarefas. Introduzir comandos num programa de desenho assistido por computador é utilização ou programação numa linguagem interpretada? Modificar uma folha de cálculo com macros é utilização ou programação? Usar um “Integrated Development Environment” ou IDE para inserir dados num ficheiro é utilização (do IDE) ou programação? A escrita de um texto usando LaTeX ou HTML é utilização ou programação numa “markup language”? Recorrer a um programa de computação simbólica é utilização ou programação? Utilizar um processador de texto é utilização ou programação visual? Ao utilizador não se exige um conhecimento completo de todos os comandos, todos os menus, todos os símbolos do software que utiliza. Nem a memorização da sintaxe e de todos os pormenores de funcionamento de um programa é um atributo necessário ou sequer útil ao utilizador; a concretização desse conhecimento não assegura maior eficiência na utilização. Quando se começa, apenas algumas instruções elementares são recebidas, por vezes de um colega, de um Professor, ou obtidas recorrendo à pesquisa na Internet. Com a familiarização, o utilizador exige mais do Software que usa e de si próprio: um manual passa a ser um recurso de grande utilidade. A confiança conquistada gera, periodicamente, a necessidade de auto-exame e de aumento do âmbito do conhecimento. Desta forma, quem utiliza computadores acaba por ser confrontado com uma tarefa que, efectivamente, pode ser considerada ou requer programação. Põe-se uma questão no imediato (se ninguém decidiu por si) que é a da selecção da linguagem de programação. A abordagem multiparadigma e longa experiência de utilização do C++ tornam-no atractivo para aplicações onde a eficiência se combina com a disponibilidade de estruturas de dados e algoritmos adoptados pela indústria (o que coloquialmente se denomina STL, Standard Template Library, cf. [#breymann, #josuttis], mais geralmente biblioteca Standard). Adicionalmente, linguagens populares como o Java, C# e PHP possuem sintaxes inspiradas e em muitas partes coincidentes com as do C e C++. Por exemplo, um ciclo “for” em Java é parcialmente coincidente com o do C99, que é um sub-conjunto do “for” do C++. São os pormenores, a eficiência e as capacidades do C++ que permitem a criação de software Profissional. Todos os sistemas operativos clássicos (Unix, Microsoft Windows, Linux) dispõem de compiladores, IDE, bibliotecas e são em grande parte construídos recorrendo a C e C++. Relativamente a outras linguagens, a quantidade de ferramentas disponível e o conhecimento adquirido durante décadas é difícil de ignorar. Esse conhecimento faz com que a sintaxe do C++ pareça muito maior do que o estritamente necessário e afaste potenciais interessados. A longa evolução do C++ introduziu também uma diferença no estilo muito marcada. Código dos anos 80 e 90 do século XX é frequentemente menos legível do que o que correntemente se produz. Muitos tutoriais disponíveis online fazem parecer a linguagem menos rigorosa (e mais complexa) do que na realidade é, já que raramente é apresentado o caso geral da sintaxe. Constata-se que muitos autores ainda usam os cabeçalhos do C, quando já não são necessários. Scott Meyers afirma que o C++ é uma federação de linguagens [#scottmeyers] e por esse facto requer perspectivas de abordagem distintas de outras linguagens. Sem alguma sistematização é difícil apreciar a sua compacidade e coerência. Porém, a forma harmoniosa como as componentes sintácticas se encaixam é uma grande mais-valia do C++ só constatada com experimentação e leitura atenta. A presente monografia dirige-se a quem pretenda utilizar o C++ como ferramenta profissional de Software. Em termos de pré-requisitos Académicos, dir-se-á que um curso (1º Ciclo) de Ciência ou de Engenharia aumentará o interesse por certos aspectos mais técnicos da linguagem mas qualquer indivíduo com gosto pela experimentação tirará proveito do conteúdo. Este texto não busca a exaustividade enciclopédica na cobertura do tema. Neste texto forneço, de forma directa, uma introdução ao C++ a qual permite começar a produzir código sem os custos da dispersão de fontes e notações na recolha de informação. Antecipo assim a sua utilização nos Países de Língua Portuguesa, uma vez que os textos que encontrei são ora mais exigentes ora menos completos, frequentemente ambos.

Preservação e índice de qualidade do látex concentrado.

1974