新型高岭土在发动机火焰筒表面涂层上应用

某型发动机的火焰筒表面采用高温陶瓷涂层防护.该涂层用添加少量高岭土的玻璃料熔烧而成.由于批量生产时曾出现涂层与金属基体结合强度以及涂层耐酸性降低的问题,追溯工艺流程,发现高岭土原料存在问题.实际上,由于原料不合格导致的涂层质量问题在工艺试制时也偶有发生,但以前主要关注主料玻璃料,较少关注辅料高岭土的问题.本文对涂层的制备工艺及高岭土的作用进行了分析,针对原高岭土存在的问题以及新型高岭土的试用效果,探讨了选用新型高岭土的依据,力图解决当前发动机火焰筒陶瓷涂层的质量控制和提高新机火焰筒组件的性能等问题.……

钢基身管内镀铬层下的激光淬火基体界面腐蚀与铬层剥落

钢基身管镀铬层在高温腐蚀性气体中服役,采用YAG激光器对身管内表面作螺旋线状离散淬火预处理后再电镀铬的复合工艺,形成了基体界面呈激光淬火区/激光未处理区周期性变化的铬层/基体结构.对该身管进行高温腐蚀介质为火药气体的靶场实验.对实验后的基体界面腐蚀形貌与铬层剥落的关系研究表明:次界面裂纹的形成是基体界面高温气体腐蚀的根本原因,基体界面腐蚀的结果是形成基体烧蚀坑,烧蚀坑上的铬层以断裂形式剥落.激光淬火预处理钢基体通过抑制次界面裂纹的形成避免了基体界面高温气体腐蚀损伤,提高了铬层的抗剥落能力.

Elastodynamic erosion of thermal barrier coatings

The finite element method is used to analyze the elastodynamic response of a columnar thermal barrier coating due to normal impact and oblique impact by an erosive particle. An assessment is made of the erosion by crack growth from preexisting flaws at the edge of each column: it is demonstrated that particle impacts can be sufficiently severe to give rise to columnar cracking. First, the transient stress state induced by the normal impact of a circular cylinder or a sphere is calculated in order to assess whether a 2D calculation adequately captures the more realistic 3D behavior. It is found that the transient stress states for the plane strain and axisymmetric models are similar. The sensitivity of response to particle diameter and to impact velocity is determined for both the cylinder and the sphere. Second, the transient stress state is explored for 2D oblique impact by a circular cylindrical particle and by an angular cylindrical particle. The sensitivity of transient tensile stress within the columns to particle shape (circular and angular), impact angle, impact location, orientation of the angular particle, and to the level of friction is explored in turn. The paper concludes with an evaluation of the effect of inclining the thermal barrier coating columns upon their erosion resistance. © 2011 The American Ceramic Society.

FeAl层对钢基铝镀层陶瓷化的影响

热浸镀铝钢材在铝铁界面处易产成FeAl冶金结合层。本文就FeAl层对铝镀层等离子体电解氧化(PEO)陶瓷层的表面形貌、截面组织、相结构和元素分布的影响进行了研究。结果表明:由于FeAl参与,PEO陶瓷层局部区域出现了50μm～80μm的贯穿性孔洞,在孔洞/FeAl界面处出现了许多微观裂纹。EDS结果显示孔洞周围的Fe、Na元素含量增高了近8倍。陶瓷层主要由γ-Al_2O_3、莫来石相、α-Al_2O_3和Fe_3O_4相组成。与FeAl层相比,PEO陶瓷层具有较高的硬度和塑性变形能力。

Growth Mechanism And Corrosion Behavior Of Ceramic Coatings On Aluminum Produced By Autocontrol Ac Pulse Peo

Ceramic coatings are produced on aluminum alloy by autocontrol AC pulse Plasma Electrolytic Oxidation (PEO) with stabilized average current. Transient signal gathering system is used to study the current, voltage, and the transient wave during the PEO process. SEM, OM, XRD and EDS are used to study the coatings evolution of morphologies, composition and structure. TEM is used to study the micro profile of the outer looser layer and inner compact layer. Polarization test is used to study the corrosion property of PEO coatings in NaCl solution. According to the test results, AC pulse PEO process can be divided into four stages with different aspects of discharge phenomena, voltage and current. The growth mechanism of AC PEO coating is characterized as anodic reaction and discharge sintering effect. PEO coating can increase the corrosion resistance of aluminum alloy by one order or two; however, too long process time is not necessarily needed to increase the corrosion resistance. In condition of this paper, PEO coating at 60 min is the most protective coating for aluminum alloy substrate. (C) 2008 Elsevier B.V. All fights reserved.

Interface Fracture Property Of Peo Ceramic Coatings On Aluminum Alloy

This paper combines the four-point bending test, SEM and finite element method to study the interface fracture property of PEO coatings on aluminum alloy. The interface failure mode of the coating on the compression side is revealed. The ceramic coating crack firstly along the 45 degrees to the interface, then the micro crack in the coating deduces the interface crack. The plastic deformation observed by SEM shows excellent adhesion property between the coating and substrate. The plastic deformation in the substrate is due to the interfacial crack extension, so the interface crack mode of PEO coatings is ductile crack. The results of FEM show that the compression strength is about 600 MPa. (C) 2008 Elsevier B.V. All rights reserved.

热浸铝钢等离子体电解氧化陶瓷层的微观力学特性

采用纳米压入方法表征了热浸镀铝钢表面由Al_2O_3层、Al层和FeAl层组成的复合涂层的纳米硬度、弹性模量及断裂韧性等微观力学性能,采用扫描电镜(SEM)观察了纳米压痕形貌,并分析了孔洞对陶瓷层的纳米压入行为和压痕裂纹扩展的影响.结果表明:等离子体电解氧化(PEO)陶瓷层中包含许多微米和亚微米尺度的细小孔洞,陶瓷层弹性模量约为226.4 GPa,纳米硬度约为19.6 GPa.当纳米压入深度为250 nm时,所测得陶瓷层的力学参数分散性较大.与FeAl层比较,PEO陶瓷层具有较高的裂纹扩展阻力.FeAl层纳米压痕顶端产生了沿直线扩展的径向裂纹;而陶瓷层纳米压痕中除径向裂纹外出现了侧边裂纹.

Structure and mechanical properties of ceramic coatings fabricated by plasma electrolytic oxidation on aluminized steel

Ceramic coatings were formed by plasma electrolytic oxidation (PEO) on aluminized steel. Characteristics of the average anodic voltages versus treatment time were observed during the PEO process. The micrographs, compositions and mechanical properties of ceramic coatings were investigated. The results show that the anodic voltage profile for processing of aluminized steel is similar to that for processing bulk Al alloy during early PEO stages and that the thickness of ceramic coating increases approximately linearly with the Al layer consumption. Once the Al layer is completely transformed, the FeAl intermetallic layer begins to participate in the PEO process. At this point, the anodic voltage of aluminized steel descends, and the thickness of ceramic coating grows more slowly. At the same time, some micro-cracks are observed at the Al2O3/FeAl interface. The final ceramic coating mainly consists of gamma-Al2O3, mullite, and alpha-Al2O3 phases. PEO ceramic coatings have excellent elastic recovery and high load supporting performance. Nanohardness of ceramic coating reaches about 19.6 GPa. (c) 2007 Elsevier B. V. All rights reserved.

Small scale, grain size and substrate effects in nano-indentation experiment of film-substrate systems

The mechanical properties of film-substrate systems have been investigated through nano-indentation experiments in our former paper (Chen, S.H., Liu, L., Wang, T.C., 2005. Investigation of the mechanical properties of thin films by nano-indentation, considering the effects of thickness and different coating-substrate combinations. Surf. Coat. Technol., 191, 25-32), in which Al-Glass with three different film thicknesses are adopted and it is found that the relation between the hardness H and normalized indentation depth h/t, where t denotes the film thickness, exhibits three different regimes: (i) the hardness decreases obviously with increasing indentation depth; (ii) then, the hardness keeps an almost constant value in the range of 0.1-0.7 of the normalized indentation depth h/t; (iii) after that, the hardness increases with increasing indentation depth. In this paper, the indentation image is further investigated and finite element method is used to analyze the nano-indentation phenomena with both classical plasticity and strain gradient plasticity theories. Not only the case with an ideal sharp indenter tip but also that with a round one is considered in both theories. Finally, we find that the classical plasticity theory can not predict the experimental results, even considering the indenter tip curvature. However, the strain gradient plasticity theory can describe the experimental data very well not only at a shallow indentation depth but also at a deep depth. Strain gradient and substrate effects are proved to coexist in film-substrate nano-indentation experiments. (c) 2006 Elsevier Ltd. All rights reserved.

测量镀铬层界面韧性的激光屈曲法

为了测量强界面电镀铬层的界面韧性，利用连续CO_2激光器对钢基体上的电镀铬层表面进行循环扫描实验。结果表明：该种加热方式能够诱发铬层沿激光扫描方向呈周期性分布的屈曲变形。在此基础上，结合涂层屈曲变形理论，提出测量镀铬层界面韧性的激光屈曲法。该方法只需对一个屈曲单元的最大屈曲高度和屈曲半长进行测量，就可给出界面韧性。作为应用举例，利用该方法对上述镀铬层／钢基体结构界面韧性进行了测量。

脆性涂层/韧性基体材料在拉伸应变作用下的开裂行为

提出一种在脆性涂层/韧性基体材料中含弹塑性界面层的剪滞模型.研究脆性涂层/韧性基体材料在拉伸应变作用下,其表面脆性涂层的开裂行为特征,探讨涂层内正应力、界面切应力、涂层的裂纹密度与涂层几何、力学等参数之间的内在联系,获得了涂层内正应力、界面切应力和(饱和)裂纹密度的解析表达式.最后利用这些参量及其间的内在联系,以工程实际中的脆性Cr涂层/韧性钢基体材料为研究对象,研究该种材料在拉伸过程中出现的断裂行为特征.研究结果表明,该材料在拉伸应变作用下出现的饱和裂纹密度与理论结果预测值符合较好.

钢基铝镀层转化为陶瓷层的演变规律研究

热浸镀铝钢经等离子体电解氧化（Plasma Electrolytic Oxidation,PEO）处理后,表面铝镀层转化为陶瓷层.实验对阳极电压变化、陶瓷层生长规律、涂层截面形貌和成分等进行了研究.结果表明：在PEO初期,热浸铝试件的阳极电压变化趋势与纯铝试件相同,在PEO后期电压有下降趋势.铝镀层消耗和陶瓷层厚度增长近似为线性变化.当铝镀层完全陶瓷化后,FeAl层参与PEO反应,但陶瓷层生长速率变慢,在界面处出现大量裂纹;陶瓷层主要成分为Al、Si、O元素,相结构主要为γ-Al_2O_3与莫来石相,在PEO后期出现α-Al_2O_3相.复合陶瓷层硬度呈区域性分布,陶瓷层最高硬度可达HV1800.

铝合金表面等离子体电解氧化陶瓷涂层在NaCl溶液中的电化学阻抗谱研究

通过调整电解液中硅酸钠的浓度，利用等离子体电解氧化（PEO）技术在铝合金LY12表面制备了各种陶瓷涂层，利用光学显微镜、XRD、电化学阻抗谱（EIS）对涂层的形貌、成分和涂层在NaCl溶液中耐腐蚀性能进行了研究．结果表明：提高电解液中硅酸钠的浓度可以使得涂层的总厚度增加，但过高或过低的浓度都会导致致密层厚度的减薄．当浓度为20g／L时，所制备的涂层的成分以氧化铝为主；当浓度为40g／L时，涂层的成分主要是莫来石和氧化铝；当浓度超过60g／L时，涂层的成分主要为非晶相．EIS的研究表明，涂层耐腐蚀性取决于涂层中的致密层，增加致密层的厚度可以提高PEO涂层的耐腐蚀性，在中性、酸性、碱性腐蚀介质中，PEO涂层都显示出对基体良好的保护作用．

热浸铝钢等离子体电解氧化陶瓷层的微观力学特性

采用纳米压入方法表征了热浸镀铝钢表面由Al2O3层、Al层和FeAl层组成的复合涂层的纳米硬度、弹性模量及断裂韧性等微观力学性能，采用扫描电镜（SEM）观察了纳米压痕形貌，并分析了孔洞对陶瓷层的纳米压入行为和压痕裂纹扩展的影响．结果表明：等离子体电解氧化（PEO）陶瓷层中包含许多微米和亚微米尺度的细小孔洞，陶瓷层弹性模量约为226．4 GPa，纳米硬度约为19．6 GPa．当纳米压入深度为250nm时，所测得陶瓷层的力学参数分散性较大．与FeAl层比较，PEO陶瓷层具有较高的裂纹扩展阻力．FeAl层纳米压痕顶端产生了沿直线扩展的径向裂纹；而陶瓷层纳米压痕中除径向裂纹外出现了侧边裂纹．

热喷涂构件中残余应力的理论分析

本文发展一种新的分析涂层结构（平板、梁）热残余应力的模型，可以研究骤冷过程（Quenching）和冷却过程（Cooling）在涂层结构内引发的残余应力分布。与以往模型相比，其优势在于：它可以考虑源于喷涂过程的涂层孔隙率、温度梯度等因素对于涂层和基底内残余应力的影响。其中孔隙率和温度分布由计算机模拟涂层沉积过程得到。另外，当基底的材料和几何参数被固定时，我们分析了诸如涂层的理想模量、厚度、热膨胀系数等参数，对于涂层结构中最终残余应力分布的改变机理。