Synthesis of M2AC (M = Ti, V, Cr, Nb, Zr, A = Al, Sn, S) (MAX) carbide phases and study of their physical behavior under extreme conditions

Materials known as Mn+1AXn phases, where n is 1, 2, or 3, and M represents an early transition metal, A an A-group element, and X is either Carbon and/or Nitrogen [1], are fast becoming technologically important materials due to the interesting combination of unique properties. However, a lot of important information about the high temperature and high pressure behavior of many of these compounds is still missing, which needs to be determined systematically. ^ In this dissertation the synthesis of M2AC (M = Ti, V, Cr, Nb, Zr) and A = (Al, Sn, S) compounds by arc melting, vacuum sintering and piston cylinder synthesis is presented along with the synthesis of Zr 2SC, which has been synthesized for first time in bulk form, by piston cylinder technique. The microstructural analysis by electron microscopy and phase analysis by x-ray diffraction is presented next. Finally, a critical analysis of the behavior of these compounds under the application of extreme pressure (as high as 50 GPa) and temperature (≈ 1000°C) is presented. ^ The high pressure studies, up to 50 GPa, showed that these compounds were structurally intact and their bulk moduli ranged from 140 to 190 GPa. The high temperature studies in the inert atmosphere showed that the M 2SnC compounds were unstable above 650°C and the expansion along the a-axis was higher than that along the c-axis, unlike the other phases. M2SC compounds on the other hand showed negligible difference in the thermal expansion along the two axes. The oxidation study revealed that Ti2AC (Al, S) compounds had highest resistance to oxidation while the M2SnC compounds had the least. Furthermore, from the oxidation study of these compounds, which were short time oxidation experiments, it was found that all of these compounds oxidized to their respective binary oxides. ^

High pressure studies on group VI metal hexacarbonyl molecular solids

Group VI metal hexacarbonyls, M(CO)6 (M = Cr, Mo and W), are of extreme importance as catalysts in industry and also of fundamental interest due to the established charge transfer mechanism between the carbon monoxide and the metal. They condense to molecular solids at ambient conditions retaining the octahedral (Oh) symmetry of gas phase and have been extensively investigated by previous workers to understand their fundamental chemical bonding and possible industrial applications. However little is known about their behavior at high pressures which is the focus of this dissertation. Metal hexacarbonyls were subjected to high pressures in Diamond-Anvil cells to understand the pressure effect on chemical bonding using Raman scattering in situ. The high-pressure results on each of the three metal hexacarbonyls are presented and are followed by a critical analysis of the entire family. The Raman study was conducted at pressures up to 45 GPa and X-ray up to 58 GPa. This is followed by a discussion on infra red spectra in conjunction with Raman and X-ray analysis to provide a rationale for polymerization. Finally the probable synthesis of extremely reactive species under high-pressures and as identified via Raman is discussed. The high-pressure Raman scattering, up to 30 GPa, demonstrated the absence of Π-backbonding. The disappearance of parental Raman spectra for (M = Cr, Mo and W) at 29.6, 23.3 and 22.2 GPa respectively was attributed to the total collapse of the Oh symmetry. This collapse under high-pressure lead to metal-mediated polymeric phase characterized by Raman active δ(OCO) feature, originating from intermolecular vibrational coupling in the parent sample. Further increase in pressures up to 45 GPa, did not affect this feature. The pressure quenched Raman spectra, revealed various chemical groups non-characteristic of the parent sample and adsorption of CO in addition to the characteristic δ(OCO) feature. The thus recorded Raman, complemented with the far and mid-infrared pressure quenched spectra, reveal the formation of novel metal-mediated polymers. The X-ray diffraction on W(CO)6 up to 58 GPa revealed the generation of amorphous polymeric pattern which was retained back to ambient conditions.

Tom Stoppard: Humanizing chaos

The purpose of this study was to critically evaluate Tom Stoppard’s application of chaos theory and quantum science in ROSENCRANTZ AND GUILDENSTERN ARE DEAD, HAPGOOD and ARCADIA; and determine the extent to which Stoppard argues for the importance of human action and choice. ^ Through critical analysis this study examined how Stoppard applies the quantum aspects of: (1) indeterminacy to human epistemology in ROSENCRANTZ AND GUILDENSTERN ARE DEAD; (2) complementarity to human identity in HAPGOOD; and (3) recursive symmetry to human history in ARCADIA. It also examined how Stoppard excavates the complexities of human action, choice and identity through the lens of chaos theory and quantum science. ^ These findings demonstrated that Tom Stoppard is not merely juxtaposing quantum science and human interactions for the sake of drama; rather, by excavating the complexities of human action, choice and identity through the lens of chaos theory and quantum science, Stoppard demonstrates the fundamental connection between individuals and the post-Newtonian universe.^

The Use of Foucault in the Creation of Educational History: A Review of Literature

This research creates a literature review. It investigates the viability of a using Foucauldian critical analysis in creating an educational history. It examines historical methods in education and Foucauldian theory looking for commonalities and offers suggestions on the usage of Foucault in creating history in education.

Oman's foreign policy: Foundations and practice

The object of this dissertation is to record and analyze the foreign policy of the Sultanate of Oman from the early twentieth century until 2004. It challenges the central assumption of the contemporary scholarship on the subject that Muscat's modern foreign policy begins in 1970. It is often presumed that the pre-1970 era does not merit a thorough investigation to understand Muscat's modus operandi today. This study argues that for a comprehensive understanding of Muscat's foreign policy since 1970, the frontier of the historical analysis of Oman's regional and international involvement should be pushed back to the 1930's, when the young Sultan Said assumed power over the country divided by the "Treaty" or the "Agreement" of Sib. Indeed, the thrust of this research lies at once in repudiating the conventional wisdom regarding both the persona of Sultan Said and the customary political/historical narrative of Said's reign. The critical analysis of this period is utilized to rebut the pervasive and largely inaccurate historical narrative of the events prior to 1970, to recount an original interpretation of the period, and to use the narrative as a preamble for subsequent foreign policy directions and initiatives. Furthermore, this dissertation covers the gaps in the literature resulting from the absence of any materials that either record or analyze Muscat's foreign policy from 1996 until 2004. In addition, his study provides new information and a fresh analysis of the international relations of the region, including great power rivalry, especially the competition between the United States and Great Britain, and the attitudes of major regional actors, such as Iran, Saudi Arabia, and Iraq. ^ The use of a thorough historical inquiry is vital to support the central claim of this dissertation; therefore, a large section of this dissertation is based almost exclusively on archival materials collected from the British Public Records Office, the University of Oxford and the Library of Congress. This project represents the most comprehensive use of archival materials on the subject matter to date. ^

Oman's foreign policy : foundations and practice

The object of this dissertation is to record and analyze the foreign policy of the Sultanate of Oman from the early twentieth century until 2004. It challenges the central assumption of the contemporary scholarship on the subject that Muscat's modern foreign policy begins in 1970. It is often presumed that the pre-1970 era does not merit a thorough investigation to understand Muscat's modus operandi today. This study argues that for a comprehensive understanding of Muscat's foreign policy since 1970, the frontier of the historical analysis of Oman's regional and international involvement should be pushed back to the 1930's, when the young Sultan Said assumed power over the country divided by the "Treaty" or the "Agreement" of Sib. Indeed, the thrust of this research lies at once in repudiating the conventional wisdom regarding both the persona of Sultan Said and the customary political/historical narrative of Said's reign. The critical analysis of this period is utilized to rebut the pervasive and largely inaccurate historical narrative of the events prior to 1970, to recount an original interpretation of the period, and to use the narrative as a preamble for subsequent foreign policy directions and initiatives. Furthermore, this dissertation covers the gaps in the literature resulting from the absence of any materials that either record or analyze Muscat's foreign policy from 1996 until 2004. In addition, his study provides new information and a fresh analysis of the international relations of the region, including great power rivalry, especially the competition between the United States and Great Britain, and the attitudes of major regional actors, such as Iran, Saudi Arabia, and Iraq. The use of a thorough historical inquiry is vital to support the central claim of this dissertation; therefore, a large section of this dissertation is based almost exclusively on archival materials collected from the British Public Records Office, the University of Oxford and the Library of Congress. This project represents the most comprehensive use of archival materials on the subject matter to date.

Violência contra mulher: expressões da opressão às mulheres sob a égide do capitalismo e do patriarcado

This dissertation is the result of a research process that sought , from the speech of women in situations of violence , examine the difficulties these women to access the "network " of assistance to women victims of violence in the city of Natal/RN . Therefore , we made a critical analysis from the perspective of totality on the processual ontological " being a woman " and " be a man " , articulating the determinations of the subjective and objective dimensions in the lives of women at this juncture . Thus , also reflecting on the system of oppression of women through Capitalism / Patriarchate , articulated with other determinations of reality , as race / ethnicity , sexual orientation , generation and territoriality . Because of the oppression of women in all aspects of social life , the feminist movement led to the public domain claims against the oppressions of women and fight for Public Social Policies that aim to the particularities of women , among them, the social policies of coping violence against women . The speeches of the women interviewed show the contradictory aspect of work in women's lives . On the one hand , can become a means to financial independence ( with the possibility of exit from violent means). On the other , it can become "cause " of justification for the exercise of violence against women by their partners or former partners . Also show that despite legal advances , there is no effective implementation of policies aimed at women . This occurs as a result of capitalism / patriarchy and the context of neoliberal management of big capital . Thus , the feminist movement , as well as the social movement of the working class , must seek the empowerment of women through the struggle to end all forms of oppression , exploitation and domination among humans.

Um olhar crítico sobre a individualização da curva de compensação em prótese total

Objetivo: Buscar na literatura evidências científicas que suportem os benefícios da individualização da curva de compensação em prótese total, pela técnica do desgaste de Paterson, em relação à curva de compensação não individualizada. Metodologia: Realizou-se, em Dezembro de 2009, uma revisão sistemática da literatura nas bases de dados MEDLINE, LILACS e BBO com os termos “prótese total” e “oclusão”. Para abranger uma maior quantidade de dados, realizou-se uma busca manual através das referências dos artigos inicialmente selecionados. Resultados: Obteve-se 1273 referências na base dados MEDLINE, 64 na LILACS e 103 na BBO, num total de 1440 referências. Dessas, apenas 24 tratavam do assunto “curva de compensação”, as quais somaram-se mais 13 artigos selecionados manualmente. Conclusão: A partir dos resultados obtidos, conclui-se que não existem dados suficientes que comprovem clinicamente os benefícios da individualização da curva de compensação em relação às próteses totais com curva de compensação não individualizada. Ensaios clínicos controlados e randomizados são necessários para que se possa determinar qual o procedimento mais adequado.

Um olhar crítico sobre a individualização da curva de compensação em prótese total

Objetivo: Buscar na literatura evidências científicas que suportem os benefícios da individualização da curva de compensação em prótese total, pela técnica do desgaste de Paterson, em relação à curva de compensação não individualizada. Metodologia: Realizou-se, em Dezembro de 2009, uma revisão sistemática da literatura nas bases de dados MEDLINE, LILACS e BBO com os termos “prótese total” e “oclusão”. Para abranger uma maior quantidade de dados, realizou-se uma busca manual através das referências dos artigos inicialmente selecionados. Resultados: Obteve-se 1273 referências na base dados MEDLINE, 64 na LILACS e 103 na BBO, num total de 1440 referências. Dessas, apenas 24 tratavam do assunto “curva de compensação”, as quais somaram-se mais 13 artigos selecionados manualmente. Conclusão: A partir dos resultados obtidos, conclui-se que não existem dados suficientes que comprovem clinicamente os benefícios da individualização da curva de compensação em relação às próteses totais com curva de compensação não individualizada. Ensaios clínicos controlados e randomizados são necessários para que se possa determinar qual o procedimento mais adequado.

Implementação das diretrizes operacionais para a educação básica nas escolas do campo: embates e limitações do trabalho docente no Rio Grande do Norte

Considering the situation of neglect existing in Brazilian public education and, specially, in the process of rural schooling, this dissertation aims to analyze the process of implementation of the Operational Guidelines for Basic Education in Rural Schools (DOEBEC), regulatory framework of the national policy of rural education. On it, we analyze the conditions of teaching work in rural schools of Rio Grande do Norte (RN), in 2010. The sample of the survey has as reference the representativeness of the chosen universe in relation to the totality of rural schools belonging to the state of RN. To answer the goals of the research, we opted to present a critical analysis of the following points: 1) Implementation of the DOEBEC; 2) Conditions of teaching work and teaching training. The points or categories of research were chosen based in the determinations of the DOEBEC (Resolution CNE/CEB n. 01/2002). For the data collection in the referred schools, we opted for the realization of interviews with the teachers and managers of these teaching establishments, in 2010. It was also utilized, for the characterization of school attendance in rural schools of RN, in 2010, official statistical data available by the State Secretary of Education and Culture (SEEC/RN). The analysis of the statistical data and of the primary data collected in field research indicated that the conditions of teaching work are still an obstacle to the development of the educative work of the teacher in rural areas. According to interviews with the participants of the research, we realized that the DOEBEC, despite being sanctioned in 2002, were still dimly known and discussed by the interviewees of the referred schools in 2010. Thus, we propose that the implementation of the policy of rural education in RN, instituted by DOEBEC’s legal landmark, and reaffirmed by the Rio Grande do Norte’s Charter to Rural Education (Brazil, 2005), is rethought and reconsidered, in the sense of ensuring that the changes proposed in this legal text, inherent to the school functioning, to the conditions of teaching work, to the rural schools’ management, to the remuneration and valorization of teaching work, to the teaching training, to the conditions of school transport, among others, be turned into concrete actions to improve the quality of education offered in the rural schools of RN state.

Implementação das diretrizes operacionais para a educação básica nas escolas do campo: embates e limitações do trabalho docente no Rio Grande do Norte

Considering the situation of neglect existing in Brazilian public education and, specially, in the process of rural schooling, this dissertation aims to analyze the process of implementation of the Operational Guidelines for Basic Education in Rural Schools (DOEBEC), regulatory framework of the national policy of rural education. On it, we analyze the conditions of teaching work in rural schools of Rio Grande do Norte (RN), in 2010. The sample of the survey has as reference the representativeness of the chosen universe in relation to the totality of rural schools belonging to the state of RN. To answer the goals of the research, we opted to present a critical analysis of the following points: 1) Implementation of the DOEBEC; 2) Conditions of teaching work and teaching training. The points or categories of research were chosen based in the determinations of the DOEBEC (Resolution CNE/CEB n. 01/2002). For the data collection in the referred schools, we opted for the realization of interviews with the teachers and managers of these teaching establishments, in 2010. It was also utilized, for the characterization of school attendance in rural schools of RN, in 2010, official statistical data available by the State Secretary of Education and Culture (SEEC/RN). The analysis of the statistical data and of the primary data collected in field research indicated that the conditions of teaching work are still an obstacle to the development of the educative work of the teacher in rural areas. According to interviews with the participants of the research, we realized that the DOEBEC, despite being sanctioned in 2002, were still dimly known and discussed by the interviewees of the referred schools in 2010. Thus, we propose that the implementation of the policy of rural education in RN, instituted by DOEBEC’s legal landmark, and reaffirmed by the Rio Grande do Norte’s Charter to Rural Education (Brazil, 2005), is rethought and reconsidered, in the sense of ensuring that the changes proposed in this legal text, inherent to the school functioning, to the conditions of teaching work, to the rural schools’ management, to the remuneration and valorization of teaching work, to the teaching training, to the conditions of school transport, among others, be turned into concrete actions to improve the quality of education offered in the rural schools of RN state.

DESENVOLVIMENTO E JUSTIÇA NA MISSÃO INTEGRAL: UMA ANÁLISE CRÍTICA DA PRESENÇA DA TEOLOGIA E PRÁXIS DA MISSÃO INTEGRAL NO SOLO PAULISTANO - Estudo da PIBSP.

No presente estudo sobre o tema: “Desenvolvimento e Justiça na Missão Integral: Uma análise crítica da presença da Teologia e Práxis da Missão Integral no Solo Paulistano” procura-se analisar a presença do conceito de desenvolvimento e justiça da Missão Integral no solo paulistano. Para tal análise tomou-se como sujeito de pesquisa a Primeira Igreja Batista de São Paulo. Esta dissertação foi desenvolvida no Programa de Pós- Graduação em Ciências da Religião, e pertence à linha de pesquisa “Religião, Sociedade e Cultura”. A metodologia adotada na coleta de dados foi de uma revisão bibliográfica e pesquisa de campo por meio de um roteiro de entrevista. Os questionamentos que nortearam a pesquisa foram: O que é desenvolvimento e Justiça na Missão Integral? É possível notar a presença desses conceitos na práxis e na teologia da Primeira Igreja Batista de São Paulo? Após uma análise da Missão Integral e da Igreja pesquisada, foi possível verificar as aproximações e distanciamentos, assim como hipóteses que justificassem esses fatos. No primeiro capítulo foi apresentada a Missão Integral, sua história, teologia e método. No segundo capítulo os conceitos de desenvolvimento e justiça foram trabalhados. O último capítulo apresentou a Primeira Igreja Batista de São Paulo; buscou estabelecer diálogo entre o conceito de Desenvolvimento e Justiça da Missão Integral e a teologia e práxis da Primeira Igreja Batista de São Paulo.

A concepção de trabalho escolar a partir de Maurício Tragtenberg: fios e tramas de debate na (des)politização dos sujeitos sociais

This thesis, part of the research line "Work, Society and Education" analyzes, in a dialectical perspective, in the light of Tragtenberg´s studies, the conception of subject of schoolwork, considering the organization and the complexity of this context and inviting the investigative gaze. Our hypothesis is that the workers of education have, in the schoolwork, a fragile politicization field and overcoming the installed model, accepting themselves as executers with self-organizing difficulties, distanced from the effective participation, autonomy and self-management. We consider studies on the logic of the work, believing that the understanding of schoolwork is constitute into the current societal model, in whom its bureaucratic and hierarchical matrix, linked to articulated / articulators of the dominant socio-economic class interests. Scholars such as Braverman, Frigotto and Tragtenberg, among others, are important contributions to this reflection. We have analyzed the logic of the work also in dialogue with pedagogies differentiated, among them, the Libertarian defended by Tragtenberg, aiming to understand the conceptions and practices of the subjects involved. We accomplished a bibliographical critical analysis, in a dialectical character, focusing on the categories: work, schoolwork, control, autonomy and self-management, in order to understand the complexity of the praxis in study, dialoguing with the pillars categories historicity, contradiction and totality, which transversalize the developed analysis. The consideration of these concepts allows us to uncover the dominant bureaucratic structure and its possible overcoming fields. We believe contribute to problematizing and proposers studies, reflections and discussions, strengthening debates, deconstructing naturalizations and contributing to the political process of the subjects.

Ecotranslation applied: Two Spanish translations of H. G. Wells "The Country of the Blind"

The birth of the ecological movement in the 1960s motivated the conception of a new branch of Translation Studies known as Ecotranslation. This scarcely known theoretical research framework sets off from two main notions: firstly, the representation of nature in literature and secondly, the importance of the different roles and interpretations that nature can be provided with in literary works. From these bases, the goal of our pilot study was to apply this new nature-centered approach to the translations of H. G. Wells’ short story The Country of the Blind, as rendered into Spanish by Íñigo Jáuregui (2014) and Alfonso Hernández Catá (1919). The acknowledgement that Ecotranslation derives from a general awareness towards nature, considering it as an intrinsic feature of humankind which simultaneously influences and is affected by human behavior, motivated the following analysis of the role that Wells attributed to it in his short story The Country Of The Blind, which evinced a strong correspondence between environment and society in the original text, where nature was shown to be an essential instrument to figuratively reflect social concerns. Setting off from that critical analysis we compared how two chronologically separate translators rendered the natural elements of the original story into a different language, in this case Spanish. In general terms, data confirmed that Jauregi´s translation, published in 2014, encompasses a much more literal approach to the source text, rendering Well´s original terminology into the closest equivalent expressions in Spanish. While Hernández Catá, seems to have focused his work on the idea of human control over nature, even if this decision meant altering the precise way in which Wells articulated his ideas.

Étude sur la prière pour autrui : critiques méthodologiques, épistémologiques et éthiques

Depuis 2000, les études concernant l’efficacité de la prière sur l’amélioration de la santé physique et psychologique des gens pour lesquels on prie se sont multipliées. La consultation de trois banques de données (PsycINFO, Medline, Current Content) a permis de répertorier 189 publications de 1979 à 2007. Outre la méta-analyse de Master, Spielmans et Goodson (2006), nous avons retenu les études qui répondaient aux deux critères suivants: a) la prière pour autrui est utilisée pour traiter un problème de santé physique ou psychologique et b) la présence d’un groupe « de prière » et d’un groupe contrôle. L’analyse des résultats soulève plusieurs questions sur des critères méthodologiques et épistémologiques ainsi que quelques considérations éthiques. Nous discutons en outre de l’éternel antagonisme entre la démarche scientifique et la démarche théologique.