Titanium dioxide based nanomaterials for photocatalytic water treatment

Water treatment using photocatalysis has gained extensive attention in recent years. Photocatalysis is promising technology from green chemistry point of view. The most widely studied and used photocatalyst for decomposition of pollutants in water under ultraviolet irradiation is TiO2 because it is not toxic, relatively cheap and highly active in various reactions. Within this thesis unmodified and modified TiO2 materials (powders and thin films) were prepared. Physico-chemical properties of photocatalytic materials were characterized with UV-visible spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectrometry (XPS), inductively coupled plasma optical emission spectroscopy (ICP-OES), ellipsometry, time-of-flight secondary ion mass spectrometry (ToF-SIMS), Raman spectroscopy, goniometry, diffuse reflectance measurements, thermogravimetric analysis (TGA) and nitrogen adsorption/desorption. Photocatalytic activity of prepared samples in aqueous environment was tested using model compounds such as phenol, formic acid and metazachlor. Also purification of real pulp and paper wastewater effluent was studied. Concentration of chosen pollutants was measured with high pressure liquid chromatography (HPLC). Mineralization and oxidation of organic contaminants were monitored with total organic carbon (TOC) and chemical oxygen demand (COD) analysis. Titanium dioxide powders prepared via sol-gel method and doped with dysprosium and praseodymium were photocatalytically active for decomposition of metazachlor. The highest degradation rate of metazachlor was observed when Pr-TiO2 treated at 450ºC (8h) was used. The photocatalytic LED-based treatment of wastewater effluent from plywood mill using commercially available TiO2 was demonstrated to be promising post-treatment method (72% of COD and 60% of TOC was decreased after 60 min of irradiation). The TiO2 coatings prepared by atomic layer deposition technique on aluminium foam were photocatalytically active for degradation of formic and phenol, however suppression of activity was observed. Photocatalytic activity of TiO2/SiO2 films doped with gold bipyramid-like nanoparticles was about two times higher than reference, which was not the case when gold nanospheres were used.

MULTIPLICAÇÃO E ALONGAMENTO IN VITRO DE CLONES HÍBRIDOS DE Eucalyptus globulus

Os híbridos de Eucalyptus globulus representam uma excelente alternativa para o setor de celulose e papel, em razão dos ganhos em qualidade da madeira para a fabricação de celulose. Entretanto, estes híbridos têm apresentado recalcitrância ao enraizamento adventício. Assim, a micropropagação é apontada como a técnica para o rejuvenescimento desses híbridos adultos, viabilizando a propagação clonal dos mesmos. O presente trabalho avaliou o cultivo in vitro de três clones de Eucalyptus grandis x Eucalyptus globulus e de três clones de Eucalyptus urophylla x Eucalyptus globulus, em relação à multiplicação in vitro, no meio MS suplementado com 0,5 mg L-1 de BAP e 0,01 mg L-1 de ANA, bem como o efeito das concentrações de 0,25; 0,50; 0,75 e 1,0 mg L-1 de AIB e dos meios de cultura MS e JADS no alongamento in vitro das brotações. Os clones diferiram quanto à multiplicação in vitro das brotações e apresentaram uma taxa de multiplicação média dos clones de 3,0 tufos de brotações em cada subcultivo, ao longo dos 25 subcultivos realizados. No alongamento in vitro, os clones diferiram quanto às concentrações de AIB adequadas para provocar o alongamento, bem como em relação aos meios de cultura MS e JADS. O intervalo médio entre 0,40 e 0,80 mg L-1 de AIB proporcionou o maior número e comprimento das brotações alongadas in vitro e com maior vigor.

SUBSTRATOS E TEMPERATURAS PARA TESTE DE GERMINAÇÃO EM SEMENTES DE MYRTACEAE

As espécies brasileiras de Myrtaceae compreendem diversas plantas arbóreas e arbustivas que podem ser utilizadas na produção de frutos para consumo in natura ou para industrialização. Informações sobre avaliação da qualidade de sementes dessas espécies não estão bem definidas, principalmente as relacionadas à adequação do teste de germinação. Objetivou-se testar substratos e temperaturas para realização do teste de germinação em sementes de Acca sellowiana (O. Berg) Burret. (goiaba-serrana), Campomanesia xanthocarpa O. Berg (guabiroba), Eugenia involucrata DC. (cereja-do-mato) e Eugenia pyriformis Camb. (uvaia). Sementes de diferentes procedências foram submetidas ao teste de germinação em substratos areia e rolo de papel tipo germitest, umedecidos com água destilada, e nas temperaturas 15 °C, 25 °C, 30 °C, 35 °C e 20-30 °C, sob luz constante, em germinadores tipo BOD. O delineamento experimental utilizado foi o inteiramente casualizado com quatro repetições de 25 sementes/tratamento/lote/espécie, e as médias dos tratamentos foram comparadas pelo teste de Tukey (P < 0,01). O teste de germinação pode ser conduzido na temperatura de 25 ºC e em substrato rolo de papel para Eugenia involucrata e Eugenia pyriformis. Ambos os substratos podem ser utilizados para o teste de germinação de Acca sellowiana, a 25 ºC. A temperatura de 25 ºC e alternância de 20-30 ºC são indicadas para Campomanesia xanthocarpa, assim como, os substratos areia e rolo de papel.

¿Es Necesario un Nuevo Nombre para el Bibliotecario?

A pesar de que conservamos el nombre arcaico, ligado a la concepción del libro y de la biblioteca como depósito de libros, frente a un acelerado desarrollo que involucro tecnologías y materiales digitales en el manejo de información, es un hecho que en las últimas décadas el prestigio del bibliotecario como erudito y especialista ha cambiado por el de ser un buscador y un proveedor ágil y especializado en la amplia gama de recursos informativos que nos rodea.La tendencia más seguida es que la profesión debe cambiar pasando a enfatizar otras habilidades como la gerencia, puesto que las bibliotecas serán evaluadas por los servicios que ofrecen y no tanto por los acervos que poseen. Sin embargo, que las bibliotecas como tal persisten es un hecho que se comprueba con la famosa Biblioteca de París, que está diseñada en forma de libro precisamente.

Os impactos tecnológicos da implantação da nota fiscal eletrônica: um estudo de casos múltiplos

Increasingly, the Information Technology is used in the society, including the private, public and third sector organizational context. Technological tools are created in order to speed, automate, control and monitor processes. These technologies generate impacts on areas that permeate their use and the objective of this study is to investigate the implementation process of the Eletronic Invoice and the impacts arising from this technological tool in companies. For that, case studies have been conducted in three companies that emit and receive Eletronic Invoice, in a Information System consultancy, that provides softwares of Eletronic Invoice, and in a State Tax Department. Data collection was performed with organizations representatives through electronic questionnaires. The study concludes that it is expected, by the investigated organizations, that the tool reaches the benefits offered by the Tax Administration. However, these benefits have not been identified yet and neither have the use of methodologies in order to identify them. Moreover, the main impact found was the need for better training and participant´s technical qualification, followed by reducing printing costs and paper purchase

Modificações na produtividade e nas características físicas e químicas da madeira de Eucalyptus grandis causadas pela adubação com lodo de esgoto tratado

O Eucalyptus grandis é uma das espécies mais cultivadas no Brasil devido à sua produtividade e qualidade da madeira. Avaliaram-se o efeito da aplicação de lodo de esgoto tratado (0 a 40 t ha-1 base seca) e uma dose de adubo mineral nos atributos físicos e químicos da madeira de Eucalyptus grandis de árvores com cinco anos de idade, no Município de Itatinga, São Paulo, Brasil. O tipo de solo foi caracterizado como Latossolo Vermelho-Amarelo Distrófico (argila = 120 g kg-1 na camada de 0-20 cm) e o clima, como mesotérmico úmido (Cwa), segundo a classificação de Köeppen. O delineamento experimental foi o de blocos ao acaso, com seis tratamentos e quatro repetições. O diâmetro à altura do peito (DAP), a altura das árvores e o volume de madeira foram obtidos em todas as parcelas de oito árvores com DAP na classe de maior freqüência. As caracterizações físicas e químicas da madeira foram realizadas de acordo com as normas da ABTCP, TAPPI e ABNT. O lodo de esgoto diminuiu a densidade básica da madeira, mas não afetou os teores de celulose, lignina, extrativos e o poder calorífico da madeira. O decréscimo de densidade da madeira pela adubação com lodo de esgoto foi compensado pela maior produtividade de madeira.

Prática de ensino supervisionada em pré-escolar e em 1º ciclo do ensino básico: a promoção do livro e da leitura na educação pré-escolar e 1º ciclo do ensino básico

O presente relatório foi elaborado no âmbito da Prática de Ensino Supervisionada em Jardim-de-Infância e 1º Ciclo do Ensino Básico, inserida no Mestrado em Educação Pré-Escolar e Ensino do 1º Ciclo do Ensino Básico. O objetivo geral foi promover o livro e a leitura, procurando contribuir para a formação de leitores com hábitos de leitura frequentes. O tema surgiu pela necessidade de compreender qual o papel do educador/professor na promoção da leitura, tendo em conta que este deve orientar o seu trabalho no sentido de transformar a escola numa comunidade de leitura, na qual o prazer de ler é uma conquista fundamental. Também foi nosso propósito incidir no papel da família, tendo em conta a promoção do livro e da leitura. A Dimensão Investigativa da PES baseou-se na observação participante; nos registos fotográficos; no caderno de formação e na aplicação de dois inquéritos por questionário, um à educadora e professora cooperantes e outro a uma amostra de seis crianças do grupo de pré-escolar, que ingressavam no ano letivo seguinte no 1º ano do 1º CEB. Os resultados mostram que em ambos os contextos, jardim-de-infância e 1º ciclo do ensino básico, existem poucos momentos de leitura de histórias, como também a utilização frequente da área da biblioteca da sala. Através da análise dos inquéritos por questionário às profissionais de educação, verifica-se que ambas mencionam que existe a rotina frequente de leitura de histórias, salientando-se que esses momentos não foram observados durante a minha observação e intervenção. Com a análise dos inquéritos por questionário ao grupo de crianças do pré-escolar, estes consideram o momento de leitura de histórias promovido pela educadora, satisfatório; Abstract: The present report has been prepared in scope of Practice of Supervised Teaching in kindergarten and 1st cycle of basic education, entered in the master’s degree in Pre-School Education and teaching of the first cycle of basic education. The overall objective was to promote the book and reading, seeking to contribute to the formation of readers with frequent reading habits. The theme came about by the need to understand what the role of the educator/teacher in promoting reading, given that this must orient their work in order to transform the school into a community of reading, in which the pleasure of reading is a fundamental achievement. It was also our purpose focus on the role of the family, taking into account the promotion of books and reading. The Research Dimension of the PES was based on participant observation; photographic records; in the formation and implementation of two surveys, one educator and cooperating teacher and another a sample of six children of the preschool group, which entered the school year following the first year of the 1st CEB. The results show that in both contexts, kindergarten and 1st cycle of basic education, there are few moments of reading stories, as well as the frequent use of the library area of the room. Through the analysis of surveys to education professionals, it turns out that both mention that there is the routine of reading stories, stressing that those moments were not observed during my observation and intervention. With the analysis of the surveys to the Group of children from preschool, they consider the moment of reading stories promoted by the educator, satisfactory.

Domestic Rhodnius ecuadoriensis (Hemiptera, Reduviidae) infestation in Northern Peru: a comparative trial of detection methods during a six-month follow-up

Two passive methods in the assessment of intradomiciliary infestation by Rhodnius ecuadoriensis were tested: (i) the Gomes Nuñez sensor box (GN), (ii) sheets of white typing paper and (iii) one active timed manual method. The study was carried out in the Alto Chicama River Valley, Province of Gran Chimú, Department of La Libertad. The study design consisted of an initial searching of triatomines inside of the domestic environment by the manual capture active procedure (man/hour) covering all the studied houses. Then, matched pairs of GN boxes and paper sheets were simultaneously installed in the bedrooms of 207 households distributed in 19 localities. A comparative prospective trial of these passive detection devices were monitored at 2, 4 and, finally 6 months follow-up. Parasitological Trypanosoma rangeli and/or T. cruzi infections were investigated in two houses with high level of infestation by R. ecuadoriensis.16.9% of the 207 households investigated by an initial active manual method were infested with R. ecuadoriensis. The proportion of infested houses fluctuated from 6.2 to 55.5% amongst the 19 localities investigated. T. rangeli natural infection was detected in R.ecuadoriensis specimens collected in two households. Parasite rates in the bugs ranged from 16.6 to 21.7% respectively. The most striking fact was an average rate of salivary gland infection ranging from 7.4 to 8.3%. At the end of the sixth month period, a cumulative incidence of 31.4% of positive GN boxes against 15.9% for paper sheets was recorded. All three methods combined detected domestic infestation in 129 (62.3%) of the 207 houses studied in the 19 localities. The range of houses infested varies from 6.7% to 92.9%. In areas with low bug density infestation rates, the methodology experienced in our studies, seems to be the best choice for investigations on domestic R. ecuadoriensis populations.

Compte rendu critique du livre Voir son steak comme un animal mort, de Martin Gibert

Compte-rendu / Review

O livro – um recurso transversal

Dissertação de Mestrado, Educação Pré-Escolar, Escola Superior de Educação e Comunicação, Universidade do Algarve, 2016

“Ela não precisava chamar a polícia...” : anestesias relacionais e duplo-vínculos na perspectiva de homens autores de violência conjugal

Tese (doutorado)—Universidade de Brasília, Instituto de Psicologia, Psicologia Clínica e Cultura, 2015.

Uso de resíduos da indústria de papel e celulose em plantios florestais: aspectos técnicos e legais.

Introdução; Principais resíduos sólidos e semi-sólidos gerados em complexos integrados de celulose e papel; Aspectos técnicos e legais voltados à elaboração de projeto agronômico para uso de resíduos em plantios florestais; Caracterização e classificação dos resíduos quanto aos seus riscos potenciais ao meio ambiente e à saúde pública; Caracterização de resíduos sob o aspecto agronômico; Critérios para definição de doses, épocas e formas de aplicação; Avaliação de problemas de ordem ambiental; Avaliação da viabilidade econômica; Seleção e caracterização das áreas de aplicação; Monitoramento agronômico e ambiental da área de aplicação; Manuseio, transporte e armazenamento; Processos adicionais de tratamento.

Lecture by Thomas Hoving, given at Florida International University, September 19, 1997

Thomas Hoving discusses his book "Greatest works of art of Western civilization", his inspiration for the book and some of the art pieces in the book. Introduction by Dahlia Morgan.

Risk premiumin the global creditMarkets: 2006-2012

¿What have we learnt from the 2006-2012 crisis, including events such as the subprime crisis, the bankruptcy of Lehman Brothers or the European sovereign debt crisis, among others? It is usually assumed that in firms that have a CDS quotation, this CDS is the key factor in establishing the credit premiumrisk for a new financial asset. Thus, the CDS is a key element for any investor in taking relative value opportunities across a firm’s capital structure. In the first chapter we study the most relevant aspects of the microstructure of the CDS market in terms of pricing, to have a clear idea of how this market works. We consider that such an analysis is a necessary point for establishing a solid base for the rest of the chapters in order to carry out the different empirical studies we perform. In its document “Basel III: A global regulatory framework for more resilient banks and banking systems”, Basel sets the requirement of a capital charge for credit valuation adjustment (CVA) risk in the trading book and its methodology for the computation for the capital requirement. This regulatory requirement has added extra pressure for in-depth knowledge of the CDS market and this motivates the analysis performed in this thesis. The problem arises in estimating of the credit risk premium for those counterparties without a directly quoted CDS in the market. How can we estimate the credit spread for an issuer without CDS? In addition to this, given the high volatility period in the credit market in the last few years and, in particular, after the default of Lehman Brothers on 15 September 2008, we observe the presence of big outliers in the distribution of credit spread in the different combinations of rating, industry and region. After an exhaustive analysis of the results from the different models studied, we have reached the following conclusions. It is clear that hierarchical regression models fit the data much better than those of non-hierarchical regression. Furthermore,we generally prefer the median model (50%-quantile regression) to the mean model (standard OLS regression) due to its robustness when assigning the price to a new credit asset without spread,minimizing the “inversion problem”. Finally, an additional fundamental reason to prefer the median model is the typical "right skewness" distribution of CDS spreads...

The use of digital educational resources : the contribution of research in the supervised teaching practice in basic education

This article aims to reflect on the impact of Information and Communication Technologies (ICT) in the educational context, focusing on the potential contributions of the use of Digital Educational Resources (RED) in the process of teaching and learning. For this purpose, the results of the use of the RED will be presented:. Digital Classroom - The World's 1st Year Carochinha The study was accomplished in a class of the 1st grade of the 1st CEB, composed of 27 students, aged 6-7 years in Castelo Branco City Schools Group within the Supervised Teaching Practice. The results obtained after the analysis and processing of the data showed that when using this RED students show they have acquired the content covered by the fact that they enhanced levels of greater interest, commitment, motivation, commitment and initiative in the course of activities proposals. But, perhaps because they are students of 1st year of the 1st CEB, do not neglect the presence and monitoring of the teacher and the use of paper-based resources. This means that there should be a complementarity that reconciles the human factor (teacher), with the use of digital media resources and paper support resources (Manual).