Analysis of the optical confinement factor in semiconductor lasers

We derive formulas for the optical confinement factor Gamma from Maxwell's equations for TE and TM modes in the slab waveguide. The numerical results show that the formulas yield correct mode gain for the modes propagating in the waveguide. We also compare the formulas with the standard definition of Gamma as the ratio of power flow in the active region to the total power flow. The results show that the standard definition will underestimate the difference of optical confinement factors between TE and TM modes, and will underestimate the difference of material gains necessary for polarization insensitive semiconductor laser amplifiers. It is important to use correct optical confinement factors for designing polarization insensitive semiconductor laser amplifiers. For vertical cavity surface-emitting lasers, the numerical results show that Gamma can be defined as the proportion of the product of the refractive index and the squared electric field in the active region. (C) 1996 American Institute of physics.

三相高压变压器型电子加速器性能研究

在当前国际上，强流大功率电子加速器的研究是应用于辐射行业辐射源的一个主要研究方向。内置加速管三相高压变压器型电子加速器与外置加速管强流大功率电子加速器相比，具有结构紧凑、造价低、结构简单等特点。本文对内置加速管三相变压器型电子加速器在研制过程中出现的高压击穿频繁、高压硅堆的损坏率高、能量脉动高、引出窗束流损失大等问题进行了研究，提出并实施了改进措施，得到了较好的调试结果。并对存在的问题进一步提出了改进方案。首先介绍了内置加速管三相变压器型电子加速器的原理、结构及组成。在此基础上，针对在加速器调试过程中出现的经常性高压击穿等严重制约加速器正常运行的问题，通过对三相高压变压器型的高压发生器在变压器特性分析、气体绝缘和电场分布计算、高压电极形状优化、过电压分布的计算、正常工作时的仿真，提出了改进方案。经过改进后，从调试结果来看，所设计的高压发生器能够正常稳定的工作。研究了作为高压发生器易损坏的关键部件之一的高压整流硅堆的性能。根据硅堆内部的结构和在高压发生器中所处的位置，合理的建立了等效电路，并对电路中各结构电容在硅堆耐高压方面的作用进行了详细的理论计算和分析。对硅堆内部管芯的排列及在加速器中的摆放位置提出了改进方案，经过改进，提高了硅堆的耐压值，也保证了高压发生器的正常稳定运行。对于加速器引出窗束流损失大和能量脉动高的问题，用PBGUN程序计算了优化后的阴极鼻锥聚束极结构在强流状态下的束流轨迹和加速管出口处的束斑；对能量脉动测量做了分析，并得到较真实的脉动值。论文最后对内置加速管三相变压器型电子加速器在整体调试中存在电子束受到变压器杂散磁场影响的问题做了介绍，提出了分离式的改进结构

三相电压型PWM整流器及其控制策略研究

本文分析了三相电压型PWM整流器在abc、DQ、dq坐标系下的数学模型，开发了基于MATLAB／SIMULINK的三相PWM整流器仿真模块，仿真结果表明基于dq同步旋转坐标系的整流器数学模型是正确的，并具有独特优点。对常用空间电压矢量控制策略进行分析，给出了合成电压矢量的不同方法；分析了固定开关频率的电流预测控制原理。分析了电流环的控制策略，推导出电流环和电压环PI参数与整流器主电路各参数之间的关系。设计了双闭环控制PWM整流器系统的硬件、软件，实现解藕整流器输入电流，并完成了系统仿真，仿真结果表明电压和电流双闭环P1参数选择的合理性以及整个系统的可行性。

Molecularly imprinted monolithic stationary phases for liquid chromatographic separation of enantiomers and diastereomers

The method for preparation of molecularly imprinted monolithic stationary phase has been improved to achieve liquid chromatographic separation of enantiomers and diastereomers. By adopting low polar porogenic solvents of toluene and dodecanol and optimal polymerization conditions, the molecularly imprinted monolithic stationary phases with good flow-through properties and high resolution were prepared. Enantiomers of amino acid derivatives and diastereomers of cinchona alkaloids were completely resolved using the monolithic stationary phases. The influence of porogenic composition, monomer-template ratio and polymerization conditions on the chromatographic performance was investigated. Some chromatographic conditions such as the composition of the mobile phase and the temperature were characterized. Scanning electron microscopy showed that the molecularly imprinted monolithic stationary phase has a large through-pore structure to allow the mobile phase to flow through the column at very low backpressure. Accelerated separations of enantiomers and diastereomers were therefore achieved at elevated flow rates. Finally, the chiral recognition performance of the prepared stationary phase in aqueous media was investigated. Hydrophobic interaction, and ionic and/or hydrogen bonding interactions were proposed to be responsible for the recognition mechanism. (C) 2002 Elsevier Science B.V. All rights reserved.

Dewetting of polymethyl methacrylate on the patterned elastomer substrate by solvent vapor treatment

The dewetting evolution process of polymethyl methacrylate (PMMA) film on the flat and prepatterned polydimethylsiloxane (PDMS) substrates (with square microwells) by the saturated solvent of methyl ethyl ketone (MEK) treatment has been investigated at room temperature by the optical microscope (OM) and atomic force microscope (AFM). The final dewetting on the flat PDMS substrate led to polygonal liquid droplets, similar to that by temperature annealing. However, on the patterned PDMS substrate, depending on the microwells' structure of PDMS substrate and defect positions that initiated the rupture and dewetting of PMMA, two different kinds of dewetting phenomena, one initiated around the edge of the microwells and another initiated outside the microwells, were observed. The forming mechanism of these two different dewetting phenomena has been discussed. The microwells were filled with liquid droplets of PMMA after dewetting due to the formation of fingers caused by the pinning of the three-phase-line at the edge of the microwells and their rupture.

Tensile modulus of polymer nanocomposites

Based on Takayanagi's two-phase model, a three-phase model including the matrix, interfacial region, and fillers is proposed to calculate the tensile modulus of polymer nanocomposites (E-c). In this model, fillers (sphere-, cylinder- or plate-shape) are randomly distributed in a matrix. If the particulate size is in the range of nanometers, the interfacial region will play an important role in the modulus of the composites. Important system parameters include the dispersed particle size (t), shape, thickness of the interfacial region (tau), particulate-to-matrix modulus ratio (E-d/E-m), and a parameter (k) describing a linear gradient change in modulus between the matrix and the surface of particle on the modulus of nanocomposites (E-c). The effects of these parameters are discussed using theoretical calculation and nylon 6/montmorillonite nanocomposite experiments. The former three factors exhibit dominant influence on E-c At a fixed volume fraction of the dispersed phase, smaller particles provide an increasing modulus for the resulting composite, as compared to the larger one because the interfacial region greatly affects E-c. Moreover, since the size of fillers is in the scale of micrometers, the influence of interfacial region is neglected and the deduced equation is reduced to Takayanagi's model. The curves predicted by the three-phase model are in good agreement with experimental results. The percolation concept and theory are also applied to analyze and interpret the experimental results.

Morphological study on water-borne conducting polyaniline-poly(ethylene oxide) blends

Conducting polyaniline-poly(ethylene oxide) blends were prepared from their aqueous solutions. The blends displayed an electrical conductivity percolation threshold as low as 1.83 wt % of polyaniline loading. As demonstrated by scanning electron microscopy, polarized optical microscopy, and wide-angle X-ray diffraction studies, the conducting polyaniline took a fibrillar morphology in the blend, and it existed only in the amorphous phase of poly(ethylene oxide). A three-phase model combining morphological factors instead of a two-phase model was proposed to explain the low-conductivity percolation threshold.

Influence of annealing on structure of Nylon 11

Differential scanning calorimeter (DSC), wide-angle X-ray diffraction (WAXD), small-angle X-ray scattering (SAXS), and density techniques have been used to investigate the structural parameters of the solid state of Nylon 11 annealed at different temperatures. The equilibrium heat of fusion Delta H-m(0) and equilibrium melting temperature T-m(0) were estimated to be 189.05 J g(-1) and 202.85 degrees C respectively by using the Hoffman-Weeks approach. The degree of crystallinity (W-c,W-x) ranged approximately 24-42% was calculated by WAXD and compared with those by calorimetry (W-c,W-h) and density (W-c,W-d) measurements. The radius of gyration R-g, crystalline thickness L-c, noncrystalline thickness L-a, long period L, semiaxes of the particles (a, b), electron-density difference between the crystalline and noncrystalline regions eta(c) - eta(a), and the invariant Q increased with increasing annealing temperature. The analysis of the SAXS data was based upon the particle characteristic function and the one-dimensional electron-density correlation function. An interphase region existed between the crystalline and noncrystalline region with a clear dimension of about 2 nm for semicrystalline Nylon 11. Instead of the traditional two-phase model, a three-phase model has been proposed to explain these results by means of SAXS.

Shear induced mixing/demixing: Blends of homopolymers, of homopolymers plus copolymers, and blends in solution

Shear may shift the phase boundary towards the homogeneous state (shear induced mixing, SIM), or in the opposite direction (shear induced demixing, SID). SIM is the typical behavior of mixtures of components of low molar mass and polymer solutions, SID can be observed with solutions of high molar mass polymers and polymer blends at higher shear rates. The typical sequence with increasing shear rate is SIM, then occurrence of an isolated additional immiscible area (SLD), melting of this island into the main miscibility gap, and finally SIM again. A three phase line originates and ends in two critical end points. Raising pressure increases the shear effects. For copolymer containing systems SID is sometimes observed at very low shear rates, preceding the just mentioned sequence of shear influences.

Separation of Th4+ and RE3+ with hollow fiber extraction

Separation of Th4+ and RE3+ was investigated by hollow fiber membrane extraction with N1923 in countercurrent recirculating operation. The effect of Hf concentration in aqueous phase and flow rates of aqueous and organic phases on mass transfer coefficient was tested. Then the extraction of Th4+ from RE sulfate obtained from Baotou ore was carried out. The results obtained show that the mass transfer coefficient of Th4+ changes with the flow rate of aqueous phase, but does not change with the flow rate of organic phase and H+ concentration in aqueous phase, which suggests that the mass transfer rate of Th4+ is controlled bg that in the water critical layer, The mass transfer rate of RE3+ does not change with the flow rate of water phase, changes a little with the flow rate of organic phase, and changes with H+ concentration, which suggests that the mass transfer rate is controlled by their reaction rate with N1923. Th4+ could be extracted completely in 8 h from RE sulfate solution of Baotou ore with relatively less extraction of RE3+. So the separation of radioactive element under the sealed condition could be done.

Crystal structure of the blend of polyamide 1010 with a bismaleimide by WAXD and SAXS

The blend polyamide 1010/N,N'-(diphenylmethane-4,4'-diyl)bismaleimide (PA1010/ BMI) has been investigated by means of WAXD and SAXS. The results obtained with the help of the Ruland, variance and 1D EDCF analysis showed that the degree of crystallinity (W-c,W-x), crystallite size (L(hikl)), long period (L) and thickness of average crystal lamellae (d) decrease with BMI content. Experimental and calculated density values (rho(c)) are in good agreement. Addition of BMT to PA1010 causes an increase in structural distortion. The results from SAXS analysis also supported that a crystalline amorphous interphase exists in the lamellae of semicrystalline polymers, so that a three-phase model instead of the traditional two-phase model should be used.

俯冲带深部流体特征——以西南天山变质俯冲杂岩为例

The subduction zone is an important site of the fluid activity and recycling of chemical elements. The fluid characteristic of deep subduction zones is a top scientific problem attracting the petrologists, geochemists and tectonists. In this dissertation, the characteristics of fluid activity within a deep subduction zone have been explored on the basis of the studies on the petrography, mineral chemistry, fluid inclusions, geochemistry and metamorphic P–T conditions of the omphacite-bearing high-pressure veins and related hosts from the low-temperature/high-pressure metamorphic belt in southwestern Tianshan, China. Multiple high-pressure veins are exposed in host eclogites and blueschists. The veins are composed predominantly of omphacite, garnet, quartz, and other minerals. Some veins contain cm-sized rutiles. In general, the vein can be divided into three types, the ‘in situ dehydration’ vein, the ‘external transport’ vein and the ‘composite’ vein. The omphacites within the veins and related host rocks contain lots of two-phase or three-phase primary fluid inclusions. The final melting temperature (Tfm) of fluid inclusions varies mainly from -0.6 to -4.3 °C, the homogeneous temperature (Th) varies from 185 to 251 °C, the salinity varies from 1.1 to 6.9 wt.% NaCl equivalent and the density varies from 0.81 to 0.9 g/cm3. The fluids were released under the conditions of T = 520–580°C and P = 15–19 kbar at blueschist facies to eclogite facies transition. The fluids include not only Li, Be, LILE, La, Pb-enriched and HFSE- and HREE-depleted aqueous fluids but also HFSE (Ti-Nb-Ta)-rich aqueous fluids. The complex composed of aluminosilicate polymers and F was the catalyst which had caused the Ti-Nb-Ta to be dissolved into the fluids. During the transport of the LILE-rich and HFSE- and HREE-poor fluids, they can exchange some chemical elements with country rocks and leach some trace elements in some extent. The rutile could be precipitated from the HFSE (Ti-Nb-Ta)-rich aqueous fluids when CO2 was added into the fluids. The host rocks could obtain some elements, such as Ca, Cs, Rb, Ba and Th, from the external fluids. The fluids with complex composition had been released within the deep subduction zone (>50 km) in Early Carboniferous during the subduction of the South Tianshan Ocean under the Yili–Central Tianshan Plate. The results obtained in this dissertation have made new progress compared with the published data (e.g. Tatsumi, 1989; Becker et al., 1999; Scambelluri and Philippot, 2001; Manning, 2004; Hermann et al., 2006; Spandler and Hermann, 2006).

盆地地下水资源开发的数值模拟研究－以山西灵石静升盆地为例

Groundwater basin is important for water supply in northern China. The paper took the Jingsheng Basin in Lingshi County, Shanxi Province as a case to study the basin groundwater system by numerical modeling. The hydrogeological characteristics were analysed basing on the field investigation, and a three-dimensional groundwater flow model was established to describe the groundwater flow system in the Jingsheng groundwater basin. The boundary of the model was determined by using geophysics and GIS data, and the lumped parameter model of runoff was used to depict the transform between the surface water and groundwater, and the groundwater dating data was used to calibrate the model. All these methods were used to improve the model. The Software Visual MODFLOW 2000 was applied to set up the numerical groundwater flow model. The groundwater flow pattern in the average year, the high-water year and the low-water year were simulated respectively by the model. Some new cognition to the groundwater movement in Jingsheng Basin was obtained in the paper. The difficult problems were resolved when using the conventional and theoretical analysis to forecast and appraise the exploitation of the groundwater, and supplies the instructional technology base for the reasonable exploitation and optimization collocation. The numerical model will improve evaluation of the basin groundwater resources.

内蒙古白云鄂博超大型REE-Nb-Fe矿床脉状矿化时代与成矿流体特征

Bayan Obo REE-Nb-Fe ore deposit is the largest REE deposit in the world. Owing to its unique type and tremendous economic value, this deposit has widely attracted interests from geological researchers and vast amount of scientific data have been accumulated. However, its genesis, especially ore-forming age and REE sources, have been under dispute for a long time. On the basis of previous research works, this paper mainly conducts studies on the Early Paleozoic ore-forming event in the Bayan Obo deposit. The following results and conclusions can be suggested: Sm-Nd isotopic analytical results of bastnaesite, beloeilite, albite and fluorite samples from a coarse-crystalline ore lode present an isochron age of 436±35Ma. Besides, Rb-Sr isotope dating of the coarse-crystalline biotite lode that intruded into banded ores gives an isochron age of 459±39Ma. The two ages verify the exist of Early Paleozoic ore-forming event at Bayan Obo, which characterized by extensive netted mineralization of REE fluorocarbonates, aeschynite and monazite, accompanied by widely fluorite-riebeckite-aegirine-apatite alteration. Sr-Nd isotope composition of vein minerals is located between EMI and ancient lower crust component in the ISr(t)-εNd(t) correlation diagram, indicating that there is a crustal contamination during veined mineralization. A large area late Paleozoic granitoids are distributed in the southeast region of east open pit of the mine. The granitoids intruded directly into the ore-bearing dolomite, and produced intense skarnization. Moreover, at 650-660m of the drill core on 22 line and 1598m level flat in the south of East Open Pit, we firstly found skarnization rocks. Single grain and low background Rb-Sr isochrone dating on phlogopite in skarn gives 309±12Ma. Considering the intruded contacting relationship, the late Paleozoic granitoids, already extended to the under part of REE ore bodies, must be posterior to the latest intense REE mineralization, and is only a destructive tectonic and magmatic activity. Fluid inclusion types of fluorite in the Bayan Obo deposit consist of multiphase daughter mineral-bearing inclusion, two or three phase CO2-bearing inclusion and two phase aqueous inclusion. Petrography, laser Raman analysis and microthermometry study indicate that the fluids involving in REE-Nb-Fe mineralization at Bayan Obo might be mainly of H2O-CO2-NaCl-(F-REE) system. The presence of REE-carbonate as a daughter mineral in fluid inclusions shows that the original ore-forming fluids are rich in REE elements.

孤东油田馆陶组河流相储层流动单元模型与剩余油分布规律研究

Since C.L. Hearn presented the concept of flow unit in 1984, its generation mechanisms and controlling factors have been studied in many aspects using different methods by researchers. There are some basic methods to do the research, and there are several concepts and classification standards about flow unit. Based on previous achievements and using methodologies from sedimentary geology, geophysics, seismic stratigraphy, and reservoir engineering, the author systemically studies the factors controlling flow unit, puts forward a series of methods for recognition, classification and evaluation of flow unit. The results obtained in this paper have important significance not only for understanding the flow unit, but also for revealing the distribution of remaining oil. As a case, this paper deals with the reservoir rocks in Guantao Group of Gudong Oilfield. Zhanhua Sag, Jiyang Depression in Bohaiwan Basin. Based on the study of stratigraphic, depositional and structural characteristics, the author establishes reservoir geological models, reveals the geological characteristics of oil-bearing reservoir of fluvial facies, points out the factors controlling flow unit and geological parameters for classification of flow unit. and summarizes methods and technologies for flow unit study when geological, well-logging and mathematical methods are used. It is the first attempt in literatures to evaluate reservoir by well-logging data constrained by geological conditions, then a well-logging evaluation model can be built. This kind of model is more precise than ever for calculating physical parameters in flow unit. In a well bore, there are six methods to recognize a flow unit. Among them, the activity function and intra-layer difference methods are the most effective. Along a section, the composition type of flow unit can be located according amplitude and impedance on seismic section. Slice method and other methods are used to distinguish flow unit. In order to reveal the distribution laws of flow unit in space, the author create a new method, named combination and composition of flow unit. Based on microscopic pore structure research, the classification methods of flow unit are developed. There are three types of flow unit in the reservoir of fluvial facies. They have their own lithology, petrophysics and pore structure character. Using judgement method, standard functions are built to determine the class of flow unit of fluvial facies. Combining reservoir engineering methods, the distribution laws of remaining oil in different types, or in different part of a flow unit are studied. It is evident that the remaining oil is controlled by the type of flow unit. The author reveals the relationship between flow unit and remaining oil distribution, builds the flowing models, predicts the variation of reservoir parameters in space, put forward different methods developing remaining oil in different flow unit. Especially, based on the results obtained in this paper, some suggestions for the adjustment of the developing flow units have been applied in Districts No.4 and No.7, and good results have been yielded. So, the results of this paper can guide oil field development. They are useful and significant for developing the remaining oil and enhancing the oil recovery efficiency.