Composition of Fe-Mn nodules from the radiolarian belt of the Pacific Ocean

Typomorphic features of the main morphogenetic types of Fe-Mn nodules from the radiolarian belt have been considered on materials from polygons in the Clarion-Clipperton ore province and in the Central Basin of the Pacific Ocean. By character of surfaces, features of internal structure, mineral and chemical compositions, behavior of trace elements at selective leaching three genetic types of nodules have been divided: predominantly sedimentary, diagenetic, and sedimentary diagenetic. Their formation results from mechanism of growth.

Composition of palygorskite-rich and montmorillonite-rich zeolite-containing sediments from DSDP Sites 164 and 196

Cretaceous, Tertiary, and Quaternary sediments from Deep Sea Drilling Project Sites 164 and 196 (13°12' N, 161°31' W and 30°07' N, 148°34' E, respectively) were analyzed for major chemical elements and mineralogy. Sediments from these sites contain large proportions of authigenic minerals: mainly palygorskite, clinoptilolite and chert in the Cretaceous, and montmorillonite, phillipsite and chert in the Tertiary. The montmorillonite-phillipsite assemblage is thought to be derived from volcanic ash or glass, and the palygorskite-clinoptilolite assemblage is thought to be derived by reaction of biogenic silica with volcanic ash or glass or with montmorillonite and phillipsite. Both assemblages have generally moderate Ti/Al ratios, ranging from 0.026 to 0.047, so most of the palygorskite, clinoptilolite, montmorillonite and phillipsite could not be derived in situ from alteration of basaltic material. Plagioclase compositions suggest that the volcanic precursors were silicic or intermediate, but it is also possible that the sediments have been extensively fractionated by redistribution from nearby seamounts. Available data on other Late Cretaceous sediments in the Pacific were analyzed. Clinoptilolite and chert are present nearly everywhere where palygorskite is abundant; phillipsite is rare where palygorskite is abundant. It is suggested that increased water temperatures during the Cretaceous increased reaction rates and determined the alteration products.

Isotopic composition of rocks from the Lau/Tonga back-arc basin, data of DSDP Leg 21 and ODP Legs 91 an 135

New trace element, Sr-, Nd-, Pb- and Hf isotope data provide insights into the evolution of the Tonga-Lau Basin subduction system. The involvement of two separate mantle domains, namely Pacific MORB mantle in the pre-rift and early stages of back-arc basin formation, and Indian MORB mantle in the later stages, is confirmed by these results. Contrary to models proposed in recent studies on the basis of Pb isotope and other compositional data, this change in mantle wedge character best explains the shift in the isotopic composition, particularly 143Nd/144Nd ratios, of modern Tofua Arc magmas relative to all other arc products from this region. Nevertheless, significant changes in the slab-derived flux during the evolution of the arc system are also required to explain second order variations in magma chemistry. In this region, the slab-derived flux is dominated by fluid; however, these fluids carry Pb with sediment-influenced isotopic signatures, indicating that their source is not restricted to the subducting altered mafic oceanic crust. This has been the case from the earliest magmatic activity in the arc (Eocene) until the present time, with the exception of two periods of magmatic activity recorded in samples from the Lau Islands. Both the Lau Volcanic Group, and Korobasaga Volcanic Group lavas preserve trace element and isotope evidence for a contribution from subducted sediment that was not transported as a fluid, but possibly in the form of a melt. This component shares similarities with that influencing the chemistry of the northern Tofua Arc magmas, suggesting some caution may be required in the adoption of constraints for the latter dependent upon the involvement of sediments from the Louisville Ridge. A key outcome of this study is to demonstrate that the models proposed to explain subduction zone magmatism cannot afford to ignore the small but important contributions made by the mantle wedge to the incompatible trace element inventory of arc magmas.

Geochemical composition and radiocarbon ages of cores from Lago Fugnano, Tierra del Fuego

Recent advances in the chronology and the palaeoclimatic understanding of Antarctic ice core records point towards a larger heterogeneity of latitudinal climate fluctuations than previously thought. Thus, realistic palaeoclimate reconstructions rely in the development of a tight array of well-constrained records with a dense latitudinal coverage. Climatic records from southernmost South America are critical cornerstones to link these Antarctic palaeoclimatic archives with their South American counterparts. At 54° S on the Island of Tierra del Fuego, Lago Fagnano is located in one of the most substantially and extensively glaciated regions of southernmost South America during the Late Pleistocene. This elongated lake is the largest (~110km long) and non-ice covered lake at high southern latitudes. A multi-proxy study of selected cores allows the characterisation of a Holocene sedimentary record. Detailed petrophysical, sedimentological and geochemical studies of a complete lacustrine laminated sequence reveal variations in major and trace elements, as well as organic content, suggesting high variability in environmental conditions. Comparison of these results with other regional records allows the identification of major known late Holocene climatic intervals and the proposal for a time for the onset of the Southern Westerlies in Tierra del Fuego. These results improve our understanding of the forcing mechanisms behind climate change in southernmost Patagonia.

Composition of rocks and minerals from the transition zone of the Reykjanes Ridge

Investigations of petrography, mineralogy, and chemical composition of gases and fluids in tuffs and lavas were carried out on samples dredged in the transition zone from the shelf and slope of Iceland to the Reykjanes Ridge. The samples were collected from the depths of 950-720 m during different expeditions of R/V Akademik Kurchatov and Mikhail Lomonosov. Mantle ultrabasite inclusions were first recognized in the region of Iceland. It can be assumed that they are related to eruptive structures formed on the ocean floor during Pliocene and are associated with the Iceland hot spot.

Composition of bottom sediments from the Central Basin of the Indian Ocean

A study of petrographic and mineral compositions of 26 sediment cores from the western part of the Central Basin of the Indian Ocean has identified biogenic, terrigenous, volcanogenic, and authigenic sediment types formed in certain facies conditions. On the basis of bio- and paleomagnetic stratigraphy data from the cores sedimentation rates of different sediment types have been calculated. Modern and Pliocene-Pleistocene positions of the main facies boundaries (the critical depth of carbonate accumulation, the geochemical boundary between hemi- and miopelagic zones, the frontal boundaries of the equatorial belt of biogenic silica accumulation) have been determined. It has been shown that the sedimentary process during Pliocene-Quaternary had cycle variations characterized by successive changes of different sedimentation types - hemipelagic, miopelagic, and biogenic.

Composition of rocks and minerals from the Cape Verde Fault Zone

Results of comprehensive geological, geophysical and geochemical studies carried out in the Cape Verde Fracture Zone (Central Atlantic) during Cruise 9 of R/V ''Antares'' (1990-1991) are published in the book. Detailed characterization of various bedrock complexes (ultrabasites, gabbroids, dolerites, basalts, metamorphic rocks) is given. Geological conditions of newly found hydrothermal mineralization in the area are described. Problems of ore melts are under consideration. New data on hydrochemical anomalies and heat flow are given. The book contains original materials on sedimentary formations of the area.

40Ar-39Ar dating and isotopic composition of groundmass and felspar samples from core AND-2A

The AND-2A drillcore (Antarctic Drilling Program-ANDRILL) was successfully completed in late 2007 on the Antarctic continental margin (Southern McMurdo Sound, Ross Sea) with the aim of tracking ice proximal to shallow marine environmental fluctuations and to document the 20-Ma evolution of the Erebus Volcanic Province. Lava clasts and tephra layers from the AND-2A drillcore were investigated from a petrographic and stratigraphic point of view and analyzed by the 40Ar-39Ar laser technique in order to constrain the age model of the core and to gain information on the style and nature of sediment deposition in the Victoria Land Basin since Early Miocene. Ten out of 17 samples yielded statistically robust 40Ar-39Ar ages, indicating that the AND-2A drillcore recovered <230 m of Middle Miocene (~128-358 m below sea floor, ~11.5-16.0 Ma) and >780 m of Early Miocene (~358-1093 m below sea floor, ~16.0-20.1 Ma). Results also highlight a nearly continuous stratigraphic record from at least 358 m below sea floor down hole, characterized by a mean sedimentation rate of ~19 cm/ka, possible oscillations of no more than a few hundreds of ka and a break within ~17.5-18.1 Ma. Comparison with available data from volcanic deposits on land, suggests that volcanic rocks within the AND-2A core were supplied from the south, possibly with source areas closer to the drill site for the upper core levels, and from 358 m below sea floor down hole, with the 'proto-Mount Morning' as the main source.

Composition of hydrothermal massive sulfide deposits from ODP Site 158-957 and Leg 169 sites

Sulfide mineral major and trace element analyses were performed on more than 50 polished slabs representing mineralization from three seafloor hydrothermal massive sulfide deposits. Samples from the Bent Hill and ODP Mound massive sulfide deposits, both on the Juan de Fuca Ridge, can be contrasted with samples from the Trans-Atlantic Geotraverse (TAG) hydrothermal mound on the Mid-Atlantic Ridge. The massive sulfide at Bent Hill is predominantly pyrite and pyrrhotite, with increasing amounts of copper-bearing sulfide minerals at the base of the massive sulfide body and through the stockwork to an interval 200 m below seafloor that hosts high copper mineralization (Deep Copper Zone). ODP Mound contains much more abundant sphalerite and copper-bearing sulfides as compared to either Bent Hill or TAG, which are predominantly pyrite with much less abundant chalcopyrite. Copper-bearing sulfides from the Deep Copper Zone beneath Bent Hill and the lowest sampled interval of ODP Mound are petrographically and chemically similar, but distinct from copper-bearing minerals higher in either sequence.