黄土高原典型土壤矿物固定态铵变化的南北差异

采集从北向南依次分布的干润砂质新成土(神木)、黄土正常新成土(延安)和土垫旱耕人为土(杨陵)等典型土壤剖面0—200 cm土层土样,通过测定土样全氮和矿物固定态铵,以阐明黄土高原典型区域土壤全氮和矿物固定态铵及二者比率随地理位置和土层的变异规律,为全面了解黄土高原土壤相对稳定氮库累积提供科学数据。结果表明,不同地理位置、不同土层全氮和矿物固定态铵含量存在显著差异。从南到北全氮和矿物固定态铵呈下降趋势,但各土壤全氮和矿物固定态铵的分布显著不同,全氮含量在0—60 cm随土层深度增加下降很明显,60—120 cm有一定下降,120 cm以下低而稳定。矿物固定态铵在全剖面上的分布比较均匀,随土层深度的变化差异不显著,不同土层间的差异基本在误差范围内,土垫旱耕人为土、黄土正常新成土和干润砂质新成土表层(0—10 cm)矿物固定态铵平均含量分别为215.80±7.45、165.80±8.73和146.50±1.83 mg/kg,表层以下(10—200 cm)平均含量分别为193.40±9.67、157.14±5.75和142.02±5.47 mg/kg。从地理位置分析,干润砂质新成土、黄土正常新成土和土垫旱耕人为土表层...

脲酶抑制剂/硝化抑制剂对土壤中尿素氮转化及形态分布的影响

运用１５Ｎ尿素示踪技术，以壤质草甸棕壤和春小麦分别作供试土壤和作物进行盆栽试验。结果表明，与单施１５Ｎ尿素或１５Ｎ尿素＋氢醌（ＨＱ）相比，配施双氰胺（ＤＣＤ），尤其与ＨＱ组合可使土壤保持较高的１５Ｎ回收率，其中有机１５Ｎ占相当大的比例．在小麦孕穗期前，上述两处理可有效地保持尿素水解后土壤中ＮＨ４＋－１５Ｎ含量，并显著降低（ＮＯ３－＋ＮＯ２－）－１５Ｎ的富集；促进肥料１５Ｎ固持－矿化的周转。ＨＱ与ＤＣＤ配合施用对尿素施用后土壤中残留１５Ｎ量及有机１５Ｎ的再矿化和ＮＨ４＋－１５Ｎ含量具有一定的协同作用。

细沟侵蚀过程与细沟水流水力学参数的关系研究

利用供沙土槽和试验土槽的双土槽径流小区 ,定量研究了在不同降雨强度下上方来水来沙对陡坡地细沟侵蚀产沙过程和细沟水流水力学参数的影响及其细沟水流水力学特征参数与细沟侵蚀产沙量的关系。结果表明 :坡面细沟侵蚀过程以侵蚀—搬运过程为主 ,坡上方来沙不仅被径流全部搬运 ,且上方来水在坡下方引起了另外的侵蚀产沙量 ,其值随上方来水含沙量的减少和降雨强度的增加而增大。上方来水的汇入或降雨强度的增大可使细沟水流流态由层流转化为紊流。上方来水对细沟水流水力学参数 (流速、水力半径、雷诺数、弗劳德数和阻力系数 )有重要影响。定量分析了细沟水流水力学特征参数 (流速、雷诺数和阻力系数 )与上坡来水引起坡下方净侵蚀产沙量的关系 ,建立了净侵蚀产沙量与细沟水流流速、雷诺数和阻力系数统计模型。

黄土区渭北旱塬苹果基地对区域水循环的影响

通过对苹果地、农田和其他塬面主要土地利用方式的比较研究 ,发现苹果地土壤入渗速率大、降雨产流率低和存在生物利用型土壤干层。这些水文学性质将增强土壤 -植物 -大气间垂直水分交换 ,削弱降雨转化为地表径流和地下水的比例 ,最终影响区域地表和地下水资源的数量。另外土壤干层的出现还削弱了土壤水库对年际和季节性干旱的调节作用 ,导致苹果产量随降雨量的自然变化呈现较大波动

长江流域区域可持续发展评价及类型划分

长江流域在我国实施可持续发展战略中具有典型代表性 ,其经济发展和资源禀赋互补性强 .从长江下游到上游 ,经济发展基本呈递减趋势 ,而资源禀赋则基本呈递增趋势 .可持续发展是人口、资源与环境之间的协调发展 .根据长江流域各省 (市、区 )的经济发展水平、社会发展水平、资源环境状况和可持续发展能力 ,建立了区域可持续发展评价指标体系 ,对其可持续发展现状进行综合加权评价 ,采用聚类分析法划分不同类型 .差异主要体现在经济发展水平、可持续发展能力和资源环境状况上 ,社会发展水平方面的差异并不大 .从长江流域省级区域可持续发展的空间分布看 ,可持续发展状况呈现沿长江下游到上游南北条带状递减的趋势 .

ANALYSIS OF DRIVING FORCES ON THE CHANGE OF HISTORICAL FARMLAND USE IN SHANDONG PROVINCE DURING THE QING DYNASTY (1644-1911)

National Natural Science Foundation of China [40201005]; Knowledge Innovation Project of Chinese Academy of Sciences [KZCX3-SW-321, KZCX2-314, KZCX1-SW-321-4]

Microstructures and mechanical properties of the Mg-4.5Zn-xGd (x = 0, 2, 3 and 5) alloys

Microstructures and mechanical properties of the peak-aged Mg-4.5Zn-xGd (x = 0, 2, 3 and 5 wt.%) alloys have been investigated. The results showed that grain size increased with increasing Gd. Phase analysis showed that MgZn2 phase was observed in the Mg-4.5Zn alloy. While with Gd additions, Mg3Gd and Mg3Gd2Zn3 phases formed, and the volume fraction of the Mg3Gd2Zn3 phase increased with increasing Gd. Tensile test results indicated that the optimal mechanical properties were obtained in the Mg-4.5Zn-2Gd alloy, and the ultimate tensile strength and yield strength were 215 MPa and 121 MPa, respectively.

生附片化学成分的HPLC/ESI-MS~n研究

采用高效液相色谱与电喷雾质谱联用技术,对生附片的化学成分进行了系统的研究.并辅以提取离子色谱方法.发现微量的化学成分.通过保留时间,质荷比及多级串联质谱数据,共鉴定了48个成分,其中双酯型生物碱8个,单酯型生物碱7个,脂型生物碱29个.其中双酯型生物碱是生附片中的主要成分,而单酯型和脂型生物碱的含量和种类较少.

Luminescent properties of a new blue long-lasting phosphor Ca2P2O7:Eu2+, Y3+

A new pyrophosphate long-lasting phosphor with composition of Ca1.96P2O7:0.02Eu(2+), 0.02Y(3+) is synthesized via the high-temperature solid-state reaction method. Its properties are systematically investigated utilizing XRD, photoluminescence, phosphorescence and thermoluminescence (TL) spectra. The phosphor emits blue light that is related to the characteristic emission of Eu2+ due to 5d-4f transitions. For the optimized sample, bright blue long-lasting phosphorescence (LLP) could be observed by naked eyes even 6 h after the excitation source is removed. The TL spectra show that the doping of Y3+ ions greatly enhanced intensity of 335 K peak and created new TL peak at about 373 K that is also responsible for the blue LLP. Based on our study, Y3+ ions are suggested to act as electron traps to improve the performance of the blue phosphorescence of Eu2+ such as intensity and persistent time.

Vaterite-type YBO3 : Eu3+ crystals: hydrothermal synthesis, morphology and photoluminescence properties

Vaterite-type YBO3:Eu3+ crystals with interesting flower and hedgehog fungus-like structures composed of nanosheets were obtained by controlled crystallization of Y2O3 and Eu2O3 in H3BO3 solutions under acidic hydrothermal (HT) conditions. Nanosheets of uniform thicknesses were formed by preferential crystal growth along the (100) crystallographic plane and specific three-dimensional structures were further developed through a homocentric growth mechanism. Optical emission measurements showed that the HT-grown nanosheet crystals exhibited a higher ratio of the emitted red-to-orange light ratio than crystals grown from solid-state reactions. The photoluminescence intensity and emission lifetimes were also studied as a function of the Eu3+ dopant concentration and the HT synthesis temperature. The effect of some additives: a chelating ligand, a surfactant and a polymer, on the YBO3:Eu3+ crystals morphology was also investigated.

Luminescence properties of CdSiO3 : Mn2+ phosphor

A novel long-lasting phosphor CdSiO3:Mn2+ is reported in this paper. The Mn2+-doped CdSiO3 phosphor emits orange light with CIE chromaticity coordinates x = 0.5814 and y = 0.4139 under 254 nm UV light excitation. In the emission spectrum of 1% Mn2+-doped CdSiO3 phosphor, there is a broad emission band centered at 575 nm which can be attributed to the,pin-forbidden transition of the d-orbital electron associated with the Mn2+ ion. The phosphorescence can be seen by the naked eyes in the dark clearly even after the 254 nm UV irradiation have been removed for about 1 h. The mechanism of the origin of the long-lasting phosphorescence was discussed using the thermoluminescence curves.

Syntheses, structures, and characterizations of four new silver(I) sulfonate coordination polymers with neutral ligands

In this paper, four novel silver(I) sulfonate coordination polymers containing neutral ligands, namely, [Ag(2)Ll (biim)(2)]center dot 2H(2)O (1). AgL2(biim) (2), [Ag(HL3)(Pic)(2)]center dot H2O (3), and [Ag-3(L3)(HL3)(4,4'-bipy)(3)(H2O)(2)]center dot 4H(2)O (4), have been synthesized [L1 = 3-carboxy-4-hydroxybenzenesulfonate, L2 = p-aminobenzenesulfonate, H(2)L3 = p-hydroxybenzenesulfonic acid, biim = 1,1'-(1.4-butanediyl)-bis(imidazole), Pic = beta-picoline, 4,4'-bipy = 4,4'-bipyridine]. For compounds 1 and 2, Ag(I) cations are bridged by biim ligands to form a one-dimensional (1D) "zigzag" chain, and L1 and L2 sulfonate ligands are not coordinated to the silver cation. Compound 3 has a dimeric structure in which two silver cations are bridged by two HL3 ligands. For compound 4, L3 ligand coordinates to a silver cation as a monodentate ligand, and Ag(l) cations are bridged by 4,4'-bipy ligands to form a ID chain. Compound 1 contains water dimers, while compound 4 contains water trimers. Compounds 1-3 display room-temperature photoluminescence.