(Table T1) Physical properties of minicores from ODP Leg 193 sites, PACMANUS field

Permeability of the ocean crust is one of the most crucial parameters for constraining submarine fluid flow systems. Active hydrothermal fields are dynamic areas where fluid flow strongly affects the geochemistry and biology of the surrounding environment. There have been few permeability measurements in these regions, especially in felsic-hosted hydrothermal systems. We present a data set of 38 permeability and porosity measurements from the PACMANUS hydrothermal field, an actively venting, felsic hydrothermal field in the eastern Manus Basin. Permeability was measured using a complex transient method on 2.54-cm minicores. Permeability varies greatly between the samples, spanning over five orders of magnitude. Permeability decreases with both depth and decreasing porosity. When the alteration intensity of individual samples is considered, relationships between depth and porosity and permeability become more clearly defined. For incompletely altered samples (defined as >5% fresh rock), permeability and porosity are constant with depth. For completely altered samples (defined as <5% fresh rock), permeability and porosity decrease with depth. On average, the permeability values from the PACMANUS hydrothermal field are greater than those in other submarine environments using similar core-scale laboratory measurements; the average permeability, 4.5 x 10-16 m**2, is two to four orders of magnitude greater than in other areas. Although the core-scale permeability is higher than in other seafloor environments, it is still too low to obtain the fluid velocities observed in the PACMANUS hydrothermal field based on simplified analytical calculations. It is likely that core-scale permeability measurements are not representative of bulk rock permeability of the hydrothermal system overall, and that the latter is predominantly fracture controlled.

Petrography, chemistry and magnetic properties of ODP Leg 115 basalts

A detailed study of the Fe-Ti oxides in four basalt samples-one from each of the four holes drilled into basement on Ocean Drilling Program Leg 115 (Sites 706, 707, 713, and 715) has been performed. Ilmenite is present only in samples from Sites 706 and 715. In the sample from Site 715, Ti-magnetite intergrowths are characteristic of subaerial (?) high-temperature oxy-exsolution; Ti-magnetite in the other three samples has experienced pervasive low-temperature oxidation to Ti-maghemite, as evidenced by the double-humped, irreversible, saturation magnetization vs. temperature (Js/T) curves. The bulk susceptibility of these samples, which are similar in terms of major element chemistry, varies by a factor of ~20 and correlates semiquantitatively with the modal abundance of Fe-Ti spinel, as determined by image analysis with an electron microprobe. The variation in Fe-Ti oxide abundance correlates with average grain size: fine-grained samples contain less Fe-Ti oxide. This prompts the speculation that the crystallization rate may also influence Fe-Ti oxide abundance.

(Table 2) Physical properties at DSDP Holes 44-391 and 76-534

Laboratory measurements on sediment samples and density well logs run at DSDP Site 534 in the Blake-Bahama Basin were used to establish an in situ velocity and density structure. Synthetic seismograms were generated for comparison to reprocessed seismic reflection data in the vicinity of the Site. Uncertainties in the relative positions of the hole and seismic reflection data, velocity corrections, and the composition of the unrecovered section were evaluated. In light of the errors and compressed section, no unique correlation of the seismic reflection data to the drill hole is completely defensible either in this chapter or elsewhere. The preferred correlation resulting from this exercise is as follows, with the Site 534 report correlation shown in parentheses where different. Horizon beta', 887 m; Horizon beta, 950 m (975 m); Horizon C , 1202 m (1250 m); Horizon C, 1268 m (1340 m); Horizon D', 1342 m (1432 m); Horizon D, 1550 m (1552 m). The major differences in these correlations arise from the use of slightly different velocities and hole location relative to the seismic profiles. The Site 534 report results rely on hole placement on a basement flank, whereas in this chapter we locate it within a basement depression still within the uncertainty of the navigation. The Site 534 report also uses drilling rates, CDP velocity analyses, sonobuoy data, and previous similar drilling correlation methods used at Site 391, along with other geologic considerations in arriving at differing results. Although the correlation method used in this investigation is more objective and the hole location uncertainties better defined, in order to have confidence in any results we will require drilling in areas where reflections are either more widely spaced or where we have better vertical velocity control in the hole.

Corrected index properties for ODP Leg 127 and 128 sites

During Legs 127 and 128, we found a systematic error in the index property measurements, in that the wet bulk density, grain density, and porosity did not satisfy well-established interrelationships. We have found that an almost constant difference exists between the weight of water lost during drying and the volume of water lost. This discrepancy is independent of volume or water content of the sample. The water losses should be equal because the density of water is close to 1.0 g/cm**3. The pycnometer wet volume measurement has been identified as the source of the systematic error. The wet volume on average is 0.2 cm**3 too low. For the rare cases when the water content is negligible, there is no offset. The source of the wet volume error results from the partial vapor pressure of water in the pycnometer cell. Newly corrected tables of index properties measured during Legs 127 and 128 are included. The corrected index properties are internally consistent. The data are in better agreement with theoretical models that relate the index properties to other physical properties, such as thermal conductivity and acoustic velocity. In future, a standard volume sampler should be used, or the wet volume should be calculated from the dry volume and the water loss by weight.

(Table T1) Paleomagnetic properties of ODP Hole 191-1179D basalts

During Ocean Drilling Program Leg 191, ~100 m of mid-Cretaceous igneous crust was cored at Site 1179 (41.08°N, 159.96°E), located within magnetic Anomaly M8 on the abyssal plain of the northwest Pacific Ocean near Shatsky Rise. Paleomagnetic data from this section are significant because they can constrain the mid-Cretaceous Pacific plate paleolatitude and paleomagnetic pole, both of which can be used to infer tectonic drift and other geodynamic processes. In this study, we analyzed the paleomagnetism of 122 samples from 40 flows in the Site 1179 basalt section. Comparison of inclination data among flows implies 13 independent measurements of the paleomagnetic field. Assuming a reversed magnetic polarity because of the site location within Anomaly M8, the data give a mean paleocolatitude of 88.1° ± 6.8° (corresponding to a paleolatitude of 1.9°N). The paleocolatitude is consistent with other mid-Cretaceous Pacific paleomagnetic data that indicate ~39° northward drift of the western Pacific plate since mid-Cretaceous time. Comparison of observed between-flow colatitude variance with that expected from secular variation data suggests that secular variation may not have been completely averaged with the 13 independent groups sampled at Site 1179. Colatitude scatter in the section is markedly less in the deepest 33 m of the hole, indicating a shift from rapidly erupted flows in the bottom ~33 m of the section to more slowly emplaced flows above.

(Table 1) Magnetic characteristic properties of selected samples of ODP Hole 134-831B

During Ocean Drilling Program Leg 134 (Vanuatu), geological high sensitivity magnetic tools (GHMT) developed by CEA-LETI and TOTAL were used at two drill sites. GHMT combine two sensors, a proton magnetometer for total magnetic field measurements with an operational accuracy of 0.1 nanoteslas (nT), and a highly sensitive induction tool to measure the magnetic susceptibility with an operational accuracy of a few 10**-6 SI units. Hole 829A was drilled through an accretionary prism and the downhole measurements of susceptibility correlate well with other well-log physical properties. Sharp susceptibility contrasts between chalk and volcanic silt sediment provide complementary data that help define the lithostratigraphic units. At Hole 831B magnetic susceptibility and total field measurements were performed through a 700-m reef carbonate sequence of a guyot deposited on top of an andesitic volcano. The downhole magnetic susceptibility is very low and the amplitude of peak-to-peak anomalies is less than a few 10**-5 SI units. Based on the repeatability of the measurements, the accuracy of the magnetic logging measurements was demonstrated to be excellent. Total magnetic field data at Hole 831B reveal low magnetic anomalies of 0.5 to 5 nT and the measurement of a complete repeat section indicates an accuracy of 0.1 to 0.2 nT. Due to the inclination of the earth's magnetic field in this area (~-40°) and the very low magnetic susceptibility of the carbonate, the contribution of the induced magnetization to the total field measured in the hole is negligible. Unfortunately, because the core recovery was extremely poor (<5%) no detailed comparison between the core measurements and the downhole magnetic data could be made. Most samples have a diamagnetic susceptibility and very low intensity of remanent magnetization (< 10**-4 A/m), but a few samples have a stable remanent magnetization up to 0.005 A/m. These variations of the intensity of the remanent magnetization suggest a very heterogeneous distribution of the magnetization in the carbonate sequence that could explain the magnetic field anomalies measured in these weakly magnetized rocks.

(Table 1) Summary of acoustic properties at DSDP Holes 60-453 and 60-459B

Laboratory measurements of physical properties are important because the results may be applied to the interpretation of seismic and other types of geophysical data, and because they can be used to estimate the in situ physical properties of different lithologies present beneath the sea floor. In this chapter, wet-bulk densities and compressional-wave velocities, measured at elevated confining pressures, are reported for a suite of seven sediment samples recovered on DSDP Leg 60. Of the seven samples studied, two are mudstones, two are vitric tuffs, and three are chalks. All but one of the samples are from Hole 459B, near the eastern limit of the Mariana fore-arc region. In five cases, velocities were measured parallel and perpendicular to bedding to test for velocity anisotropy.

Physical properties of sediment core CRP-1

The relationship between whole-core compressional wave velocities and gamma-ray attenuation porosities of sediments cored at CRP-1 is examined and compared with results from core-plug samples and global models. Both core-plug and whole-core velocities show a strong dependence on porosity: this relationship appears to be independent of lithology. In the range from 0.1 to 0.4 of fractional porosity (Miocene strata), plug velocities are generally 0.2 - 0.5 km s-1 higher than whole-core velocities. Possible reasons include decreased rigidity in the whole core and diagenetic changes in the plugs. Possibly both velocity measurements are correct but neither is fully representative for in situ conditions. It appears that the core-plug results are more compatible with data from other regions than the whole-core data. After removing first-order compaction control from the whole-core porosity record, a second-order control by clay content can be quantified as a simple positive linear regression (R=0.6). In contrast, after correction for first-order control, porosity and velocity are not significantly influenced by lonestone abundance except for rare, very large lonestones.

Photoelectronic properties of zinc phosphide crystals, films and heterojunctions : quarterly progress report no. 6 for the period July 1 - September 30, 1980 /

The purpose of this research program is to investigate the photoelectronic properties of zinc phosphide (Zn₃P₂ in single crystal form, in thin-film form, and in heterojunctions in which Zn₃P₂ forms one of the elements. This research will be directed toward understanding the role of crystalline defects and impurities in Zn₃P₂, the nature of the electronic charge transport in single crystal and thin-film material, and the properties of photovoltaic heterojunctions involving Zn₃P₂. The scope of the program extends from basic investigations of materials properties on single crystals to the preparation and characterization of all-thin-film heterojunction divices. One of the principal motivations behind this research program is the realization that Zn₃P₂ is a relatively uninvestigated yet ideal component for photovoltaic heterojunction use in solar energy conversion. The proposed program will concentrate on the basic materials problems involved with Zn₃P₂, providing the kind of information needed for other more developmental programs directed toward actual practical cells.

Determining Spatial Distribution and Physical Properties of the Vashon Advance Outwash near Mountlake Terrace, Washington

This study is aimed at determining the spatial distribution, physical properties, and groundwater conditions of the Vashon advance outwash (Qva) in the Mountlake Terrace, WA area. The Qva is correlative with the Esperance Sand, as defined at its type section; however, local variations in the Qva are not well-characterized (Mullineaux, 1965). While the Qva is a dense glacial unit with low compressibility and high frictional shear strength (Gurtowski and Boirum, 1989), the strength of this unit can be reduced when it becomes saturated (Tubbs, 1974). This can lead to caving or flowing in excavations, and on a larger scale, can lead to slope failures and mass-wasting when intersected by steep slopes. By studying the Qva, we can better predict how it will behave under certain conditions, which will be beneficial to geologists, hydrogeologists, engineers, and environmental scientists during site assessments and early phases of project planning. In this study, I use data from 27 geotechnical borings from previous field investigations and C-Tech Corporation’s EnterVol software to create three-dimensional models of the subsurface geology in the study area. These models made it possible to visualize the spatial distribution of the Qva in relation to other geologic units. I also conducted a comparative study between data from the borings and generalized published data on the spatial distribution, relative density, soil classification, grain-size distribution, moisture content, groundwater conditions, and aquifer properties of the Qva. I found that the elevation of the top of the Qva ranges from 247 to 477 ft. I found that the Qva is thickest where the modern topography is high, and is thinnest where the topography is low. The thickness of the Qva ranges from absent to 242 ft. Along the northern, east-west trending transect, the Qva thins to the east as it rises above a ridge composed of Pre- Vashon glacial deposits. Along the southern, east-west trending transect, the Qva pinches out against a ridge composed of pre-Vashon interglacial deposits. Two plausible explanations for this ridge are paleotopography and active faulting associated with the Southern Whidbey Fault Zone. Further investigations should be done using geophysical methods and the modeling methods described in this study to determine the nature of this ridge. The relative density of the Qva in the study area ranges from loose to very dense, with the loose end of the spectrum probably relating to heave in saturated sands. I found subtle correlations between density and depth. Volumetric analysis of the soil groups listed in the boring logs indicate that the Qva in the study area is composed of approximately 9.5% gravel, 89.3% sand, and 1.2% silt and clay. The natural moisture content ranges from 3.0 to 35.4% in select samples from the Qva. The moisture content appears to increase with depth and fines content. The water table in the study area ranges in elevation from 231.9 to 458 ft, based on observations and measurements recorded in the boring logs. The results from rising-head and falling-head slug tests done at a single well in the study area indicate that the geometric mean of hydraulic conductivity is 15.93 ft/d (5.62 x 10-03 cm/s), the storativity is 3.28x10-03, and the estimated transmissivity is 738.58 ft2/d in the vicinity of this observation well. At this location, there was 1.73 ft of seasonal variation in groundwater elevation between August 2014 and March 2015.

The prediction and representation of phase equilibria and physicochemical properties in complex slag systems

The development of new experimental techniques for the determination of phase equilibria in complex slag systems, chemical thermodynamic, and viscosity models is reported. The new experimental data, and new thermodynamic and viscosity models, have been combined in a custom-designed computer software package to produce limiting operability diagrams for slag systems. These diagrams are used to describe phase equilibria and physicochemical properties in complex slag systems. The approach is illustrated with calculations on the system FeO-Fe2O3-CaO-SiO-Al2O3 at metallic iron saturation, slags produced in coal slagging gasifiers, and in the reprocessing of nonferrous smelting slags. This article was presented at the Mills Symposium Molten Metals, Slags and Glasses-Characterisation of Properties and Phenomena held in London in August 2000.

Metalorganic chemical vapor deposition of GaAsN epilayers: microstructures and optical properties

In this article, we investigate the parameters used in the MOCVD growth of GaAsN epilayers on GaAs substrates and some of their microstructures and optical properties. The N incorporation was found to mainly depend on the growth temperature and the fractional 1,1-dimethylhydrazine molar flow. A thin highly strained interface layer was observed between GaAsN and GaAs, which, contrary to previously published results, was not N enriched. The low-temperature (10 K) photoluminescence spectra were composed of several emissions that we attribute to a combination of interband transition and transitions involving localized defect states. (C) 2004 Elsevier B.V. All rights reserved.

Enhanced optical properties of the GaAsN/GaAs quantum-well structure by the insertion of InAs monolayers

Microstructural and optical properties of InAs-inserted and reference single GaAsN/GaAs quantum-well (QW) structures grown by metalorganic chemical vapor deposition were investigated using cross-sectional transmission electron microscopy and photoluminescence (PL). Significant enhancement of PL intensity and a blueshift of PL emission were observed from the InAs-inserted GaAsN/GaAs QW structure, compared with the single GaAsN/GaAs QW structure. Strain compensation and In-induced reduction of N incorporation are suggested to be two major factors affecting the optical properties. (C) 2004 American Institute of Physics.