基于图像获取技术的发射度测量方法研究

介绍了HIRFL上利用荧光靶图像获取装置构成多孔屏束流发射度测量系统,对测量数据的处理、光斑面积、周长和束流发射度的计算方法做了重点介绍,该系统具有可靠性好、测量直观、界面友好等优点。

State-selective electron capture for keV He2+ ions on helium collisions studied by recoil momentum spectroscopy

State-selective single electron capture cross sections are measured by recoil ion momentum spectroscopy technique for He2+ on He at 30 keV incident energy. The cross sections for capture into ground and excited states are obtained and compared to classical model calculations as well as to the quantum mechanical calculations. The experimental results are in good agreement with quantum mechanical results.

气相C60在纳秒激光场中的内能分布以及退激研究

本工作建立了激光飞行时间质谱仪，与示波器获取质谱全图技术联合运作，研究了气相C60分子在具有不同空间分布的纳秒激光场中的内能分布规律以及退激产物的分布特征。研究表明，C60分子的内能分布在较低内能区遵循幂指数衰减形式E-b，并且幂指数值b随激光场发散度的增加而增加；在较高内能区的内能分布迅速偏离各自对应的幂指数规律。实验结果与把激光束和分子束看作高斯分布的理论预言符合的很好。对碎片质谱的研究表明，质谱具有明显的双峰分布特征，且激光通量较低时，碎片表现出明显的幻数结构，随着激光通量的增加，幻数结构在质谱中逐渐消失。碎片离子的产额分布表明，激光场的发散度越大，C60分子的碎裂程度随激光通量变化趋势就越快；分析轻碎片离子的峰形分布得到，所有轻碎片离子具有相同的平均初始动能；在近似认为富勒烯离子蒸发一个C2分子具有相同的动能释放的情况下，得到该动能释放值约为0.40±0.02eV。不同激光场中延迟电离与非延迟电离的产额分布表明，激光场发散度越大，两种电离成分随激光通量变化趋势越快，延迟电离成分占总电离成分的百分比越高。通过分析不同激光场中延迟电离离子飞行质谱，实验测量C60分子蒸发中性C2对应的蒸发势垒为10.59±0.17eV

Heat capacity and thermodynamic properties of crystalline ornidazole (C7H10ClN3O3)

The molar heat capacities of 1-(2-hydroxy-3-chloropropyl)-2-methyl-5-nitroimidazole (Ornidazole) (C7H10CIN3O3) with purity of 99.72mol% were measured with an adiabatic calorimeter in the temperature range between 79 and 380K. The melting-point temperature, molar enthalpy Delta(fus)H(m), and entropy, Delta(fus)S(m), of fusion of this compound were determined to be 358.59 +/- 0.04K, 21.38 +/- 0.02 kJ mol(-1) and 59.61 +/- 0.05 J K-1 mol(-1), respectively, from fractional melting experiments. The thermodynamic function data relative to the reference temperature (298.15 K) were calculated based on the heat capacities measurements in the temperature range from 80 to 380 K. The thermal stability of the compound was further investigated by DSC and TG. From the DSC curve an intensive exothermic peak assigned to the thermal decomposition of the compound was observed in the range of 445-590 K with the peak temperature of 505 K. Subsequently, a slow exothermic effect appears when the temperature is higher than 590 K, which is probably due to the further decomposition of the compound. The TG curve indicates the mass loss of the sample starts at about 440K, which corresponds to the decomposition of the sample. (C) 2003 Elsevier B.V. All rights reserved.

长白山北坡水甲虫多样性与环境因子的关系

为了解水甲虫多样性与环境的关系,于2004—2006年每年6—10月在长白山北坡采集不同环境条件下水甲虫标本,共发现水甲虫8科38属70种。研究发现不同的环境,水甲虫的种类、数量、个体大小明显不同。通过多元回归分析发现:水甲虫Shannon-Wiener多样性指数与海拔(r=0.507)、底泥有机质含量(r=0.638)和全磷含量(r=0.668)成明显正相关,与水电导率(r=-0.470)、水深度(r=-0.461)和水pH值(r=-0.470)负相关显著;均匀度指数与底泥有机质含量(r=0.542)和全磷含量(r=0.489)正相关显著;物种数与海拔(r=0.590)、底泥有机质含量(r=0.593)和全磷含量(r=0.618)成正相关,与水深度(r=-0.636)、水电导率(r=-0.558)、水pH值(r=-0.535)成显著负相关。环境因子影响水甲虫的分布,但人类是最终决定因素,了解水甲虫多样性与环境的关系,有助于揭示生物-环境-人类三者之间的关系,为生态系统和生物多样性的修复和保护提供服务。

Primmorphs from archaeocytes-dominant cell population of the sponge Hymeniacidon perleve: Improved cell proliferation and spiculogenesis

Marine sponges (Porifera) possess an extraordinary diversity of bioactive metabolites for new drug discovery and development. In vitro cultivation of sponge cells in a bioreactor system is very attractive for the sustainable production of sponge-derived bioactive metabolites; however, it is still a challenging task. The recent establishment of sponge primmorphs, multicellular aggregates from dissociated mixed-cell population (MCP), has been widely acknowledged to hold great promise for cultivation in vitro. Here we present a new method to establish an in vitro sponge primmorph culture from archaeocyte-dominant cell population (ADCP) enriched by a Ficoll gradient, rather than a mixed-cell population (MCP). Our rationale is based upon the totipotency (the ability of a cell to differentiate into other cell types) of archaeocyte cells and the different biological functions of various sponge cell types. A sponge, Hymeniacidon perleve collected from the China Yellow Sea was used as a model system for this investigation. Distinct dynamics of primmorph formation were observed while significant increases in DNA synthesis, cell proliferation (up to threefold), and cell growth (up to fourfold) were achieved. Furthermore, a time-dependent spiculogenesis was clearly demonstrated in our longterm culture, indicating high metabolic activity of primmorphs from the ADCP. This new method represents an important step forward to advance sponge cell culture in vitro that may lead to commercial exploitation of sponge-derived drugs. (C) 2003 Wiley Periodicals, Inc.

潮滦河小流域鱼鳞坑内外植被群落特征与环境关系

通过对小流域不同坡面上鱼鳞坑的内外群落植被调查,研究了该地区鱼鳞坑内外植被群落特征与海拔及坡向的关系。(1)阴坡鱼鳞坑内的盖度大于阳坡鱼鳞坑内的盖度,并且达到极显著水平。(2)坡向不是控制该区域植被群落多样性的主导因子。(3)不同土地类型鱼鳞坑外的群落丰富度指数,Shannon- Wiener指数及同一土地类型的鱼鳞坑内外群落的指数均与海拔高度成极显著的抛物线函数关系,但是与鱼鳞坑内群落的多样性指数不成显著相关关系。结果显示,可以通过像鱼鳞坑这样的整地方式来改变小生境以促进群落植被的物种多样性。

纳豆的研究与应用

纳豆的研究与应用李宁（中国科学院沈阳应用生态研究所，１１００１５）纳豆是一种简单易得的有营养的优质发酵食品。它是将接种过纳豆菌（Ｂａｃｉｌｌｕｓｎａｔｔｏ）的蒸煮大豆在适当温度、湿度下发酵得到的。纳豆以其特殊的风味广受日本人的喜爱，它作为传统食物在日...

人工合成麝香的环境污染、生态行为与毒理效应研究进展

人工合成麝香作为一种替代型香料被广泛应用于日用化工行业,由于其持续不断地输入环境,其中的一些典型化合物如加乐麝香和吐纳麝香等在水、土壤和大气环境中的浓度日益升高,并且在动物体和人体组织中产生了蓄积作用,其效应相当于持久性有机污染物.因此,人工合成麝香作为一种新型污染物,已成为药物和个人护理品污染物(PPCPs)的重要组成部分.首先对人工合成麝香的种类与应用情况、环境来源和污染水平进行了简要介绍.在此基础上,从人工合成麝香的生物蓄积行为、环境降解行为和生物转化行为等3个方面,对人工合成麝香所具有的持久性有机污染物的行为特征进行了分析;概述了人工合成麝香的环境激素毒性、遗传毒性效应、生理生态毒性、对酶活性的影响以及对微生物毒性效应的研究进展,展示了人工合成麝香所可能产生的不良生态效应.最后,根据目前对人工合成麝香的研究进展,提出了今后有关重点研究内容的建议,为合理评价和降低人工合成麝香的生态风险提供理论基础.

新型TCAS吸附树脂对水中Cd~(2+)的吸附去除研究

通过静态吸附试验,研究一种由超分子受体化合物磺化硫杂杯芳烃(TCAS)与树脂结合的产物——新型TCAS吸附树脂对重金属Cd2+的吸附去除性能,并初步探讨了吸附机理。试验研究结果表明,TCAS吸附树脂对Cd2+的饱和吸附量为14.45 mg/g。当温度为20℃,0.5 g TCAS吸附树脂对10 mL浓度为5 mg/L的Cd2+溶液吸附60 min时,Cd2+的去除率可达到99%以上。pH值是影响TCAS吸附树脂吸附效果的重要因素,在pH=5~9时,Cd2+的去除率随着pH值的升高而增大。在试验范围内,TCAS吸附树脂对Cd2+吸附符合Freundlich方程。吸附在TCAS吸附树脂上的Cd2+可洗脱回收,TCAS吸附树脂也可再生利用。TCAS吸附树脂对重金属Cd2+的吸附机理主要归因于TCAS对Cd2+的络合作用。

Photoluminescence properties of LaF3: Eu3+ nanoparticles prepared by refluxing method

The europium-doped LaF3 nanoparticles were prepared by refluxing method in glycerol/water mixture and characterized with X-ray diffraction(XRD), field emission scanning electron microscopy(FE-SEM), UV-vis diffuse reflectance spectrum, and photoluminescence spectra. The results of XRD indicated that the obtained LaF3: Eu3+ nanoparticles were well crystallized with a hexagonal structure. ne FE-SEM image illustrated that the LaF3: Eu3+ nanoparticles were spherical with an average size around 30 nm. Under irradiation of UV light, the emission spectrum of LaF3: Eu3+ nanoparticles exhibited the characteristic line emissions arising front the D-5(0)-> F-7(J), (J=1, 2, 3, 4) transitions of the Eu3+ ions, with the dominating emission centered at 590 nm. In addition, the emissions from the 51), level could be clearly observed due to the low phonon energies (-350 cm(-1)) of LaF3 matrix. The optimum doping concentration for LaF3: Eu3+ nanoparticles was determined to be 20mol.%.

Nanoreactor of Fe3O4@SiO2 Core-Shell Structure with Nanochannels for Efficient Catalysis

We introduced a new nanoreactor system consisting of nanochannel-filled Fe3O4 core and SiO2 shell. Different morphologies of Fe3O4@SiO2 Core-shell nanostructures could be obtained through simple HCI etching of the magnetic cores. The outer silica shells were permeable and the Fe3O4 cores were accessible to the reactants. Therefore, the present nanoreactor system was applied to catalyze the reduction of H2O2, and it showed outstanding catalytic activity compared with bare Fe3O4 or Fe3O4@SiO2 core-shell nanoparticles.