Concentrations of organic compounds in suspended matter from surface waters and surface layer bottom sediments of the Obskay Guba (Ob River estuary) and the Kara Sea

Data are presented on concentrations of aliphatic and polycyclic aromatic hydrocarbons (AHC and PAH) in interstitial waters and bottom sediments of the Kara Sea compared to distribution of particulate matter and organic carbon. It was found that AHC concentrations within the water mass (aver. 16 µg/l) are mainly formed by natural processes. Distribution of AHC represents variability of hydrological and sedimentation processes in different regions of the sea. The widest ranges of the concentrations occurred in the Obskaya Guba - Kara Sea section: in water (10-310 µg/l for AHC and 0.4-7.2 ng/l for PAH) and in the surface layer of the bottom sediments (8-42 µg/l for AHC and 9-94 ng/g for PAH). Differentiation of hydrocarbons (HC) in different media follows regularities typical for marginal filters; therefore no oil and pyrogenic compounds are supplied to the open sea. In sediments contents of HC depend on variations in redox conditions in sediments and on their composition.

Chemical and mineral compositions of bottom sediments from the East Pacific Rise near 13°N

During underwater photography and sampling of the rift valley bottom in the axial part of the East Pacific Rise, where water transparency is reduced due to hydrothermal input, ore manifestations have been found. The bottom is covered by them as by a jacket on both sides from the EPR axial zone. However, exposed pillow-lavas and clumpy blocks in rift ledges are covered by a thin metal-bearing film. It is supposed that sedimentation results mainly from hydrothermal input of dissolved chemical elements in seawater, their transformation on the geochemical barrier, and subsequent deposition as particulates. Contents of ore components in metalliferous sediments have been measured by atomic-absorption and X-ray radiometry methods. Sediment age has been determined as Middle Pleistocene - Holocene. Maximal hydrothermal activity was at the beginning of Early Holocene, about 10 Ka. A smoker has been found on the western slope of the rift valley.

Composition of sediments, rocks, and ores from the Northern and Equatorial Indian Ocean

The monograph has been written on the base of data obtained from samples and materials collected during the 19-th cruise of RV ''Akademik Vernadsky'' to the Northern and Equatorial Indian Ocean. Geological features of the region (stratigraphy, tectonic structure, lithology, distribution of ore-forming components in bottom sediments, petrography of igneous rocks, etc.) are under consideration. Regularities of trace element concentration in Fe-Mn nodules, nodule distribution in bottom sediments, and engineering-geological properties of sediments within the nodule fields have been studied. Much attention is paid to ocean crust rocks. The wide range of ore mineralization (magnetite, chromite, chalcopyrite, pyrite, pentlandite, and other minerals) has been ascertained.

Results of bulk sediment X-ray diffraction analysis and quantification of mineral phases based on the RockJock and on the QUAX quantitative analysis

We have performed quantitative X-ray diffraction (qXRD) analysis of 157 grab or core-top samples from the western Nordic Seas between (WNS) ~57°-75°N and 5° to 45° W. The RockJock Vs6 analysis includes non-clay (20) and clay (10) mineral species in the <2 mm size fraction that sum to 100 weight %. The data matrix was reduced to 9 and 6 variables respectively by excluding minerals with low weight% and by grouping into larger groups, such as the alkali and plagioclase feldspars. Because of its potential dual origins calcite was placed outside of the sum. We initially hypothesized that a combination of regional bedrock outcrops and transport associated with drift-ice, meltwater plumes, and bottom currents would result in 6 clusters defined by "similar" mineral compositions. The hypothesis was tested by use of a fuzzy k-mean clustering algorithm and key minerals were identified by step-wise Discriminant Function Analysis. Key minerals in defining the clusters include quartz, pyroxene, muscovite, and amphibole. With 5 clusters, 87.5% of the observations are correctly classified. The geographic distributions of the five k-mean clusters compares reasonably well with the original hypothesis. The close spatial relationship between bedrock geology and discrete cluster membership stresses the importance of this variable at both the WNS-scale and at a more local scale in NE Greenland.

Grain size distribution and percentiles of the sand component from sediments obtained in the southern Great Belt, Baltic Sea

Im Sedimentationsraum der südwestlichen Ostsee verdient der nordöstliche Teil der Kieler Bucht besonderes Interesse. Dort öffnet sich die wichtigste Verbindung zwischen Ostsee und Nordsee. Von den Austauschvorgängen, durch welche diese Meeresräume aufeinander Einfluß nehmen, ist gerade jenes Gebiet entscheidend betroffen. Die Beobachtung der Dynamik des Austausches, die Beobachtung der Transportlast, welche von den Wassermassen bewegt wird, und schließlich auch die Beobachtung der Beziehungen, welche sich zwischen dem Zusammentreffen von Wassermassen unterschiedlicher physikalischer Eigenschaften und der Sedimentbildung ergeben, läßt deshalb vor allem dort wesentliche Hinweise zum Verständnis der Sedimentationsvorgänge in der südlichen Ostsee erhoffen. In der vorliegenden Arbeit wurden an 49 Durchschnittsproben die Korngrößenverteilungen und Schwermineralgehalte von Sedimenten aus dem Südausgang des Großen Beltes untersucht. 1. Es wurden sechs in sich morphologisch etwa gleichwertige Gebiete ausgegliedert, die jeweils durch Sedimente mit ähnlichen Korngrößenverteilungen ausgezeichnet sind. Nach Lage, Typ und genetischer Ausdeutbarkeit fügen sich diese Gebiete dem von O. PRATJE (1939, 1948) gegebenen Modell der Sedimentationszonen gut ein. 2. Innerhalb dieser Gebiete ergibt sich für Sande in mehr als 20 m Wassertiefe südwärts gerichteter Transport. Oberhalb dieser Tiefe läßt sich stellenweise nordwärts gerichteter Transport nachweisen. 3. Der Schwermineralgehalt der Sedimente bleibt immer unter zwei Prozent. Die höchsten Anteile (1,7 bzw. 1,9%) werden in den Sedimenten der Tiefen Rinne und der ufernahen Bereiche des Großen Beltes angetroffen. 4. Die Korngrößenverteilungen der Sedimente werden nach der Lage der Modi in bis zu drei (Kies-, Sand-, Silt-) Komponenten zerlegt. Die Beteiligung der Silt-Komponente wird entscheidend von der Salzgehaltssprungschicht beeinflußt. 5. Es bestehen offensichtlich Zusammenhänge zwischen der Schlicksedimentation und der Salzgehaltsschichtung auch in der weiteren südlichen Ostsee.

Composition of minerals from peridotides at the Mid-Atlantic Ridge, 13°N

Peridotites (diopside-bearing harzburgites) found at 13°N of the Mid-Atlantic Ridge fall into two compositional groups. Peridotites P1 are plagioclase-free rocks with minerals of uniform composition and Ca-pyroxene strongly depleted in highly incompatible elements. Peridotites P2 bear evidence of interaction with basic melt: mafic veinlets; wide variations in mineral composition; enrichment of minerals in highly incompatible elements (Na, Zr, and LREE); enrichment of minerals in moderately incompatible elements (Ti, Y, and HREE) from P1 level to abundances 4-10 times higher toward the contacts with mafic aggregates; and exotic mineral assemblages Cr-spinel + rutile and Cr-spinel + ilmenite in peridotite and pentlandite + rutile in mafic veinlets. Anomalous incompatible-element enrichment of minerals from peridotites P2 occurred at the spinel-plagioclase facies boundary, which corresponds to pressure of about 0.8-0.9 GPa. Temperature and oxygen fugacity were estimated from spinel-orthopyroxene-olivine equilibria. Peridotites P1 with uniform mineral composition record temperature of the last complete recrystallization at 940-1050°C and FMQ buffer oxygen fugacity within the calculation error. In peridotites P2, local assemblages have different compositions of coexisting minerals, which reflects repeated partial recrystallization during heating to magmatic temperatures (above 1200°C) and subsequent reequilibration at temperatures decreasing to 910°C and oxygen fugacity significantly higher than FMQ buffer (delta log fO2 = 1.3-1.9). Mafic veins are considered to be a crystallization product from basic melt enriched in Mg and Ni via interaction with peridotite. The geochemical type of melt reconstructed by the equilibrium with Ca-pyroxene is defined as T-MORB: (La/Sm)_N~1.6 and (Ce/Yb) )_N~2.3 that is well consistent with compositional variations of modern basaltic lavas in this segment of the Mid-Atlantic Ridge, including new data on quenched basaltic glasses.

Chemical composition of phosphorites from the Peru and Chile shelves

Recent and Late Quaternary shelf phosphorites have low Fe, Ti and Al contents. These elements enter the phosphorites with terrigenous impurities and organic detritus. Ti, Al, and some Fe are removed when the phosphorites are lithified, whereas remaining iron settles in the phosphorites as sulfides. Ti/Fe, Al/Fe and Ti/Al ratios are used as examples of difference between behavior of Fe and that of Ti and Al.