Carbonate and Aluminium accumulation in the central equatorial Pacific Ocean

We examined the flux of Al to sediment accumulating beneath the zone of elevated productivity in the central equatorial Pacific Ocean, along a surface sediment transect at 135°W as well as downcore for a 650 kyr record at 1.3°N, 133.6°W. Across the surface transect, a pronounced, broadly equatorially symmetric increase in Al accumulation is observed, relative to Ti, with Al/Ti ratios reaching values 3-4 times that of potential detrital sources. The profile parallels biogenic accumulation and the modeled flux of particulate 234Th, suggesting rapid and preferential adsorptive removal of Al from seawater by settling biogenic particles. Normative calculations confirm that most Al is unsupported by the terrigenous fraction. The observed distributions are consistent with previous observations of the relative and absolute behavior of Al and Ti in seawater, and we can construct a reasonable mass balance between the amount of seawater-sourced Al retained in the sediment and the amount of seawater Al available in the overlying column. The close tie between Al/Ti and biogenic accumulation (as opposed to concentration) emphasizes that biogenic sedimentary Al/Ti responds to removal-transport phenomena and not bulk sediment composition. Thus, in these sediments dominated by the biogenic component, the bulk Al/Ti ratio reflects biogenic particle flux, and by extension, productivity of the overlying seawater. The downcore profile of Al/Ti at 1.3°N displays marked increases during glacial episodes, similar to that observed across the surface transect, from a background value near Al/Ti of average upper crust. The excursions in Al/Ti are stratigraphically coincident with maxima in both bulk and CaCO3 accumulation and the excess Al appears to not be preferentially affiliated with opaline or organic phases. Consistent with the similar behavioral removal of Al and 234Th, the latter of which responds to the total particle flux, the Al flux reflects carbonate accumulation only because carbonate comprises the dominant flux in these particular deposits. These results collectively indicate that (1) Al in biogenic sediment and settling biogenic particles is strongly affected by a component adsorbed from seawater. Therefore, the common tenet that Al is dominantly associated with terrestrial particulate matter, and the subsequent use of Al distributions to calculate the abundance and flux of terrestrial material in settling particles and sediment, needs to be reevaluated. (2) The Al/Ti ratio in biogenic sediment can be used to trace the productivity of the overlying water, providing a powerful new paleochemical tool to investigate oceanic response to climatic variation. (3) The close correlation between the Al/Ti productivity signal and carbonate maxima downcore at 1.3°N suggests that the sedimentary carbonate maxima in the central equatorial Pacific Ocean record increased productivity during glacial episodes.

The hydropolyp fauna of the Red Sea area

46 hydropolyp species of 28 genera and 10 families were sampled during the "Meteor" passage 1964/65 (IIOE) through the Red Sea and its northern and southern exits and on the occasion of several ecological investigations of 29 selected coral reef sections of the central Red Sea and the Gulf of Aqaba. These collections comprise 128 single records of hydropolyp species. Three species and two genera each with one species are doubtful. 25 species, seven genera, one family and one subfamily, together from 49 records have not previously been found in the Red Sea and its exits. Including these newly reported species, the total list increases from 64 species and 112 records to 89 species and 240 single records and 51 additional ones. Scanning microscopical photos, made for the first time for the illustration of the hydropolyps, have been shown to be suitable for a better characterization and diagnosis of the species. Qualified results on the reasons for the horizontal distribution of the species known from the Red Sea area cannot be given because of the low number of samples sporadically distributed through the whole area. In contrast with this fact, the vertical spread of the species sampled seems primarily to be regulated by water exchange and light intensity. For example, four species of hydropolyps are excellent indicators of certain abiotic factors or combinations of them: Gymnangium eximium reacts extremely stenophote-photophobe-rheophil, Eudendrium ramosum moderately stenophote-photophobe-rheophobe, Lytocarpus philippinus moderately stenophote-photophil-rheophil, and Halocordyle disticha var. australis extremely stenophote-photophil but moderately rheophil. Other species have been found throughout all the light zones. Combined with the small size of their colonies their euryphotic behaviour does not allow their use as indicator species.

Element concentrations and isotopic composition of tholeiite and whole rocks samples from the east Mariana Basin

Studies of seafloor magnetic anomaly patterns suggest the presence of Jurassic oceanic crust in a large area in the western Pacific that includes the East Mariana, Nauru and Pigafetta Basins. Sampling of the igneous crust in this area by the Deep Sea Drilling Program (DSDP) and the Ocean Drilling Program (ODP) allows direct evaluation of the age and petrogenesis of this crust. ODP Leg 129 drilled a 51 m sequence of basalt pillows and massive flows in the central East Mariana Basin. 40Ar/39Ar ages determined in this study for two Leg 129 basalts average 114.6 +/- 3.2 Ma. This age is in agreement with the Albian-late Aptian paleontologic age of the overlying sediments, but is distinctively younger than the Jurassic age predicted by magnetic anomaly patterns in the basin. Compositionally, the East Mariana Basin basalts are uniformly low-K tholeiites that are depleted in highly incompatible elements compared to moderately incompatible ones, which is typical of mid-ocean ridge basalts (MORB) erupted near hotspots. The Sr, Nd and Pb isotopic compositions of the tholeiites (87Sr/86Sr init = 0.70360-0.70374; 143Nd/144Nd init = 0.512769-0.512790; 206Pb/204Pb meas = 18.355-18.386) also overlap with some Indian Ocean Ridge MORB, although they are distinct from the isotopic compositions of Jurassic basalts drilled in the Pigafetta Basin, the oldest Pacific MORB. The isotopic compositions of the East Mariana Basin tholeiites are also similar to those of intraplate basalts, and in particular, to the isotopic signature of basalts from the nearby Ontong Java and Manihiki Plateaus. The East Mariana Basin tholeiites also share many petrologic and isotopic characteristics with the oceanic basement drilled in the Nauru Basin at DSDP Site 462. In addition, the new 110.8 +/- 1.0 Ma 40Ar/39Ar age for two flows from the bottom of Site 462 in the Nauru Basin is indistinguishable from the age of the East Mariana Basin flows. Thus, while magnetic anomaly patterns predict that the igneous basement in the Nauru and East Mariana Basins is Jurassic in age, the geochemical and chronological results discussed here suggest that the basement formed during a Cretaceous rifting event within the Jurassic crust. This magmatic and tectonic event was created by the widespread volcanism responsible for the genesis of the large oceanic plateaus of the western Pacific.

(Table 3) Stable oxagen isotope record of planktonic foraminifera from Central Walvish Ridge

Above the Walvis Ridge, in the SE Atlantic Ocean, we collected living plantkic foraminifera from the upper water column using depth stratified plantkon tows. The oxygen isotope composition (d18Oc) in shells of foraminifera and shell concentration profiles show seasonal and depth habitats of individual species. The tow results are compared with the average annual deposition d18Oc from sediment traps and the interannual average d18Oc of fossil specimens in top sediments at the same site. The species Globigerinita glutinata best reflects the austral winter/spring sea surface temperature (SST). Its d18Oc signal in top sediments remains pristine. In contrast, tow results also show that Globigerinoides ruber continues to calcify below the surface mixed layer (SML), i.e., down to the deep chlorophyll maximum (DCM); hence its d18Oc signature of exported specimens reflects the SST only when SML incorporates the DCM. Deep tow and sediment trap results show that both Globorotalia truncatulinoides and Globorotalia inflata record the temperature between 150 and 350 m, depending on the season and the shell size. However, for all fossil taxa in sediments apart from Globigerinita glutinata, we observe a positive d18Oc shift with respect to the sediment trap and plankton tow values, likely related to the interannual flux changes and deep encrustation.

Recorriendo las Tolderías de Valentín Sayhueque : Reminiscencias de Francisco Moreno 1870-1880

El presente trabajo tiene como objetivo mostrar y analizar las relaciones fronterizas entre indígenas, cronistas, viajeros y agentes del gobierno de Buenos Aires en el período de 1870 a 1880. Se prestará especial atención a las vinculaciones entre estos "mundos" a partir de los viajes que realizó Moreno a los toldos del cacique Valentín Sayhueque y su comunidad en las regiones aledañas al Lago Nahuel Huapi. No se descarta la influencia de otros cronistas de época (Cox y Musters) como tampoco la impronta de personajes centrales en el contexto (Zeballos y Roca). Los viajeros que recorrieron la Patagonia dejaron testimonios claves para comprender el proceso que se dio entre las sociedades indígenas y el Estado nacional argentino a fines del siglo XIX. Su análisis a través de una mirada crítica da la pauta de cómo las sociedades nativas fueron observadas y estudiadas desde el gobierno de Buenos Aires y países extranjeros. La actual Patagonia fue un punto de atracción (y lo sigue siendo), para muchos individuos que no conocen el lugar. Su naturaleza, paisaje, vegetación eran únicos y muy atractivos. Sus tierras eran habitadas por sujetos que no tenían las mismas formas de vida que el resto de las regiones del momento. Habían desarrollado costumbres, formas de comunicación, comercio e intercambio, relaciones sociales, festividades. Cronistas como Francisco Moreno son nodales para adentrarnos al mundo nativo desde otro ángulo, ya que nos muestra las relaciones en el espacio de frontera y los propósitos del gobierno de Buenos Aires en el momento de las campañas militares. Desde el punto de vista metodológico se ha recurrido a la Etnohistoria para abordar nuestro problema desde una óptica diferente y alimentando la investigación en curso

Hydrochemistry measured on water bottle samples during the METEOR International Indian Ocean Expedition 1964/65

The present volume gives the observed physical and chemical data obtained by R.V. "Meteor" in the Indian Ocean during cruise 1964/65. The tables are based on the computations made by the National Oceanographic Data Center (NODC) in Washington. In addition to the normally communicated data, the tables contain four chemical parameters: alkalinity, ammonia, fluoride, and calcium.

Abundances and ebridian skeleton contents from IODP Exp302

Abundant and diversified ebridians recovered during IODP Expedition 302 (ACEX) have been identified and counted in order to establish their taxonomy and to decipher the biostratigraphic potential of ebridians in the central Arctic Ocean. In the ACEX samples these fossils are preserved in Lithologic Units 1/6 and 2, which consist mainly of dark silty clay and biosiliceous ooze, respectively. Thirty taxa have been distinguished, three of which are described as new species (Ammmodochium lomonosovense, Pseudammodochium karyon, and pseudammodochium psichion). The most dominant ebridian species is Pseudammodochium dictyoides throughout the biosiliceous section. The second dominant species varies alternately throughout the section. Based on the characteristic occurrences of major ebridian taxa, the ebridian assemblageswere divided into GroupsAtoDin stratigraphic order. The ebridian assemblages in piston core USGS Fl-422 from the Alpha Ridge probably correlate to our assemblage Group A of early middle Eocene age, although rare younger taxa are irregularly included.

Abundances and contents of major silicoflagellates from IODP Holes of Exp302

The silicoflagellate taxa obtained in IODP Expedition 302 (ACEX) were identified and counted in order to establish the silicoflagellate biostratigraphy in the central Arctic Ocean. These microfossils in the ACEX samples were preserved in the Lithology Units 1/6 and 2, which are dark silty clay and biosiliceous ooze, respectively. The silicoflagellate skeletons in the ACEX samples are assigned to 56 taxa. Seven taxa were described as new species, which were abundant in Lithology Unit 2. Comparison with several study cases outside the Eocene Arctic Ocean suggested that the silicoflagellate assemblages in ACEX were unique in Lithology Unit 2. The dominance of silicoflagellate taxa varied throughout the lithological section. Based on the cluster analysis by Morishita similarity index C(Lambda), the silicoflagellate assemblageswere divided into nine assemblage groups. The silicoflagellate datum event of the first occurrence of Corbisema hexacantha in the lower part of Lithology Unit 1/6 is regarded. Based on the datum events for silicoflagellate and palynomorphs, the assigned epoch of Lithology Units 1/6 and 2 is the middle Eocene.

Chemistry and accumulation rates of Jurassic to early Cretaceous sediments from the central equatorial Pacific

Sedimentation in the central Pacific during the Jurassic and Early Cretaceous was dominated by abundant biogenic silica. A synthesis of the stratigraphy, lithology, petrology, and geochemistry of the radiolarites in Sites 801 and 800 documents the sedimentation processes and trends in the equatorial central Pacific from the Middle Jurassic through the Early Cretaceous. Paleolatitude and paleodepth reconstructions enable comparisons with previous DSDP sites and identification of the general patterns of sedimentation over a wide region of the Pacific. Clayey radiolarites dominated sedimentation on Pacific oceanic crust within tropical paleolatitudes from at least the latest Bathonian through Tithonian. Radiolarian productivity rose to a peak within 5° of the paleoequator, where accumulation rates of biogenic silica exceeded 1000 g/cm**2/m.y. Wavy-bedded radiolarian cherts developed in the upper Tithonian at Site 801 coinciding with the proximity of this site to the paleoequator. Ribbon-bedding of some radiolarian cherts exposed on Pacific margins may have formed from silicification of radiolarite deposited near the equatorial high-productivity zone where radiolarian/clay ratios were high. Silicification processes in sediments extensively mixed by bioturbation or enriched in clay or carbonate generally resulted in discontinuous bands or nodules of porcellanite or chert, e.g., a "knobby" radiolarite. Ribbon-bedded cherts require primary alternations of radiolarian-rich and clay-rich layers as an initial structural template, coupled with abundant biogenic silica in both layers. During diagenesis, migration of silica from clay-rich layers leaves radiolarian "ghosts" or voids, and the precipitation in adjacent radiolarite layers results in silicification of the inter-radiolarian matrix and infilling of radiolarian tests. Alternations of claystone and clay-rich radiolarian grainstone were deposited during the Callovian at Site 801 and during the Berriasian-Valanginian at Site 800, but did not silicify to form bedded chert. Carbonate was not preserved on the Pacific oceanic floor or spreading ridges during the Jurassic, perhaps due to an elevated level of dissolved carbon dioxide. During the Berriasian through Hauterivian, the carbonate compensation depth (CCD) descended to approximately 3500 m, permitting the accumulation of siliceous limestones at near-ridge sites. Carbonate accumulation rates exceeded 1500 g/cm**2/m.y. at sites above the CCD, yet there is no evidence of an equatorial carbonate bulge during the Early Cretaceous. In the Barremian and Aptian, the CCD rose, coincident with the onset of mid-plate volcanic activity. Abundance of Fe and Mn and the associated formation of authigenic Fe-smectite clays was a function of proximity to the spreading ridges, with secondary enrichments occurring during episodes of spreading-center reorganizations. Callovian radiolarite at Site 801 is anomalously depleted in Mn, which resulted either from inhibited precipitation of Mn-oxides by lower pH of interstitial waters induced by high dissolved oceanic CO2 levels or from diagenetic mobilization of Mn. Influx of terrigenous (eolian) clay apparently changed with paleolatitude and geological age. Cyclic variations in productivity of radiolarians and of nannofossils and in the influx of terrigenous clay are attributed to Milankovitch climatic cycles of precession (20,000 yr) and eccentricity (100,000 yr). Diagenetic redistribution of biogenic silica and carbonate enhanced the expression of this cyclic sedimentation. Jurassic and Lower Cretaceous sediments were deposited under oxygenated bottom-water conditions at all depths, accompanied by bioturbation and pervasive oxidation of organic carbon and metals. Despite the more "equable" climate conditions of the Mesozoic, the super-ocean of the Pacific experienced adequate deep-water circulation to prevent stagnation. Efficient nutrient recycling may have been a factor in the abundance of radiolarians in this ocean basin.

(Table 2) Observations of anticyclonic lenses of Mediterranean water in the Central North Atlantic

Analyses of spatial structure of hydrophysical fields and its vertical evolution in the Northeast Atlantic in a layer from the surface down to 2-2.5 km are carried out based on results of measurements in a testing area (31°-36°N, 20°-26°W) southeast of the Azores in autumn 1993. A description of an anti-cyclonic lens (ACL) of Mediterranean water (MW), which was found in the eastern part of the testing area from data of sets of sequential surveys, is presented. Analysis of CTD and XBT measurements in an area west of the lens allows to conclude that despite some contraction of width of the Azores Current directed eastward (from 60-80 km to 50-60 km) its total eastward volume transport for a period of time from October to November does not vary much. It is shown that intermediate salinity maxima in the northern part of the testing area formed by advection of MW and meddy destruction weakens while intersecting the Azores frontal zone (AFZ) from north to south, displacing itself to larger depth, and increases in thickness. Analysis of data shows that the number of lenses observed within the selected area north of the AFZ is two times more than that observed south of it. North of the AFZ observed salinity maximum and local temperature maxima may be associated with accumulation of heat and salt because of the fact that the AFZ is not only a southern boundary of penetration of MW into the North Atlantic, but also is a "semitransparent" boundary for Mediterranean lenses.