Is the pinning of ordinary dislocations in γ-TiAl intrinsic or extrinsic in nature? A combined atomistic and kinetic Monte Carlo approach

We address the question of the observed pinning of 1/2

Pinning down the solid-state polymorphism of the ionic liquid [bmim][PF6]

The solid-state polymorphism of the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate, [bmim][PF6], has been investigated via low-temperature and high-pressure crystallisation experiments. The samples have been characterised by single-crystal X-ray diffraction, optical microscopy and Raman spectroscopy. The solid-state phase behaviour of the compound is confirmed and clarified with respect to previous phase diagrams. The structures of the previously reported gamma-form, which essentially exhibits a G'T cation conformation, as well as those of the elusive beta- and alpha-forms, are reported. Crystals of the beta-phase are twinned and the structure is heavily disordered; the cation conformation in this form is predominantly TT, though significant contributions from other less frequently encountered conformers are also observed at low temperature and high pressure. The cation conformation in the alpha-form is GT; the presence of the G'T conformer at 193 K in this phase can be eliminated on cooling to 100 K. Whilst X-ray structural data are overall in good agreement with previous interpretations based on Raman and NMR studies, they also reveal a more subtle interplay of intermolecular interactions, which give rise to a wider range of conformers than previously considered.

Fermi level de-pinning of aluminium contacts to n-type germanium using thin atomic layer deposited layers

Fermi-level pinning of aluminium on n-type germanium (n-Ge) was reduced by insertion of a thin interfacial dielectric by atomic layer deposition. The barrier height for aluminium contacts on n-Ge was reduced from 0.7 eV to a value of 0.28 eV for a thin Al2O3 interfacial layer (∼2.8 nm). For diodes with an Al2O3 interfacial layer, the contact resistance started to increase for layer thicknesses above 2.8 nm. For diodes with a HfO2 interfacial layer, the barrier height was also reduced but the contact resistance increased dramatically for layer thicknesses above 1.5 nm.

Ab initio study of the charge order and Zener polaron formation in half-doped manganites

The character of the electronic ground state of La0.5Ca0.5MnO3 has been addressed with quantum chemical calculations on large embedded clusters. We find a charge ordered state for the crystal structure reported by Radaelli et al. [Phys. Rev. B 55, 3015 (1997)] and Zener polaron formation in the crystal structure with equivalent Mn sites proposed by Daoud-Aladine et al. [Phys. Rev. Lett. 89, 097205 (2002)]. Important O to Mn charge transfer effects are observed for the Zener polaron.

Influence of z-pinning on the buckling of composite laminates under edge-wise compression

Z-pinning is a newly developed technique to enhance the strength of composite laminates in the thickness direction. Recent experimental and theoretical studies have shown that z-pins significantly improve mode I and mode II fracture toughness. In practice, buckling accompanying delamination is a typical failure mode in laminated composite structures. For a complete understanding of the z-pinning technique towards improvements of the overall mechanical properties of laminated composites, a numerical model is developed in this paper to investigate the influence of z-pins on the buckling composite laminates with initial delaminations under edge-wise compression. The numerical results indicate that z-pinning can indeed effectively increase the compressive strength of the composite laminates provided that the initial imperfection is within a certain range. The magnitude of the improvement is consistent with available experimental data.

Pinning down the elemental

Book review of 'The taste of river water' by Cate Kennedy.

A reevaluation of forces measured across thin polymer films : nonequillibrium and pinning effects

We have measured forces between molecularly smooth solid surfaces separated by thin films of molten polydimethylsiloxane. We show that a long-range repulsion reported in earlier work is not an equilibrium force, but can be attributed to viscous drag effects. Consistent with previous results, the viscosity of the film can be modeled by assuming that a layer of polymer molecules is immobilized or ‘‘pinned’’ at each surface for a time longer than the time scale of the measurements. We propose that this pinning is a result of entanglement-like effects in the vicinity of a wall.

Synchronization of singular Markovian jumping complex networks with additive time-varying delays via pinning control

Abstract
This study examines the problem of synchronization for singular complex dynamical networks with Markovian jumping parameters and two additive time-varying delay components. The complex networks consist of m modes which switch from one mode to another according to a Markovian chain with known transition probability. Pinning control strategies are designed to make the singular complex networks synchronized. Based on the appropriate Lyapunov-Krasovskii functional, introducing some free weighting matrices and using convexity of matrix functions, a novel synchronization criterion is derived. The proposed sufficient conditions are established in the form of linear matrix inequalities. Finally, a numerical example is presented to illustrate the effectiveness of the obtained results.

Surface effects on vortex dynamics in thin type-II superconducting stripes with random pinning

We analyze the dynamics of a driven vortex lattice moving in a thin Superconducting stripe. The two dimensional stripe is assumed to be finite in the longitudinal direction, where we take into account the Surface effects, and infinite in the transversal direction. The numerical simulations are performed using the Langevin dynamics, including the vortex-vortex interaction, interaction of vortices with the surface current, vortex images, transport current and randomly distributed pinning centers. We show results for the differential resistivity and the vortex trajectories as a function of the external force. (C) 2004 Elsevier B.V. All rights reserved.