987 resultados para C-12(LI-6,D)O-16


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Pour toute demande de reproduction de contenu se trouvant dans cette publication, communiquer avec l’Association des diplômés de l’UdeM.

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Pour toute demande de reproduction de contenu se trouvant dans cette publication, communiquer avec l’Association des diplômés de l’UdeM.

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Les penseurs de l’herméneutique du XXe siècle ont redéfini essentiellement l’humain comme un être en quête de sens, interprétant sans cesse le ‘monde’ à travers ‘son propre monde’, cette compréhension transformante contribuant à son devenir. Serait-il pertinent dans une recherche de sens qui caractérise une démarche de foi, d’utiliser des outils herméneutiques ouvrant les Écritures sur d’autres possibles que ce que la Tradition chrétienne propose aujourd’hui ? Le présent mémoire veut répondre par l’affirmative à ce défi, en appliquant une approche processuelle sur le chapitre 16 du livre d’Ézéchiel, un prophète avec lequel la tradition juive a gardé une certaine prudence et un texte particulièrement osé que la pastorale chrétienne a ignoré. Après une mise en situation qui trace les paramètres fondamentaux de la démarche entreprise dans ce mémoire (chapitre 1), une traduction littérale du texte hébreu est proposée, faisant ressortir les nuances que suggèrent les formes verbales et les éléments particuliers que révèle une analyse macro-syntaxique (chapitre 2); la méthode d’analyse processuelle choisie pour interpréter le texte est inédite dans le monde francophone, tout comme la perspective processuelle de l’étude telle qu’elle se déploie dans les chapitres 3 et 4 du mémoire. L’analyse débouche sur des propositions théologiques originales, redéfinissant notamment la Toute-Puissance divine comme un entêtement qui cherche à convaincre, et inscrivant le pardon divin au creux de la liberté et de la responsabilité humaines.

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Se narra el proceso de gestaci??n del Proyecto 'From their past comes our future' y las actividades realizadas en el encuentro que alumnos de los centros participantes realizaron, en mayo de 2006, en la localidad francesa de Saint Witz, cerca de Par??s. El proyecto gira en torno la historia de las guerras mundiales, est?? coordinado por el IES S??nchez Lastra de Mieres (Asturias) y en el participan los centros de Ense??anza Secundaria: Lyc??e Leonard de Vinci de Saint Witz; Gimnazjum nr 1 Mikolaja Kopernika (Laziska G??rne, Polonia); Mainholm Academy (Ayrshire, Escocia); y VOSP a Stredni pedagogicka skola (Litomysl, Rep??blica Checa).

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A rare mu(6)-oxo-centered Mn-6 mixed-valent cluster (1) is prepared and used as a secondary building unit for the self-assembly of its azido-bridged polymeric analogue (2) in a systematic way with the retention of the Mn-6 core of (1). Both complexes are characterized by X-ray single-crystal structure determination. The complex 1 was crystallized in a monoclinic system, space group P2(1), a = 11.252(5) A, b = 20.893(9) A, c = 12.301(6) A, and beta = 115.853(7)degrees, whereas the polymeric analogue was crystallized in an orthorhombic system, space group P2(1)2(1)2(1), a = 13.1941(8) A, b = 14.9897(9) A, and c = 27.8746(14) A. Variable-temperature magnetic behavior showed the presence of strong antiferromagnetic interaction in both cases.

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This paper considers the motion planning problem for oriented vehicles travelling at unit speed in a 3-D space. A Lie group formulation arises naturally and the vehicles are modeled as kinematic control systems with drift defined on the orthonormal frame bundles of particular Riemannian manifolds, specifically, the 3-D space forms Euclidean space E-3, the sphere S-3, and the hyperboloid H'. The corresponding frame bundles are equal to the Euclidean group of motions SE(3), the rotation group SO(4), and the Lorentz group SO (1, 3). The maximum principle of optimal control shifts the emphasis for these systems to the associated Hamiltonian formalism. For an integrable case, the extremal curves are explicitly expressed in terms of elliptic functions. In this paper, a study at the singularities of the extremal curves are given, which correspond to critical points of these elliptic functions. The extremal curves are characterized as the intersections of invariant surfaces and are illustrated graphically at the singular points. It. is then shown that the projections, of the extremals onto the base space, called elastica, at these singular points, are curves of constant curvature and torsion, which in turn implies that the oriented vehicles trace helices.

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The interaction between the nonionic surfactant C(12)E(5) and a high molar mass (M = 5.94 x 10(5)) poly(ethylene oxide) (PEG) in aqueous solution has been examined as a function of temperature by dynamic light scattering and fluorescence methods over a broad concentration range. Clusters of small surfactant micelles form within the PEO coil, leading to its extension. The hydrodynamic radius of the complex increases strongly with temperature as well as with the concentrations of surfactant and polymer. At high concentrations of the surfactant, the coil/micellar cluster complex coexists with free C(12)E(5) micelles in the solution. Fluorescence quenching measurements show a moderate micellar growth from 155 to 203 monomers in PEO-free solutions of C(12)E(5) over a wide concentration range (0.02-2.5%) at 8 degrees C. Below 0.25% C(12)E(5), the average aggregation number (N) of the micelles is smaller in the presence of PEO than in its absence. However, N increases with increasing surfactant concentration up to a plateau value of about 270 at about 1.2% (ca. 30 mM) C(12)E(5). At high surfactant concentrations, N is larger in the presence of polymer than in its absence, a finding which is connected to a significant lowering of the clouding temperature due to the PEO at these compositions. Similar results of increasing aggregation number followed by a plateau were also found at a fixed concentration of surfactant (2.5%) and varied PEO.

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An exocellular β-(1→6)-d-glucan (lasiodiplodan) produced by a strain of Lasiodiplodia theobromae (MMLR) grown on sucrose was derivatized by sulfonation to promote anticoagulant activity. The structural features of the sulfonated β-(1→6)-d-glucan were investigated by UV-vis, FT-IR and 13C NMR spectroscopy, and the anticoagulant activity was investigated by the classical coagulation assays APTT, PT and TT using heparin as standard. The content of sulfur and degree of substitution of the sulfonated glucan was 11.73% and 0.95, respectively. UV spectroscopy showed a band at 261 nm due to the unsaturated bond formed in the sulfonation reaction. Results of FT-IR and 13C NMR indicated that sulfonyl groups were inserted on the polysaccharide. The sulfonated β-(1→6)-d-glucan presented anticoagulant activity as demonstrated by the increase in dose dependence of APTT and TT, and these actions most likely occurred because of the inserted sulfonate groups on the polysaccharide. The lasiodiplodan did not inhibit the coagulation tests. © 2012 Elsevier Ltd.