Fractional abundances of isoprenoid and branched glycerol dialkyl glycerol tetraethers (GDGT) of cores SO201-2-12KL and SO201-2-114KL

It has been proposed that North Pacific sea surface temperature (SST) evolution was intimately linked to North Atlantic climate oscillations during the last glacial-interglacial transition. However, during the early deglaciation and the Last Glacial Maximum, the SST development in the subarctic northwest Pacific and the Bering Sea is poorly constrained as most existing deglacial SST records are based on alkenone paleothermometry, which is limited prior to 15 ka B.P. in the subarctic North Pacific realm. By applying the TEXL86 temperature proxy we obtain glacial-Holocene-SST records for the marginal northwest Pacific and the Western Bering Sea. Our TEXL86-based records and existing alkenone data suggest that during the past 15.5 ka, SSTs in the northwest Pacific and the Western Bering Sea closely followed millennial-scale climate fluctuations known from Greenland ice cores, indicating rapid atmospheric teleconnections with abrupt climate changes in the North Atlantic. Our SST reconstructions indicate that in the Western Bering Sea SSTs drop significantly during Heinrich Stadial 1 (HS1), similar to the known North Atlantic climate history. In contrast, progressively rising SST in the northwest Pacific is different to the North Atlantic climate development during HS1. Similarities between the northwest Pacific SST and climate records from the Gulf of Alaska point to a stronger influence of Alaskan Stream waters connecting the eastern and western basin of the North Pacific during this time. During the Holocene, dissimilar climate trends point to reduced influence of the Alaskan Stream in the northwest Pacific.

Sea surface temperature reconstruction for the middle Pleistocene from sediment core MD03-2699

Past sea surface water conditions of the western Iberian Margin were reconstructed based on biomarker analyses of a marine deep sea core MD03-2699 from the Estremadura Spur north off Lisbon, providing new insights into orbital and suborbital-scale climate variability between marine isotope stage (MIS) 15 to MIS 9 (580 to 300 ka). We use biomarker-based proxy records such as the alkenone unsaturated index to estimate sea surface temperature (SST), the total alkenone concentration to reconstruct phytoplankton productivity, and terrestrial biomarkers to evaluate the continental input. The results extend the existing biomarker record, namely the SST for the Iberian Margin, back to the sixth climatic cycle (580 ka). A general trend of stable interglacials contrasts with glacial periods and glacial inceptions which are marked by high-frequency variability. Thus, several short-lived climatic coolings were identified by large SST decreases, the occurrence of ice-rafted detritus and high percentages of the tetraunsaturated alkenone C 37:4. Some of these events were extremely cold and similar in their general trends to the well-known Heinrich events of the last glaciation. We identified eight Heinrich-type events between 580 and 300 ka. The general deglaciation pattern detected between MIS 15 and MIS 9 is similar in their general trends to that characterizing the more recent climatic cycles, i.e., marked by two coolings separated by a short warming episode which may reflect the southward, northward, and southward migration of the Polar Front.

Element concentrations of bulk sediment from the Southern Cape Basin

High-resolution records of Ca and Sr were obtained from shipboard XRF analyses of bulk sediments in five gravity cores from the southern Cape Basin, South Atlantic Ocean. Sr/Ca ratios display regular glacial/interglacial variations of 14-40% and reveal a close correlation with the SPECMAP record, minimum Sr/Ca ratios appearing during glacial (delta18 O) maxima, distinct increases during periods of deglaciation, and highest ratios in interstadials. Shifts in carbonate-producing phytoplankton and/or zooplankton assemblages over glacial/interglacial cycles are suggested to be the main cause for the observed variations in Sr/Ca patterns. Quick assessment of the relationship between Sr/Ca ratios and the SPECMAP record made it possible to easily transfer an age model to the newly collected cores already during the cruise.

Dinoflagellate cyst counts of sediment core GIK23071-3

Marine sediments from the Vøring Plateau (Norwegian Sea) have been studied for their dinoflagellate cyst (dinocyst) and foraminiferal content in order to reconstruct sea-surface conditions in the eastern Norwegian Sea during Marine Isotope Stage (MIS) 5e. In combination with stable oxygen isotope and ice rafted detritus (IRD) data, the variations in foraminiferal and dinocyst assemblage composition reflect a stepwise transition from the final phase of deglaciation (Termination II) into typical interglacial conditions. This stepwise change is repeated subsequently during the cooling conditions of glacial inception towards MIS 5d. The interval studied is characterized by relatively high abundances of Bitectatodinium tepikiense, in comparison to present-day values in the area, indicating a larger seasonal temperature amplitude with enhanced surface water stratification during MIS 5e. The important occurrence of the warm-temperate dinocyst Spiniferites mirabilis s.l. concurrent with subpolar foraminifers Turborotalita quinqueloba, Globigerina bulloides, and Globigerinita glutinata reveals that most pronounced interglacial marine conditions prevailed in the area just prior to the transition towards MIS 5d. The late stratigraphic position of this phase in the interglacial is verified by comparison with dinocyst data from south of Iceland, manifesting its over-regional implication. Besides the good agreement in dinocyst and foraminiferal assemblage changes, the variations in and between both fossil assemblages also point to the existence of some significant surface water variability in the eastern Norwegian Sea during MIS 5e.

The South Atlantic carbon isotope record of planktic foraminifera

We reviewed the paleoceanographic application of the carbon isotope composition of planktic foraminifera. Major controls on the distribution of d13C of dissolved CO2 (d13CSCO2) in the modern ocean are photosynthesis-respiration cycle, isotopic fractionation during air-sea exchange, and circulation. The carbon isotope composition of surface waters is not recorded without perturbations by planktic foraminifera. Besides d13CSCO2 of the surrounding seawater, the d13C composition of planktic foraminifera is affected by vital effects, the water depth of calcification and postdepositional dissolution. We compared several high-resolution (>10cm/ka) carbon isotope records from the Southern Ocean, the Benguela upwelling system, and the tropical Atlantic. In the Southern Ocean, carbon isotope values are about 1.2 per mil lower during the LGM and up to 1.7 per mil lower during the last deglaciation, when compared to the Holocene. These depletions might be explained with a combination of a subsurface nutrient enrichment and reduced air-sea exchange due to an increased stratification of surface waters. In the Benguela Upwelling system, waters originating in the south are upwelled. While the deglacial minimum is transferred and recorded in its full extent in the d13C record of Globigerina bulloides, glacial values show only little changes. This might suggest, that the lower glacial d13C values of high-latitude surface waters are not upwelled off Namibia, or that G. bulloides records post-upwelling conditions, when increased seasonal production has already increased surface-water d13C. Synchronous to the d13C depletions in high latitudes, low d13C values were recorded in Globigerinoides sacculifer during the LGM and during the last deglaciation in the nutrient-depleted western equatorial Atlantic. Hence, part of the glacial-interglacial variability presumably transferred from high to low latitudes seems to be related to changes in thermodynamic fractionation. The variability in d13C is lowest in the northernmost core M35003-4 from the eastern Caribbean, implying that the Antarctic Intermediate Water might have acted as a conduit to transfer the deglacial minimum to tropical surface waters.

(Table 2) Age determination of sediment cores from the Portuguese Margin

We demonstrate that changes in the behavior of the Mediterranean Outflow Water (MOW) prior to and through the last deglaciation played an important role in promoting Meridional Overturning Circulation (MOC). Estimation of past MOW salt and heat fluxes indicates that they gradually increased through the last deglaciation. Between 17.5 and 14.6 thousand years ago (ka B.P., where B.P. references year 1950), net evaporation from the Mediterranean exported sufficient fresh water from the North Atlantic catchment to cause an average salinity increase of 0.5 psu throughout the upper 2000 m of the entire North Atlantic to the north of 25°N. Combined with rapid intensification and shoaling of the MOW plume, which we identify around 15-14.5 ka B.P., this deglacial MOW-related salt accumulation preconditioned the North Atlantic for abrupt resumption of the MOC at 14.6 ka B.P.

Sedimentological analysis of eight cores from the Amundsen Sea

Recent palaeoglaciological studies on the West Antarctic shelf have mainly focused on the wide embayments of the Ross and Amundsen seas in order to reconstruct the extent and subsequent retreat of the West Antarctic Ice Sheet (WAIS) since the Last Glacial Maximum (LGM). However, the narrower shelf sectors between these two major embayments have remained largely unstudied in previous geological investigations despite them covering extensive areas of the West Antarctic shelf. Here, we present the first systematic marine geological and geophysical survey of a shelf sector offshore from the Hobbs Coast. It is dominated by a large grounding zone wedge (GZW), which fills the base of a palaeo-ice stream trough on the inner shelf and marks a phase of stabilization of the grounding line during general WAIS retreat following the last maximum ice-sheet extent in this particular area (referred to as the Local Last Glacial Maximum, 'LLGM'). Reliable age determination on calcareous microfossils from the infill of a subglacial meltwater channel eroded into the GZW reveals that grounded ice had retreated landward of the GZW before ~20.88 cal. ka BP, with deglaciation of the innermost shelf occurring prior to ~12.97 cal. ka BP. Geophysical sub-bottom information from the inner-, mid- and outer shelf indicates grounded ice extended to the shelf edge prior to the formation of the GZW. Assuming the wedge was deposited during deglaciation, we infer the timing of maximum grounded ice extent occurred before ~20.88 cal. ka BP. This could suggest that the WAIS retreat from the outer shelf was already underway during or even prior to the global LGM (~23-19 cal. ka BP). Our new findings give insights into the regional deglacial behaviour of this understudied part of the West Antarctic shelf and at the same time support early deglaciation ages recently presented for adjacent drainage sectors of the WAIS. If correct, these findings contrast with the hypothesis that initial deglaciation of Antarctic Ice Sheets occurred synchronously at ~19 cal. ka BP.

Magnetic properties of maar lake sediments from Otago, New Zealand

Foulden Maar is a highly resolved maar lake deposit from the South Island of New Zealand comprising laminated diatomite punctuated by numerous diatomaceous turbidites. Basaltic clasts found in debris flow deposits at the base of the cored sedimentary sequence yielded two new 40Ar/39Ar dates of 24.51±0.24 Ma and 23.38±0.24 Ma (2sigma). The younger date agrees within error with a previously published 40Ar/39Ar date of 23.17±0.19 Ma from a basaltic dyke adjacent to the maar crater. The diatomite is inferred to have been deposited over several tens of thousands of years in the latest Oligocene/earliest Miocene, and may have overlapped with the period of rapid glaciation and subsequent deglaciation of Antarctica known as the Mi-1 event. Sediment magnetic properties and SEM measurements indicate that the magnetic signal is dominated by pseudo-single domain pyrrhotite. The most likely source of detrital pyrrhotite is schist country rock fragments from the inferred tephra ring created by the phreatomagmatic eruption that formed the maar. Variations in magnetic concentration and lamina thickness indicate a decrease in erosional input and increase in diatom productivity throughout the depositional period, suggesting a long-term (tens of thousands of years) climatic change in New Zealand in the latest Oligocene/earliest Miocene.

Palliser Rockslide cosmogenic 36Cl exposure ages (raw data) and erosion effect on the cosmogenic

This paper presents the results of a combined study, using cosmogenic 36Cl exposure dating and terrestrial digital photogrammetry, of the Palliser Rockslide located in the southeastern Canadian Rocky Mountains. This site is particularly well-suited to demonstrate how this multi-disciplinary approach can be used to differentiate distinct rocksliding events, estimate their volume, and establish their chronology and recurrence interval. Observations suggest that rocksliding has been ongoing since the late Pleistocene deglaciation. Two major rockslide events have been dated at 10.0 ± 1.2 kyr and 7.7 ± 0.8 kyr before present, with failure volumes of 40 Mm3 and 8 Mm3, respectively. The results have important implications concerning our understanding of the temporal distribution of paraglacial rockslides and rock avalanches; they provide a better understanding of the volumes and failure mechanisms of recurrent failure events; and they represent the first absolute ages of a prehistoric high magnitude event in the Canadian Rocky Mountains.

(Table 1) Luminescence datings from Varchushka and Pyoza rivers, Russia

The Pyoza River area in the Arkhangelsk district exposes sedimentary sequences suitable for study of the interaction between consecutive Valdaian ice sheets in Northern Russia. Lithostratigraphic investigations combined with luminescence dating have revealed new evidence on the Late Pleistocene history of the area. Overlying glacigenic deposits of the Moscowian (Saalian) glaciation marine deposits previously confined to three separate transgression phases have all been connected to the Mikulinian (Eemian) interglacial. Early Valdaian (E. Weichselian) proglacial, lacustrine and fluvial deposits indicate glaciation to the east or north and consequently glacier damming and meltwater run-off in the Pyoza area around 90-110 ka BP. Interstadial conditions with forest-steppe tundra vegetation and lacustrine and fluvial deposition prevailed at the end of the Early Valdaian around 75-95 ka BP. A terrestrial-based glaciation from easterly uplands reached the Pyoza area at the Early to Middle Valdaian transition around 65-75 ka BP and deposited glaciofluvial strata and subglacial till (Yolkino Till). During deglaciation, laterally extensive glaciolacustrine sediments were deposited in ice-dammed lakes in the early Middle Valdaian around 55-75 ka BP. The Barents-Kara Sea ice sheet deposited the Viryuga Till on the lower Pyoza from northerly directions. The ice sheet formed the Pyoza marginal moraines, which can be correlated with the Markhida moraines further east, and proglacial lacustrine deposition persisted in the area during the first part of the Middle Valdaian. Glacio-isostatic uplift caused erosion followed by pedogenesis and the formation of a deflation horizon in the Middle Valdaian. Widely dispersed periglacial river plains were formed during the Late Valdaian around 10-20 ka BP. Thus, the evidence of a terrestrial-based ice sheet from easterly uplands in the Pyoza area suggests that local piedmont glaciers situated in highlands such as the Timan Ridge or the Urals could have developed into larger, regionally confined ice sheets. Two phases of ice damming and development of proglacial lakes occurred during the Early and Middle Valdaian. The region did not experience glaciation during the Late Valdaian.

(Table 2) Age determination of sediment cores MD95-2002 and MD03-2692

We have compiled results obtained from four high sedimentation rate hemipelagic sequences from the Celtic sector of the NW European margin (NE Atlantic) to investigate the paleoceanographic and paleoclimatic evolution of the area over the last few climatic cycles. We focus on periods characteristic of deglacial transitions. We adopt a multiproxy sedimentological, geochemical, and micropaleontological approach, applying a sampling resolution down to ten microns for specific intervals. The investigation demonstrates the relationships between the Bay of Biscay hydrography and the glacial/deglacial history of both the proximal British-Irish Ice Sheet (BIIS) and the western European continent. We identify recurrent phases of laminae deposition concurrent with major BIIS deglacial episodes in all the studied cores. Evidence for abrupt freshwater discharges into the open ocean highlights the influence of such events at a regional scale. We discuss their impact at a global scale considering the present and past key location of the Bay of Biscay versus the Atlantic Meridional Overturning Circulation (AMOC).

(Fig. 11c) Alkenones (di and tri alkenones of 37 carbons) from sediment core MD95-2043

The present paper is a synopsis of the research on the climatic evolution of the Western Mediterranean Sea developed within the MATER programme. The sea surface temperature (SST) evolution during the last glacial period, deglaciation and present interglacial have been examined in detail. Special attention has been focussed to millennial-centennial scale changes related to rapid global climatic oscillations. The results have shown the extreme sensitivity of the Western Mediterranean oceanography to this rapid climatic variability giving rise to amplified climatic signals, e.g. strong SST oscillation, that follow the changes recorded in the North Atlantic Ocean or in Greenland ice. Overall, the Western Mediterranean Sea appears to be an ideal environment for the study of the climatic processes occurring at high and intermediate latitudes.

Sea surface temperatures, alkenones and sedimentation rates at the Alboran basin

Sea surface temperatures (SSTs) recorded by alkenones and oxygen isotopes in the Alboran basin are used here to describe, at an unprecedented fine temporal resolution, the present interglaciation (PIG, initiated at 11.7 ka BP), the last interglaciation (LIG, onset approximately at 129 ka) and respective deglaciations. Similarities and dissimilarities in the progression of these periods are reviewed in comparison with ice cores and stalagmites. Cold spells coeval with the Heinrich events (H) described in the North Atlantic include multi-decadal scale oscillations not previously obvious (up to 4 °C in less than eight centuries within the stadials associated with H1 and H11, ca 133 ka and 17 ka respectively). These abrupt oscillations precede the accumulation of organic rich layers deposited when perihelion moves from alignment with NH spring equinox to the summer solstice, a reference for deglaciations. Events observed during the last deglaciation at 17 ka, 14.8 ka and 11.7 ka are reminiscent of events occurred during the penultimate deglaciation at ca 136 ka, 132 ka and 129 ka, respectively. The SST trend during the PIG is no more than 2 °C (from 20 °C to 18 °C; up to ?0.2 °C/ka). The trend is steeper during the LIG, i.e. up to a 5 °C change from the early interglaciation to immediately before the glacial inception (from 23 °C to 18 °C; up to -0.4 °C/ka). Events are superimposed upon a long term trend towards colder SSTs, beginning with SST maxima followed by temperate periods until perihelion aligned with the NH autumn equinox (before ca 5.3 ka for the PIG and 121 ka for the LIG). A cold spell of around eight centuries at 2.8 ka during the PIG was possibly mimicked during the LIG at ca 118 ka by a SST fall of around 1 °C in a millennium. These events led interglacial SST to stabilise at around 18 °C. The glacial inception, barely evident at the beginning ca 115 ka (North Atlantic event C25, after perihelion passage in the NH winter solstice), culminated with a SST drop of at least 2 °C in two millennia (event C24, ca 111 ka). The Little Ice Age (0.7 ka) also occurred after the latest perihelion passage in the NH winter solstice and could be an example of how a glacial pre-inception event following an interglaciation might be.