Microstructure, vibrational and visible emission properties of low frequency ultrasound (42 kHz) assisted ZnO nanostructures

Size and shape tuneable ZnO nanostructures were prepared by a low frequency ultrasound (42 kHz) route using various organic solvents as the reaction media. The crystalline nature, lattice parameters and microstructural parameters such as microstrain, stress and energy density of the prepared ZnO nanostructures were revealed through X-ray diffraction (XRD) analysis. The organic solvents influenced the size and morphology of the ZnO nanostructures, and interesting morphological changes involving a spherical to triangular shaped transition were observed. The visible emission properties and lattice vibrational characteristics of the nanostructures were drastically modified by the changes in size and shape. Raman spectral measurements revealed the presence of multiphonon processes in the ZnO nanostructures. The intensity of the visible emission band was found to vary with the size and morphology of the structures. The strongest visible emission band corresponded to the structure with the largest surface/volume ratio and could be attributed to surface oxygen vacancies. The control over the size and morphology of ZnO nanostructures has been presented as a means of determining the intensity of the visible emission band

O contributo da animação na qualidade de vida dos idosos do serviço de apoio domiciliário do centro comunitário de Estoi

Dissertação de Mestrado, Educação Social, Escola Superior de Educação e Comunicação, Universidade do Algarve, 2016

Recruitment patterns and processes of coastal fish species in a temperate rocky reef

Tese de Doutoramento, Ciências do Mar, da Terra e do Ambiente, Ramo: Ciências do Mar, Especialização em Ecologia Marinha, Faculdade de Ciências e Tecnologia, Universidade do Algarve, 2016

Diversidade de bactérias de solo sob vegetação natural e cultivo de hortaliças.

Os microrganismos do solo são componentes essenciais na manutenção do equilíbrio físico-químico e biológico do mesmo e exercem importante função que inclui a degradação de resíduos de plantas e animais e a liberação de nutrientes na cadeia alimentar. Este trabalho teve como objetivo comparar a microbiota de um solo com cobertura de mata (SMS) e outro cultivado com hortaliças (SHC), supressivos ou não a Rhizoctonia solani. Foram feitas extrações do DNA total dos solos e a partir dos mesmos, amplificação por PCR dos genes 16S rDNA, clonagem dos fragmentos e seqüenciamento dos genes do RNA ribossomal. A análise dos resultados demonstrou que essa metodologia foi eficiente para avaliação de bactérias. No solo supressivo de mata os filos mais encontrados pertencem aos das Acidobactérias, Verrucomicrobia e Actinobactérias e no solo conducente cultivado com hortaliças a maioria pertence aos filos das Proteobactérias, Firmicutes e Bacteroidetes.

Development of water-soluble polyanionic carbosilane dendrimers as novel and highly potent topical anti-HIV-2 microbicides

This is the author’s version of a work that was accepted for publication in Nanoscale.

Tiro de Artilharia vs. Tiro de Morteiro : Procedimentos

A presente investigação tem como objetivo identificar as diferenças existentes entre os procedimentos técnicos relativos ao tiro de Artilharia de Campanha e ao tiro de Morteiro. Tem por finalidade estudar a possibilidade de uniformização dos procedimentos, no que respeita aos procedimentos de Pontaria, cálculo dos Elementos de Tiro, Pedido e Regulação de Tiro e à Segurança, utilizados pelas unidades de tiro de Artilharia de Campanha e de Morteiro. O trabalho estuda cada tipo de procedimento, começando por enunciá-los e explicar os seus métodos, finalidade e determinação, tanto para o tiro de Artilharia de Campanha como para o tiro de Morteiro. Os procedimentos são comparados através de tabelas e sínteses, com o objetivo de analisar o porquê de serem executados da maneira prevista na doutrina, remetendo dessa forma para o estudo da sua possível padronização. Como método de recolha de dados foram submetidos inquéritos livres a oficiais subalternos de diversas unidades de formação e operacionais relacionadas com a instrução e execução do tiro de Artilharia de Campanha e de Morteiro, de forma a recolher a sua opinião sobre a viabilidade de adoção dos procedimentos e esclarecimento de dúvidas. Foram depois realizadas análises comparativas para verificar quais os procedimentos que apresentam possibilidade de uniformização. No final os procedimentos padronizáveis foram identificados e comparados com os procedimentos executados pelo Grupo de Artilharia de Campanha da Brigada de Reação Rápida, à qual pertence uma Bateria integrada na NATO Response Force 16. Sendo a única unidade orgânica a nível nacional que opera com meios de tiro de Artilharia de Campanha e de Morteiro, a sua análise foi crucial para a investigação. Dado que a finalidade do trabalho é estudar a possibilidade de adoção de procedimentos comuns, as conclusões tiveram a sua origem na análise comparativa com os procedimentos desta unidade. Verificou-se assim que os procedimentos são padronizáveis, mas que são necessárias algumas condições para que possam ser aplicados, devido às diferenças na orgânica e tática entre as unidades de tiro de Artilharia de Campanha e de Morteiro, à diferença técnica das armas e dos meios auxiliares de cálculo dos Elementos de Tiro e técnica dos dois tipos de tiro.

Reporte financiero Burkenroad / Latinoamérica – Colombia Avianca Holdings S.A.

La recomendación de compra expuesta y el valor estimado de la acción para los próximos 12 meses se sustentan en los siguientes aspectos -- El crecimiento esperado en los próximos años en el transporte de pasajeros en la región donde principalmente opera Avianca Holdings (Latinoamérica), las inversiones de capital proyectadas por la empresa en materia de flota y eficiencia, la capacidad demostrada para mantener sostenidamente altos índices de ocupación, el posicionamiento de la marca y las estrategias concebidas al interior para reducir costos y gastos -- No obstante, a pesar de los logros obtenidos por la empresa en temas como la distribución de los ingresos y la estabilidad en los índices de ocupación, tras evaluar los resultados del análisis de sensibilidad al que se sometió la valoración realizada, debe aclararse que el alto grado de incertidumbre que caracteriza algunas de las variables determinantes de los resultados de la empresa, como el precio de los combustibles fósiles y la tasa de cambio, hacen que el valor de la acción pueda diferir de lo aquí estimado con un nivel de probabilidad considerable -- Esto hace que la recomendación de compra se adapte mejor a un perfil arriesgado de inversión

Espacios colectivos como escenarios culturales - Centro Cultural San Juan de Dios, Bogotá

Bogotá (Colombia): Universidad de La Salle. Facultad de Ciencias del Hábitat. Programa de Arquitectura

Influence of the metal precursor on the catalytic behavior of Pt/Ceria catalysts in the preferential oxidation of CO in the presence of H2 (PROX)

The effect of the metal precursor (presence or absence of chlorine) on the preferential oxidation of CO in the presence of H2 over Pt/CeO2 catalysts has been studied. The catalysts are prepared using (Pt(NH3)4)(NO3)2 and H2PtCl6, as precursors, in order to ascertain the effect of the chlorine species on the chemical properties of the support and on the catalytic behavior of these systems in the PROX reaction. The results show that chloride species exert an important effect on the redox properties of the oxide support due to surface chlorination. Consequently, the chlorinated catalyst exhibits a poorer catalytic activity at low temperatures compared with the chlorine-free catalyst, and this is accompanied by a higher selectivity to CO2 even at high reaction temperatures. It is proposed that the CO oxidation mechanism follows different pathways on each catalyst.

Ir supported over carbon materials for the selective hydrogenation of chloronitrobenzenes

In the present work we have studied the effect of carbon supports with different graphitic character (carbon nanotubes, mesoporous graphite and activated carbon) on the catalytic performance of iridium nanoparticles on the liquid phase chemoselective hydrogenation of para-chloronitrobenzene at room temperature. The effect of the oxygen groups was also evaluated by oxidizing a portion of the carbon nanotubes. The Raman and XRD spectra showed that the mesoporous graphite displayed the strongest graphitic character. The characterization of the catalysts by HR-TEM, XPS and TPR-H2, showed that the catalysts had similar particle size and that the catalysts prepared over the previously oxidized support, Ir/CNTox, was not fully reduced. The activity and selectivity achieved with the catalyst Ir/CNT was the best among the samples and the presence of irdium oxide on Ir/CNTox diminished the yield to p-chloroaniline, being the worse catalyst. The reactivity of different isomers was also studied over Ir/CNT and it followed the order m > o > p.

Platinum supported on highly-dispersed ceria on activated carbon for the total oxidation of VOCs

Catalysts consisting in platinum supported on cerium oxide highly dispersed on activated carbon, with a Pt loading of 1 wt.% and ceria loadings of 5, 10 and 20 wt.% have been prepared by impregnation method and characterized by several techniques (N2 adsorption at 77 K, ICP, XRD, H2-TPR and XPS). Their catalytic behavior has been evaluated in the total oxidation of ethanol and toluene after reduction at 473 K. The obtained results show that the prepared catalysts have better performances than platinum supported on bulk CeO2. The best catalytic performance was obtained for 10 wt.% ceria loading, likely due to an optimum synergistic interaction between highly dispersed cerium oxide and platinum particles. Pt-10Ce/C achieves total conversion of ethanol and toluene to CO2 at 433 K and 453 K, respectively, and shows no deactivation during a test for 100 h. Under humid conditions (relative humidity, RH, of 40 and 80%), the activity was only slightly influenced due to the hydrophobic character of the activated carbon support, which prevents the adsorption of water.

High performance of Cu/CeO2-Nb2O5 catalysts for preferential CO oxidation and total combustion of toluene

Copper-based catalysts supported on niobium-doped ceria have been prepared and tested in the preferential oxidation of CO in excess of H2 (PROX) and in total oxidation of toluene. Supports and catalysts have been characterized by several techniques: N2 adsorption, ICP-OES, XRF, XRD, Raman Spectroscopy, SEM, TEM, H2-TPR and XPS, and their catalytic performance has been measured in PROX, with an ideal gas mixture (CO, O2 and H2) with or without CO2 and H2O, and in total oxidation of toluene. The effects of the copper loading and the amount of niobium in the supports have been evaluated. Remarkably, the addition of niobia to the catalysts may improve the catalytic performance in total oxidation of toluene. It allows us to prepare cheaper catalysts (niobia it is far cheaper than ceria) with improved catalytic performance.

Highly dispersed Ptδ+ on TixCe(1−x)O2 as an active phase in preferential oxidation of CO

Structure–activity relationships for 1 wt.% Pt catalysts were investigated for a series of TixCe(1−x)O2 (x = 1, 0.98, 0.9, 0.5, 0.2 and 0) supports prepared by the sol–gel method. The catalysts prepared by impregnation were characterized in detail by applying a wide range of techniques as N2-isotherms, XRF, XRD, Raman, XPS, H2-TPR, Drifts, UV–vis, etc. and tested in the preferential oxidation of CO in the presence of H2. Also several reaction conditions were deeply analyzed. A strong correlation between catalyst performance and the electronic properties let us to propose, based in all the experimental results, a plausible reaction mechanism where several redox cycles are involved.

Bimetallic PtSn/C catalysts obtained via SOMC/M for glycerol steam reforming

A detailed study on the preparation of bimetallic PtSn/C catalysts using surface-controlled synthesis methods, and on their catalytic performance in the glycerol steam reforming reaction has been carried out. In order to obtain these well-defined bimetallic phases, techniques derived from Surface Organometallic Chemistry on Metals (SOMC/M) were used. The preparation process involved the reaction between an organometallic compound ((C4H9)4Sn) and a supported transition metal (Pt) in a H2 atmosphere. Catalysts with Sn/Pt atomic ratios of 0.2, 0.3, 0.5, and 0.7 were obtained, and characterized using several techniques: ICP, H2 chemisorption, TEM and XPS. These systems were tested in the glycerol steam reforming varying the reaction conditions (glycerol concentration and reaction temperature). The best performance was observed for the catalysts with the lowest tin contents (PtSn0.2/C and PtSn0.3/C). It was observed that the presence of tin increased the catalysts’ stability when working under more severe reaction conditions.

Green synthesis of polypyrrole-supported metal catalysts: application to nitrate removal in water

Pt and Pt/Sn catalysts supported on polypyrrole (PPy) have been prepared using Ar plasma to reduce the metal precursors dispersed on the polymer. The PPy support was synthesized by chemical polymerization of pyrrole with FeCl3·6H2O, this leading to the conducting form of the polymer (conductimetric measurements). The Ar plasma treatment produced a partial reduction of platinum ions, anchored as platinum chloro-complexes to the PPy chain, into metallic platinum. A homogeneous distribution of Pt and Sn nanoparticles was observed by TEM. Activity of the PPy-supported catalysts was evaluated in the reduction of aqueous nitrate with H2 at room temperature. Nitrate concentration in water below the maximum acceptable level of 50 mg L−1 was achieved with all catalysts. However, considering not only efficiency in nitrate reduction, but also minimized concentrations of undesired nitrite and ammonium, the monometallic Pt catalyst seems to be the most promising one.