Pagamento por Serviços Ambientais nas propriedades rurais do alto curso da bacia do Ribeirão Vai e Vem, munícipio de Santo Anastácio (SP)

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Influence of physical protectors with different filters on the initial development of Peltophorum dubium (Spreng.) Taub seedlings

The use of physical protectors has been considered as an efficient technique for tillage farming of different species, mainly native ones. Based on the importance of the species, Peltophorum dubium for revegetation of degraded areas, this study evaluated the emergence, survival and initial development of P. dubium seedlings under the influence of physical protectors with different filters. Thus, the following treatments were adopted: absence of physical protector (APP), transparent physical protector (TPP), transparent physical protector + blue cellophane (BPP) and transparent physical protector + red cellophane (RPP). The evaluated characteristics were: emergence velocity index (EVI), seedling survival and emergence percentage, plant height, leaf area and root collar diameter. All of these physical protectors increased the mean values of EVI and survival. In conclusion, the emergence speed and initial development of P. dubium (Spreng.) seedlings grown in the interior of physical protectors, independent on the filters, presented positive results. The reduction on the light intensity interferes positively in the initial growth of these plants.

Geoprocessamento aplicado na determinação das áreas de preservação permanente e áreas de conflito com cultivo agrícola no município de Lençóis Paulista/SP

The city of Lençóis Paulista has a great part of its agricultural land cultivated by sugar cane and reforestation of eucalyptus and pine trees. In the county there are industries that exploit energy extracted from energy cogeneration. The city of Lençóis Paulista, in recent years, has been demonstrating considerable levels of economic and social growth with the industries that are working with sugarcane and eucalyptus mainly responsible. However, the expansion of agricultural land in many cases does not take into consideration the permanent preservation areas that are protected by the law. The APP's are of fundamental importance in the management and conservation of the environment preserving the natural plants and wildlife, and also preventing erosion and the silting of drainage networks. This objective of this study was to diagnose land use, analyze if Permanent Preservation Areas are regulated to the Brazilian Forestry Code (1965) and also diagnose areas of conflict. In relation to the use and occupation of land, the research has shown how the land is divided (agricultural crops and urban zones), and highlighted areas of conflict with the Permanent Preservation Areas. All of the information is contained in maps using Geographic Information Systems. However, it has become clear that environmental laws are not respected as much in urban areas as they are in rural areas. The PPA's are virtually nonexistent, thus creating damage to the environment and local population.

Diagnóstico de conflitos em áreas de preservação permanente na bacia do Rio Capivara - Botucatu (SP)

The permanent preservation areas (PPA) established by Brazilian law are there to protect the natural environment. With the expansion of space occupied by man and development of economic activities in these areas were engaged in conflicts characterized PPA, where the use is other than the natural vegetation. According to these paradigms work aims to raise these conflict areas in the River Basin Capivara, Botucatu (SP) with the help of GIS Ilwis 3.4, topographic maps of IBGE and satellite images CBERS 2B. The map was generated from PPA in the GIS by distance calculation in relation to drainage, springs and break line on Cuesta de Botucatu. The classes of land use and natural vegetation were determined by interpretation of satellite images and field visits to check their veracity. With the cutting of the map of land use and natural vegetation in relation to PPA unit it was determined that the total 44,63% PPA is in conflict occupied by pasture, forest plantation, orange, annual crops, farms and irrigated rice project in lowland. This diagnostic characterizes the degradation of the environment and highlights the need to harmonize the economic and urban development with the preservation of the environment to ensure sustainability of the region.

Cultivo da cana-de-açúcar e o uso do solo em áreas de preservação permanente

This study aimed to recognize the significant temporal changes in land use between 1984 and 2008 in Barra Bonita City/ SP and to analyze the conflicts of land use in permanent preservation areas (PPA) with reference to the Forest Code and Resolution N. 303/2002 of CONAMA. The GIS Idrisi Andes 5.0 – geographic information system was used and the images were processed by LANDSAT TM5. Maps of land use were obtained by Maxver supervised classification and showed that in 1984 the area occupied by sugar cane crop was about 10.50 ha (70%) in 1984 and 10.90 ha in 2008. In analysis of conflicts about land use in permanent preservation areas showed that in 24 years the sugar-cane crops increased 3.6% on PPA. The occupation was represented by adequate forest of 279.25 ha (31.5% of total) in 1984. In 2008, the sugar-cane crop was the biggest conflict in PPA occupying 357.9 ha and 11.4% corresponds to areas in preparation for use. This year, 59.5% of total PPA is at odds with environmental legislation.

Uso inadequado de áreas de preservação permanente

O grande desafio da população mundial é a conservação ambiental, pois as Áreas de Preservação Permanentes, que têm papel vital dentro de uma microbacia, por serem responsáveis pela manutenção, preservação e conservação dos ecossistemas ali existentes. O presente trabalho visou analisar os conflitos de uso do solo em áreas de preservação permanentes (APPs) da microbacia do Alto Capivara - Botucatu (SP) através do uso de Sistema de Informações Geográficas e de imagem de satélite digital. A área com 4551,19ha, situa-se entre as coordenadas geográficas: 22o 51’ 57” a 22o 57’ 55” de latitude S e 48o 21’ 58” a 48o 26’ 38” de longitude WGR. O mapa de uso do solo de 2006 foi obtido a partir da classificação supervisionada em imagem de satélite digital de 23/10/2006. Na identificação digital dos alvos foram utilizadas as chaves de interpretação para imagens e as áreas foram determinadas através do software SIG – IDRISI. Os conflitos de uso nas áreas de preservação permanente foram analisados ao longo da rede de drenagem e das nascentes, conforme itens dos artigos 2º e 3º da Resolução nº 303 do CONAMA. A área de APP discriminada ao longo da rede de drenagem foi de 416,5ha (9,15%) . No entanto, 201,15ha da área de APP está ocupada com pastagem (48,3%), reflorestamento (1,23%) e 0,48% por área urbana de forma inadequada (conflito). Portanto, quase 50% de área de APP vem sendo parcialmente utilizada adequadamente.

SIG aplicado na identificação e localização potencial de áreas de preservação permanente numa microbacia

O uso inadequado do solo é um fator agravante da degradação ambiental e desequilíbrio ecológico. Este trabalho visou avaliar os conflitos de uso da terra em áreas de preservação permanentes (APP) na microbacia do São Pedro - Botucatu (SP) através de Sistema de Informações Geográficas e imagem de satélite de 2006. A área de estudo localiza-se entre as coordenadas geográficas 48º 21’ a 48º 23’ de longitude WGr. e 22º 52’S e 22º 56’ de latitude S com uma área de 1458,4ha. Os resultados permitiram verificar que as técnicas de geoprocessamento foram de importância fundamental na identificação das áreas de uso de terra, de APPs e de conflitos entre uso e APPs onde uma pequena parte das áreas de APPs está conflitando. Em termos de sustentabilidade ambiental, pode ser deduzido que a microbacia é desfavorável, uma vez apresenta com quase 44% da área usada inadequadamente por pastagens.

Adequabilidade das áreas de vegetação ripária da microbacia do Córrego Comur - Botucatu (SP) em função da legislação ambiental

The inadequate soil use is an aggravating factor of the environmental degradation and ecological unbalance. The analysis of the use and covering of the soil, by information of Remote Sensing, constitutes a technique of great usefulness to the planning and administration of the ordered occupation and rational of the physical middle, besides making possible to evaluate and to monitor the preservation of areas of natural vegetation. This work sought to evaluate the conflicts of soil use in permanent preservation areas (PPA) in Stream Comur watershed - Botucatu (SP) through Geographical Information System and satellite image of 2009. The study area is located among the geographical coordinates 48o 23’ 04” to 48o 25’ 54” of longitude WGr. and 22o 44’ 42” to 22o 48” 12” of latitude S with an area of 1,719.6 ha. The results allowed to verify that the geoprocessing techniques were of fundamental importance in the identification of the areas of soil use, of APP and of conflicts among use and PPA where it leaves of the areas of APP is being used inadequately. In terms of environmental sustainability, it can be deduced that the watershed is very unfavorable, once it presents 70.67% of area used inadequately with sugarcane and pasture.

Identificação de áreas degradadas por extração de argila no município de Ourinhos (SP): recuperação do passivo ambiental e proteção dos recursos hídricos

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Processo contraditório de uso e ocupação em Áreas de Preservação Permante, às margens do rio Poti - Teresina, PI

Pós-graduação em Geografia - IGCE

Influence of the relative amounts of crystalline and amorphous phases on the mechanical properties of polyamide-6 nanocomposites

The relative amounts of amorphous and crystalline ?- and a-phases in polyamide-6 nanocomposites, estimated from the deconvolution of X-ray diffraction peaks using Gaussian functions, correlates with their mechanical, thermomechanical, and barrier properties. The incorporation of organoclay platelets (Cloisite 15A and 30B) induced the crystallization of the polymer in the ? form at expense of the amorphous phase, such that 12 wt % of Cloisite is enough to enhance the mechanical and the thermomechanical properties. However, higher nanofiller loads were necessary to achieve good barrier effects, because this property is mainly dependent on the tortuous path permeation mechanism of the gas molecules through the nanocomposite films. (C) 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012

Natural rubber latex LbL films: Characterization and growth of fibroblasts

The recent biomedical applications of natural rubber (NR) latex, mostly in dry membranes, have motivated research into novel, more noble uses of this low-cost biomaterial. In this article, we provide the first report on the fabrication of layer-by-layer (LbL) films of NR alternated with the polyelectrolytes polyethylenimine (PEI) and polyallylamine hydrochloride (PAH). Stable (PAH/NR)n and (PEI/NR)n LbL films displayed similar physicochemical properties, but differed in terms of film morphology according to atomic force microscopy (AFM) and scanning electron microscopy (SEM) data. Most significantly, (PEI/NR)5 LbL films were made of smaller and flattened particles, which were not efficient for the growth and proliferation of normal human fibroblasts (NHF). In contrast, efficient NHF proliferation could be obtained with (PAH/NR)n LbL films, with the fibroblasts exhibiting the expected elongated morphology. Furthermore, cell growth did not occur for cast films of NR, thus demonstrating the suitability of the LbL method for this biologically related application. The differences between the two polyelectrolytes illustrate the importance of the film architecture and morphology, which open the way for exploiting the molecular control inherent in the LbL technique for further applications of NR-containing films. (c) 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012

Regioregular improvement on the oxidative polymerization of poly-3-octylthiophenes by slow addition of oxidant at low temperature

Many pathways can be used to synthesize polythiophenes derivatives. The polycondensation reactions performed with organometallics are preferred since they lead to regioregular polymers (with high content of heat-to-tail coupling) which have enhanced conductivity and luminescence. However, these pathways have several steps; the reactants are highly moisture sensitive and expensive. On the other hand, the oxidative polymerization using FeCl3 is a one-pot reaction that requires less moisture sensitive reactants with lower cost, although the most common reaction conditions lead to polymers with low regioregularity. Here, we report that by changing the reaction conditions, such as FeCl3 addition rate and reaction temperature, poly-3-octylthiophenes with different the regioregularities can be obtained, reaching about 80% of heat-to-tail coupling. Different molar mass distributions and polydispersivities were obtained. The preliminary results suggest that the oxidative polymerization process could be improved to yield polythiophenes with higher regioregularity degree and narrower molar mass distributions by just setting some reaction conditions. We also verified that it is possible to solvent extract part of the lower regioregular fraction of the polymer further improving the regioregularity degree. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012

Compatibilization of polypropylene/poly(3-hydroxybutyrate) blends

Blending polypropylene (PP) with biodegradable poly(3-hydroxybutyrate) (PHB) can be a nice alternative to minimize the disposal problem of PP and the intrinsic brittleness that restricts PHB applications. However, to achieve acceptable engineering properties, the blend needs to be compatibilized because of the immiscibility between PP and PHB. In this work, PP/PHB blends were prepared with different types of copolymers as possible compatibilizers: poly(propylene-g-maleic anhydride) (PPMAH), poly (ethylene-co-methyl acrylate) [P(EMA)], poly(ethylene-co-glycidyl methacrylate) [P(EGMA)], and poly(ethylene-co-methyl acrylate-co-glycidyl methacrylate) [P(EMAGMA)]. The effect of each copolymer on the morphology and mechanical properties of the blends was investigated. The results show that the compatibilizers efficiency decreased in this order: P(EMAGMA) > P(EMA) > P(EGMA) > PP-MAH; we explained this by taking into consideration the affinity degree of the compatibilizers with the PP matrix, the compatibilizers properties, and their ability to provide physical and/or reactive compatibilization with PHB. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci 123: 3511-3519, 2012

Influence of the base and diluent methacrylate monomers on the polymerization stress and its determinants

The aim of this study was to evaluate the effect of the association between bisphenol-A diglycidyl dimethacrylate (BisGMA) or its ethoxylated version (BisEMA) with diluents derived from the ethylene glycol dimethacrylate (EGDMA), with increasing number of ethylene glycol units (1: EGDMA, 2: DEGDMA, 3: TEGDMA, or 4: TETGDMA), or trimethylol propane trimethacrylate (TMPTMA) or 1,10-decanediol dimethacrylate (D3MA) on polymerization stress, volumetric shrinkage, degree of conversion, maximum rate of polymerization (Rpmax), and elastic modulus of experimental composites. BisGMA containing formulations presented lower shrinkage and stress but higher modulus and Rpmax than those containing BisEMA. TMPTMA presented the lowest stress among all diluents, as a result of lower conversion. EGDMA, DEGDMA, TEGDMA, and TETGDMA presented similar polymerization stress which was higher than the stress presented by D3MA and TMPTMA. D3MA presented similar conversion when copolymerized with both base monomers. The other diluents presented higher conversion when associated with BisEMA. EGDMA showed similar shrinkage compared with DEGDMA and higher than the other diluents. The lower conversion achieved by TMPTMA did not jeopardize its elastic modulus, similar to the other diluents. Despite the similar conversion presented by D3MA in comparison with EGDMA and DEGDMA, its lower elastic modulus may limit its use. Rather than proposing new materials, this study provides a systematic evaluation of off the shelf monomers and their effects on stress development, as highlighted by the analysis of conversion, shrinkage and modulus, to aid the optimization of commercially available materials. (c) 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012