Distribution of coccoliths in surface sediments of the south-eastern South Atlantic Ocean

Recent coccoliths from 52 surface sediment samples recovered from the south-eastern South Atlantic were examined qualitatively and quantitatively in order to assess the controlling mechanisms for their distribution patterns, such as ecological and preservational factors, and their role as carbonate producers. Total coccolith abundances range from 0.2 to 39.9 coccoliths*10**9/ g sediment. Four assemblages can be delineated by their coccolith content characterising the northern Benguela, the middle to southern Benguela, the Walvis Ridge and the deeper water. Distinctions are based on multivariate ordination techniques applied on the relative abundances of the most abundant taxa, Emiliania huxleyi, Calcidiscus leptoporus, Gephyrocapsa spp., Coccolithus pelagicus and subtropical to tropical species. The coccolith distribution seems to be temperature and nutrient controlled co-varying with the seaward extension of the upwelling filament zone in the Benguela. A preservation index (CEX') based on the differential dissolution behaviour of the delicate E. huxleyi and Gephyrocapsa ericsonii versus the robust C. leptoporus is applied in order to detect the position of the coccolith lysocline. Although some samples were recognised as dissolution-affected, the distribution of the coccoliths in the surface-sediments reflects the different oceanographic surface-water conditions. Mass estimations of the coccolith carbonate reveal coccoliths to be only minor contributors to the carbonate preserved in the surface sediments. The mean computed coccolith carbonate content is 17 wt.%, equivalent to a mean contribution of 23% to the bulk carbonate.

Relative abundance of diatom species in surface samples from the Southern Ocean, major open ocean species

Diatom assemblages from 228 core-top samples were investigated to determine the modern geographic distributions of 10 major open ocean species or species groups in the Atlantic and Indian sectors of the Southern Ocean. Our study gives a more comprehensive view of the relationships between diatom distribution and environmental pressures than previous studies, as our modern database covers a much wider area, and additionally highlights the relationships with sea ice cover and concentration. The 10 species or species categories can mainly be lumped into three groupings. First, a cool open ocean grouping composed of Rhizosolenia pointed group, Thalassiosira gracilis group and Trichotoxon reinboldii with maximum relative abundances occurring within the maximum winter sea-ice edge. Second, a pelagic open ocean grouping composed of Fragilariopsis kerguelensis, Thalassiosira lentiginosa, Thalassiosira oliverana and Thalassiothrix spp. group with maximum occurrences at the Antarctic Polar Front. Third, a warm open ocean grouping with maximum abundances observed within the Polar Front Zone and composed of the Rhizosolenia rounded group, the Thalassionema nitzschioides var. nitzschioides group and the Thalassionema nitzschioides var. lanceolata. Comparisons of the abovementioned 10 species or species groups with modern February sea-surface temperatures and sea-ice duration and concentration reveal species-specific sedimentary distributions regulated both by sea-surface temperatures and sea ice conditions that support the use of diatom remains to reconstruct past variations of these environmental parameters via qualitative and transfer function approaches.

Relative abundance of diatom species in surface samples from the Southern Ocean, Tropical/Subtropical species

This paper gives a modern circumscription of Tropical/Subtropical diatoms regarding their relationship with sea-surface temperatures (SST) and sea ice cover. Diatoms from 228 core-top sediment samples collected from the Southern Ocean were studied to determine the geographic distribution of eight major diatom species/taxa preserved in surface sediments generally located north of the Subantarctic Front. The comparison of the relative contribution of diatom species with modern February SST and sea-ice cover reveals species-specific sedimentary distributions regulated both by water temperatures and sea ice conditions. Although selective preservation might have played some role, their presence in surface and downcore sediments from the Southern Ocean are reliable indicators of high SST and poleward transport of waters from the Tropical/Subtropical Atlantic. Our work supports the use of diatom remains to reconstruct past variations of these environmental parameters via qualitative and transfer function approaches.

Dissolved Iron, Aluminium, and Dissolved Inorganic Phosphorus in the (Sub-)Tropical Atlantic Surface Ocean

Inorganic nitrogen depletion restricts productivity in much of the low-latitude oceans, generating a selective advantage for diazotrophic organisms capable of fixing atmospheric dinitrogen (N2). However, the abundance and activity of diazotrophs can in turn be controlled by the availability of other potentially limiting nutrients, including phosphorus (P) and iron (Fe). Here we present high-resolution data (~0.3°) for dissolved iron, aluminum, and inorganic phosphorus that confirm the existence of a sharp north-south biogeochemical boundary in the surface nutrient concentrations of the (sub)tropical Atlantic Ocean. Combining satellite-based precipitation data with results from a previous study, we here demonstrate that wet deposition in the region of the intertropical convergence zone acts as the major dissolved iron source to surface waters. Moreover, corresponding observations of N2 fixation and the distribution of diazotrophic Trichodesmium spp. indicate that movement in the region of elevated dissolved iron as a result of the seasonal migration of the intertropical convergence zone drives a shift in the latitudinal distribution of diazotrophy and corresponding dissolved inorganic phosphorus depletion. These conclusions are consistent with the results of an idealized numerical model of the system. The boundary between the distinct biogeochemical systems of the (sub)tropical Atlantic thus appears to be defined by the diazotrophic response to spatial-temporal variability in external Fe inputs. Consequently, in addition to demonstrating a unique seasonal cycle forced by atmospheric nutrient inputs, we suggest that the underlying biogeochemical mechanisms would likely characterize the response of oligotrophic systems to altered environmental forcing over longer timescales.

Radionuclides of bulk and terrigenous surface sediments in the Southern Ocean

Sr and Nd isotopic compositions of Late Quaternary surface sediment and sediment cores from the south Atlantic and southeast Pacific sectors of the Southern Ocean are used to constrain the provenance and transport mechanisms of their terrigenous component. We report isotopic and mineralogical data for core samples from three localities, the Mid-Atlantic Ridge at 41°S and the northern and southern Scotia Sea. In addition, data for surface sediment samples from the south Atlantic and southeast Pacific sectors of the Southern Ocean are presented. The variations of Sr and Nd isotopic compositions of the bulk sediment samples in all cores were correlated with the magnetic susceptibility of the sediment and with the inferred glacial-interglacial stages. The isotopic data indicate that, during glacial periods, sediment was delivered from continental crust with a shorter residence time than that supplying material during interglacial periods. At the core site near the Mid-Atlantic Ridge, Nd isotopic, combined with mineralogical evidence indicates interglacial period deposition of a relatively high amount of kaolinite and silt with low epsilon-Nd values < -8. The material was probably supplied by North Atlantic Deep Water from low latitudes. For glacial periods, a high contribution of silt and clay with epsilon-Nd > -4.5, probably derived from southern South America, was indicated. The glacial-interglacial shift in sources may be due to either a decreasing influence of North Atlantic Deep Water during glacial times or by a larger contribution of glaciogenic detritus from southern South America. At the core site in the northern Scotia Sea, sediment of interglacial periods is dominated by smectite with epsilon-Nd < - 6 and silt with epsilon-Nd > -4. We suggest that smectite was derived from the Falkland shelf and silt was derived from the Argentinian shelf. During glacial periods, the Argentinian shelf was an important source for silt and chlorite with epsilon-Nd > -4. The contribution from the Falkland shelf seems to have remained similar during glacial and interglacial periods. Hydrographic transport by bottom currents and turbidites could account for the high glacial detrital flux. An evaluation of the significance of an aeolian contribution to deep sea sediment suggests that it plays only a minor role. In the southern Scotia Sea, the Antarctic Peninsula is considered an important source for young material with epsilon-Nd > -4, in particular during glacial periods. During interglacial periods, sediment supply from the Antarctic Peninsula was lower than during glacial times, resulting in a relatively high contribution of old material (epsilon-Nd < -8) from East Antarctica. Deep water currents and icebergs could account for the transport of the old component to the southern Scotia Sea. The accumulation rates of material from the various source regions for glacial times are in agreement with an increase in the strength of the Antarctic Circumpolar Current. The production rate and the circulation pattern of bottom water in the Weddell Sea appear to have remained similar over most of the last 150 kyr.

Distribution of heavy minerals in sediment cores from the Laptev Sea continental margin and the central Arctic Ocean

Focussing on heavy-mineral associations in the Laptev-Sea continental margin area and the eastern Arctic Ocean, 129 surface sediment samples, two short and four long gravity cores have been studied. By means of the accessory components, heavy-mineral associations of surface sediment samples from the Laptev-See continental slope allowed the distinction into two different mineralogical provinces, each influenced by fluvial input of the Siberian river Systems. Transport pathways via sea ice from the shallow shelf areas into the Arctic Ocean up to the final ablation areas of the Fram Strait can be reconstructed by heavy-mineral data of surface sediments from the central Arctic Ocean. The shallow shelf of the Laptev Sea seems to be the most important source area for terrigenous material, as indicated by the abundant occurence of amphiboles and clinopyroxenes. Underneath the mixing Zone of the two dominating surface circulation Systems, the Beaufort- Gyre and Transpolar-Drift system, the imprint of the Amerasian shelf regions up to the Fram Strait is detectable because of a characteristical heavy-mineral association dominated by detrital carbonate and opaque minerals. Based On heavy-mineral characteristics of the potential circum-Arctic source areas, sea-ice drift, origin and distribution of ice-rafted material can be reconstructed during the past climatic cycles. Different factors controlling the transport of terrigenous material into the Arctic Ocean. The entrainment of particulate matter is triggered by the sea level, which flooded during highs and lows different regions resulting in the incorporation of sediment from different source areas into the sea ice. Additionally, the fluvial input even at low stands of sea level is responsible for the delivery of material of distinct sources for entrainment into the sea ice. Glacials and interglacials of climate cycles of the last 780 000 years left a characteristical signal in the central Arctic Ocean sediments caused by the ice- rafted material from different sources in the circum-Arctic regions and its change through time. Changes in the heavy-mineral association from an amphibole-dominated into a garnet-epidote-assemblage can be related to climate-related changes in source areas and directions of geostrophic winds, the dominating drive of the sea-ice drift. During Marine Isotope Stage (MIS) 6, the central Arctic Ocean is marked by an heavy-mineral signal, which occurs in recent sediments of the eastern Kara Sea. Its characteristics are high amounts of epidote, garnet and apatite. On the other hand, during the Same time interval a continuous record of Laptev Sea sediments is documented with high contents of amphiboles on the Lomonosov Ridge near the Laptev Sea continental slope. A nearly similar Pattern was detected in MIS 5 and 4. Small-scale glaciations in the Putorana-mountains and the Anabar-shield may have caused changes in the drainage area of the rivers and therefore a change in fluvial input. During MIS 3, the heavy-mineral association of central Arctic sediments show similar patterns than the Holocene mineral assemblage which consists of amphiboles, ortho- and clinopyroxenes with a Laptev Sea source. These minerals are indicating a stable Transpolar-Drift system similar to recent conditions. An extended influence of the Beaufort Gyre is only recognized, when sediment material from the Amerasian shelf areas reached the core location PS2757-718 during Termination Ib. Based On heavy-mineral data from Laptev-Sea continental slope Core PS2458-4 the paleo-sea-ice drift in the Laptev Sea during 14.000 years was reconstructed. During Holocene sea-level rise, the bathymetrically deeper parts of the Western shelf were flooded first. At the beginning of the Atlantic stage, nearly the entire shelf was marine influenced by fully marine conditions and the recent surface circulation was established.

Ostracoda in surface sediments of the Arctic Ocean

Ostracodes were studied from deep Arctic Ocean cores obtained during the Arctic 91 expedition of the Polarstern to the Nansen, Amundsen and Makarov Basins, the Lomonosov Ridge, Morris Jesup Rise and Yermak Plateau, in order to investigate their distribution in Arctic Ocean deep water (AODW) and apply these data to paleoceanographic reconstruction of bottom water masses during the Quaternary. Analyses of coretop assemblages from Arctic 91 boxcores indicate the following: ostracodes are common at all depths between 1000 and 4500 m, and species distribution is strongly influenced by water mass characteristics and bathymetry; quantitative analyses comparing Eurasian and Canada Basin assemblages indicate that distinct assemblages inhabit regions east and west of the Lomonosov Ridge, a barrier especially important to species living in lower AODW; deep Eurasian Basin assemblages are more similar to those living in Greenland Sea deep water (GSDW) than those in Canada Basin deep water; two upper AODW assemblages were recognized throughout the Arctic Ocean, one living between 1000 and 1500 m, and the other, having high species diversity, at 1500-3000 m. Downcore quantitative analyses of species' abundances and the squared chord distance coefficient of similarity reveals a distinct series of abundance peaks in key indicator taxa interpreted to signify the following late Quaternary deep water history of the Eurasian Basin. During the Last Glacial Maximum (LGM), a GSDW/AODW assemblage, characteristic of cold, well oxygenated deep water > 3000 m today, inhabited the Lomonosov Ridge to depths as shallow as 1000 m, perhaps indicating the influence of GSDW at mid-depths in the central Arctic Ocean. During Termination 1, a period of high organic productivity associated with a strong inflowing warm North Atlantic layer occurred. During the mid-Holocene, several key faunal events indicate a period of warming and/or enhanced flow between the Canada and Eurasian Basins. A long-term record of ostracode assemblages from kastenlot core PS2200-5 (1073 m water depth) from the Morris Jesup Rise indicates a quasi-cyclic pattern of water mass changes during the last 300 kyr. Interglacial ostracode assemblages corresponding to oxygen isotope stages 1, 5, and 7 indicate rapid changes in dissolved oxygen and productivity during glacial-interglacial transitions.

Sample locations, stratigraphic information and listing of carbon and oxygen isotope data of the measured planktonic foraminifera of surface sediments in the western South Atlantic Ocean (Table 1)

We explored the potential to use the stable isotopic compositions of planktonic foraminifera as a proxy for the position of the Brazil-Malvinas Confluence (BMC) in the Argentine Basin. For this purpose, we measured the oxygen and carbon isotopic compositions of Globigerinoides ruber (pink and white varieties measured separately), Globigerinoides trilobus, Globigerina bulloides, Globorotalia inflata and Globorotalia truncatulinoides (left- and right-coiling forms measured separately) from a latitudinal transect of 56 surface sediment samples from the continental slope off Brazil, Uruguay and Argentina between 20 and 48°S. Lowest oxygen isotopes values were found in G. ruber (pink), followed by G. ruber (white) and G. trilobus reflecting the highly stratified near surface water conditions north of the BMC. Globigerina bulloides was present mainly south of the BMC and records subsurface conditions supporting earlier plankton tow studies. Globorotalia inflata and G. truncatulinoides (left and right) were both available over the whole transect and calcify in the depth level with the steepest temperature change across the BMC. Accordingly, the delta18O of these species depict a sharp gradient of 2? at the confluence with remarkably stable values north and south of the BMC. Our data show that the oxygen isotopic composition of G. inflata and G. truncatulinoides (left and right) are the most reliable indicators for the present position of the BMC and can therefore be used to define the past migration of the front if appropriate cores are available.

Sea-surface temperature reconstruction and calibration-function of sediment cores from the Southern Ocean

We provide a new multivariate calibration-function based on South Atlantic modern assemblages of planktonic foraminifera and atlas water column parameters from the Antarctic Circumpolar Current to the Subtropical Gyre and tropical warm waters (i.e., 60°S to 0°S). Therefore, we used a dataset with the abundance pattern of 35 taxonomic groups of planktonic foraminifera in 141 surface sediment samples. Five factors were taken into consideration for the analysis, which account for 93% of the total variance of the original data representing the regional main oceanographic fronts. The new calibration-function F141-35-5 enables the reconstruction of Late Quaternary summer and winter sea-surface temperatures with a statistical error of ~0.5°C. Our function was verified by its application to a sediment core extracted from the western South Atlantic. The downcore reconstruction shows negative anomalies in sea-surface temperatures during the early-mid Holocene and temperatures within the range of modern values during the late Holocene. This pattern is consistent with available reconstructions.

Sea-surface reconstructions of the western Pacific Ocean during the last 5.3 million years

The late Neogene was a time of cryosphere development in the northern hemisphere. The present study was carried out to estimate the sea surface temperature (SST) change during this period based on the quantitative planktonic foraminiferal data of 8 DSDP sites in the western Pacific. Target factor analysis has been applied to the conventional transfer function approach to overcome the no-analog conditions caused by evolutionary faunal changes. By applying this technique through a combination of time-slice and time-series studies, the SST history of the last 5.3 Ma has been reconstructed for the low latitude western Pacific. Although the present data set is close to the statistical limits of factor analysis, the clear presence of sensible variations in individual SST time-series suggests the feasibility and reliability of this method in paleoceanographic studies. The estimated SST curves display the general trend of the temperature fluctuations and reveal three major cool periods in the late Neogene, i.e. the early Pliocene (4.7 3.5 Ma), the late Pliocene (3.1-2.7 Ma), and the latest Pliocene to early Pleistocene (2.2-1.0 Ma). Cool events are reflected in the increase of seasonality and meridional SST gradient in the subtropical area. The latest Pliocene to early Pleistocene cooling is most important in the late Neogene climatic evolution. It differs from the previous cool events in its irreversible, steplike change in SST, which established the glacial climate characteristic of the late Pleistocene. The winter and summer SST decreased by 3.3-5.4°C and 1.0 2.1C in the subtropics, by 0.9°C and 0.6C in the equatorial region, and showed little or no cooling in the tropics. Moreover, this cooling event occurred as a gradual SST decrease during 2.2 1.0 Ma at the warmer subtropical sites, while that at cooler subtropical site was an abrupt SST drop at 2.2 Ma. In contrast, equatorial and tropical western Pacific experienced only minor SST change in the entire late Neogene. In general, subtropics was much more sensitive to climatic forcing than tropics and the cooling events were most extensive in the cooler subtropics. The early Pliocene cool periods can be correlated to the Antarctic ice volume fluctuation, and the latest Pliocene early Pleistocene cooling reflects the climatic evolution during the cryosphere development of the northern hemisphere.

Surface wave and storm surge prediction during Hurricane Sandy

Hurricane Sandy was the largest storm on historical record in the Atlantic Ocean basin with extensive coastal damage caused by large waves and high storm surge. The primary objectives of this thesis are to compare and evaluate three different spatially-varying surface wind fields of Hurricane Sandy to investigate the impact of the differences between the complex wind fields on predictions of the sea surface evolution, and to evaluate the impact of the storm on the hydrodynamics in Great South Bay (GSB) and the discharge of ocean water into the back-barrier bay from overwash over Fire Island. Three different spatially-varying surface wind fields were evaluated and compared to wind observations, including the parametric Holland (1980) model (H80), the parametric Generalized Asymmetric Holland Model (GAHM), and results from the WeatherFlow Regional Atmospheric Modelling System (WRAMS). The winds were used to drive the coupled Delft3D-SWAN hydrodynamic and ocean wave models on a regional grid. The results indicate that the WRAMS wind field produces wave model predictions in the best agreement with significant wave height observations, followed by the GAHM and H80 wind fields and that a regional atmospheric wind model is best for hindcasting hurricane waves and water levels when detailed observations are available, while a parametric vortex model is best for forecasting hurricane sea surface conditions. Using a series of four connected Delft3D-SWAN grids to achieve finer resolution over Fire Island and GSB, a higher resolution WRAMS was used to predict waves and storm surge. The results indicate that strong local winds have the largest influence on water level fluctuations in GSB. Three numerical solutions were conducted with varying extents of barrier island overwash. The simulations allowing for minor and major overwash indicated good agreement with observations in the east end of GSB and suggest that island overwash provided a significant contribution of ocean water to GSB during the storm. Limiting the overwash in the numerical model directly impacts the total discharge into GSB from the ocean through existing inlets. The results of this study indicate that barrier island overwash had a significant impact on the water levels in eastern GSB.

The Roles of Land and Orography on Precipitation and Ocean Circulation in Global Climate Models

Thesis (Ph.D.)--University of Washington, 2016-08

Reconstructability of 3-Dimensional Upper Ocean Circulation from SWOT Sea Surface Height Measurements

Utilizing the framework of effective surface quasi-geostrophic (eSQG) theory, we explored the potential of reconstructing the 3D upper ocean circulation structures, including the balanced vertical velocity (w) field, from high-resolution sea surface height (SSH) data of the planned SWOT satellite mission. Specifically, we utilized the 1/30°, submesoscale-resolving, OFES model output and subjected it through the SWOT simulator that generates the along-swath SSH data with expected measurement errors. Focusing on the Kuroshio Extension region in the North Pacific where regional Rossby numbers range from 0.22 to 0.32, we found that the eSQG dynamics constitutes an effective framework for reconstructing the 3D upper ocean circulation field. Using the modeled SSH data as input, the eSQG-reconstructed relative vorticity (ζ) and w fields are found to reach a correlation of 0.7–0.9 and 0.6–0.7, respectively, in the 1,000m upper ocean when compared to the original model output. Degradation due to the SWOT sampling and measurement errors in the input SSH data for the ζ and w reconstructions is found to be moderate, 5–25% for the 3D ζ field and 15-35% for the 3D w field. There exists a tendency for this degradation ratio to decrease in regions where the regional eddy variability (or Rossby number) increases.