995 resultados para FAAS determinations
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Mode of access: Internet.
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"USCSC/OLMR-78/05."
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This study was undertaken to develop a simple laboratory-based method for simulating the freezing profiles of beef trim so that their effect on E. coli 0157 survival could be better assessed. A commercially available apparatus of the type used for freezing embryos, together with an associated temperature logger and software, was used for this purpose with a -80 degrees C freezer as a heat sink. Four typical beef trim freezing profiles, of different starting temperatures or lengths, were selected and modelled as straight lines for ease of manipulation. A further theoretical profile with an extended freezing plateau was also developed. The laboratory-based setup worked well and the modelled freezing profiles fitted closely to the original data. No change in numbers of any of the strains was apparent for the three simulated profiles of different lengths starting at 25 degrees C. Slight but significant (P < 0.05) decreases in numbers (similar to 0.2 log cfu g(-1)) of all strains were apparent for a profile starting at 12 degrees C. A theoretical version of this profile with a freezing plateau phase extended from 11 h to 17 h resulted in significant (P < 0.05) decreases in numbers (similar to 1.2 log cfu g(-1)) of all strains. Results indicated possible avenues for future research in controlling this pathogen. The method developed in this study proved a useful and cost-effective way for simulating freezing profiles of beef trim. (c) 2005 Elsevier B.V. All rights reserved.
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Continental margin sediments off Nova Scotia accumulate at high rates (up to 360 cm/kyr) and contain a history of millennial-scale environmental changes which are dominated by the proximity of the Laurentide ice sheet during the latest Quaternary. Using stable isotope ratios of oxygen, accelerator mass spectrometer radiocarbon dating, micropaleontology, and sedimentology, we document these changes in six piston cores ranging in water depth from ab. 450 to ab. 4300 m. We find that maximum d18O in N. pachyderma occurred about 15 ka and preceded the maximum abundance of this species in these cores by ab. 1000 years. Between 13 and 14 ka we find a second peak in abundance of N. pachyderma, minimum d18O, and two pulses of ice rafting. The sediment lithology supports terrestrial studies which indicate that there was a general withdrawal of ice beyond the upper Paleozoic and Mesozoic red beds by 14 ka in southeastern Canada, so the ice rafting events between 13 and 14 ka probably reflect ice stream activity in the St. Lawrence valley. The Younger Dryas event is recognized as a peak in abundance of N. pachyderma and ice rafting (dated as ab. 11.3 ka), but meltwater discharge to the Gulf of St. Lawrence was either too small or occurred over too long a time to leave a distinct d18O minimum off Nova Scotia. At 7.1 ka, in the middle of Holocene warming, we find a third peak in abundance of N. pachyderma and another d18O minimum but no ice rafting. We interpret these data as evidence of a late-occurring meltwater event which, if correct, could have originated in the Great Lakes, in the Labrador-Ungava region, or in both. The final millennial-scale phenomenon off Nova Scotia is the onset of "Neoglaciation," marked by increased ice rafting and increased % N. pachyderma beginning about 5 kyr ago.
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On the base of data on benthic foraminifera and sediment biogeochemistry (contents of total organic carbon, calcium carbonate and biogenic opal) in two cores (1265 and 1312 m water depth) from the southeastern Sakhalin slope and one core (839 m water depth) from the southwestern Kamchatka slope variations of the oxygen minimum zone during the last 50 ka in the Okhotsk Sea are reconstructed. The oxygen minimum zone was less pronounced during cooling in the MIS 2 that is suggested to be caused by maximal expansion of the sea ice cover, decrease of marine productivity and increase of production of oxygenated Okhotsk Sea Intermediate Water (OSIW). Two-step-like strengthening of oxygen minimum zone during warmings in the Terminations 1a and 1b was combined with (1) enhanced oxygen consumption due to decomposition of large amount of organic matter in the water column and bottom sediments due to increased marine productivity and supply of terrigenous material from submerged northern shelves; (2) sea ice cover retreat and reduction of OSIW production; (3) freely inflow of the oxygen-depleted intermediate water mass from the North Pacific.
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Cold-water corals are widely distributed along the Atlantic continental margin with varying growth patterns in relation to their specific environment. Here, we investigate the long-term development of cold-water corals that once thrived on a low-latitude (17°40'N) cold-water coral mound in the Banda Mound Province off Mauritania during the last glacial-interglacial cycle. U/Th dates obtained from 20 specimens of the cold-water coral Lophelia pertusa, revealed three distinct periods of coral growth during the last glacial at 65 to 57 kyr BP, 45 to 32 kyr BP and 14 kyr BP, thus comprising the cool periods of Marine Isotopic Stages (MIS) 2-4. These coral growth periods occur during periods of increased productivity in the region, emphasizing that productivity seems to be the major steering factor for coral growth off Mauritania, which is one of the major upwelling regions in the world. This pattern differs from the well studied coral mounds off Ireland, where the current regime predominantly influences the prosperity of the cold-water corals. Moreover, coral growth off Ireland takes place during rather warm interglacial and interstadial periods, whereas off Mauritania coral growth is restricted to glacial and stadial periods. However, the on-mound sedimentation patterns off Mauritania largely resemble the observations reported from the Irish mounds. The bulk of the preserved sediments derives from periods of coral growth, whereas during periods without corals hardly any net sedimentation or mound growth took place.
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Sediments in the North Atlantic ocean contain as eries of layers that are rich in ice-rafted debris and unusally poor in foraminifera. Here we present evidence that the most recent six of the 'Heinrich layers', deposited between 14,000 and 70,000 years ago, record marked decreases in sea surface temperature and salinity, decreases in the flux of planktonic forminifera to the sediments, and short-lived, massive discharges of icebergs originating in eastern Canada. The path of the icebergs, clearly marked by the presence of ice-rafted detrital carbonate, can be traced for more than 3,000 km - a remarkable distance, attesting to extreme cooling of surface waters and enormous amounts of drifiting ice. The cause of these extreme events is puzzling. They may reflect repated rapid advances of the Laurentide ice sheet, perhaps associated with reductions in air temperatures, yet temperature records from Greenland ice cores appear to exhibit only a weak corresponding signal. Moreover, the 5-10,000-yr intervals between the events are inconsistent with Milankovitch orbital periodicities, raising the question of what the ultimate cause of the postulated cooling may have been.
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The age correlation between the three main geomorphological terraces in the Lena Delta, especially that of the second sandy terrace (Arga Island) and the third terrace (Ice Complex and underlying sands) is still being discussed, Knowledge about the age of the lee Complex and its underlying sands, and the Arga sands is necessary for understanding the past and modern structure of the delta. Geochronometrie data have been acguired for three sediment seguences from the Lena Delta by lumineseence dating using the potassium feldspar IR-OSL technique. Additionally, 14C dates are available for geochronological discussion. Typical sediments of the upper part of Arga Island as found in the area of Lake Nikolay are of Late Pleistoeene age (14.5-10.9 ka), Typical third terrace sediments from two seguenees located at the Olenyokskaya branch are older. At the profile "Nagym" sandy seguences were most probably deposited between about 65 ka and 50 ka before present. The lower part of the sandy seguence at "Kurungnakh Island" is possibly older than the sediments of the section at Nagym. However, methodological difficulties in luminescence dating (insufficient bleaching at the time of deposition) and younger 14C dates make the discussion of the results difficult.
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Boron and Li are light, incompatible elements that preferentially partition into the liquid phase, whether melt or aqueous fluid, and thus are useful for tracking fluid-related processes in rocks. Most of the Li isotopic data presently available on subduction-related rocks are from whole-rock analyses; and the B isotopic analyses of subduction material have been carried out either on whole-rocks or in-situ on an accessory phase, such as tourmaline. The new method presented here couples an ESI New Wave UP-193-FX ArF* (193 nm) excimer laser-ablation microscope with a Neptune Plus (Thermo Scientific) MC-ICP-MS aiming to measure both Li and B isotopes in situ with good spatial resolution (metamorphic minerals are commonly chemically zoned, and whole-rock analyses lose this detail). The data thus obtained are compared with SIMS analyses on the same mineral samples for B, and with MC-ICP-MS analyses on whole-rock or mineral separates from the same sample for Li. Additionally, data acquired on tourmaline standards were compared to SIMS values. The results show that for B concentrations above 5 μg/g, the data obtained by LA-MC-ICP-MS and by SIMS are identical within error, for mica (phengitic muscovite), pyroxene (jadeite), serpentine (antigorite), and tourmaline. For Li concentrations above 10 μg/g, the data obtained by LA-MC-ICP-MS and by MC-ICP-MS are also identical, within error, for mica (phengitic muscovite), and pyroxene (jadeite). However, analyses of tourmaline standards have shown significant differences with reference values, so LA-MC-ICP-MS does not yet appear to be an appropriate method to analyze Li isotopes in tourmalines. Thus, LA-MC-ICP-MS is a suitable method to measure Li and B isotopes with good spatial resolution in major rock-forming silicates from subduction-related rocks where concentrations exceed 10 μg/g and 5 μg/g, respectively, with an error on individual measurements equal to or less than previously used methods, but obtainable in a significantly shorter amount of time. The external reproducibility is ± 2.88 to 3.31 ‰ for B and ± 1.50 to 1.75 for Li, which is lower than or equal to the variations encountered within a given chemically zoned sample (up to 10 ‰ of variation within a given natural sample).