The effects of CO2 addition on the partial oxidation of heptane for hydrogen generation

The effects of CO2 on the partial oxidation of heptane for hydrogen generation have been studied. Based on the experimental results and thermodynamic equilibrium calculations, the validity of CO2 addition to weaken the hot spots, and the feasibility of the autothermal operation are discussed.

Catalytic partial oxidation of n-heptane for hydrogen production

Partial oxidation of n-heptane (POH) for hydrogen generation was studied over several catalysts between 700 and 850degreesC. Modified Ni-based/gamma-Al2O3 catalyst exhibited not only good catalytic activity but also good carbon deposition resistance ability. Under the modified reaction conditions, 100% n-heptane conversion and 93% hydrogen selectivity can be obtained.

基于能值理论的生态足迹方法改进

生态足迹方法自提出以来受到广泛关注,其缺点也受到一些学者的批评。Zhao Sheng等2005年提出能值足迹法,弥补了生态足迹法以土地生产能力为限制的缺点。论文提出区域能值足迹法,以弥补其改进方法不能够反映区域实际情况和技术进步带来影响的不足。最后,以岷江上游1982到2002年为例应用3种方法进行计算分析。结果表明研究区生态足迹呈缓慢上升趋势,生态足迹方法计算结果<能值足迹<区域能值足迹;生态承载力计算结果显示生态足迹与区域能值足迹方法结果呈平缓下降趋势,而能值足迹方法结果呈不规则变动。区域能值足迹法能够考虑到区域实际情况和技术进步,但它不能完全代替生态足迹方法,将其结合应用将得到更多信息。

中国木生革菌研究2.高加索纹枯状革菌和粉状杰克革菌(英文)

高加索纹枯状革菌Hypochnicium caucasicum Parmasto和粉状杰克革菌Jacksonomyces furfurellus(Bres.) Sheng H. Wu & Z.C.Chen采自湖南省和广西壮族自治区,高加索纹枯状革菌是中国新记录种,粉状杰克菌在中国大陆首次报道。本文根据采集的材料对这两个种进行了详细的描述和显微结构绘图。

ANALYSIS OF DRIVING FORCES ON THE CHANGE OF HISTORICAL FARMLAND USE IN SHANDONG PROVINCE DURING THE QING DYNASTY (1644-1911)

National Natural Science Foundation of China [40201005]; Knowledge Innovation Project of Chinese Academy of Sciences [KZCX3-SW-321, KZCX2-314, KZCX1-SW-321-4]

Preparation and Characterization of Interpenetration Polymer Network Films Based on Poly(vinyl alcohol) and Poly(acrylic acid) for Drug Delivery

A series of full interpenetrating polymer network (full-IPN) films of poly(acrylic acid) (PAA)/poly (vinyl alcohol) (PVA) were prepared by radical solution polymerization and sequential IPN technology. Attenuated total reflectance-Fourier transform infrared spectroscopy, swelling properties, mechanical properties, morphology, and glass transition temperature of the films were investigated. FTIR spectra analysis showed that new interaction hydrogen bonds between PVA and PAA were formed. Swelling property of the films in distilled water and different pH buffer solution was studied. Swelling ratio increased with increasing PAA content of IPN films in all media, and swelling ratio decreased with increasing PVA crosslink degree. Tensile strength and elongation at break related not only to the constitution of IPNs but also to the swelling ratio of IPNs.

AGET ATRP of acrylamide in aqueous media

The recently developed initiation system, the activator generated by electron transfer (AGET) was used in atom transfer radical polymerization (ATRP) to synthesize well-controlled polyacrylamide in aqueous media at 25 degrees C. The different reducing agents involved ascorbic acid and glucosa; well-controlled polymers were obtained when ascorbic acid was used as water-soluble reducing agent. The polymerizations targeted at degrees of polymerization in the range of 400 resulted in polymers with low polydispersity indices. Moreover, first order plots were linear.

Fabrication and characterization of microstructured and pH sensitive interpenetrating networks hydrogel films and application in drug delivery field

Novel microstructured and pH sensitive poly(acryliac acid-co-2-hydroxyethyl methacrylate)/poly(vinyl alcohol) (P(AA-co-HEMA)/PVA) interpenetrating network (IPN) hydrogel films were prepared by radical precipitation copolymerization and sequential IPN technology. The first P(AA-co-HEMA) network was synthesized in the present of IPN aqueous solution by radical initiating, then followed by condensation reaction (Glutaraldehyde as crosslinking agent) within the resultant latex, it formed multiple IPN microstructured hydrogel film. The film samples were characterized by IR, SEM and DSC. Swelling and deswelling behaviors and mechanical property showed the novel multiple IPN nanostuctured film had rapid response and good mechanical property. The IPN films were studied as controlled drug delivery material in different pH buffer solution using cationic compound, crystal violet as a model drug.

Crystal structure of a noval poly(aryl ether ketone) containing meta-phenyl linkage

Crystal structure of a novel aryl ether ketone polymer poly(aryl ether ketone ether ketone ketone containing meta-phenyl linkage)(PEKEKmK) was determined by means of WAXD and ED. An orthorhombic unit cell is proposed containing two chains with a=0.772 nm, b=0.604 nm and c=2.572 nm. According to the orthorhombic system, the 10 reflections of this polymer were indexed.