Grain counts and relative abundances of volcaniclastic sands and sandstones of ODP Leg 180 sites

Modal analysis of middle Miocene to Pleistocene volcaniclastic sands and sandstones recovered from Sites 1108, 1109, 1118, 1112, 1115, 1116, and 1114 within the Woodlark Basin during Leg 180 of the Ocean Drilling Program indicates a complex source history for sand-sized detritus deposited within the basin. Volcaniclastic detritus (i.e., feldspar, ferromagnesian minerals, and volcanic rock fragments) varies substantially throughout the Woodlark Basin. Miocene sandstones of the inferred Trobriand forearc succession contain mafic and subordinate silicic volcanic grains, probably derived from the contemporary Trobriand arc. During the late Miocene, the Trobriand outerarc/forearc (including Paleogene ophiolitic rocks) was subaerially exposed and eroded, yielding sandstones of dominantly mafic composition. Rift-related extension during the late Miocene-late Pliocene led to a transition from terrestrial to neritic and finally bathyal deposition. The sandstones deposited during this period are composed dominantly of silicic volcanic detritus, probably derived from the Amphlett Islands and surrounding areas where volcanic rocks of Pliocene-Pleistocene age occur. During this time terrigenous and metamorphic detritus derived from the Papua New Guinea mainland reached the single turbiditic Woodlark rift basin (or several subbasins) as fine-grained sediments. At Sites 1108, 1109, 1118, 1116, and 1114, serpentinite and metamorphic grains (schist and gneiss) appear as detritus in sandstones younger than ~3 Ma. This is thought to reflect a major pulse of rifting that resulted in the deepening of the Woodlark rift basin and the prevention of terrigenous and metamorphic detritus from reaching the northern rift margin (Site 1115). The Paleogene Papuan ophiolite belt and the Owen Stanley metamorphics were unroofed as the southern margin of the rift was exhumed (e.g., Moresby Seamount) and, in places, subaerially exposed (e.g., D'Entrecasteaux Islands and onshore Cape Vogel Basin), resulting in new and more proximal sources of metamorphic, igneous, and ophiolitic detritus. Continued emergence of the Moresby Seamount during the late Pliocene-early Pleistocene bounded by a major inclined fault scarp yielded talus deposits of similar composition to the above sandstones. Upper Pliocene-Pleistocene sandstones were deposited at bathyal depths by turbidity currents and as subordinate air-fall ash. Silicic glassy (high-K calc-alkaline) volcanic fragments, probably derived from volcanic centers located in Dawson and Moresby Straits, dominated these sandstones.

(Table 1) Heavy mineral content in sediments of the southern Mediterranean Ridge, Nile Cone and Egyptian Shelf

Petrographic analysis of Quaternary terrigenous sand layers in eastern Mediterranean cores reveals distinct mineralogical differences between the Egyptian Shelf-Nile Cone region and the southern part of the Mediterranean Ridge. A compositionally and texturally immature suite in Ridge cores, mixed with a Nile-derived assemblage, identifies a fresh non-recycled mineral component derived from proximal igneous and metamorphic surface or near-surface exposures, probably in the south-central Ridge area rather than from distal African sources. The presence of such basement terrains would be consistent with a compressive thrust-belt origin for this part of the Mediterranean Ridge.

Composition of sedimentary rocks from the Shapkina River valley, Bolshezemelskaya Tundra

A facies-genetic and stratigraphic subdivision of the Quaternary sequence in the Shapkina River valley has been accomplished. The riverbank shows outcrops of three glacial complexes with different mineralogical-petrographic compositions and structural characteristics, which can be correlated and stratificated. Datings of intermoraine horizons (alluvial, marine, lacustrine, and lacustrine-boggy sediments) have been based on palynological and paleomicrotheriological data. The Middle Neopleistocene section can be divided into two till horizons corresponding to two autonomous glaciations (Pechora and Vychegda). They are separated by a member of subaqueous Rodionov sediments. The Pechora till formed in the course of glacier motions from the northeast. Glacial horizons are mainly composed of the Vychegda till transported from the Northwest terrigenous provenance. Lithology of the Upper Neopleistocene Polyarnyi till testifies to its formation in the upper course of the river from material transported from the Northeast terrigenous-mineralogical provenance in the upper course of the river and from the Fennoscandian glaciation center in the lower course of the river. The paper presents the first lithological investigation and substantiation of genesis of various facies of Neopleistocene intermoraine marine sediments (sediments of the beach and fore-beach zones and shallow-water shelf).

Analysis of minerals from Arctic Ocean sediments

The Arctic Ocean System is a key player regarding the climatic changes of Earth. Its highly sensitive ice Cover, the exchange of surface and deep water masses with the global ocean and the coupling with the atmosphere interact directly with global climatic changes. The output of cold, polar water and sea ice influences the production of deep water in the North Atlantic and controls the global ocean circulation ("the conveyor belt"). The Arctic Ocean is surrounded by the large Northern Hemisphere ice sheets which not only affect the sedimentation in the Arctic Ocean but also are supposed to induce the Course of glacials and interglacials. Terrigenous sediment delivered from the ice sheets by icebergs and meltwater as well as through sea ice are major components of Arctic Ocean sediments. Hence, the terrigenous content of Arctic Ocean sediments is an outstanding archive to investigate changes in the paleoenvironment. Glazigenic sediments of the Canadian Arctic Archipelago and surface samples of the Arctic Ocean and the Siberian shelf regions were investigated by means of x-ray diffraction of the bulk fraction. The source regions of distinct mineral compositions were to be deciphered. Regarding the complex circumpolar geology stable christalline shield rocks, active and ancient fold belts including magmatic and metamorphic rocks, sedimentary rocks and wide periglacial lowlands with permafrost provide a complete range of possible mineral combinations. Non- glaciated shelf regions mix the local input from a possible point source of a particular mineral combination with the whole shelf material and function as a sampler of the entire region draining to the shelf. To take this into account, a literature research was performed. Descriptions of outcropping lithologies and Arctic Ocean sediments were scanned for their mineral association. The analyses of glazigenic and shelf sediments yielded a close relationship between their mineral composition and the adjacent source region. The most striking difference between the circumpolar source regions is the extensive outcrop of carbonate rocks in the vicinity of the Canadian Arctic Archipelago and in N Greenland while siliciclastic sediments dominate the Siberian shelves. In the Siberian shelf region the eastern Kara Sea and the western Laptev Sea form a destinct region defined by high smectite, (clino-) pyroxene and plagioclase input. The source of this signal are the extensive outcrops of the Siberian trap basalt in the Putorana Plateau which is drained by the tributaries of the Yenissei and Khatanga. The eastern Laptev Sea and the East Siberian Sea can also be treated as one source region containing a feldspar, quartz, illite, mica, and chlorite asscciation combined with the trace minerals hornblende and epidote. Franz Josef Land provides a mineral composition rich in quartz and kaolinite. The diverse rock suite of the Svalbard archipelago distributes specific mineral compositions of highly metamorphic christalline rocks, dolomite-rich carbonate rocks and sedimentary rocks with a higher diagenetic potential manifested in stable newly built diagenetic minerals and high organic maturity. To reconstruct the last 30,000 years as an example of the transition between glacial and interglacial conditions a profile of sediment cores, recovered during the RV Polarstern" expedition ARK-VIIIl3 (ARCTIC '91), and additional sediment cores around Svalbard were investigated. Besides the mineralogy of different grain size fractions several additional sedimentological and organo-geochemical Parameterswere used. A detailed stratigraphic framework was achieved. By exploiting this data set changes in the mineral composition of the Eurasian Basin sediments can be related to climatic changes. Certain mineral compositions can even be associated with particular transport processes, e.g. the smectitel pyroxene association with sea ice transport from the eastern Kara Sea and the western Laptev Sea. Hence, it is possible to decipher the complex interplay between the influx of warm Atlantic waters into the Southwest of the Eurasian Basin, the waxing and waning of the Svalbard1Barents- Sea- and Kara-Sea-Ice-Sheets, the flooding of the Siberian shelf regions and the surface and deep water circulation. Until now the Arctic Ocean was assumed to be a rather stable System during the last 30,000 years which only switched from a completely ice covered situation during the glacial to seasonally Open waters during the interglacial. But this work using mineral assemblages of sediment cores in the vicinity of Svalbard revealed fast changes in the inflow of warm Atlantic water with the Westspitsbergen Current (< 1000 years), short periods of advances and retreats of the marine based Eurasian ice sheets (1000-3000 years), and short melting phases (400 years?). Deglaciation of the marine-based Eurasian and the land-based north American and Greenland ice sheets are not simultaneous. This thesis postulates that the Kara Sea Ice Sheet released an early meltwater signal prior to 15,000 14C years leading the Barents Sea Ice Sheet while the western land-based ice sheets are following later than 13,500 14C years. The northern Eurasian Basin records the shift between iceberg and sea-ice material derived from the Canadian Arctic Archipelago and N-Greenland and material transported by sea-ice and surface currents from the Siberian shelf region. The phasing of the deglaciation becomes very obvious using the dolomite and quartd phyllosilicate record. It is also supposed that the flooding of the Laptev Sea during the Holocene is manifested in a stepwise increase of sediment input at the Lomonosov Ridge between the Eurasian and Amerasian Basin. Depending on the strength of meltwater pulses from the adjacent ice sheets the Transpolar Drift can probably be relocated. These movements are traceable by the distribution of indicator minerals. Based on the outcome of this work the feasibility of bulk mineral determination can be qualified as excellent tool for paleoenvironmental reconstructions in the Arctic Ocean. The easy preparation and objective determination of bulk mineralogy provided by the QUAX software bears the potential to use this analyses as basic measuring method preceding more time consuming and highly specialised mineralogical investigations (e.g. clay mineralogy, heavy mineral determination).

Investigation of sediment core PS2556 from Bellingshausen Sea, Antarctica

Die Rekonstruktion der glaziomarinen Sedimentationsprozesse am antarktischen Kontinentalrand des westlichen Bellingshausenmeeres erfolgte durch die sedimentologische Auswertung eines 962 cm langen Schwerelotkernes aus 3594 m Wassertiefe. Der Kern wurde während des Fahrtabschnittes ANT-XI/3 mit dem FS "Polarstern" vom Scheitel einer Sediment- "Drift" gezogen. An dem Sedimentkern wurde eine lithologische Beschreibung, sowie sedimentologische Untersuchungen und sedimentphysikalische Messungen durchgeführt. Anhand der Ergebnisse konnten signifikante Änderungen in der Zusammensetzung und Struktur der Sedimente erkannt, und drei Faziestypen unterschieden werden. Die Faziestypen charakterisieren jeweils glaziale oder interglaziale Zeiträume. Der größte Teil der Sedimentabfolge gehört der Laminitfazies an. Dabei handelt es sich um feinlaminierte Sedimentabschnitte, die vorwiegend aus feinkörnigen, terrigenen Komponenten zusammengesetzt sind. In die feinlaminierten Abschnitte sind vereinzelte, wenige Milimeter bis Zentimeter mächtige Siltlagen eingeschaltet. Die biogenen Anteile sind gering, Anzeichen für Bodenleben fehlen völlig. Die Manganfazies wird von authigen gebildeten Mangankonkretionen dominiert, die jeweils diskrete Lagen bilden. Dabei handelt es sich zum einen um Mikromanganknollen und -krusten und zum andern um manganhaltige Gangfüllungen. Biogene und terrigene Anteile sind in diesem Faziestyp unbedeutend. Die Biogenfazies ist von strukturlosen und stark bioturbierten Sedimenten gekennzeichnet. In diesen Sedimentabschnitten ist der hohe Anteil an Eisfracht (IRD) und die erhöhten Gehalte an Kalziumkarbonat und Opal in der Sandfraktion markant. Die stratigraphische Einordnung des Sedimentkernes erfolgte über die von Grobe & Mackensen (1992) entwickelte Lithostratigraphie, mit deren Einheiten die Faziestypen des Sedimentkernes korreliert werden konnten. Dabei ergaben sich zwei mögliche Altersmodelle und ein Basisalter von ca. 250.000 Jahren. Anhand der stratigraphischen Fixpunkte wurden Sedimentationsraten des Gesamtsedimentes und Akkumulationsraten des Kalziumkarbonates, des Biogenopals und des organisch gebundenen Kohlenstoffes berechnet. Dabei wurde gezeigt, daß lediglich das Kalziumkarbonat und der Biogenopal als Anzeiger für biologische Produktion dienen können, wobei Lösungsprozesse in der Wassersäule und im Sediment eine große Rolle spielen. Der Gehalt an organisch gebundenem Kohlenstoff ist in dem Sedimentkern nur erhaltungsbedingt zu erklären. Die Sedimentationsprozesse der einzelnen Faziestypen sind von den Eisverhältnissen, der biologischen Produktion, dem gravitativen Transport und der Umlagerung durch Meeresströmungen abhängig. Die Auswirkung der einzelnen Faktoren ist jeweils unterschiedlich ausgeprägt und wirkt sich spezifisch auf die einzelnen Parameter aus. In den Glazialen hatte ein Vorstoß des Schelfeises über die Schelfkante zur Anlieferung großer Sedimentmassen geführt, die über gravitativen Transport den Kontinentalhang hinunter transportiert wurden. Die Feinfracht wurde über parallel zum Kontinentalhang laufende Konturströme westwärts transportiert und in der Larninitfazies der Driftkörper abgelagert. Am Ende der Glaziale kam es zur Sedimentation der Manganfazies. Die geringen Sedimentationsraten am Kamm der Sedimentdrift kamen aufgrund reduzierter Intensität der Konturströme und fehlender Umlagerung von Schelfsedimenten in Folge rückschreitender Schelfeisrnassen zustande. In den Interglazialen kam es durch den aufsteigenden Meeresspiegel zum Aufschwimmen des Schelfeises. Der damit verbundene Abbau der Eisrnassen über dem Schelf, hatte eine hohe Sedimentation von IRD zur Folge. Mit fortschreitendem Interglazial kam es in Zeiten nur saisonaler Meereisbedeckung zu verstärkter biologischer Produktion und zur Sedimentation biogenen Materials.

Microchemistry and microstructures of hydrothermally altered shock-metamorphosed basement gneiss, Woodleigh impact structure, Southern Carnarvon Basin, Western Australia

Hydrothermally altered shock-metamorphosed gneisses consisting of relic igneous biotite-K-feldspor-Na-rich alkali feldspar - plagioclase - quartz assemblages ( accessory garnet, corundum, titanite, monazite, zircon), and showing extensive replacement by montmorillonite, illite, sericite, and to a lesser extent chlorite, calcite, epidote, zoisite and pyrite, occur in the basement core uplift of the Woodleigh impact structure, Western Australia. The rocks display extensive hydrothermal clay alteration, complicating identification of pre-hydrothermal and pre-impact textures and compositions. Analysis of quartz-hosted planar deformation features (PDFs) indicates a majority of indexed sets parallel to omega{10 (1) over bar3}, a lesser abundance of sets parallel to pi{10 (1) over bar2}, and some sets parallel to the basal plane (0001) and r,z {10 (1) over bar1}, consistent with pressures about or over 20 GPa. Feldspar-hosted FDFs form reticulate vein networks displaying checkerboard-like to irregular and serrated patterns attributable to preferential replacement of shock-damaged PDFs and/or perthitic twin lamella by clay minerals. The gneisses are pervaded by clay-dominated intergranular and intragranular veins of cryptocrystalline material that display marked departures from bulk-rock chemistry and from mineral compositions. XRD analysis identifies the cryptocrystalline components as illite - montmorillonite, illite and chlorite, while laser Raman analysis identifies high-fluorescence sub-micrometre clay assemblage, feldspar, quartz and minor mica. SEM/EDS-probe and laser-ICPMS analysis indicate low-K high-Mg clay mineral compositions consistent with montmorillonite. Quartz PDF-hosted cryptocrystalline laminae display distinct enrichments in Al, Mg, Ca and K. Altered intergranular veins and feldspar-hosted cryptocrystalline components show consistent enrichment in the relatively refractory elements (Al, Cc, Mg, Fe) and depletion in relatively volatile elements (Si, K, Na). The clay alteration retards determination whether clay-dominated vein networks represent altered shock-induced pseudotachylite veins, diaplectic zones and/or shock-damaged twin lamella, and/or result from purely mineralogical and chemical differentiation affected by hydrothermal fluids, Overall enrichment of the shocked gneiss and of the cryptocrystalline components in Mg and trace ferromagnesian elements (Ni, Cc, Cr) may be attributed alternatively to introduction of siderophile element-rich fluid from the projectile, or/and contamination of hydrothermal fluids by MgO from dolomites surrounding the basement uplift. High Ni/Co and Ni/Cr and anomalous DGE (platinum group elements) may support the former model.

Bajo de la Alumbrera copper-gold deposit: Stable isotope evidence for a porphyry-related hydrothermal system dominated by magmatic aqueous fluids

Alteration zones at the gold-rich Bajo de la Alumbrera porphyry copper deposit in northwestern Argentina are centered on several porphyritic intrusions. They are zoned from a central copper-iron sulfide and gold-mineralized potassic (biotite-K-feldspar +/- quartz) core outward to propylitic (chlorite-illite-epidote-calcite) assemblages. A mineralized intermediate argillic alteration assemblage (chlorite-illite +/- pyrite) has overprinted the potassic alteration zone across the top and sides of the deposit and is itself zoned outward into phyllic (quartzinuscovite-illite +/- pyrite) alteration. This study contributes new data to previously reported delta(18)O and delta D compositions of fluids responsible for the alteration at Bajo de la Alumbrera, and the data are used to infer likely ore-forming processes. Measured and calculated delta(18)O and delta D values of fluids (+8.3 to +10.2 and -33 to -81 parts per thousand, respectively) confirm a primary magmatic origin for the earliest potassic alteration phase. Lower temperature potassic alteration formed from magmatic fluids with lower delta D values (down to -123 parts per thousand). These depleted compositions are distinct from meteoric water and consistent with degassing and volatile exsolution of magmatic fluids derived from an underlying magma. Variability in the calculated composition of fluid associated with potassic alteration is explained in terms of phase separation (or boiling). if copper-iron sulfide deposition occurred during cooling (as proposed elsewhere), this cooling was largely a result of phase separation. Magmatic water was directly involved in the formation of overprinting intermediate argillic alteration assemblages at Bajo de la Alumbrera. Calculated delta(18)O and delta D values of fluids associated with this alteration range from +4.8 to +8.1 and -31 to -71 per mil, respectively Compositions determined for fluids associated with phyllic alteration (-0.8 to +10.2 and -31 to -119 parts per thousand) overlap with the values determined for the intermediate argillic alteration. We infer that phyllic alteration assemblages developed during two stages; the first was a high-temperature (400 degrees-300 degrees C) stage with D-depleted water (delta D = -66 to -119 parts per thousand). This compositional range may have resulted from magma degassing and/or the injection of new magmatic water into a compositionally evolved hydrothermal system. The isotopic variations also can be explained by increased fluid-rock interaction. The second stage of phyllic alteration occurred at a lower temperature (similar to 200 degrees C), and variations in the modeled isotopic compositions imply mixing of magmatic and meteoric waters. Ore deposition that occurred late in the evolution of the hydrothermal system was probably associated with further cooling of the magmatic fluid, in part caused by fluid-rock interaction and phase separation. Changing pH and/or oxygen fuoracity may have caused additional ore deposition. The ingress of meteoric water appears to postdate the bulk of mineralization and occurred as the system at Bajo de la Alumbrera waned.

Petrologia do Plutão Bom Jardim de Goiás (PBJG): implicação na evolução neoproterozoica da Província Tocantins

The Bom Jardim de Goiás Pluton (PBJG) is a semi-circular body, located in the central portion of the Tocantins Province, intrusive into orthogneisses and metassupracrustals of the Arenópolis Magmatic Arc. These metasupracrustals present a low to moderate dipping banding or schistosity, have a low to moderate angle of banding / foliation, defined by mica, andalusite and sillimanite and cordierite, which characterize an amphibolite facies metamorphism. This structure is crosscut by the emplacement of the PBJG rocks. The abrupt nature of the contacts and the absence of ductile structures indicate that the intrusion took place in a relatively cold crust. Under petrographic grounds, the pluton consists mainly of monzodiorites, tonalite and granodiorite, following the low to medium-K calk-alkaline alkaline trend. Rocks of the PBJG have hornblende and biotite as the main mafic phases, besides subordinate clinopyroxene, titanite, epidote and opaque. Late dikes of leucogranite contain only mineral biotite as relevant accessory mineral. One U-Pb zircon dating of a monzodiorite yielded an age of 550 ± 12 Ma (MSWD = 1.06). Whole-rock and mineral chemistry suggest that the studied rocks are calc-alkaline, having evolved by fractional crystallization of Ca- and Fe-Mg minerals under high oxygen fugacity. Using the amphibole-plagioclase geothermometer and the Al-in amphibole geobarometer, we calculate temperatures and pressures of, respectively, 692-791 °C e 2.4-5.0 kbar for the intrusion of the PBJG, which is corroborated by previous metamorphic assemblages in the country rocks. The geological, geochemical and geochronological features of PBJG demonstrate their post-tectonic or post-collisional nature, with emplacement into an already uplifted and relatively cool crust at the end of brasiliano orogeny in this portion of the Tocantins Province.

Petrologia do Plutão Bom Jardim de Goiás (PBJG): implicação na evolução neoproterozoica da Província Tocantins

The Bom Jardim de Goiás Pluton (PBJG) is a semi-circular body, located in the central portion of the Tocantins Province, intrusive into orthogneisses and metassupracrustals of the Arenópolis Magmatic Arc. These metasupracrustals present a low to moderate dipping banding or schistosity, have a low to moderate angle of banding / foliation, defined by mica, andalusite and sillimanite and cordierite, which characterize an amphibolite facies metamorphism. This structure is crosscut by the emplacement of the PBJG rocks. The abrupt nature of the contacts and the absence of ductile structures indicate that the intrusion took place in a relatively cold crust. Under petrographic grounds, the pluton consists mainly of monzodiorites, tonalite and granodiorite, following the low to medium-K calk-alkaline alkaline trend. Rocks of the PBJG have hornblende and biotite as the main mafic phases, besides subordinate clinopyroxene, titanite, epidote and opaque. Late dikes of leucogranite contain only mineral biotite as relevant accessory mineral. One U-Pb zircon dating of a monzodiorite yielded an age of 550 ± 12 Ma (MSWD = 1.06). Whole-rock and mineral chemistry suggest that the studied rocks are calc-alkaline, having evolved by fractional crystallization of Ca- and Fe-Mg minerals under high oxygen fugacity. Using the amphibole-plagioclase geothermometer and the Al-in amphibole geobarometer, we calculate temperatures and pressures of, respectively, 692-791 °C e 2.4-5.0 kbar for the intrusion of the PBJG, which is corroborated by previous metamorphic assemblages in the country rocks. The geological, geochemical and geochronological features of PBJG demonstrate their post-tectonic or post-collisional nature, with emplacement into an already uplifted and relatively cool crust at the end of brasiliano orogeny in this portion of the Tocantins Province.

Heavy mineral investigations from surface sediments of the East Greenland continental margin

During the expeditions ARK-VII/1, ARK-VII/3 and ARK-Xl2 sediment cores were taken by "RV Polarstern" from the shelf and the fjords of East Greenland and the Greenland Sea. The magnetic susceptibility and heavy mineral were determined at 48 surface sediment samples from undisturbed box cores. The main objective of this study was the identification of source areas and transport processes of terrigenous sediments at the East Greenland continental margin. The results can be summarized as lollows: 1a) Magnetic susceptibility in the North Atlantic is useful to detect delivery regions of the material transported by currents. b) The magnetic susceptibility is controlled by the ferromagnetic particles of the silt fraction. c) There are four important source areas: . The ferromagnetic particles of the box core PS2644-2 are transported from the Iceland Archipelago. . The material from the Geiki-Plateau effects the magnetic susceptibility in the Scoresby Sund Basin. . The magnetic susceptibility in the shelf regions in the North are produced by material from the fjords. . The ferromagnetic particles in the Greenland Sea are derived from the Mid Atlantic Ridges in the east. d) It is possible to determine the rock type, which delivers the ferromagnetic material because of differences in magnetic susceptibility of different intensity. . The erosion of the basalts of the Geiki-Plateau and the basalts of the Mid Atlantic ridges produce the high magnetic susceptibility in the south. . The magnetic susceptibility on the shelf in the north are probably produced by erosionproducts of the gneises of East Greenland. (2a) Heavy mineral assemblages show a significant difference between material transported by the Transpolar Drift from the Eurasian shelf regions (amphiboles, clinopyroxene, orthopyroxene) and material derived from East Greenland (garnets and opaque minerals). Transport via ice is dominant. b) lt is also possible to show different petrographic provenances (volcanic and metamorphic provenances). These associations verify the source areas. c) The information of heavy mineral composition gives no more detailed hint on the rock type or rock formation in the source area, due to mixing processes, large area of investigation and the sample quantity.