Electrodeposition of Ni-B and Ni-Co-B Alloys by Using Boric Acid as Boron Source

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Determinação da resistência à flexão de ligas odontológicas, utilizadas em prótese parcial fixa e prótese sobre implante, soldadas por brasagem e a laser

Pós-graduação em Odontologia Restauradora - ICT

Estudo da corrosão em ligas de alumínio utilizadas na indústria aeronáutica

A resistência e o mecanismo de corrosão das ligas de alumínio 2024, 7010, 7050 e 7475 foram estudados em solução de NaCl. Os efeitos do tratamento térmico nas ligas, concentração de oxigênio, pH, adição de oxi-ânions e temperatura do meio constituem algumas das variáveis estudadas. Primeiramente, procedeu-se à caracterização físicoquímica dos materiais através de análise química e metalográfica, mediante microscopia eletrônica de varredura e espectroscopia de energia dispersiva. As ligas 2024, 7010, 7050 e 7475 como recebidas, recozidas e envelhecidas, revelaram a existência de partículas ternárias e quaternárias, constituídas por Al:Cu:Fe e Mg ou Zn. Também foi observado um maior número de partículas pequenas de composição variável situando-se, preferencialmente, nos contornos dos grãos. Os resultados dos ensaios de corrosão em meios aerados e desaerados indicam que o cromato é efetivo como inibidor da corrosão localizada em ambas ligas e que o molibdato somente na liga 7050. O efeito inibidor do tungstato se revela em meio desaerado e é comparativamente menor daquele observado com os outros oxi-ânions. As análises quantitativas de superfície das ligas após os ensaios de imersão indicam que ainda na presença de inibidor, se pites foram nucleados, eles crescem.

Martensite decomposition in Cu-Al-Mn-Ag alloys

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Structural, morphological and magnetic characterization of electrodeposited Co-Fe-W alloys

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Corrosion properties of Fe-Cr-Nb-B amorphous alloys and coatings

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Corrosion-fatigue life of commercially pure titanium and Ti-6Al-4V alloys in different storage environments

Statement of problem. Removable partial dentures are affected by fatigue because of the cyclic mechanism of the masticatory system ansi frequent insertion and removal. Titanium and its alloys have been used in the manufacture of denture frameworks; however, preventive agents with fluorides are thought to attack titanium alloy surfaces.Purpose. This study evaluated, compared, analyzed the corrosion-fatigue life of commercially pure titanium and Ti-6Al-4V alloy in different storage environments.Material and methods. For each metal, 33 dumbbell rods, 2.3 mm in diameter at the central segment, were cast in the Rematitan system. Corrosion-fatigue strength test was carried out through a universal testing machine with a load 30% lon er than the 0.2% offset yield strength and a combined influence of different: environments: in air at room temperature, with synthetic saliva, and with fluoride synthetic saliva. After failure, the number of cycles were recorded, and fracture surfaces were examined with on SEM.Results. ANOVA and Tukey's multiple comparison rest indicated that Ti-6Al-4V alloy achieved 21,269 cycles (SD = 8,355) against 19,157 cycles (SD = 3,624) for the commercially purr Ti. There were no significant differences between either metal in the corrosion-fatigue life for dry specimens, but when the solutions were present, the fatigue life was significantly reduced, probably because of the product-ion of corrosion pits caused by superficial reactions.

Adsorption/desorption of arsenic by tropical peat: influence of organic matter, iron and aluminium

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Estudo da usinagem por torneamento de ligas de alumínio

The non-ferrous materials have got so many mechanical, physical and chemical advantageous properties so that is provided to them consolidated position in industry. In this context, aluminium alloys have been seen a lot on many applications of engineering areas – specially on automotive, aeronautical and aerospace due to their main properties such as low density, high corrosion resistance, favorable structure weight / material resistance relation, among others characteristics that are mencioned through this study. This study aims to analyze the aluminium alloys behavior on a general context when they are used on turning process, taking for examples the 6262 and 7050 aluminium alloys. In this way, the analysis studies the datas obtained during the turning tests realized on 3 steps each one; those datas are concerning the medium and total rugosities – obtained with the assistance of a portable Surface Roughness Finish Tester, as well as the chips obtained during the tests - visual analysis, and the cutting tools wear – with the assistance of an optical microscope, under different conditions of application of cutting fluids (dry machining, application of coolant in abundance and MQL – Minimum Quantity of Lubricant). The results concerning this study show detailed information about influence of cutting fluids on the machining by turning of the aluminium alloys related on this work and also about aluminium alloys in general when they are used on turning processes with different conditions from one another. By this way, it was evident the MQL technique is the best one for the 6262 alloy. However, for 7050 alloy, it was evident that the dry machining is responsible for the best results

Cinética de degradação do sistema resina epóxi/fibra de carbono

With the increasing demand for electricity, the retraining of transmission lines is necessary despite environmental restrictions and crossings in densely populated areas to build new transmission and distribution lines. Solution is reuse the existent cables, replacing the old conductor cables for new cables with higher capacity power transmission, and control of sag installed. The increasing demand for electrical power has increased the electric current on the wires and therefore, it must bear out temperatures of 150°C or more, without the risk of the increasing sag beyond the established limits. In the case of long crossings or densely populated areas, sag is due to high weight of the cable on clearance. The cable type determines the weight, sag, height and the towers dimensions, which are the items that most influence the investment of the transmission line. Hence, to reduce both cost of investment and maintenance of the line, the use of a lighter cable can reduce both number and the height of the towers, with financial return on short and long term. Therefore, in order to increase the amount of transmitted energy and reduce the number of built towers and sag, is recommended in the current work substitute the current core material (steel or aluminium) for alternatives alloys or new materials, in this case a composite, which has low density, elevated stiffness (elasticity module), thus apply the pultruded carbon fiber with epoxy resin as matrix systems and perform the study of the kinetics of degradation by thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA) and differential scanning calorimetry (DSC), according to their respective standards

Caracterização da liga do sistema binário Ti-15Mo para aplicações biomedicas

As they have excellent mechanical properties, corrosion resistance and biocompatibility, much research has been conducted with respect to biomedical applications of titanium alloys. This work aims to study the experimental system binary alloy Ti-15Mo, in the raw state of fusion and heat treatment after homogenization, solubilization and calcination (simulating conditions employed for nanotube growth) targeting biomedical applications. Samples were obtained by casting the components in an electric arc furnace with inert atmosphere of argon. After obtaining the alloy, it was heat treated at three different heat treatments, namely homogenizing, calcining and simulation solubilization. The phases present were analyzed by X-ray diffraction, optical microscopy and microhardness testing

Estudo da influência do agente nucleante )ALTi5%B1%) na microestrutura de chapas AA8011 obtidas por lingotamento contínuo

The aluminum includes several properties with excellent relation between weight and mechanical resistance. With technological advances, increasingly demand the development of new alloys and other production processes in order to reduce the cost of production and insert these new alloys in broader applications. The process of continuous caster (TRC promoted the unite of the aluminum smelting process with the first stage of rolling, making it most economical through the merger these two phases besides transform the continuous casting process. The AA8xxx series is one of the most versatile aluminum alloys and the most often used in continuous caster process provided a great potential application in the market. In order to further, optimize the process it is necessary to increase awareness of the aluminum solidification phenomena associated with the addition of grain refiner, and control of some aluminum production parameters in the process (production rate, metal temperature, etc.). In this study, AA8011 alloy samples were taken in the raw state obtained by the continuous casting process. The samples were laminated to a thickness of 7mm during the process itself and analyzed at three points along its width by microstructural analysis throughout its thickness, the variation rate of addition of the grain refiner in order to assess the influence of this addition with crystallographic formation and some formation of intermetallic precipitates during the solidification. Through this work, it was possible to improve the knowledge related to the addition of refiner with the monitoring of these production processes

Análise da pulsação térmica do processo TIG na soldagem da liga AA6063T6

Pós-graduação em Engenharia Mecânica - FEB

Streptococcus mutans adhesion and releasing of metallic ions in dental alloys

AIM: To evaluate the adherence of Streptococcus mutans to the surface of the amalgam and copper/aluminum alloy samples and also evaluate the release of metallic ions. METHODS: The prepared medium was changed every 72 h and analyzed by atomic absorption spectrophotometer. Samples were removed from the prepared medium at 15, 30, 48 and 60 days. RESULTS: The result shows that ions released were statistically different among all groups, and so were both biofilm and pits formation and the corrosion induced by the S. mutans in both types of samples. SEM observation of the samples immersed in the prepared medium with S. mutans showed adherence of microorganisms on the whole surface, in all groups. CONCLUSIONS: The S. mutans adhere to both amalgam and copper/aluminum alloy causing corrosion of those restorations. S. mutans produced a greater ions release in Cu/Al alloy; in amalgam, the ions release was not influenced by exposure to S. mutans.

Nonlinear angle control of a sectioned airfoil by using shape memory alloys

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)