Effects of adding Bauxite and Oyster shell on the properties of metakaolin-based geopolymer cements

This work has investigated the possibility of use bauxite and oyster shell as mineral admixtures,to enhance the properties of metakaolin-based geopolymer cements. Raw materials(metakaolin, bauxite and oyster shell) were characterized in the first time by determination of their chemical and mineralogical compositions, particles size distribution, specific surface area, thermal analysis and then in the second time use to synthesized geopolymers. Different methods of analysis such as Fourier Transform Infrared spectroscopy(FTIR), X-Ray Diffractometry (XRD), and Scanning Electron Microscopy (SEM) were used to assess the variation of setting time, linear shrinkage and 28 days compressive strength of geopolymer pastes. The results of these analysis has showed that bauxite and oyster shells are source of Al2O3 and CaO respectively, and also contain crystalline phases. The geopolymers obtained by mixing metakaolin and bauxite have their setting time between 235 and 420min and their compressive strength between 40 and 57MPa ; for those obtained by mixing metakaolin and oyster shell the setting time is between 330 and 485min and compressive strength between 40 and 58MPa . The addition of a moderate amount (20% by mass) of bauxite or oyster shell led to improve the compressive strength of a metakaolin-based geopolymer of 43% (metakaolin-bauxite-based geopolymers) and 45% (metakaolin-oyster shell-based geopolymers) and decrease the linear shrinkage. More than 20% mineral additive has a deleterious effect on compressive strength and increase the setting time. Keywords: Metakaolin ; Bauxite ; Oyster shell ; synthesis ; Optimization; Geopolymer cements.

DEVELOPMENT OF POROUS CONCRETE GEOPOLYMER USING HYDROGEN PEROXIDE AS BLOWING AGENT.

Metakaolin and volcanic ashes respectively called MK and ZG were used as aluminosilicate raw materials for the synthesis of porous geopolymers. The hydrogen peroxide was used as a blowing agent. The geopolymer prepared were characterized by Spectroscopy Fourier Transform Infrared (SFTI), X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and the determination of some physical properties such as bulk density, total porosity, volume shrinkage, compressive strength and thermal conductivity was also carried out. The presence of pores in the geopolymer obtained is function of the percentage of hydrogen peroxide added, causing the concomitantly decrease in compressive strength, apparent density and thermal conductivity. The use of hydrogen peroxide as a blowing agent gave some thermal insulation properties to these geopolymers which could be close to the properties of some commercial insulation materials.

The Intersection of Economics and Politics in a Small OPEC Country: the Case of Ecuador, 1990 - March 2014

Today, crude oil remains a vital resource all around the world. This non-renewable resource powers countries worldwide. Besides serving as an energy source, crude oil is also the most important component for different world economies, especially in developing countries. Ecuador, a small member of the OPEC oil cartel, presents a case where its economy is oil dependent. A great percentage of the country¿s GDP and government¿s budget comes from oil revenues. Ecuador has always been a primary exporter of raw materials. In the last centuries, the country experienced three important economic booms: cacao, bananas, and, ultimately, crude oil. In this sense, the country has not been able to fully industrialize and begin to export manufactured goods, i.e., Ecuador suffers from the Dutch disease. The latter has deterred Ecuador from achieving broad-based economic development. Given crude oil¿s importance for the Ecuadorian economy, the government has always tried to influence the oil industry in search of profits and benefits. Therefore, this thesis, explores the question: how and to what extent have political interventions affected the oil industry in Ecuador from 1990 until March 2014? In general, this thesis establishes an economic history context during the last twenty-four years, attempting to research how political interventions have shaped Ecuador¿s oil industry and economy. In the analysis, it covers a period where political instability prevailed, until Rafael Correa became president. The thesis examines Ecuador¿s participation in OPEC, trying to find explanations as to why the country voluntarily left the organization in 1992, only to rejoin in 2007 when Correa rose to power. During the ¿Revolución Ciudadana¿ period, the thesis researches reforms to the Law of Hydrocarbons, variations in the relations with other nations, the controversy surrounding the Yasuní-ITT oil block, and the ¿Refinería del Pacífico¿ construction. The thesis is an Industrial Organization detailed case study that analyzes, updates, and evaluates the intersection of economics and politics in Ecuador¿s crude oil industry during the last 24 years. In this sense I have consulted past theses, newspaper articles, books, and other published data about the petroleum industry, both from a global and Ecuadorian perspective. In addition to published sources, I was able to interview sociologists, public figures, history and economics academics, and other experts, accessing unique unpublished data about Ecuador¿s oil industry. I made an effort to collect information that shows the private and public side of the industry, i.e., from government-related and independent sources. I attempted to remain as objective as possible to make conclusions about the appropriate Industrial Organization policy for Ecuador¿s oil industry, addressing the issue from an economic, social, political, and environmental point of view. I found how Ecuador¿s political instability caused public policy to fail, molding the conduct and market structure of the crude oil industry. Throughout history, developed nations have benefited from low oil prices, but things shifted since oil prices began to rise, which is more beneficial for the developing nations that actually possess and produce the raw material. Nevertheless, Ecuador, a victim of the Dutch disease due to its heavy reliance on crude oil as a primary product, has not achieved broad-based development.

Batch scheduling in process industries: an application of resource-constrained project scheduling

The paper deals with batch scheduling problems in process industries where final products arise from several successive chemical or physical transformations of raw materials using multi–purpose equipment. In batch production mode, the total requirements of intermediate and final products are partitioned into batches. The production start of a batch at a given level requires the availability of all input products. We consider the problem of scheduling the production of given batches such that the makespan is minimized. Constraints like minimum and maximum time lags between successive production levels, sequence–dependent facility setup times, finite intermediate storages, production breaks, and time–varying manpower contribute to the complexity of this problem. We propose a new solution approach using models and methods of resource–constrained project scheduling, which (approximately) solves problems of industrial size within a reasonable amount of time.

Mobilities and Pottery Production Archaeological and Anthropological Perspectives

Our workshop aims at a deeper understanding of various itineraries of pottery and dif-ferent forms of human mobilities in which pottery is relevant, bringing together archae-ological and anthropological perspectives. For thousands of years, pottery has been an important part of many societies’ material culture and therefore a major research topic in both disciplines. In past and present societies the material existence of ceramic vessels is informed by various movements across time and space but also by periods of stasis: from the mo-ment of their production until their exclusion from daily practices, either disposed as waste, excluded as funerary objects or stored as collectibles. In their seemingly endless material durability, ceramic vessels might outlive their human producers, distributors or consumers and travel farther and longer. Still they are embedded in the regimes of human mobility, ranging from daily subsistence-based mobility to long-term migrations. In such processes, pottery shifts between spatial, temporal, social, economic and cultural contexts. Thereby ceramic vessels are appropriated and integrated in new contexts of action and meaning, sometimes leading to material transformations. This workshop takes place in the context of our archaeological research project „Mobili-ties, Entanglements and Transformations in Neolithic Societies on the Swiss Plateau (3900-3500 BC)“ to which our PhDs are connected. We address the above outlined topic by analysing the production of pottery. Based on dendrochronologically dated settle-ments between 3900 and 3500 BC, two regional pottery styles and their local variations are well known, Pfyn and Cortaillod. The vessels share the same habitus and were made of clays and temper deriving from the settlements’ surroundings. However, some vessels specific to other pottery styles are also present on the sites. They are characteristic for pottery styles known from more or less far off regions (Michelsberg, Munzingen or Néo-lithique Moyen Bourguignon). Some of them were travelling objects, as their non local raw materials show. Others seem to have been produced locally, pointing to long-term mobility and a change of residence from neighbouring social groups.

Itineraries of pottery: a mixed methods approach to mobility

Neolithic wetland sites in the Swiss Plateau provide an extraordinary database for the study of mobilities, entanglements and transformations in material culture. Based on dendrochronologically dated settlements between 3900 and 3500 BC, two regional pottery styles and their local variations are well known, Pfyn and Cortaillod. The vessels share the same habitus and were made of local raw materials. However, some vessels specific to other pottery styles are also present in the sites. By focusing on itineraries of vessels and shifts in pottery knowledge, their appropriation in different contexts and the resulting material entanglements, we want to approach the multiple regimes of mobility: At Lake Constance - known for Pfyn pottery - specific Michelsberg vessels like tulip beakers and lugged jars occur in small numbers. These travelling objects were produced with exogenous raw materials and transported to the sites from Southern Germany. At Concise (Lake Neuchâtel) besides the local Cortaillod pottery the whole repertoire of NMB pottery, characteristic for Eastern France, was also produced. Further cases from the same space-time frame point to other regimes of mobility. In our two PhD-projects we compare pottery practices - styles, techniques, raw materials - from over 20 key sites in the region. Based on Bourdieu’s reflexive anthropology, we apply different qualitative and quantitative archaeological and archaeometrical methods, thus striving for a deeper understanding of habitus and the transformative potential of moving people, objects and ideas on local and regional scales and related social contexts.

Pottery as an indication of mobilities?

Pottery is one of the most common and stylistically differentiated sources in prehistoric archaeology. This might be the reason why it served as a waste projection surface for archaeological notions about culture, identity, and mobility in the past. As we do not have access to emic categorisations of Neolithic societies we focus on contexts of practice in which pottery was incorporated. It is the moment of production, which left some of the clearest traces on the vessels. Different ways of using raw materials, specific techniques, and characteristic pottery styles can be observed. We understand them as a result of habitus, as socially shared internalized schemes, patterns and habits in pottery production. Taking this as a staring point, two main pottery groups can be differed on the Swiss Plateau between 3900 and 3500 BC: the Mediterranean influenced Cortaillod pottery in Western Switzerland and the Danubian influenced Pfyn pottery in North-Eastern Switzerland. These pottery styles were not only entangled to some degree. Furthermore, in some settlements vessels made in “foreign” styles - Michelsberg, Munzingen, Néolithique Moyen Bourguignon - are present too. Some of them were travelling objects, as their nonlocal raw materials show. Others were locally made, indicating long-term mobility of their producers. To analyse these phenomena of mobilites and entanglements in our PhDs we plan to apply different archaeological and archaeometrical methods, thus striving for a deeper understanding of the transformative potential of moving people, objects and ideas in Neolithic societies on the Swiss Plateau.

Rendimiento de aceite de colza cultivada bajo riego : Mendoza (Argentina)

En el 2010 será obligatorio cortar en un 5% los combustibles de origen fósil (gasoil y naftas) con biocombustibles (biodiesel y bioetanol). La principal materia prima para elaborar biodiesel son los aceites vegetales. Cada región tiene ventajas comparativas para producir alguna oleaginosa. En Cuyo, una de las limitantes para la producción agrícola es la disponibilidad de agua, fundamentalmente en verano, cuando demandan este recurso los cultivos tradicionales de la región. En este contexto, se estudió el rendimiento del cultivo de colza, oleaginosa de ciclo invernal, en el oasis Norte de la región de Cuyo, con el objetivo de valorar su aptitud para proveer aceite. Se probaron tres cultivares en tres fechas de siembra (abril, mayo y junio), durante los ciclos 2005 y 2006. Las siembras de abril y mayo rindieron más que la de junio y estuvieron asociadas a mayor duración de ciclo del cultivo. No hubo diferencias de porcentaje de aceite de las semillas entre tratamientos, que osciló entre el 48 y 49%. El rendimiento de aceite por ha superó los 1500 kg en las siembras de abril y mayo y estuvo algo por debajo en las de junio.

Tecnología cerámica : estudios experimentales sobre la cerámica del sitio arqueológico San Ignacio (Noroeste de Mendoza)

El propósito de este trabajo es explorar la disponibilidad de materias primas que pudieron ser utilizadas en el proceso de manufactura de la cerámica gris del sitio arqueológico San Ignacio, en el Valle de Potrerillos, ubicado al Norte de la provincia de Mendoza (640 dC). Se pretende, además, reproducir las técnicas de producción y cocción cerámica, a fin de obtener un producto de características análogas a las de la colección estudiada. La metodología utilizada presentó las siguientes etapas: recolección de materiales arcillosos; caracterización de las propiedades físicas en estado crudo; análisis químicos; desarrollo experimental de cocción y ensayos post-cocción de los mismos. Los productos obtenidos muestran una buena estructura y sinterización, aunque no se logró una atmósfera completamente reductora con este tipo de combustible.

Extracción y análisis de pectinas a partir de arándano (Vaccinium corymbosum L.) cv. O'Neall

El arándano (Vacinium corymbosum) es un fruto muy apreciado debido a sus propiedades nutricionales, bajo valor energético y alto contenido de antioxidantes. Su remanente no exportable es destinado a la industria local para la elaboración de zumos, siendo una fuente potencial de pectinas. El presente estudio tuvo como objetivos: medir la influencia del pH 2,0; 2,75 y 3,36 natural y el tiempo de calentamiento entre 60 y 90 minutos a 90°C, sobre la extracción de pectina de arándano por medio de una hidrólisis ácida; evaluar la calidad de la pectina mediante el grado de esterificación; elaborar y evaluar desde el aspecto sensorial las gelatinas provenientes de pectinas extraídas a 35°, 50° y 65°Brix. El mayor rendimiento de pectina, 0,93% (p/p), se obtuvo a pH 2,0 y en 90 minutos. El grado de esterificación no superó el 50% en la mayoría de los tratamientos, clasificando las pectinas como de "bajo metoxilo". Los geles elaborados a 50°Brix tuvieron un mayor nivel de aceptabilidad por los panelistas, clasificándolos como "me gusta levemente". En relación con el atributo sensorial color de los geles elaborados, fue evaluado por los panelistas como "pálido", dado el leve color de las pectinas utilizadas.

Producción de agrocombustibles : ¿Territorios objetivos o territorios posibles?

Desde de la colonización los territorios de América Latina y de Africa fueron puestos al servicio de las metrópolis. La globalización del capitalismo financiero sigue el mismo patrón, deslocalizando la producción de agrocombustibles y concentrando el capital en las transnacionales agrarias. Recorremos cinco mitos que buscan legitimar esta producción y abordamos dos estudios de caso (Guatemala y Senegal) que ponen en evidencia la utilización de los territorios objetivos perjudicando las poblaciones indígenas y fundamentalmente las mujeres. El artículo finaliza con una reflexión sobre el pasaje de los territorios objetivos a Territorios Posibles, de la mano de la Inteligencia Territorial

Agroindústria familiar : Um mecanismo de estímulo à especialização das atividades na propriedade rural?

Family agroindustry has been considered by several authors as an important reproduction alternative for family-based agriculture. However, this production process, which includes primary (production of raw-materials) and secondary (industrialization of production) activities, is generating a general concern. Can agroindustry, by promoting non-agricultural income for farmers, cause a reduction or, in extreme cases, an extinction of agricultural production in farm estates developing industrialization activities for selling in markets (family agroindustries)? In this sense, the purpose of this research was to analyse whether agroindustry can promote specialisation in family-based farm estates, or whether it is a form of economic diversification, being merely an activity similar to those developed in farm estates before the emergence of this process. The empirical study was conducted in 45 family agroindustries of sugarcane derivatives located in the Northeast of Rio Grande do Sul (Brazil).

Cadenas de valores en el sector agroindustrial en la provincia de San Luis : Industrialzación

En la Provincia de San Luis existen 400.000 hectáreas activas de superficie cultivable con un potencial de 700.000 hectáreas. Los cultivos preponderantes son las oleaginosas, principalmente soja, maíz y girasol. En los últimos años, la provincia se expandió tanto en agricultura como en ganadería: en 2010 el sector ganadería creció un 7; por su parte, la agricultura se encuentra en una transición importante gracias a que los productores han incorporado tecnología que permite el crecimiento en una provincia con un clima muy diferente al de la pampa húmeda. La conjunción de esta circunstancia y de la realización de obras públicas provoca un sinergismo que ha llevado a la expansión del sector productivo. En la cadena de productos agroindustriales, uno de los eslabones principales para agregar valor en origen es la industrialización, con vistas a la posterior comercialización tanto del producto obtenido como de los subproductos. En San Luis se dan las dos situaciones: la venta de granos sin procesar y la de productos y subproductos obtenidos a partir de los granos y las oleaginosas. Como consecuencia de los beneficios impositivos con los cuales cuenta la provincia, que se suman a la ventaja de su localización en el corredor bioceánico, la radicación industrial fue más importante que en otras provincias. Del total de este sector en San Luis, las industrias alimentarías representan el 8 (29 empresas), entre las cuales se encuentran empresas que utilizan como materia prima la soja y el maíz. El objetivo del presente trabajo es presentar datos de mercado de la soja y del maíz a nivel mundial, nacional y provincial y estudiar el eslabón de industrialización en la cadena de valor de dichas oleaginosas en la Provincia de San Luis. Para ello, se realizaron entrevistas a informantes clave del sector industrial, búsqueda bibliográfica, lectura de papers, asistencia a exposiciones de la agroindustria, validación de información obtenida a partir de páginas web y recopilación de datos del Ministerio de Economía de la Nación y de la Dirección Provincial de Estadística y Censos

Agroindústria familiar : Um mecanismo de estímulo à especialização das atividades na propriedade rural?

Family agroindustry has been considered by several authors as an important reproduction alternative for family-based agriculture. However, this production process, which includes primary (production of raw-materials) and secondary (industrialization of production) activities, is generating a general concern. Can agroindustry, by promoting non-agricultural income for farmers, cause a reduction or, in extreme cases, an extinction of agricultural production in farm estates developing industrialization activities for selling in markets (family agroindustries)? In this sense, the purpose of this research was to analyse whether agroindustry can promote specialisation in family-based farm estates, or whether it is a form of economic diversification, being merely an activity similar to those developed in farm estates before the emergence of this process. The empirical study was conducted in 45 family agroindustries of sugarcane derivatives located in the Northeast of Rio Grande do Sul (Brazil).

Cadenas de valores en el sector agroindustrial en la provincia de San Luis : Industrialzación

En la Provincia de San Luis existen 400.000 hectáreas activas de superficie cultivable con un potencial de 700.000 hectáreas. Los cultivos preponderantes son las oleaginosas, principalmente soja, maíz y girasol. En los últimos años, la provincia se expandió tanto en agricultura como en ganadería: en 2010 el sector ganadería creció un 7; por su parte, la agricultura se encuentra en una transición importante gracias a que los productores han incorporado tecnología que permite el crecimiento en una provincia con un clima muy diferente al de la pampa húmeda. La conjunción de esta circunstancia y de la realización de obras públicas provoca un sinergismo que ha llevado a la expansión del sector productivo. En la cadena de productos agroindustriales, uno de los eslabones principales para agregar valor en origen es la industrialización, con vistas a la posterior comercialización tanto del producto obtenido como de los subproductos. En San Luis se dan las dos situaciones: la venta de granos sin procesar y la de productos y subproductos obtenidos a partir de los granos y las oleaginosas. Como consecuencia de los beneficios impositivos con los cuales cuenta la provincia, que se suman a la ventaja de su localización en el corredor bioceánico, la radicación industrial fue más importante que en otras provincias. Del total de este sector en San Luis, las industrias alimentarías representan el 8 (29 empresas), entre las cuales se encuentran empresas que utilizan como materia prima la soja y el maíz. El objetivo del presente trabajo es presentar datos de mercado de la soja y del maíz a nivel mundial, nacional y provincial y estudiar el eslabón de industrialización en la cadena de valor de dichas oleaginosas en la Provincia de San Luis. Para ello, se realizaron entrevistas a informantes clave del sector industrial, búsqueda bibliográfica, lectura de papers, asistencia a exposiciones de la agroindustria, validación de información obtenida a partir de páginas web y recopilación de datos del Ministerio de Economía de la Nación y de la Dirección Provincial de Estadística y Censos