Aplicación integral en construcción de materiales eco-eficientes con incorporación de cenizas de biomasa

El empleo de biomasa como combustible para la generación de bio-energía va en aumento en la actualidad, debido a su impacto medioambiental nulo en cuanto a las emisiones de CO2. Por lo tanto la generación de cenizas de biomasa, residuo de la producción de esta energía, constituye un problema medioambiental con un claro impacto social y económico. Este tipo de ceniza tiene contenidos en óxidos que la hacen atractiva para su empleo como sustituto parcial del cemento Portland, lo cual proporciona una salida eco-eficiente a este residuo, reduciendo al mismo tiempo la emisión de gases de efecto invernadero asociada a la fabricación del cemento. Esta investigación se centra en el desarrollo de nuevos e innovadores materiales base-cemento eco-eficientes que incorporan ceniza de biomasa para su aplicación integral en construcción. Para ello, se emplea una ceniza de biomasa (CB) procedente de un combustor de lecho fluidizado, cuya biomasa de combustión es principalmente restos de corteza de eucalipto, suministrada por el grupo ENCE-Navia (Asturias). El trabajo desarrollado en la presente tesis doctoral, tiene como primera fase la caracterización de esta ceniza y el análisis de viabilidad de su valorización en materiales base-cemento. Dentro de este análisis, se propone la activación de la ceniza CB mediante tratamiento hidrotermal (TH) en diferentes condiciones de medio activante, temperatura y tiempo de proceso, con el objetivo de favorecer la formación de fases hidratadas que potencien la valorización de la ceniza en el campo de los materiales de construcción. Como fase hidratada de interés se obtiene la fase tobermorita (Ca2.25(Si3O7.5(OH)1.5)(H2O)), precursora del gel C-S-H, responsable del desarrollo de resistencias mecánicas en los materiales base-cemento. El proceso de TH se optimiza para la síntesis más eficiente de esta fase. El estudio posterior de las propiedades mecánicas y micro-estructurales de pastas de cemento eco-eficientes que incorporan la ceniza CB y la ceniza tratada hidrotermalmente, CB-TH, confirma una mayor viabilidad de incorporación de la ceniza CB como sustituto parcial del cemento Portland. Como siguiente paso en el desarrollo de estos innovadores materiales base-cemento eco-eficientes se amplía el estudio multi-escalar de los materiales que incorporan CB mediante diferentes ensayos físico-mecánicos y de durabilidad. Los resultados indican que la presencia de la ceniza de biomasa no tiene efectos negativos sobre las propiedades físicas de los morteros eco-eficientes estudiados. Sin embargo, la adición de CB proporciona una mejor durabilidad del material al producir modificaciones de la microestructura que dificultan el transporte de agentes agresivos. Por otro lado, los morteros con un 10 y 20% de sustitución parcial de cemento por la ceniza de biomasa CB (CB-10 y CB-20) presentan una resistencia a compresión de 53.3 y 50.5 MPa a 28 días de curado, respectivamente. Estos morteros son comparables con un cemento Portland tradicional tipo CEM I de clase de resistencia 42.5 R. Por último, y con el fin de proporcionar la apertura de estos nuevos cementos eco-eficientes al mercado en el campo de los materiales de construcción, se estudian propiedades concretas relacionadas con diferentes tipos de aplicaciones. Concretamente se estudian en detalle las propiedades relativas a la aplicación en baldosas de mortero y los resultados indican unas prestaciones del material eco-eficiente con incorporación de CB similares o mejoradas con respecto al cemento Portland. Se analiza también la viabilidad de aplicación estructural de los cementos eco-eficientes desarrollados mediante el estudio de la adherencia al acero, que resulta similar a la del material de referencia. En cuanto a los resultados de extracción y caracterización de la fase acuosa de los poros, en todas las matrices eco-eficientes se obtiene un pH que garantiza la pasivación de la armadura. Sin embargo, el alto contenido en cloruros de dicha fase acuosa sugiere la conveniencia de realizar un análisis más detallado para la aplicación de los nuevos materiales eco-eficientes en hormigón armado. Se comprueba que todas las matrices que incorporan CB en porcentajes entre un 10 y un 90%, se pueden considerar adecuadas como nuevos materiales de construcción más eco-eficientes en aplicaciones con distintos niveles de exigencias mecánicas y sin problemas ambientales asociados con procesos de lixiviación. Con el presente trabajo de investigación se completan los objetivos iniciales de la tesis, con la obtención de nuevos e innovadores materiales base-cemento eco-eficientes que incorporan cenizas de biomasa (CB) con aplicación integral en el campo de la construcción. ABSTRACT The use of biomass as a fuel for the generation of bio-energy is increasing nowadays, due to its zero environmental impact in terms of CO2 emissions. Therefore the generation of biomass ash, a by-product of this energy, is an environmental problem with a clear social and economic impact. This type of ash contains oxides that make it attractive to be used as a partial replacement of Portland cement, providing an eco-efficient solution to this residue, while reducing the emission of greenhouse gases associated with the production of cement. The present research is focused on the development of new and innovative eco-efficient cement-based materials that incorporate biomass ash for their comprehensive application in construction. For this purpose a biomass ash (CB) is used from a fluidized bed forest combustor mainly fed with the bark of eucalyptus trees, provided by the ENCE-Navia (Asturias) group. The work includes in the first stage the characterization of the raw materials and the analysis of viability of their valorization in cement-based materials. Within this analysis, the activation of the ash is proposed by hydrothermal treatment (HT) in different conditions of activation medium, temperature and process duration, aiming an enhanced formation of hydrated phases to improve the ash valorization in the construction materials field. As an interesting hydrated phase, the tobermorite (Ca2.25(Si3O7.5(OH)1.5)(H2O)) is obtained from the process. This phase is considered as a precursor of the gel C-S-H, responsible for the development of mechanical strength in cement-based materials. HT process is optimized for the most efficient synthesis of tobermorite. The analysis of mechanical and microstructural properties of eco-efficient cement pastes incorporating CB ash and hydrothermally treated ash, CB-TH, confirms an improved viability of incorporation of CB ash as a partial replacement for Portland cement in the case. As a next step in the development of these innovative eco-efficient cement-based materials, a multiscale study of the materials that incorporate CB by different physical-mechanical and durability tests is carried out. The results indicate that the presence of biomass ash does not give rise to negative effects on the physical properties of the eco-efficient mortars analyzed. Nevertheless, the addition of CB produces a better durability performance due to microstructural modifications that hinder the transport of aggressive agents through the material. Moreover, mortars with a 10% and 20% of partial substitution of cement by the CB biomass ash (CB-10 and CB-20) show a compressive resistance of 53.3 and 50.5 MPa at 28 days of curing, respectively. These mortars are comparable to an ordinary Portland cement type CEM I with a resistance class of 42.5R. Finally, and in order to provide the opening of these new eco-efficient cement to the market in the field of construction materials, certain properties specifically related to different types of applications are studied. Among these, the properties concerning the application in mortar tiles are analyzed and the results indicate a similar, or even better performance of the eco-efficient mortar that incorporates CB, with respect to Portland cement. The viability of structural application of the developed eco-efficient cement is also performed considering the study of the adhesion to steel, with results similar to those of the reference material. Regarding the results of extraction and analysis of the aqueous phase of the pores, a pH value guaranteeing reinforcement passivation is obtained for all the eco-efficient matrices. However, high chloride content is obtained suggesting the suitability of a more detailed study to evaluate the application of these new eco-efficient materials in reinforced concrete. It is established that all the matrices incorporating CB in percentages between 10 and 90% may be considered adequate as new more eco-efficient construction materials in applications with different levels of mechanical demand and without environmental problems associated to leaching processes. In this research the initial objectives of the thesis are fulfilled by obtaining new and innovative eco-efficient cement-based materials that incorporate biomass ashes (CB) with comprehensive application in the construction field.

Dynamic modeling of gene expression data

We describe the time evolution of gene expression levels by using a time translational matrix to predict future expression levels of genes based on their expression levels at some initial time. We deduce the time translational matrix for previously published DNA microarray gene expression data sets by modeling them within a linear framework by using the characteristic modes obtained by singular value decomposition. The resulting time translation matrix provides a measure of the relationships among the modes and governs their time evolution. We show that a truncated matrix linking just a few modes is a good approximation of the full time translation matrix. This finding suggests that the number of essential connections among the genes is small.

Profiling in sport using momentum and perturbations

Examining a team’s performance from a physical point of view their momentum might indicate unexpected turning points in defeat or success. Physicists describe this value as to require some effort to be started, but also that it is relatively easy to keep it going once a sufficient level is reached (Reed and Hughes, 2006). Unlike football, rugby, handball and many more sports, a regular volleyball match is not limited by time but by points that need to be gathered. Every minute more than one point is won by either one team or the other. That means a series of successive points enlarges the gap between the teams making it more and more difficult to catch up with the leading one. This concept of gathering momentum, or the reverse in a performance, can give the coaches, athletes and sports scientists further insights into winning and losing performances. Momentum investigations also contain dependencies between performances or questions if future performances are reliant upon past streaks. Squash and volleyball share the characteristic of being played up to a certain amount of points. Squash was examined according to the momentum of players by Hughes et al. (2006). The initial aim was to expand normative profiles of elite squash players using momentum graphs of winners and errors to explore ‘turning points’ in a performance. Dynamic systems theory has enabled the definition of perturbations in sports exhibiting rhythms (Hughes et al., 2000; McGarry et al., 2002; Murray et al., 2008), and how players and teams cause these disruptions of rhythm can inform on the way they play, these techniques also contribute to profiling methods. Together with the analysis of one’s own performance it is essential to have an understanding of your oppositions’ tactical strengths and weaknesses. By modelling the oppositions’ performance it is possible to predict certain outcomes and patterns, and therefore intervene or change tactics before the critical incident occurs. The modelling of competitive sport is an informative analytic technique as it directs the attention of the modeller to the critical aspects of data that delineate successful performance (McGarry & Franks, 1996). Using tactical performance profiles to pull out and visualise these critical aspects of performance, players can build justified and sophisticated tactical plans. The area is discussed and reviewed, critically appraising the research completed in this element of Performance Analysis.

Primary school teacher’s noticing of students’ mathematical thinking in problem solving

Professional noticing of students’ mathematical thinking in problem solving involves the identification of noteworthy mathematical ideas of students’ mathematical thinking and its interpretation to make decisions in the teaching of mathematics. The goal of this study is to begin to characterize pre-service primary school teachers’ noticing of students’ mathematical thinking when students solve tasks that involve proportional and non-proportional reasoning. From the analysis of how pre-service primary school teachers notice students’ mathematical thinking, we have identified an initial framework with four levels of development. This framework indicates a possible trajectory in the development of primary teachers’ professional noticing.

SOA-Based Model for Value-Added ITS Services Delivery

Integration is currently a key factor in intelligent transportation systems (ITS), especially because of the ever increasing service demands originating from the ITS industry and ITS users. The current ITS landscape is made up of multiple technologies that are tightly coupled, and its interoperability is extremely low, which limits ITS services generation. Given this fact, novel information technologies (IT) based on the service-oriented architecture (SOA) paradigm have begun to introduce new ways to address this problem. The SOA paradigm allows the construction of loosely coupled distributed systems that can help to integrate the heterogeneous systems that are part of ITS. In this paper, we focus on developing an SOA-based model for integrating information technologies (IT) into ITS to achieve ITS service delivery. To develop our model, the ITS technologies and services involved were identified, catalogued, and decoupled. In doing so, we applied our SOA-based model to integrate all of the ITS technologies and services, ranging from the lowest-level technical components, such as roadside unit as a service (RS S), to the most abstract ITS services that will be offered to ITS users (value-added services). To validate our model, a functionality case study that included all of the components of our model was designed.

Ukraine on the financial front – the problem of Ukraine’s foreign public debt. OSW COMMENTARY NUMBER 178|05.08.2015

One of the key challenges that Ukraine is facing is the scale of its foreign debt (both public and private). As of 1st April it stood at US$ 126 billion, which is 109.8% of the country’s GDP. Approximately 45% of these financial obligations are short-term, meaning that they must be paid off within a year. Although the value of the debt has fallen by nearly US$ 10 billion since the end of 2014 (due to the private sector paying a part of the liabilities), the debt to GDP ratio has increased due to the recession and the depreciation of the hryvnia. The value of Ukraine’s foreign public debt is also on the rise (including state guarantees); since the beginning of 2015 it has risen from US$ 37.6 billion to US$ 43.6 billion. Ukraine does not currently have the resources to pay off its debt. In this situation a debt restructuring is necessary and this is one of the top priorities for the Ukrainian government as well as for the International Monetary Fund (IMF) and its assistance programme. Without this it will be much more difficult for Ukraine to overcome the economic crisis.

The truth lies within: the reconstructive value of inner livores in a homicide case.

Through the widespread use of postmortem computed tomography, inner livores of the lungs have become a frequently observed phenomenon in the field of forensic medicine. Yet their time-dependent development, notably in comparison with the widely studied external livores, remains poorly understood. We present a unique homicide case where the victim was discovered in supine position with correspondent external livores fixed exclusively on the rear side. Yet upon postmortem computed tomography, the victim presented pronounced inner livores within the depending dorsal areas of both lungs but also vertical sedimentation levels solely within the right lung, suggesting an initial right-hand side position and a postmortem re-positioning of the body. Interestingly, this was consistent with tangible hints of postmortem manipulation on-site. It is likely that this repositioning occurred sometime during the early postmortem interval (<6 h) as the external livores have completely rearranged to the final supine position. The presented case suggests different development patterns of inner and outer livores, highlighting the necessity for controlled studies that explore the formation and fixation processes of livor mortis in internal organs. A better understanding of these issues can prove useful in forensic examinations.

Optimum Design of Electromagnets for Magnetic Levitation of Transport Systems based on the Inverse Problem Solutions

Article is devoted to design of optimum electromagnets for magnetic levitation of transport systems. The method of electromagnets design based on the inverse problem solution of electrical equipment is offered. The method differs from known by introducing a stage of minimization the target functions providing the stated levitation force and magnetic induction in a gap, and also the mass of an electromagnet. Initial values of parameters are received, using approximate formulas of the theory of electric devices and electrical equipment. The example of realization of a method is given. The received results show its high efficiency at design. It is practical to use the offered method and the computer program realizing it as a part of system of the automated design of electric equipment for transport with a magnetic levitation.

Impact of a driver intervention program on DWI recidivism and problem drinking. Final report.

National Highway Traffic Safety Administration, Washington, D.C.

Education for efficiency; a discussion of certain phases of the problem of universal education, with special reference to academic ideals and methods,

Education for efficiency.--Industrial education with special reference to the high school.--Industrial education a phase of the problem of universal education.--The educative value of labor.--The culture aim in education.--Unity in education.--Agriculture in the high schools.--Agriculture in the elementary schools.--Agriculture in the normal schools.--The development of American agriculture - what it is and what it means.

A Sham Delight Has No Exchange Value: Henri Lefebvre and the evolution of Bernard Tschumi's early architectural theory

Thesis (Master's)--University of Washington, 2016-06

Inter-organisational networks, value creation and the process of technology integration in research and development

Traditional methods of R&D management are no longer sufficient for embracing innovations and leveraging complex new technologies to fully integrated positions in established systems. This paper presents the view that the technology integration process is a result of fundamental interactions embedded in inter-organisational activities. Emerging industries, high technology companies and knowledge intensive organisations owe a large part of their viability to complex networks of inter-organisational interactions and relationships. R&D organisations are the gatekeepers in the technology integration process with their initial sanction and motivation to develop technologies providing the first point of entry. Networks rely on the activities of stakeholders to provide the foundations of collaborative R&D activities, business-to-business marketing and strategic alliances. Such complex inter-organisational interactions and relationships influence value creation and organisational goals as stakeholders seek to gain investment opportunities. A theoretical model is developed here that contributes to our understanding of technology integration (adoption) as a dynamic process, which is simultaneously structured and enacted through the activities of stakeholders and organisations in complex inter-organisational networks of sanction and integration.

Impact of the Corporate Law Economic Reform Program Act 1999 on initial public offering prospectus earnings forecasts

Commencing 13 March 2000, the Corporate Law Economic Reform Program Act 1999 (Cth) introduced changes to the regulation of corporate fundraising in Australia. In particular, it effected a reduction in the litigation risk associated with initial public offering prospectus disclosure. We find that the change is associated with a reduction in forecast frequency and an increase in forecast value relevance, but not with forecast error or bias. These results confirm previous findings that changes in litigation risk affect the level but not the quality of disclosure. They also suggest that the reforms' objectives of reducing fundraising costs while improving investor protection, have been achieved.

Multiplicity results for second-order two-point boundary value problems with nonlinearities across several eigenvalues

We consider the boundary value problems for nonlinear second-order differential equations of the form u '' + a(t)f (u) = 0, 0 < t < 1, u(0) = u (1) = 0. We give conditions on the ratio f (s)/s at infinity and zero that guarantee the existence of solutions with prescribed nodal properties. Then we establish existence and multiplicity results for nodal solutions to the problem. The proofs of our main results are based upon bifurcation techniques. (c) 2004 Elsevier Ltd. All rights reserved.

Global behavior of positive solutions of nonlinear three-point boundary value problems

We investigate the structure of the positive solution set for nonlinear three-point boundary value problems of the form u('') + h(t) f(u) = 0, u(0) = 0, u(1) = lambdau(eta), where eta epsilon (0, 1) is given lambda epsilon (0, 1/n) is a parameter, f epsilon C ([0, infinity), [0, infinity)) satisfies f (s) > 0 for s > 0, and h epsilon C([0, 1], [0, infinity)) is not identically zero on any subinterval of [0, 1]. Our main results demonstrate the existence of continua of positive solutions of the above problem. (C) 2004 Elsevier Ltd. All rights reserved.