Islamismo e terrore: un grande Jihad contro il senso comune (essay)

What implies the conversion to fundamentalist Islam? What are the repercussions and implications of ‘political Islam’ in specific contexts? The relation between Islam, democracy and violence is often represented in a reductive or simplistic way. In order to contribute to a reasoned debate on these pressing questions, this essay covers some key dynamics stemming from long-term ethnographic observation regarding the conversion to neo Salafism among Arab Bedouin citizens in southern Israel, placing them in the context of contemporary developments of Islamic political thought. The ethnographic sensitivity, combined with the voices of some eminent Islamic intellectuals, allows to go beyond both the rhetoric of cultural complexity and the common-sense view that Islamic terrorism would be a kind of ‘anti imperialism of the losers’, arguments employed often to contest emerging neo-orientalist discourses. In this sense, the essay states the need to shed light on coordinates and interpretative categories that are not placed in an essentially different but in often unexpected ways.

Nucleophilic addition of Nitrones to Electron deficient acetylenes and related studies

Nitrones or azomethine-N-oxides are important precursors for the synthesis of several heterocyclic systems. They belong to the allyl anion type 1,3-dipoles and possess unique structural features which make them extraordinarily useful synthons. They behave as 1,3-dipoles in 1,3-dipolar cycloaddition reactions and as electrophiles in reactions with organometallic reagents. These are the two basic reactions given by nitrones. Nitrones also act as ‘spin traps’ in which they react with short-lived radicals to furnish stable nitroxide radicals which can be detected and identified by electron paramagnetic resonance (EPR) spectroscopy. Recently SmI2 catalysed reductive cross-coupling reactions of nitrones have gained significant interest in which the reactions are initiated by single electron transfer (SET) to nitrones. Apart from these reactions, nitrones are also known to participate in reactions which are initiated by the nucleophilic attack of nitrone-oxygen. In our group, we have also explored the nucleophilic character of nitrones through various reactions. The results obtained enabled us to develop a novel two-step one-pot strategy for quinolines and indoles - the heterocycles renowned for their pharmacological applications, from nitrones and electron deficient acetylenes. Using dibenzoylacetylene and phenylbenzoylacetylene as dipolarophiles, we could introduce a desired functional group at a predetermined position of the quinolines or indoles to be synthesised. In this context, the thesis entitled “NUCLEOPHILIC ADDITION OF NITRONES TO ELECTRON DEFICIENT ACETYLENES AND RELATED STUDIES” portrays our attempt to expand the scope of our x novel synthetic protocol using ester functionalised acetylenes: dimethyl acetylenedicarboxylate (DMAD) and methyl propiolate. The thesis is organised in to five chapters. The first chapter briefly describes the different classes of reactions that nitrone functionality can tolerate. The research problem is defined at the end of this chapter. The second chapter describes the synthesis of different nitrones used for the present study. The optimisation and expansion of scope of the novel strategy towards quinoline synthesis is discussed in the third chapter. The fourth chapter portrays the synthesis of indole-3-carboxylates using the novel strategy. In the fifth chapter, the reaction of N-(2,6-dimethylphenyl) and N-(2,4,6-trimethylphenyl)nitrones are discussed. Here we also discuss the mechanistic reinvestigation of Baldwin’s proposal in the isoxazoline-oxazoline rearrangement. The major outcome of the work is given at the end of the thesis. The structural formulae, schemes, tables and figures are numbered chapter-wise since each chapter of the thesis is organized as an independent unit. All new compounds (except two compounds reported in fourth chapter) are fully characterised on the basis of spectral and analytical data and single crystal X-ray analysis on representative examples. Relevant references are included at the end of individual chapters.

Les définitions dans les codes civils

"Omnis definitio in jure civili periculosa est". Le principe selon lequel toute définition est périlleuse constitue l’une des idées séculaires véhiculées par la tradition de droit civil. Malgré cela, le Code civil français et, plus récemment, le "Code civil du Québec" contiennent tous deux un nombre important de définitions légales. Abordées du point de vue du lexicographe, ces définitions soulèvent la question de savoir à quel point elles doivent être prises en considération dans les dictionnaires juridiques : en présence d’une définition légale, le lexicographe devrait-il simplement la paraphraser ou devrait-il plutôt chercher à rendre compte du sens tel qu’il est véhiculé dans le discours juridique? En étudiant les enjeux soulevés par cette question, le présent texte propose une démarche lexicographique qui relativise l’influence des définitions légales sur le contenu des dictionnaires de droit civil.

As variedades linguísticas do espanhol e os desafios ao seu ensino/aprendizagem

O Espanhol é, cada vez mais, uma língua de destaque no panorama mundial. Daí que surja a necessidade de garantir a qualidade e constante aprimoramento do ensino/aprendizagem desta língua. Um dos nossos propósitos, com o presente estudo, foi aprofundar e refletir sobre os conhecimentos dos alunos acerca da diversidade (intra)linguística do Espanhol, promovendo, deste modo, a sua valorização. Elaborámos, como ponto de partida, um enquadramento teórico que sustenta a investigação onde abordamos a dimensão atual do Espanhol e das suas variedades, bem como a questão dos estereótipos relacionada com o ensino das variedades (intra)linguísticas espanholas. De seguida, procedemos à implementação de um estudo de caso, tendo em conta o Espanhol como língua internacional e pluricêntrica, com variedades distintas. O referido estudo apresenta contornos de investigação-ação e foi desenvolvido num agrupamento de escolas da região de Aveiro, no ano letivo 2014/2015. No decurso do nosso projeto, socorremo-nos de diversas técnicas e instrumentos de recolha de dados, nomeadamente um inquérito por questionário e fichas de atividades para identificar e descrever os estereótipos dos alunos. Neste projeto, analisamos os resultados de uma investigação onde destacamos, por um lado, os estereótipos que alunos portugueses, do 8.º ano de escolaridade, têm sobre a realidade da língua espanhola e das suas variedades, no mundo; por outro lado, a presença/ausência dessa diversidade (intra)linguística nos manuais escolares que acompanharam a turma-alvo do estudo. Com base nos resultados obtidos, foi realizada ainda uma sessão de sensibilização às variedades do Espanhol. Os resultados demonstram que os manuais escolares analisados contêm visões estereotipadas e redutoras sobre a diversidade linguística espanhola, sobrevalorizando, em certa medida, a norma peninsular. Os dados recolhidos através do inquérito por questionário, permitiram-nos concluir que os alunos possuíam visões estereotipadas sobre o Espanhol e as suas variedades. No entanto, mediante a sessão de sensibilização para a valorização da diversidade linguística espanhola, concluímos que foi criado um espaço de reflexão que permitisse quer a reconstrução de estereótipos quer ainda um espaço de diálogo e debate coletivo sobre como as diferenças da língua a podem enriquecer.

Amélioration des propriétés pharmacocinétiques de peptides par différentes alkylations N-terminales

Modélisations moléculaires réalisés avec le logiciel HyperChem 8.

Chemical and physical effects of ultrasound: sonoluminescence and materials

When a liquid is irradiated with ultrasound, acoustic cavitation (the formation, growth, and implosive collapse of bubbles in liquids irradiated with ultrasound) generally occurs. This is the phenomenon responsible for the driving of chemical reactions (sonochemistry) and the emission of light (sonoluminescence). The implosive collapse of bubbles in liquids results in an enormous concentration of sound energy into compressional heating of the bubble contents. Therefore, extreme chemical and physical conditions are generated during cavitation. The study of multibubble sonoluminescence (MBSL) and single-bubble sonoluminescence (SBSL) in exotic liquids such as sulfuric acid (H2SO4) and phosphoric acid (H3PO4) leads to useful information regarding the intracavity conditions during bubble collapse. Distinct sonoluminescing bubble populations were observed from the intense orange and blue-white emissions by doping H2SO4 and H3PO4 with sodium salts, which provides the first experimental evidence for the injected droplet model over the heated-shell model for cavitation. Effective emission temperatures measured based on excited OH• and PO• emission indicate that there is a temperature inhomogeneity during MBSL in 85% H3PO4. The formation of a temperature inhomogeneity is due to the existence of different cavitating bubble populations: asymmetric collapsing bubbles contain liquid droplets and spherical collapsing bubbles do not contain liquid droplets. Strong molecular emission from SBSL in 65% H3PO4 have been obtained and used as a spectroscopic probe to determine the cavitation temperatures. It is found that the intracavity temperatures are dependent on the applied acoustic pressures and the thermal conductivities of the dissolved noble gases. The chemical and physical effects of ultrasound can be used for materials synthesis. Highly reactive species, including HO2•, H•, and OH• (or R• after additives react with OH•), are formed during aqueous sonolysis as a consequence of the chemical effects of ultrasound. Reductive species can be applied to synthesis of water-soluble fluorescent silver nanoclusters in the presence of a suitable stabilizer or capping agent. The optical and fluorescent properties of the Ag nanoclusters can be easily controlled by the synthetic conditions such as the sonication time, the stoichiometry of the carboxylate groups to Ag+, and the polymer molecular weight. The chemical and physical effects of ultrasound can be combined to prepare polymer functionalized graphenes from graphites and a reactive solvent, styrene. The physical effects of ultrasound are used to exfoliate graphites to graphenes while the chemical effects of ultrasound are used to induce the polymerization of styrene which can then functionalize graphene sheets via radical coupling. The prepared polymer functionalized graphenes are highly stable in common organic solvents like THF, CHCl3, and DMF. Ultrasonic spray pyrolysis (USP) is used to prepare porous carbon spheres using energetic alkali propiolates as the carbon precursors. In this synthesis, metal salts are generated in situ, introducing porous structures into the carbon spheres. When different alkali salts or their mixtures are used as the precursor, carbon spheres with different morphologies and structures are obtained. The different precursor decomposition pathways are responsible for the observed structural difference. Such prepared carbon materials have high surface area and are thermally stable, making them potentially useful for catalytic supports, adsorbents, or for other applications by integrating other functional materials into their pores.

Causalité et explication causale chez James Woodward

Certains philosophes affirment que les relations causales sont fondées sur les lois de la nature. Cette conception cadre mal avec la réalité des sciences biomédicales et des sciences humaines. Pour se rapprocher de la pratique réelle des diverses sciences, James Woodward propose une conception de la causalité et de l’explication causale fondée sur une relation beaucoup moins exigeante que celle de loi de la nature, qu’il appelle l’invariance. Le but de ce mémoire est de présenter le concept d’invariance et les autres concepts causaux qui s’y rattachent et, d’identifier certaines difficultés, dans le but de cerner l’usage approprié de cette famille de concepts. La conception causale de Woodward suppose que le but de la recherche des causes est pratique plutôt que simplement épistémique : il s’agit pour les agents de s’appuyer sur les causes pour modifier les phénomènes. Cette conception est également non-réductive; elle utilise des contrefactuels et reflète les méthodes expérimentales des diverses sciences. La cohérence de cette conception avec les généralisations causales réelles des sciences fait en sorte qu’elle abandonne l’objectif d’universalité rattaché à la notion de loi de la nature, en faveur d’un objectif de fiabilité temporaire. De plus, comme le critère d’invariance est peu exigeant, d’autres critères doivent lui être ajoutés pour identifier, parmi les relations causales (c’est-à-dire invariantes), les relations les plus susceptibles d’être employées pour modifier les phénomènes de façon fiable.

Classical Invariants for Principal Series and Isomorphisms of Root Data

We develop some new techniques to calculate the Schur indicator for self-dual irreducible Langlands quotients of the principal series representations. Using these techniques we derive some new formulas for the Schur indicator and the real-quaternionic indicator. We make progress towards developing an algorithm to decide whether or not two root data are isomorphic. When the derived group has cyclic center, we solve the isomorphism problem completely. An immediate consequence is a clean and precise classification theorem for connected complex reductive groups whose derived groups have cyclic center.

Food-Web Complexity in Guaymas Basin Hydrothermal Vents and Cold Seeps

In the Guaymas Basin, the presence of cold seeps and hydrothermal vents in close proximity, similar sedimentary settings and comparable depths offers a unique opportunity to assess and compare the functioning of these deep-sea chemosynthetic ecosystems. The food webs of five seep and four vent assemblages were studied using stable carbon and nitrogen isotope analyses. Although the two ecosystems shared similar potential basal sources, their food webs differed: seeps relied predominantly on methanotrophy and thiotrophy via the Calvin-Benson-Bassham (CBB) cycle and vents on petroleum-derived organic matter and thiotrophy via the CBB and reductive tricarboxylic acid (rTCA) cycles. In contrast to symbiotic species, the heterotrophic fauna exhibited high trophic flexibility among assemblages, suggesting weak trophic links to the metabolic diversity of chemosynthetic primary producers. At both ecosystems, food webs did not appear to be organised through predator-prey links but rather through weak trophic relationships among co-occurring species. Examples of trophic or spatial niche differentiation highlighted the importance of species-sorting processes within chemosynthetic ecosystems. Variability in food web structure, addressed through Bayesian metrics, revealed consistent trends across ecosystems. Food-web complexity significantly decreased with increasing methane concentrations, a common proxy for the intensity of seep and vent fluid fluxes. Although high fluid-fluxes have the potential to enhance primary productivity, they generate environmental constraints that may limit microbial diversity, colonisation of consumers and the structuring role of competitive interactions, leading to an overall reduction of food-web complexity and an increase in trophic redundancy. Heterogeneity provided by foundation species was identified as an additional structuring factor. According to their biological activities, foundation species may have the potential to partly release the competitive pressure within communities of low fluid-flux habitats. Finally, ecosystem functioning in vents and seeps was highly similar despite environmental differences (e.g. physico-chemistry, dominant basal sources) suggesting that ecological niches are not specifically linked to the nature of fluids. This comparison of seep and vent functioning in the Guaymas basin thus provides further supports to the hypothesis of continuity among deep-sea chemosynthetic ecosystems.

Indium-Mediated Cleavage of the Trityl Group from Protected 1H-Tetrazoles

On treatment with indium metal in MeOH–THF, trityl groups undergo reductive removal from 1H-protected tetrazoles (including aliphatic, aromatic, and heteroaromatic substituents), affording the corresponding free tetrazoles in excellent yields, without any decomposition of the tetrazole ring or reduction of any other group.

37° Sur a 19° Norte: Fotografía contemporánea de Australia

Curatorial considerations, aims and objectives:The title for this exhibition (37 ° South to 19 ° North) refers to the Latitude of Melbourne, Australia and Cuernavaca, Mexico.My curatorial objective for making such a reference to the geographical was to invoke a sense of both distance and connection between the two locations of Australia and Mexico and to also create a sense of sharing, not only between our distant landscapes and cultures but also between the feelings and emotions that we all experience in response to the places in which we live out the moments which make up our daily lives.In developing this project I considered the work of more than 35 contemporary Australian photographers and finally selected 15 photographers (including myself). Most of these artists have or have had close connection to Melbourne and to the southern/eastern line of Australian continent. The final selection ranged from Hobart to Maroochydore and one artist who had lived in Melbourne for many years but was now living in Mexico. These photographers (and the specific works) were selected because their long term creative practice captures a sense of location (place and space) with a deep introspective sensibility which I feel offers a viewer a personal and softly spoken vision of some particular aspect of an Australian location, be that exterior landscape or interior place and a sense of unique connection to such places. These images are not documents but rather representations of feelings, stories, memories and dreams which emerge in the milieu of our inhabitants.In selecting the works, careful consideration was also given to diversity of approaches to photographic practice in conjunction to thematic content. Formats and media included black and white, pin hole photography, toy camera, large format (both 4” x 5” and 10”x 8”), phone camera, various digital camera images and other experimental approaches. The local art scene in Cuernavaca is very strong and there is a strong interest in photography. This is partially due to the number of local arts schools and universities which offer studies in photography as well as the political dimension regarding Mexican art in general - as a tool of both political media, reportage and documentary work, photography is a significant medium for many of the people who would be visiting the exhibition. I therefore felt it was important to address the diversity of approaches to the medium which are currently being explored by Australian practitioners.The City Museum of Cuernavaca provided two large walls and some smaller sections of side walls on both the grounds level and the upper level of the main museum galleries for exhibition.The works were arranged with a simple thematic structure. Top level, left to right, then bottom level, left to right starting with images which presented a sense of wilderness and landscape (which were also quite abstract and reductive) to more representational landscape images moving to landscape with small figures (people) emerging within the images (Ash Kerr) to landscapes with larger figures and the emerging presence of man-made elements to urban landscapes and then to interior urban scapes and finally to interior locations with people and finally finishing on the metaphorical image by Harry Nankin of Bogong Moths and the politics of climate change. (It is also interesting to note that the migration path of the Bongong moth matches well the distribution of the artists selected for this project)Broadly speaking the images started outside with broad landscape to intimate interior locations. With these works a great deal of personal content from each photographer was presented. Most artists chose to present 3 large format images while some only presented 2 images. Other graphic and visual elements were considered in the final placement of the images.It must also be noted that the artists selected ranged broadly from very highly established and significant local artists to mid-career/younger establishing artist to some lesser known and emerging artists. From a curatorial perspective I feel this is offers the possibility of what I shall term, a more balanced representation of the local Australian practice and it provides a context in which both established and emerging artists / works must engage on a dialogue, within the exhibition. I believe it also placing the curatorial premise on the strength of the work rather than on whom the artists are and their status. It also supports the younger emerging artists and provides a less formal and predictable outcome for the established artists and for as a collective presentation as a whole.

Consumers' responses to front-of-pack labels that vary by interpretive content

Previous research has shown that front-of-pack labels (FoPLs) can assist people to make healthier food choices if they are easy to understand and people are motivated to use them. There is some evidence that FoPLs providing an assessment of a food's health value (evaluative FoPLs) are easier to use than those providing only numerical information on nutrients (reductive FoPLs). Recently, a new evaluative FoPL (the Health Star Rating (HSR)) has been introduced to Australia and New Zealand. The HSR features a summary indicator, differentiating it from many other FoPLs being used around the world. The aim of this study was to understand how consumers of all ages use and make sense of reductive FoPLs and evaluative FoPLs including evaluative FoPLs with and without summary indicators. Ten focus groups were conducted in Perth, Western Australia with adults (n = 50) and children aged 10–17 years (n = 35) to explore reactions to one reductive FoPL (the Daily Intake Guide), an existing evaluative FoPL (multiple traffic lights), and a new evaluative FoPL (the HSR). Participants preferred the evaluative FoPLs over the reductive FoPL, with the strongest preference being for the FoPL with the summary indicator (HSR). Discussions revealed the cognitive strategies used when interpreting each FoPL (e.g., using cut offs, heuristics, and the process of elimination), which differed according to FoPL format. Most participants reported being motivated to use the evaluative FoPLs (particularly the HSR) to make choices about foods consumed as part of regular daily meals, but not for discretionary foods consumed as snacks or deserts. The findings provide further evidence of the potential utility of evaluative FoPLs in supporting healthy food choices and can assist policy makers in selecting between alternative FoPL formats.

Phenomenology and naturalism: a hybrid and heretical proposal

In this paper I aim to develop a largely non-empirical case for the compatibility of phenomenology and naturalism. To do so, I will criticise what I take to be the standard construal of the relationship between transcendental phenomenology and naturalism, and defend a ‘minimal’ version of phenomenology that is compatible with liberal naturalism in the ontological register (but incompatible with scientific naturalism) and with weak forms of methodological naturalism, the latter of which is understood as advocating ‘results continuity’, over the long haul, with the relevant empirical sciences. Far from such a trajectory amounting to a Faustian pact in which phenomenology sacrifices its soul, I contend that insofar as phenomenologists care about reigning in the excesses of reductive versions of naturalism, the only viable way for this to be done is via the impure and hybrid account of phenomenology I outline here.

A study of culture specific items and translation strategies in Bahram Beyza'i’s play “Marionettes”

L'objectif de cette recherche est de fournir une analyse de la pièce de théâtre perse ''Marionettes'' de Bahrām Beyzā'ī (1963) ainsi que de sa traduction anglaise (1989) afin de comparer et de mettre en contraste les traits propres à la culture «Culture-specific items» (CSI) et des stratégies de traduction. Les formes problématiques pertinentes des différences culturelles seront étudiées et les procédés suggérés par Newmark (1988) seront examinés afin de déterminer dans quelle mesure ils sont pertinents dans la traduction des différences culturelles du perse à l'anglais. La pièce a été traduite par une équipe de traducteurs: Sujata G.Bhatt, Jacquelin Hoats, Imran A. Nyazee et Kamiar K. Oskouee. (Parvin Loloi et Glyn Pursglove 2002:66). Les oeuvres théâtrales de Beyzā'ī sont basées sur les traditions ainsi que sur le folklore iranien. L'auteur aborde la réalité sous une perspective philosophique. « (Un point de vue) enveloppé dans une cape de comparaisons complexes à tel point que nombre des personnages de son oeuvre errent entre des symboles de la mythologie et de l’histoire, ou sociaux» (M.R. Ghanoonparvar, John Green 1989, p.xxii notre traduction). La classification des éléments culturels de Newmark (1988) va comme suit: «Écologie, culture matérielle, culture sociale, organisations, coutumes / moeurs, gestes et habitudes» (Newmark 1988:95). La recherche mettra l’accent sur les procédés suggérés pour traduire les CSI ainsi que sur les stratégies de traduction selon Newmark. Ces procédés comprennent : «traduction littérale, transfert, équivalent culturel, neutralisation, équivalent fonctionnel, équivalent descriptif, synonymie, par le biais de la traduction, transposition, modulation, traduction reconnue, étiquette de traduction, compensation, analyse componentielle, réduction et expansion, paraphraser, distique, notes, additions, gloses» (Newmark 1988:81-93). L'objectif ici est de déterminer si les procédés suggérés sont applicables à la traduction des CSIs du perse à l'anglais, et quels sont les procédés les plus fréquemment utilisés par les traducteurs.

Taking Issue with History: Empathy and the Ethical Imperatives of Creative Interventions

The purpose of this thesis was to contribute to a dialogue that considers the relationship between history, literature, and empathy as a literary affect. Specifically, I explored sites of literature’s transformative potential as it relates to cultural studies and the ethics of deconstruction. Via a deconstructive, post-colonial reading of Toni Morrison’s Beloved and Junot Díaz’s The Brief Wondrous Life of Oscar Wao, I considered how subjects in our current socio-political moment can feel history. Emerging from a post-structurally mediated engagement with history, signification, and feeling, I argued that empathy, as it is contentiously presented in the context of deconstruction, is not necessarily a reductive or essentialist approach towards relating or “being-with” an-other. Instead, I proposed that the act of reading historiographical novels that take constructions of the Atlantic Slave Trade to task might generate an affective empathy, which could in turn engender a more empathetic relationality and way of being-in-the-world.