非常缺中子Re核的负三轴形变研究(英文)

利用在束核谱学实验技术,建立了169Re基于9/2-[514]组态的强耦合转动带.该带在已知的奇ARe核中具有最大的低自旋旋称劈列.对于奇ARe中的9/2-[514]转动带,研究了它们的能量旋称劈列和M1跃迁矩阵元相对旋称劈列与核形状偏离轴对称的关系,揭示了非常缺中子的奇ARe核具有相当的负三轴形变.

双奇核~(170)Re高自旋态实验研究

在 16 6MeV的束流能量下 ,利用重离子熔合蒸发反应14 2 Nd(3 2 S ,1p3nγ) 170 Re布居了170 Re的高自旋激发态 .用 12套带BGO反康普顿抑制的高纯锗探测器阵列进行了在束X -γ和γ -γ符合测量 .基于对实验测量结果及周围邻近核已知信息的综合分析 ,首次建立了双奇核170 Re的转动带能级纲图 .根据实验提取出的准粒子顺排、旋称劈裂等结构特征和Re双奇核同位素带结构系统学知识的比较分析 ,指出该带的准粒子组态是πh11 2 υi13 2 .

~(169)Re的转动带结构组态相关性研究(英文)

研究了~(169)Re的高自旋态能级结构,建立了组态为π9/2~-[514]的强耦合带和组态为π1/2~-[541]的退耦合带,推转壳模型(Cranked shell model)计算结果表明组态相关的不同形变能够解释这些转动带的不同带交叉频率,在已知的奇ARe核中,~(169)Re的9/2~-[514]转动带在低自旋时具有最大的能量旋称劈裂,当一对i_(13/2)中子顺排后,旋称劈裂发生了反转,并且劈裂的幅度非常显著地减少了,另外,还观测到了一个三准粒子激发带,并指定了它的最可能组态为π9/2~-[514](?)νAE。

双奇核~(172)Re高自旋态转动带结构实验研究

利用重离子熔合蒸发反应 14 9Sm (2 7Al,4nγ) 172 Re布居了形变双奇核 172 Re的高自旋态 ,用 12套带有BGO反康普顿抑制的高纯锗探测器阵列进行了在束γ实验测量 ,首次建立了形变双奇核172 Re由 3个转动带构成的高自旋态能级纲图 .研究和讨论了 3个转动带的结构特征 ,基于已有的高自旋态核结构知识并通过系统学比较和分析指出它们的准粒子组态分别为πh11 2 νi13 2 ,πh9 2 νi13 2 和π1 2 -[5 41] ν1 2 -[5 2 1].发现前两个转动带在自旋小于 18.5时其转动能级呈现反常的旋称劈裂 .

~(169)Re的转动带结构研究(英文)

利用在束γ谱学方法 ,通过反应1 4 4 Sm( 2 8Si,1p3n) 1 69Re研究了1 69Re的激发态能级结构 .实验进行了X γ符合、γ γ符合、DCO系数和带内B(M1 ) B(E2 )比率测量 .基于这些测量 ,建立了组态为π9 2 - [51 4 ]的强耦合带和组态为π1 2 -[54 1 ]的退耦合带 .通过比较1 69Re的转动带与邻近奇质子核已知转动带的结构和B(M1 ) B(E2 )比率 ,指定了1 69Re转动带的组态 .实验观测到π9 2 - [51 4 ]和π1 2 - [54 1 ]转动带的中子AB带交叉的转动频率分别为 0 .2 3和 0 .2 7MeV .着重讨论了1 69Re转动带的中子AB带交叉频率、转动角动量顺排和旋称劈列等 ,并讨论了奇ARe核转动带结构的系统性

奇奇核~(174)Re的转动带(英文)

利用重离子熔合蒸发反应~ (１５９)Ｔｂ（~(２０)Ｎｅ，５ｎ）~(１７４)Ｒｅ，并通过激发函数、ＫＸ－ γ和γ－γ符合测量，研究了~(１７４)Ｒｅ核的高自旋态．鉴别并指定了~(１７４)Ｒｅ核的一个 基于л１／２－［５４１］ｖ１／２~ -［５２１］准粒子组态上的双退耦带．还发现了两个分别具 有半退耦特征和强耦合特征的转动带，定性地讨论了它们的粒子组态．

Identification of a new band and its signature inversion in Re-174

High spin states in Re-174 are investigated via the Sm-152(Al-27, 5n gamma)Re-174 reaction and gamma-gamma coincidence relationships are analysed carefully. A new band is identified due to its spectroscopic connection with the known pi 1/2(-)[541] circle times nu 1/2(-)[521] band. This band is proposed to be the ground-state band built on the pi 1/2(-)[541] circle times nu 5/2(-)[512] configuration in view of the low-lying intrinsic states in the neighbouring odd-mass nuclei. It is of particular interesting that the new band exhibits a phenomenon of low-spin signature inversion, providing a new situation for theoretical investigations.

双奇核~(172)Re的高自旋态；High Spin States in Odd-odd ~(172)Re

对149Sm(27Al,4n)172Re反应产生的172Re在束γ的实验数据进行了重新分析,新发现了可归属于172Re的3个转动带,由此建立了由6个转动带构成的172Re高自旋态能级纲图。依据相邻核的带结构知识和推转壳模型分析方法,对新发现的3个转动带的准粒子组态进行了指定,讨论了它们的转动特征。

双奇核~(170)Re高自旋转动带分析(英文)；Analysis of High-spin Rotational Band in Odd-odd ~(170)Re

通过重离子熔合蒸发反应142Nd(32S,1p3nγ)170Re布居了缺中子双奇核170Re的高自旋激发态,识别出了该核的一条转动带并建议了其组态为πh1/2 νi13/2。基于对同中子素能级系统性、旋称反转系统性、带内B(M1)/B(E2)、准粒子Routhians、动力学转动惯量和Total Routhian Surface(TRS)等带结构特征的详细分析和讨论,进一步确认了对A=170核区目前最缺中子双奇核高自旋转动带组态、宇称和自旋值的指定。

Crystallization and Si incorporation mechanisms of SAPO-34

In this study of the synthesis of SAPO-34 molecular sieves, XRD, SEM, XRF, IR and NMR techniques were applied to monitor the crystalloid, structure and composition changes of the samples in the whole crystallization process in order to get evidence for the crystallization as well as Si incorporation mechanism of SATO-34. XRD results revealed that the crystallization contained two stages. In the first 2.5 h (the earlier stage), high up to similar to80% of relative crystallinity could be achieved and the crystal size of SAPO-34 was almost the same as that of any longer time, indicating a fast crystallization feature of the synthesis. In this stage, IR revealed that the formation of SAPO-34 framework structure was accompanied by the diminution of hydroxyls, suggesting that crystal nuclei of SAPO-34 may arise from the structure rearrangement of the initial gel and the condensation of the hydroxyls. NMR results reveal that the template and the ageing period are crucial for the later crystallization of SAPO-34. Preliminary structure units similar to the framework of SAPO-34 have already formed before the crystallization began (0 h and low temperature). Evidence from IR, NMR, and XRF shows that the formation of the SAPO-34 may be a type of gel conversion mechanism, the solution support and the appropriate solution circumstance are two important parameters of the crystallization of SAPO-34. Meanwhile, NMR measurements demonstrated that about 80% of total Si atoms directly take part in the formation of the crystal nuclei as well as in the growth of the crystal grains in the earlier stage (<2.5 h). Evidence tends to support that Si incorporation is by direct participation mechanism rather than by the Si substitution mechanism for P in this stage (<2.5 h). In the later stage (>2.5 h), the relative content of Si increased slightly with a little decrease of Al and P. The increase of Si(4Al) and the appearance of the Si(3Al), Si(2Al), Si(1Al) and Si(OAl) in this stage suggest that substitution of the Si atoms for the phosphorus and for the phosphorus and aluminum pair takes place in the crystallization. The relationship among structure, acidity and crystallization process is established, which suggests a possibility to improve the acidity and catalytic properties by choosing a optimum crystallization time, thus controlling the number and distribution of Si in the framework of SAPO-34. (C) 2002 Elsevier Science Inc. All rights reserved.