Contaminação por crômio de águas de rios proveniente de curtumes em Minas Gerais

In order to evaluate the chromium contamination from tannery discharges into rivers in the State of Minas Gerais, samples of water and suspended material were collected and submitted to chemical analysis. The total content of chromium in the samples was measured by flame atomic absorption spectrophotometry. Water samples were analysed by standard addition method, while chromium concentration in suspended materials was determined by calibration curves. Localities investigated were Ipatinga, Matias Barbosa, Dores de Campo, Ressaquinha, Ubá and Juiz de Fora. Samples from a not-industrialized area were also analysed to obtain regional background values. Metal inputs were related to effluent discharges into the rivers. Suspended material transported Cr downriver. Chromium concentration in river water exceeded 656 times the value of the Brazilian Environmental Standards, while its concentration in suspended material ranged from 15 to 11066 µg g-1.

A proposta curricular de química do Estado de Minas Gerais: fundamentos e pressupostos

This article presents the basic ideas that oriented the elaboration of the new Chemistry Curriculum for the High Schools in the State of Minas Gerais, Brazil. The main features of traditional Brazilian Chemistry Curriculum are critically discussed, namely, the excessive number of concepts, the overemphasis in procedures and rituals instead of chemical principles and the lack of relationship between the concepts and the social, technological and environmental contexts. Trying to overcome these features, the proposed curriculum deals with a fewer number of concepts, clearly related in a conceptual structure, opening space to a balanced emphasis on phenomena, theory and representation, and on conceptual and contextual aspects of chemical knowledge.

Implantación y ajuste de la aplicación GLPI para la administración de recursos informáticos en la Secretaría Distrital de Planeación

El proyecto GLPI consistió en apoyar el proceso de implantación, ajustes y aprendizaje de la aplicación de software libre GLPI para su uso en la Secretaría Distrital de Planeación de la ciudad de Bogotá, entidad de carácter público que, a través de esta herramienta, requirió mejorar el sistema de atención de incidencias y gestionar el inventario de software y hardware disponible en sus instalaciones con el claro objetivo de fortalecer su gestión.

La regulación de la Administración electrónica y sus principios rectores

[spa] Actualmente, nos encontramos inmersos en un proceso de globalización y tecnificación al que las Administraciones públicas, como parte integrante de l a sociedad, no pueden permanecer ajenas. Todas las Administraciones, en sus distintos niveles y ámbitos de actuación, han introducido en su actividad las nuevas tecnologías de la información y la comunicación, y han puesto en marcha un proceso transformación de carácter cultural, organizativo y jurídico que ha fructificado en un nuevo modelo de gestión de la actividad pública conocido bajo el nombre de Administración electrónica. El uso de las nuevas tecnologías y la transición de una Administración «en pa pel» a una Administración electrónica han conllevado una serie de reformas de nuestro ordenamiento jurídico: nuevas normas y reforma de otras ya existentes que regulan los aspectos técnicos derivados de la utilización de las nuevas tecnologías por parte de la Administración, así como los derechos y garantías de los que están revestidos los ciudadanos cuando se relacionan con la Administración por medios telemáticos. Con este telón de fondo, podemos definir un elenco de principios que regirán la actuación de la Administración electrónica y en los que se erigen como protagonistas aquellos que persiguen garantizar la igualdad y la no discriminación de los ciudadanos, combatiendo la denominada brecha digital.

La Administración electrónica en España: de la 'administración en papel' a la 'e-administración'

[spa] Desde principios de los noventa, nuestra sociedad está sufriendo una serie de cambios asociados al uso masivo de las nuevas tecnologías de la información y la comunicación (TIC). En este nuevo modelo social, conocido bajo el nombre de sociedad de la información, las Administraciones públicas han tenido que adaptarse, introduciendo las nuevas tecnologías en su actividad cotidiana. No obstante, la transformación de las Administraciones públicas va más allá del uso de las TIC, pues supone una auténtica transformación de una administración en papel a una verdadera administración electrónica. Todo ello conlleva modificaciones en el ordenamiento jurídico, así como en las relaciones entre la Administración con los ciudadanos. En este trabajo, analizamos el desarrollo de este proceso en las Administraciones públicas españolas.

Efectos de la reforma contable en la administración local

L' any 2006 entra en vigor una nova instrucció de comptabilitat per a l' administració local que provocarà alguns efectes que s' intenten analitzar en aquest article. En primer lloc, s' analitza el pas de dos models comptables a tres, després s' estudien les modificacions més importants,i s' acaba amb les principals conclusions obtingudes i la repercussió en la gestió comptable

Determinação dos teores de cobre e grau alcoólico em aguardentes de cana produzidas no estado de Minas Gerais

The objective of this work was to investigate if producers of sugar cane spirits in Minas Gerais, Brazil, have improved the copper content of their products and also if they have adjusted to the new standards of identity for 'cachaça' and 'aguardente'. Seventy-one samples, obtained from May 2003 until March 2004, were analyzed. Mean copper content was 2.30 mg/L, which indicates a significant reduction in levels. The mean alcohol content was 45.6 % v/v. All of the 'aguardente' but only 79% of the 'cachaça' attended to the standard of identity for alcohol content for these products.

La técnica de la rejilla en la orientación personal: Estudio de un caso

La Técnica de Rejilla (TR) se origina en el seno de la Psicología de los Constructos Personales de Kelly, y ha mostrado su utilidad en el campo de la psicología clínica. En este trabajo se ilustra el uso de esta técnica, tanto en lo que respecta a administración como a análisis e interpretación psicológica, aplicada a un caso sin rasgos patológicos. Sin embargo, la TR resulta también útil a la hora de mostrar su capacidad para darnos una imagen amplia y detallada acerca de la forma como la persona se construye a sí misma y su mundo interpersonal. A pesar de su complejidad, la TR es una técnica útil para la comprensión de problemas no clínicos pero que requieran orientación.

Teores de carbamato de etila e outros componentes secundários em diferentes cachaças produzidas em três regiões do estado de Minas Gerais: Zona da mata, sul de minas e vale do jequitinhonha

Minas Gerais is the highest producer of handmade spirits. Research has been carried out aiming to contribute to progress. Thus, the goal of this work is to evaluate the quality of spirits in three different regions of Minas Gerais state. We analyzed ethyl carbamate, alcoholic grade, volatile acidity, higher alcohols, aldehyde, esters, methanol, furfural and copper. The values obtained for ethyl carbamate varied from undetectable to 643.5 µg L-1, with only one region not following the legislation (150 µg L-1). Most of the compounds in the spirits were present within the limits estabilished by the legislation.

Composição elementar do material particulado presente no aerossol atmosférico do município de Sete Lagoas, Minas Gerais

The main objective of this study was the identification of sources generating particulate matter in the atmospheric aerosols of Sete Lagoas, Minas Gerais. The measurement of the mineral composition was accomplished by X-ray diffractometry and the elemental concentration by neutron activation analysis. The results showed that Al, Cl, Cu, Fe, K, Mg and Na are the predominant chemical elements in the total suspended particles (TPS). The presence of Na, Ba, Cl, Cu, Eu, Fe and Sm in those particles with aerodynamic diameter smaller than 10 µm (PM10), indicates that soil dust and ceramic and pig iron industries are the main sources of air quality degradation in the region.

Arsenic mobilization from sulfidic materials from gold mines in Minas Gerais State

Acid drainage results from exposition of sulfides to the atmosphere. Arsenopyrite is a sulfide that releases arsenic (As) to the environment when oxidized. This work evaluated the As mobility in six sulfidic geomaterials from gold mining areas in Minas Gerais State, Brazil. Grained samples (<2 mm) were periodically leached with distilled water, during 70 days. Results suggested As sorption onto (hydr)oxides formed by oxidation of arsenopyrite. Low pH accelerated the acid generation, dissolving Fe oxihydroxides and releasing As. Presence of carbonates decreased oxidation rates and As release. On the other hand, lime added to a partially oxidized sample increased As mobilization.

Determinação de metais traço no material particulado em suspensão em Ouro Preto, Minas Gerais

The determination of the airborne particulate matter (PTS) mass and trace metals concentrations were performed in three sites in Ouro Preto, MG, Brazil. It was evaluated 288 samples. The legal limit of annual geometric average (60 µg m-3) to PTS concentrations didn't exceed, but the legal limit for 24 h (240 µg m-3) did in three measurements. Seven metals (Al, Cr, Cu, Fe, Mn, Ni, Pb) analysed by ICP-AES were quantified in 18 samples. Aluminum and iron showed the highest concentrations, indicating the contribution of the soil and of one aluminum plant. The high nickel concentration is probably due to vehicular emissions and industrial combustion processes.

Estudo químico de uma amostra de própolis verde de Passa Quatro, Minas Gerais, Brasil

The phytochemical investigation of a sample of propolis from Passa Quatro-Minas Gerais State, Brazil, where nine constituents were isolated: a mixture of α- and β-amyrin, lupeol, a mixture of flavonols ramnocitrin and eupalitin, acacetin, 3-prenyl-4-hydroxycinnamic acid, 3,5-diprenyl-4-hydroxycinnamic acid the new compound, the (E)-3-[4-(3-phenylpropanoiloxy)]-3,5-diprenil-cinnamic acid. The structures of the isolated compounds were characterized by 1D- and 2D-NMR experiments, MS and IR spectrometry, and comparison with data described in the literature.

Percepção dos pós-graduandos em química da Universidade Federal de Minas Gerais sobre a própria formação docente

The pedagogic training of university professors has been overlooked in institutions of higher education. In the second semester of 2009, students of the Graduate Chemistry Program at the Federal University of Minas Gerais participated in an investigation that aimed to evaluate the students' perceptions of their own training to become professors. It was found that a large number of students felt prepared to teach at institutions of higher education, despite their lack of experience at this education level. A significant point in this work was the finding that most students do not acknowledge the need of associating the teaching practice with teaching-learning theories, but instead consider the knowledge of scientific content important.

Análise de pinturas rupestres do Abrigo do Janelão (Minas Gerais) por microscopia raman

Rock art paintings from Abrigo do Janelão (Minas Gerais, Brazil) were non-destructively investigated by Raman Microscopy, aiming at the identification of materials used, their interaction and degradation. This technique is particularly tailored for heterogeneous samples and allows unequivocal identification of the substances present in the investigated sample. Pigments, were identified together with products of microbiological degradation; no binders were detected. White pigment was identified as calcite (CaCO3), whereas charcoal was used as black, goethite (α-FeOOH) as yellow and hematite (α-Fe2O3) as red. Whewellite (CaC2O4.H2O) and weddelite (CaC2O4.2H2O) were detected and their origin was assigned to degradation products from microbiological activity.