Development of an on-demand beam pulsing system for Pixe-analysis of thick targets

This work concerns the developnent of a proton irduced X-ray emission (PIXE) analysis system and a multi-sample scattering chamber facility. The characteristics of the beam pulsing system and its counting rate capabilities were evaluated by observing the ion-induced X-ray emission from pure thick copper targets, with and without beam pulsing operation. The characteristic X-rays were detected with a high resolution Si(Li) detector coupled to a rrulti-channel analyser. The removal of the pile-up continuum by the use of the on-demand beam pulsing is clearly demonstrated in this work. This new on-demand pu1sirg system with its counting rate capability of 25, 18 and 10 kPPS corresponding to 2, 4 am 8 usec main amplifier time constant respectively enables thick targets to be analysed more readily. Reproducibility tests of the on-demard beam pulsing system operation were checked by repeated measurements of the system throughput curves, with and without beam pulsing. The reproducibility of the analysis performed using this system was also checked by repeated measurements of the intensity ratios from a number of standard binary alloys during the experimental work. A computer programme has been developed to evaluate the calculations of the X-ray yields from thick targets bornbarded by protons, taking into account the secondary X-ray yield production due to characteristic X-ray fluorescence from an element energetically higher than the absorption edge energy of the other element present in the target. This effect was studied on metallic binary alloys such as Fe/Ni and Cr/Fe. The quantitative analysis of Fe/Ni and Cr/Fe alloy samples to determine their elemental composition taking into account the enhancement has been demonstrated in this work. Furthermore, the usefulness of the Rutherford backscattering (R.B.S.) technique to obtain the depth profiles of the elements in the upper micron of the sample is discussed.

The effects of the changing energy situation on demand for industrial heat exchangers

The Project arose during a period in which the World was still coming to terms with the effects and implications of the so called 'energy crisis' of 1973/74. Serck Heat Transfer is a manufacturer of heat exchangers which transfer heat between fluids of various sorts. As such the company felt that past and possible future changes in the energy situation could have an impact upon the demand for its products. The thesis represents the first attempt to examine the impact of changes in the energy situation (a major economic variable) on the long term demand for heat exchangers. The scope of the work was limited to the United Kingdom, this being the largest single market for Serek's products. The thesis analyses industrial heat exchanger markets and identifies those trends which are related to both the changing energy situation and the usage of heat exchangers. These trends have been interpreted In terms of projected values of heat exchanger demand. The projections cover the period 197S to the year 2000. Also examined in the thesis is the future energy situation both internationally and nationally and it is found that in the long term there will be increasing pressure on consumers to conserve energy through rising real prices. The possibility of a connection between energy consumption and heat exchanger demand is investigated and no significant correlation found. This appears to be because there are a number of determinants of demand besides energy related factors and also there is a wide diversity of individual markets for heat exchangers. Conclusions are that in all markets, bar one, the changing energy situation should lead to a higher level of heat exchanger demand than would otherwise be the case had the energy situation not changed. It is also pointed out that it is misleading to look at changes in one influence on the demand for a product and ignore others.

Survey on demand side sensitivity to power quality in Ireland

Power systems require a reliable supply and good power quality. The impact of power supply interruptions is well acknowledged and well quantified. However, a system may perform reliably without any interruptions but may have poor power quality. Although poor power quality has cost implications for all actors in the electrical power systems, only some users are aware of its impact. Power system operators are much attuned to the impact of low power quality on their equipment and have the appropriate monitoring systems in place. However, over recent years certain industries have come increasingly vulnerable to negative cost implications of poor power quality arising from changes in their load characteristics and load sensitivities, and therefore increasingly implement power quality monitoring and mitigation solutions. This paper reviews several historical studies which investigate the cost implications of poor power quality on industry. These surveys are largely focused on outages, whilst the impact of poor power quality such as harmonics, short interruptions, voltage dips and swells, and transients is less well studied and understood. This paper examines the difficulties in quantifying the costs of poor power quality, and uses the chi-squared method to determine the consequences for industry of power quality phenomenon using a case study of over 40 manufacturing and data centres in Ireland.

Stimuli-Responsive Microneedle Arrays For On-Demand Drug Delivery

Pulsatile, or “on-demand”, delivery systems have the capability to deliver a therapeutic molecule at the right time/site of action and in the right amount (1). Pulsatile delivery systems present multiple benefits over conventional dosage forms and provide higher patient compliance. The combination of stimuli-responsive materials with the drug delivery capabilities of hydrogel-forming MN arrays (2) opens an interesting area of research. In the present work we describe, a stimuli-responsive hydrogel-forming microneedle (MN) array that enable delivery of a clinically-relevant model drug (ibuprofen) upon application of UV radiation (Figure 1A). MN arrays were prepared using a micromolding technique using a polymer prepared from 2-hydroxyethyl methacrylate (HEMA) and ethylene glycol dimethacrylate (EGDMA) (Figure 1B). The arrays were loaded with up to 5% (w/w) ibuprofen included in a light-responsible conjugate (3,5-dimethoxybenzoin conjugate) (2). The presence of the conjugate inside the MN arrays was confirmed by Raman spectroscopy measurements. MN arrays were tested in vitro showing that they were able to deliver up to three doses of 50 mg of ibuprofen after application of an optical trigger (wavelength of 365 nm) over a long period of time (up to 160 hours) (Figure 1C and 1D). The work presented here is a probe of concept and a modified version of the system should be used as UV radiation is shown to be the major etiologic agent in the development of skin cancers. Consequently, for future applications of this technology an alternative design should be developed. Based on the previous research dealing with hydrogel forming MN arrays a suitable strategy will be to use hydrogel-forming MN arrays containing a backing layer made with the material described in this work as the drug reservoir (2). Finally, a porous layer of a material that blocks UV radiation should be included between the MN array and the drug reservoir. Therefore radiation can be applied to the system without reaching the skin surface. Therefore after modification, the system described here interesting properties as “on-demand” release system for prolonged periods of time. This technology has potential for use in “on-demand” delivery of a wide range of drugs in a variety of applications relevant to enhanced patient care.

On-demand generation and removal of alginate biocompatible microvalves for flow control in microfluidics

[EN] This paper describes, for the first time, the use of alginate hydrogels as miniaturised microvalves within microfluidic devices. These biocompatible and biodegradable microvalves are generated in situ and on demand, allowing for microfluidic flow control. The microfluidic devices were fabricated using an origami inspired technique of folding several layers of cyclic olefin polymer followed by thermocompression bonding. The hydrogels can be dehydrated at mild temperatures, 37◦C, to slightly open the microvalve and chemically erased using an ethylenediaminetetraacetic acid disodium salt (EDTA) solution, to completely open the channel, ensuring the reusability of the whole device and removal of damaged or defective valves for subsequent regeneration.

Light-driven transport of plasmonic nanoparticles on demand

Laser traps provide contactless manipulation of plasmonic nanoparticles (NPs) boosting the development of numerous applications in science and technology. The known trapping configurations allow immobilizing and moving single NPs or assembling them, but they are not suitable for massive optical transport of NPs along arbitrary trajectories. Here, we address this challenging problem and demonstrate that it can be handled by exploiting phase gradients forces to both confine and propel the NPs. The developed optical manipulation tool allows for programmable transport routing of NPs to around, surround or impact on objects in the host environment. An additional advantage is that the proposed confinement mechanism works for off-resonant but also resonant NPs paving the way for transport with simultaneous heating, which is of interest for targeted drug delivery and nanolithography. These findings are highly relevant to many technological applications including micro/nano-fabrication, micro-robotics and biomedicine.

Sviluppo di YouCrowd: una piattaforma per campagne mobile crowdsensing on-demand

Con il termine "crowdsensing" si intende una tecnica in cui un folto gruppo di individui aventi dispositivi mobili acquisiscono e condividono dati di natura diversa in maniera collettiva, al fine di estrarre informazioni utili. Il concetto di Mobile Crowdsensing è molto recente e derivante dalle ultime innovazioni tecnologiche in materia di connettività online e cattura di dati di vario genere; pertanto non si trova attualmente una vera e propria applicazione in campo reale, la modellazione solo teorica e fin troppo specifica pone un limite alla conoscenza di un ambito che può rivelarsi molto utile ai fini di ricerca. YouCrowd è un piattaforma web che va ad implementare un sistema di crowdsourcing completo, in grado di leggere dati dai numerosi sensori di uno smartphone e condividerli, al fine di ottenere una remunerazione per gli utenti che completano una campagna. La web application vede la sua implementazione di base supportata da NodeJS e si configura come una piattaforma dinamica che varia la propria interfaccia con l'utente in base alle richieste di dati da parte degli administrators. Il test di YouCrowd ha coinvolto un buon numero di partecipanti più o meno esperti nell'utilizzo degli strumenti informatici, rivelando delle buone prestazioni in relazione alla difficoltà del task e alle prestazioni del device in test.

L'animazione giapponese come nuova frontiera dello streaming on demand

L’obiettivo di questo lavoro è prendere in analisi in che modo l’animazione seriale giapponese così come i film d’animazione siano pian piano diventati elementi imprescindibili dell’offerta di una piattaforma di streaming, e di come in futuro lo saranno sempre di più andando a convergere con altre esperienze mediali come i videogiochi. Animazione quindi come una nuova frontiera nella quale le piattaforme on demand dovranno giocarsela per il proprio spazio vitale ma anche per acquisire nuovi utenti.

Solução doméstica para televisão digital

Mestrado em Engenharia Electrotécnica e de Computadores

Estudo e análise de soluções de acessos Wimax partilhados em cenários residenciais

Mestrado em Engenharia Electrotécnica e de Computadores

A proposal for media component brokerage

This paper describes how MPEG-4 object based video (obv) can be used to allow selected objects to be inserted into the play-out stream to a specific user based on a profile derived for that user. The application scenario described here is for personalized product placement, and considers the value of this application in the current and evolving commercial media distribution market given the huge emphasis media distributors are currently placing on targeted advertising. This level of application of video content requires a sophisticated content description and metadata system (e.g., MPEG-7). The scenario considers the requirement for global libraries to provide the objects to be inserted into the streams. The paper then considers the commercial trading of objects between the libraries, video service providers, advertising agencies and other parties involved in the service. Consequently a brokerage of video objects is proposed based on negotiation and trading using intelligent agents representing the various parties. The proposed Media Brokerage Platform is a multi-agent system structured in two layers. In the top layer, there is a collection of coarse grain agents representing the real world players – the providers and deliverers of media contents and the market regulator profiler – and, in the bottom layer, there is a set of finer grain agents constituting the marketplace – the delegate agents and the market agent. For knowledge representation (domain, strategic and negotiation protocols) we propose a Semantic Web approach based on ontologies. The media components contents should be represented in MPEG-7 and the metadata describing the objects to be traded should follow a specific ontology. The top layer content providers and deliverers are modelled by intelligent autonomous agents that express their will to transact – buy or sell – media components by registering at a service registry. The market regulator profiler creates, according to the selected profile, a market agent, which, in turn, checks the service registry for potential trading partners for a given component and invites them for the marketplace. The subsequent negotiation and actual transaction is performed by delegate agents in accordance with their profiles and the predefined rules of the market.

Redes “Fiber To The Home – FTTH”. O despertar de novos serviços de telecomunicações

Se ha poucos anos nao imaginavamos as nossas vidas sem o conforto proporcionado pela iluminacao artificial, fruto do desenvolvimento e proliferacao da producao, transporte e distribuicao de energia electrica, seguramente que nos dias de hoje e indissociavel juntar a esse mesmo conforto e estilo de vida a utilizacao dos meios de telecomunicacoes actuais. Com efeito, a vulgarizacao do uso de telemoveis, a recepcao e transmissao de dados a velocidades cada vez maiores, o aparecimento de televisao de alta definicao (TVAD) em substituicao do actual formato PAL, a surgimento de ofertas de novos servicos como o Video on Demand a par da emergente televisao digital terrestre constituem, seguramente, uma nova revolucao nas infra-estruturas de telecomunicacoes domesticas e profissionais. O sector das telecomunicacoes tem sido aquele que se encontra em pleno crescimento, com os fabricantes e operadores a lancarem novos produtos e solucoes de forma continuada, bem como uma atenta e perspicaz reaccao por parte dos legisladores. Assiste-se verdadeiramente na industria das telecomunicacoes a um movimento relacionado com a convergencia para as redes IP (“Internet Protocol”, ou Protocolo de Internet).

Management Driven Hybrid Multicast Framework for Content Aware Networks

The need for better adaptation of networks to transported flows has led to research on new approaches such as content aware networks and network aware applications. In parallel, recent developments of multimedia and content oriented services and applications such as IPTV, video streaming, video on demand, and Internet TV reinforced interest in multicast technologies. IP multicast has not been widely deployed due to interdomain and QoS support problems; therefore, alternative solutions have been investigated. This article proposes a management driven hybrid multicast solution that is multi-domain and media oriented, and combines overlay multicast, IP multicast, and P2P. The architecture is developed in a content aware network and network aware application environment, based on light network virtualization. The multicast trees can be seen as parallel virtual content aware networks, spanning a single or multiple IP domains, customized to the type of content to be transported while fulfilling the quality of service requirements of the service provider.