953 resultados para SHELL-CORONA MICELLES
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Dissertação para obtenção do Grau de Mestre em Engenharia Civil - Perfil Estruturas
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Self-assembly is a phenomenon that occurs frequently throughout the universe. In this work, two self-assembling systems were studied: the formation of reverse micelles in isooctane and in supercritical CO2 (scCO2), and the formation of gels in organic solvents. The goal was the physicochemical study of these systems and the development of an NMR methodology to study them. In this work, AOT was used as a model molecule both to comprehensively study a widely researched system water/AOT/isooctane at different water concentrations and to assess its aggregation in supercritical carbon dioxide at different pressures. In order to do so an NMR methodology was devised, in which it was possible to accurately determine hydrodynamic radius of the micelle (in agreement with DLS measurements) using diffusion ordered spectroscopy (DOSY), the micellar stability and its dynamics. This was mostly assessed by 1H NMR relaxation studies, which allowed to determine correlation times and size of correlating water molecules, which are in agreement with the size of the shell that interacts with the micellar layer. The encapsulation of differently-sized carbohydrates was also studied and allowed to understand the dynamics and stability of the aggregates in such conditions. A W/CO2 microemulsion was prepared using AOT and water in scCO2, with ethanol as cosurfactant. The behaviour of the components of the system at different pressures was assessed and it is likely that above 130 bar reverse microemulsions were achieved. The homogeneity of the system was also determined by NMR. The formation of the gel network by two small molecular organogelators in toluene-d8 was studied by DOSY. A methodology using One-shot DOSY to perform the spectra was designed and applied with success. This yielded an understanding about the role of the solvent and gelator in the aggregation process, as an estimation of the time of gelation.
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The Cutia-nut (Couepia edulis Prance), a species originally from the Amazon region, has a kernel with reasonable nutritional value and a hard and thick woody shell that constitute most of the fruit. After the kernel removal, the shells are regarded as waste. The possibility of using such shells, as raw material for burning or charcoal production, as well as milled residue for structural reinforcement materials is quite feasible, considering environmental and economical aspects. There is, however, a complete lack of characterization of the Cutia-nut shell and other similar species which can aggregate desirable qualities for application as engineering material. In this study some analyses are presented aiming at providing information for potential uses of these residues. In general, the shells follow a regular shape with certain dimensional proportionality to the kernel. The shell is a fibrous material with high lignin content, present low water absorption and high resistance to natural degradation.
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Magdeburg, Univ., Fak. für Naturwiss., Diss., 2010
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[s.c.]
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no.23(1926)
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Morphometric characters of two populations of Difflugia corona Wallich, 1864 collected in two climatic stations (Spring, Autumn) in lentic environments of Chaco Province, Argentina, are studied. In the first climatic station it was registered specimens of bigger size; in the second, the size of the individuals was very below the minimum values registered. It is suggested a possible relationship between the size of the organisms and the availability of the inhabitable vegetable substratum.
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Shell selection by the hermit crab Paguristes tortugae Schmitt, 1933 from Anchieta Island (Brazil) was analyzed using the six most frequently occupied shell species in the field and taking into account the sexual condition of the individuals, the shell size and the shell species. The experiments were conducted under laboratory conditions and the shell species preference was estimated on the basis of the frequency that each species was chosen by the individuals. The preferred shell species and size were determined by regression analysis. The highest correlation coefficients were obtained for the relations between the hermit dimensions and shell dry weight. The ovigerous females preferred shells with larger internal volume: Leucozonia nassa (Gmelin, 1791) and Cerithium atratum (Born, 1778). In the experiment of shell size, males preferred heavier shells whereas females selected the shape characteristics of the shell, such as the aperture and the internal volume, which are probably related to the growth and offspring guarantee, respectively. In general, and independent of sex condition, P. tortugae showed significant selection among all shells utilized. The results suggest that shell selection by P. tortugae involves sexual and reproductive condition preferences.
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We evaluated the gastropod shell utilization pattern of the hermit crab Clibanarius vittatus (Bosc, 1802) at Pescadores Beach in São Vicente, State of São Paulo, Brazil. Specimens were collected monthly from May 2001 through April 2003, in the intertidal zone at low tide. The crabs were weighed and their carapace shield length measured. All gastropod shells were identified and had their shell biometric parameters (total length and aperture length) measured (mm) and weighed (g). A total of 2,344 hermit crabs (644 males, 1,594 females, 45 ovigerous females and 61 individuals in intersex), using 13 species of gastropod shells, were collected. Stramonita haemastoma (Linnaeus, 1767), Cymatium parthenopeum (Von Salis, 1793) and Achatina fulica (Bowdich, 1822) comprised over 98% of all the shells. Male and intersex crabs were significantly larger than the females. This size difference strongly influenced the shell utilization pattern, principally in A. fulica, which has the largest shell size, that was only used by males and intersexual individuals of C. vittatus. Cymatium parthenopeum was the only shell species that showed a high determinant coefficient in all the biometric correlations evaluated. The high abundance of S. haemastoma shells and a strong correlation between crab size and shell aperture length established by a significant determination coefficient, indicated that C. vittatus uses this species as the principal resource for shell occupation at Pescadores Beach.
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The purpose of this short note is to prove that a stable separable C*-algebra with real rank zero has the so-called corona factorization property, that is, all the full multiplier projections are properly in finite. Enroute to our result, we consider conditions under which a real rank zero C*-algebra admits an injection of the compact operators (a question already considered in [21]).
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Estudi realitzat a partir d’una estada Istituto di Storia dell'Europa Mediterranea - CNR, Itàlia, entre 2006 i 2008. L’objectiu principal d’aquest projecte és profunditzar en el coneixement de les relacions de poder que es teixeixen entre la Monarquia, les assemblees de Corts i les ciutats de la Corona d’Aragó durant el regnat d’Alfons el Magnànim. La recerca ha permès elaborar un estudi comparatiu de les dites relacions entre els estats italians i els territoris peninsulars de l’esmentada Corona, donant un pes rellavant a la documentació urbana dels territoris italians, escassament estudiada fins al moment. Un altre punt clau d’aquest estudi és l’anàlisi de la figura del síndic enviat a corts, essent el representant municipal a les dites assemblees el nexe d’unió entre la ciutat, els tres estats i el rei. Des del punt de vista metodològic, s’ha prioritzat l’estudi documental i bibliogràfic sobre Sardenya, si bé també s'ha procedit a un estudi sobre les fonts del Regne de Sicília i de Nàpols. Els resultats d’aquest treball es concentren especialment en la posició econòmica, prosopografia i estratègies de poder de l’elit que controla el govern municipal de les ciutas reials, així mateix com en el tipus de relació que aquest grup social estableix amb la monarquia i l’administració reial. Les conclusions assenyalen que el poder de la monarquia sobre les seves ciutats a Sardenya durant aquest període és major respecte a altres estats ibèrics de la Corona, en especial Catalunya. D’altra banda, l’elit que controla el govern urbà presenta un grau d’enobliment també superior, lligat al fet de la recent conquesta de l’illa. Els sistemes electius dins del municipi són pràcticament idèntics als catalans (...)
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Two new spumellarian radiolarian genera, Mendacastrum and Domuzdagia, are described from the lower Tithonian and lower Pliensbachian respectively. Both have a spherical cortical shell of actinommid type and a spherical or subspherical double medullary shell with the inner medullary shell of hagiastrid s.l. type. The inner medullary shell of Mendacastrum is of dactyliosphaerid or higumastrid s. sit. type, whereas that of Domuzdagia is of angulobracchiid type. Since they cannot be assigned to any described Mesozoic pyloniacean families, they are considered as type genera of two new families: Mendacastridae and Domuzdagiidae respectively.
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A new technique for fixation of Biomphalaria glabrata for histologic studies is described. It consists in performing several external holes in the shell, before placing the entire snail into the fixative. It is a very practical and quick procedure that showed excellent results when compared to the usual techniques.