Effect of Cyclic Topology on Charge-Transfer Properties of Organic Molecular Semiconductors: The Case of Cycloparaphenylene Molecules

We have studied the role played by cyclic topology on charge-transfer properties of recently synthesized π -conjugated molecules, namely the set of [n]cycloparaphenylene compounds, with n the number of phenylene rings forming the curved nanoring. We estimate the charge-transfer rates for holes and electrons migration within the array of molecules in their crystalline state. The theoretical calculations suggest that increasing the size of the system would help to obtain higher hole and electron charge-transfer rates and that these materials might show an ambipolar behavior in real samples, independently of the different mode of packing followed by the [6]cycloparaphenylene and [12]cycloparaphenylene cases studied.

Forest typology of broadleaf forests from Sierra Maestra, Eastern Cuba

A phytosociological study of the forests from Sierra Maestra is conducted, following the methodology of the Zurich- Montpelier School. They are transformed into a forest typology using the standards of the Institute of Agro-Forestry Research. In general, 35 types and/or subtypes are presented. From this group, the most abundant ones belong to semi-deciduous microphyll forest, followed by those from mangroves and mountain rainforest, respectively. Silvicultural treatments are needed; among them, the protection forests are those found above 800 m asl and mangroves. 

Quintus Curtius before his sources: the episode of Alexander and the Scythians on the Tanais

Quintus Curtius found in his sources a speech where a Scythian censured Alexander, followed by the King’s reply. Curtius drastically abridged this second discourse in order to highlight the criticism of the Macedonian. The Scythian’s words have a striking rhetorical language and some allusions taken from Greek literature, in addition to possible indirect references to Caligula. Curtius declares that he follows his source word-for-word aiming to justify these inconsistencies, but also trying to hide the manipulations he has done to achieve his own narrative purposes.

El proceso de la elaboración de los códices "Borgia" y "Vaticano B" basado en su estudio codicológico

El objetivo de este artículo es presentar las observaciones realizadas durante la consulta de los originales de los códices Borgia (Borg. Mess. 1) y Vaticano B (Vat. Lat. 3773) en la Biblioteca Apostólica Vaticana en 2014. Este estudio codicológico, aunque a la fuerza parcial, dado que fue realizado solamente por medio de una observación directa, revela nuevos datos acerca de la elaboración de los manuscritos prehispánicos, tanto en la preparación de la piel como soporte como en los procedimientos aplicados a la hora de trazar las imágenes y corregir las equivocaciones.

El valor mitográfico del "Anonymi in Statii Achilleida commentum"

El breve commentum in Statii Achilleida resulta muy interesante para el estudio de la transmisión mitográfica de la Antigüedad tardía al Medievo, pues no sólo participa de las características propias de la mitografía (narraciones de mitos, exégesis racionalista y/o alegórica, interpretaciones etimológicas, anonimato, pseudepigrafía,…), sino que también es otro eslabón en la cadena textual de transmisión, simplificación y canonización de los mitos clásicos.

Justicia juvenil a debate

A los 15 años de ponerse en marcha la L.O. 5/2000 de responsabilidad penal de los menores es necesario realizar una revisión de sus logros y deficiencias. Para ello se repasarán las distintas formas de implementación que ha tenido esta ley en las comunidades autónomas de nuestro páis.

Systematic Improvement of Density Functionals through Parameter-Free Hybridization Schemes

It is suggested here that the ultimate accuracy of DFT methods arises from the type of hybridization scheme followed. This idea can be cast into a mathematical formulation utilizing an integrand connecting the noninteracting and the interacting particle system. We consider two previously developed models for it, dubbed as HYB0 and QIDH, and assess a large number of exchange-correlation functionals against the AE6, G2/148, and S22 reference data sets. An interesting consequence of these hybridization schemes is that the error bars, including the standard deviation, are found to markedly decrease with respect to the density-based (nonhybrid) case. This improvement is substantially better than variations due to the underlying density functional used. We thus finally hypothesize about the universal character of the HYB0 and QIDH models.

Is Spain Different? Innovation systems in the long-term development of the tourism sector. The IBEROSTAR case study.

Tourism is a highly competitive sector which is characterized by permanent transformation. Therefore, tourism firms depend largely on innovation to adapt themselves and compete, ensuring their survival and competitiveness. Despite research on innovation concludes that tourism firms are in most cases only moderately innovative, there are outstanding exceptions in specific fields and destinies. Spain, which is an unquestionable leader in tourism, constitutes one of them. In fact, Spanish tourism firms have shown a strong innovation capacity. They have improved and diversified their products thus meeting the requirements of a changing demand. This raises the need to properly understand how and why innovation takes place and who is involved in such a process. This paper aims to address these questions through the case study of one of the largest Spanish hospitality firms. The long history of Iberostar Group confirms that family firms and the networks they provide, along with environments that foster competition as was the case of the Spanish tourism industry, are important determinants of innovation particularly in a late-developed country.

José Segovia Pérez, Director General de Enseñanzas Medias : diálogo con Felipe B. Pedraza Jiménez.

Entrevista con José Segovia Pérez, Director General de Enseñanzas Medias, en la que se aborda la nueva situación como Director General y sus aspiraciones en cuanto a la reforma de las enseñanzas medias, su vocación universitaria, el papel de la psicología en la educación, del profesorado y las modificaciones necesarias para alcanzar la reforma política, entre otras.

Proyecto curricular de segundo ciclo de educación primaria.

El desarrollo curricular se realiza en el centro y ha de constituir un proceso de investigación del propio profesorado. Sirve para establecer una revisión de la fundamentación a la luz de la práctica, así como un replanteamiento de ésta. La formulación del proyecto curricular ha de convertirse a la vez en un isntrumento de renovación para el profesorado. La escuela aquí juega un papel como agente de cambio. La presente propuesta curricular, además de transmitir conocimientos, habilidades y actitudes, pretende ayudar al alumnado a interpretar las tendencias objetivas del desarrollo humano y social, y a discernir sobre ellas de forma que les capacite para tomar la opción más racional y beneficiosa para todos, en un marco ético maduro y equilibrado.

Pagos de una capellanía a Diego Pérez de Oviedo

Registro de los pagos realizados por Juan Jiménez administrador de la rentas del Colegio Mayor del Rosario al cura de la Catedral Diego Pérez de Oviedo entre 1715- 1727 por una capellanía que se debía pagar al presbítero Juan Pingaron quien se encontraba en España.