Risk management measures for REACH registered intermediate substances in pulp mill

Tämän työn tavoitteena on antaa kuvaus riskinhallintamenetelmistä viidelle välituotekemikaalille, joita käytetään Stora Enson Imatran tehtailla. Välituotekemikaalit ovat mustalipeä, viherlipeä, valkolipeä, natriumbisulfiitti ja natriumsulfiitti. Nämä kemikaalit ovat jo rekisteröityjä ECHA:an ja rekisteröintiin liittyen ECHA:an on toimitettava myös kuvaus riskinhallintamenetelmistä. Työn alussa kuvaillaan työn kannalta olennaiset säädökset ja viranomaiset, jotka valvovat kemikaalien käyttöä ja valmistusta Euroopan Unionin alueella. Tämän jälkeen kerrotaan yleisesti välituotekemikaalien rekisteröintikriteereistä. Työn loppuosa käsittää kuvauksen riskinhallintamenetelmistä jokaiselle kemikaalille. Riskinhallintamenetelmät sisältävät eristyksen teknisin keinoin, menettelytapa- ja valvontatekniikat, johtamistavat ja henkilökunnan koulutuksen ja välituotekemikaalien kuljetuksen. Myös jokaisen kemikaalin ominaisuudet on kuvattu ja lyhyt prosessikuvaus kemikaalien valmistuksesta ja käytöstä on esitetty helpottamaan ymmärtämistä.

Maritime safety in the Gulf of Finland. Evaluation of the regulatory system

Growing traffic is believed to increase the risk of an accident in the Gulf of Finland. As the consequences of a large oil accident would be devastating in the vulnerable sea area, accident prevention is performed at the international, regional and national levels. Activities of shipping companies are governed with maritime safety policy instruments, which can be categorised into regulatory, economic and information instruments. The maritime regulatory system has been criticised for being inefficient because it has not been able to eliminate the violations that enable accidents. This report aims to discover how maritime governance systems or maritime safety policy instruments could be made more efficient in the future, in order to improve the maritime safety level. The results of the research are based on a literature review and nine expert interviews, with participants from shipping companies, interest groups and authorities. Based on the literature and the interviews, a suggestion can be made that in the future, instead of implementing new policy instruments, maritime safety risks should be eliminated by making the existing system more efficient and by influencing shipping companies’ safety culture and seafarers’ safety related attitudes. Based on this research, it can be stated that the development of maritime safety policy instruments should concentrate on harmonisation, automation and increasing national and cross-border cooperation. These three tasks could be primarily accomplished by developing the existing technology. Human error plays a role in a significant number of maritime accidents. Because of this, improving companies’ safety culture and voluntary activities that go beyond laws are acknowledged as potential ways of improving maritime safety. In the future, maritime regulatory system should be developed into a direction where the private sector has better possibilities to take part in decision-making.

Kuluttajapalveluita tarjoavien yritysten turvallisuuskulttuurin kehittäminen

Tällä tutkimuksella oli tavoitteena selvittää kuluttajapalveluita tarjoavien yritysten turvallisuuskulttuurin taso sekä mahdollisuuksia tason kehittämiseksi. Turvallisuuskulttuuria ja miten se kytkeytyy kuluttajaturvallisuuteen, käsiteltiin teorian kautta. Samalla luotiin yleiskatsaus turvallisuusajattelun kehitykseen Suomessa. Turvallisuuskulttuurin taso selvitettiin kyselytutkimuksella kuluttajapalveluita valvoville viranomaisille. Samalla saatiin katsaus myös siihen, millaisia menetelmiä valvonnan käytössä on ollut ja kuinka aktiivisesti esimerkiksi jälkivalvontaa on tehty. Kyselyn perusteella turvallisuuskulttuuri on tasolla, jolla pyritään vain täyttämään lainsäädännön ja viranomaisten antamat vaatimukset. Tason korottamiseksi löytyi mahdollisuuksia niin viranomaisten valvontaa ajatellen kuin myös toiminnanharjoittajille. Tällaisia mahdollisuuksia ovat muun muassa toiminnanharjoittajille yhteisesti järjestettävät koulutustilaisuudet. Toiminnanharjoittajilla kokonaisturvallisuusjohtaminen ja laatuajattelu pitää sisällään usein työturvallisuus-, työterveys- ja ympäristöasioita. Mikäli tätä ajattelua laajentaa asiakasnäkökulmalla, lisäisi se kuluttajaturvallisuutta kokonaisuudessaan. Oman haasteen kuluttajaturvallisuuden kehittymiseen tuo mukanaan valvonnan valtiollistaminen ja etenkin sen käytännön toteuttaminen.

L'exception de non-subrogation: l'influence de ses principes justificatifs sur sa mise en oeuvre

À la lecture de l'article 2365 c.c.Q., le créancier et la caution ne peuvent pas percevoir les droits et les libertés que ce texte concrétise à leur encontre ou à leur profit. Pour pallier ce problème, les auteurs et la jurisprudence ont alors laissé place à leur imagination afin de tenter de classifier cette disposition à l'intérieur d'institutions juridiques éprouvées, le tout en vue de démythifier le contenu de la règle de droit. Pour notre part, nous considérons que l'exception de non-subrogation est une notion originale en soi, qui trouve sa source à l'intérieur même de son institution. La thèse que nous soutenons est que l'exception de non-subrogation, mode de libération qui a pour mission de combattre le comportement opportuniste, cristallise l'obligation de bonne foi en imposant implicitement au créancier une obligation de bonne subrogation. Tout manquement du créancier à cette obligation a comme conséquence de rendre le droit de créance du créancier irrecevable à l'égard de la caution devant les tribunaux. Ce précepte éclaircit le contexte de l'article 2365 C.c.Q. et, par le fait même, il permet de délimiter le contour de son domaine et de préciser ses conditions d'application. L'exception de non-subrogation est un mécanisme juridique qui date de l'époque romaine. Elle est maintenant intégrée dans presque tous les systèmes juridiques du monde, tant en droit civil qu'en common law. Dans la législation québécoise, elle s'est cristallisée à l'article 2365 C.c.Q. Il s'agit d'une disposition d'ordre public qui ne peut être invoquée que par la caution. Son application dépend du cumul de quatre conditions: 1) le fait du créancier; 2) la perte d'un droit subrogatoire; 3) le préjudice de la caution; 4) le lien causal entre les trois derniers éléments. Lorsque ces quatre conditions sont remplies, la caution est libérée de son engagement dans la mesure du préjudice qu'elle subit.

La négociation de l’identité organisationnelle : une étude narrative du travail des employés de Médecins Sans Frontières

Ce mémoire de maîtrise porte sur le concept d’identité organisationnelle, appliqué au milieu des organisations humanitaires. Le contexte mondial actuel dans lequel évoluent ces organisations leur impose de revoir certaines de leurs valeurs et façons de faire. En effet, les équipes des ONG sur le terrain sont confrontées à des conflits de plus en plus nombreux et complexes, qui remettent en question l’identité de leur organisation. Cette recherche vise à dresser un portrait du travail des employés de l’organisation Médecins Sans Frontières (MSF) lors de missions humanitaires, alors que ceux-ci doivent justifier et négocier la présence de l’organisation auprès de la population et des autorités locales. En nous basant sur le concept de sensemaking développé par Karl E. Weick, nous présentons une analyse narrative des récits de mission de cinq employés de MSF. Cette analyse permet d’étudier comment, au quotidien, les employés d’une ONG le terrain sont impliqués dans des négociations où l’identité organisationnelle est continuellement menacée et remise en question.

Legal Control of Industrial Pollution

Industries constitute the main spring of development. Without industrial development no country could reach a stage in which a decent living for its citizens would be achieved. Increasing production to meet the basic needs of society augmented scientific invention and machine oriented industrial order.Environmental pollution ls a burning global issue. It is more serious and dangerous than terrorism. Started with the discovery of fire and development of civilization. Pollution went unnoticed throughout the centuries of human growth until its adverse effects on human environment become explicit.National concern tor environment started in our country only atter the cause of protection of environment received global attention. At present legal control ot industrial pollution is in a scattered framework of piece meal processes with overlapping provisions and authorities.Environmental protection- should be an item not only in the concurrent list of schedule 7 to the Constitution but also in the list of matters entrusted to the panchayati institutions in the Schedule 11. It is heartening to note that so far as municipalities are concerned the Constitution of India lives up to the expectation. In the wake of New Industrial Policy based on liberalisation a long list of small scale industries fall outside the purview of environmental clearance. The Indian concept of environmental im»act assessment introduced under the Environment Act by notification excludes the entire gamut of small scale industries and r.elates only to scheduled industries covered by the notifica~ion. Most of them are subjected to ETA only it the investment goes above ~.50 crores. This provision dilutes the impact assessment considerably A mandatory impact assessment with public partiCipation and with provision for a review by specialized environmental courts will eliminate the possible evils of this judicial passiveness.

Emergence of a small-world functional network in cultured neurons

The functional networks of cultured neurons exhibit complex network properties similar to those found in vivo. Starting from random seeding, cultures undergo significant reorganization during the initial period in vitro, yet despite providing an ideal platform for observing developmental changes in neuronal connectivity, little is known about how a complex functional network evolves from isolated neurons. In the present study, evolution of functional connectivity was estimated from correlations of spontaneous activity. Network properties were quantified using complex measures from graph theory and used to compare cultures at different stages of development during the first 5 weeks in vitro. Networks obtained from young cultures (14 days in vitro) exhibited a random topology, which evolved to a small-world topology during maturation. The topology change was accompanied by an increased presence of highly connected areas (hubs) and network efficiency increased with age. The small-world topology balances integration of network areas with segregation of specialized processing units. The emergence of such network structure in cultured neurons, despite a lack of external input, points to complex intrinsic biological mechanisms. Moreover, the functional network of cultures at mature ages is efficient and highly suited to complex processing tasks.

Resilience of protein-protein interaction networks as determined by their large-scale topological features

The relationship between the structure and function of biological networks constitutes a fundamental issue in systems biology. Particularly, the structure of protein-protein interaction networks is related to important biological functions. In this work, we investigated how such a resilience is determined by the large scale features of the respective networks. Four species are taken into account, namely yeast Saccharomyces cerevisiae, worm Caenorhabditis elegans, fly Drosophila melanogaster and Homo sapiens. We adopted two entropy-related measurements (degree entropy and dynamic entropy) in order to quantify the overall degree of robustness of these networks. We verified that while they exhibit similar structural variations under random node removal, they differ significantly when subjected to intentional attacks (hub removal). As a matter of fact, more complex species tended to exhibit more robust networks. More specifically, we quantified how six important measurements of the networks topology (namely clustering coefficient, average degree of neighbors, average shortest path length, diameter, assortativity coefficient, and slope of the power law degree distribution) correlated with the two entropy measurements. Our results revealed that the fraction of hubs and the average neighbor degree contribute significantly for the resilience of networks. In addition, the topological analysis of the removed hubs indicated that the presence of alternative paths between the proteins connected to hubs tend to reinforce resilience. The performed analysis helps to understand how resilience is underlain in networks and can be applied to the development of protein network models.

Bens patrimoniais e escolas públicas: uma aproximação necessária

Este trabalho busca colocar em foco a necessidade do estreitamento dos laços entre instituições educacionais públicas e bens tombados. Mostra ainda que seus efeitos fortalecem o latente sentimento de pertencimento - existente nos jovens alunos com relação a esses tombados - ampliam conhecimento, desenvolvem sua capacidade, atitude e valores por meio da educação patrimonial.Como apresenta a pesquisa aplicada aos professores de algumas unidades do Colégio PII, aos alunos pertencentes ao programa PIC-JUNIOR - realizado em parceria com o Museu Nacional - às autoridades das respectivas instituições e funcionários do Museu que atendem ao público na construção e parque tombados, o trabalho levanta opiniões e interesses necessários à realização de um debate sobre a valorização do patrimônio como recurso educacional.Nessa linha de desenvolvimento ganha realce o mapeamento que expressa o interesse dos alunos, professores e autoridades quanto à necessidade da construção de vínculos de aproximação entre instituições escolares e as existentes em bens tombados. Propõe-se, então, a realização de um projeto cívico, educacional e cultural que, no entanto, só se tornará possível por meio de parcerias onde todos os envolvidos, dotados de sentimento público, colaborem ativamente no objetivo.Consubstanciando tais formulações o trabalho investe na valorização dos bens patrimoniais, bem como na construção de identidades sociais, coerentes com referenciais de igualdade, direito, justiça social, cidadania e espaço público. Para tanto o palco inicial às articulação são as instituições, construções bem como os protagonistas citados.Finalmente recebe destaque um projeto básico envolvendo educação patrimonial, cuja formação confere aos participantes conhecimentos sobre bens tombados, ampliando os da história do patrimônio em questão, capacitando-os com agentes multiplicadores, que passam esse saber a colegas de aula, amigos, familiares e às comunidades que pertencem.Palavras chave: Bens patrimoniais, escolas públicas, educação patrimonial, Programa PIC-JUNIOR.

Comércio internacional, politica comercial brasileira e a atuação da Câmara de Comércio Exterior (CAMEX) na condução das políticas para o setor

The proposal of this study is to present an assessment of the performance of the Brazilian Government Chamber of Foreign Trade (Camex), which is a board of the Council of Government responsible for the formulation, implementation and coordination of the Brazilian trade policy. The study begins with a historical approach to the international trade and the Brazilian foreign trade, mentioning its origins, features and interfaces with the economic development of the country. Based on the approach aforementioned, several interviews were made with authorities, who have remarkable knowledge about the subject, in order to obtain their views, experiences and suggestions concerning the performance of Camex since its creation in 1995. The list of interviewees includes authorities that are currently responsibles for the conduct of the policy on foreign trade, representatives of the organized society, and authorities who were in important positions in this segment of the federal public administration, regarding both the Minister of State, as Director of Cacex and the Executive Secretary of Camex. The conclusions of the study indicate that the Camex has not been succeeding in fully exercise its mandate of formulate, implement and coordinate the foreign trade policy of Brazil. A combination of factors contributes to this situation, especially its small strutcure, the fact that some ministries compete in the segment of foreign trade ¿don't understand¿ Chamber¿s real purpose, and, at last, the absence of a political mandate"(words taken from Motta Veiga) that would fortify its existing legal mandate. Finally, the study suggests some changes in the current organizational modeling of Camex, especially in its hierarchical position in the federal public administration."

Impacto das privatizações nas relações trabalhistas e sindicais - estudo comparativo de três casos ocorridos no sudeste brasileiro

O presente estudo discute o movimento das privatizações recentemente ocorridas e seus impactos nas relações trabalhistas e sindicais brasileiras. A discussão está focada em estudo de caso de três organizações, pertencentes a ramos de negócio diferentes e busca entender os reflexos havidos nas relações entre os agentes SOCIaIS envolvidos: empregados, empregadores, gerentes, sindicatos e autoridades. O fenômeno estudado se situa a partir da década de noventa e trás conseqüências ao movimento trabalhista, ao emprego e às relações capital e trabalho pelo potencial de conflito que as privatizações apresentam. Para organizar o pensamento desenvolvemos uma abordagem histórica que mostra o desenvolvimento das relações trabalhistas, com as organizações aperfeiçoando os instrumentos de regulação de conflito e construindo, com os empregados, uma considerável experiência de convivência ainda que marcada por interesses imediatos conflitantes. Um pouco à frente observamos uma ruptura que é explicitada pela definição do modelo vigente, pela internacionalização da economia que é imposta como um determinismo histórico e pela necessidade de sobrevivência das empresas submetidas à globalização e competição sem fronteiras. Ainda procuramos entender o movimento de flexibilização dos direitos trabalhistas que de algum modo se constituem em obstáculo à equalização competitiva dos custos das empresas e estão a sofrer forte pressão para que possam se adequar às novas realidades econômicas e necessidades empresariais. Na narrativa dos fatos apontamos erros e acertos observados e, de forma crítica, sugerimos alternativas aos modelos políticos e gerenciais adotados.

Relações civis-militares e as leis de acesso a informação na América Latina e no Brasil

Na América Latina, um vasto legado de regimes militares tem contribuído para o fortalecimento de uma cultura de sigilo nos governos. Além da defesa da pátria contra a ameaça comunista, a maioria destes golpes se deveu a um senso de dever das Forças Armadas em preservar o Estado. Deste ponto de vista, os próprios militares seriam os mais qualificados para determinar quando e como intervir na ordem política interna. No entanto, justificar a intervenção militar na ordem política interna é sempre um empreendimento repleto de contradições e riscos graves para a liberdade. Este contexto levou os estudiosos e autoridades a repensarem o controle civil sobre os militares, e a redefinirem os papéis das forças armadas. Neste processo de consolidação da democracia, os militares ainda mantêm alguns poderes políticos e de veto dentro dos governos civis. O controle civil democrático das Forças Armadas na América Latina enfrenta a falta de incentivos políticos para os civis a se envolverem e se especializarem no assunto, já que não há ameaças internas, quer externas observadas. De fato, a região tem sido considerada como uma "zona de paz", onde os esforços diplomáticos prevaleceriam sobre conflitos armados. A promulgação de leis de acesso à informação pública (LAI) abre uma maneira inteiramente nova de escrutínio público – uma democracia monitorial, que afeta diretamente a autonomia militar e sua cultura organizacional. No estudo do surgimento e da força legal das LAI na América Latina, as relações entre civis e militares não foram consideradas em profundidade como um fator influente. Buscou-se traçar uma relação entre, por um lado, a existência de LAI, a data de aprovação da LAI e sua força geral e exceções, e por outro lado, as relações civis-militares na América Latina. Um número considerável de países suporta que as relações civis-militares influenciam a regulamentação das exceções e o momento em que a lei foi aprovada. Há uma tendência geral na América Latina a adotar LAI fracas na regulamentação de exceções. Também foi feito um estudo de caso do Brasil, país muito representativo da influência militar na política. Concluiu-se que as relações entre civis e militares no Brasil foram um fator de grande influência na aprovação final da LAI no país. Este estudo contribui para a construção de uma ponte entre as agendas de pesquisa de transparência e de relações civis-militares, com várias possibilidades de estudos de casos comparados.

Entre a fé, a obra social e a publicidade: uma análise crítica do discurso da responsabilidade social da Igreja Universal do Reino de Deus

Situated on Applied Linguistics (PENNYCOOK, 1998; MOITA LOPES, 2003, 2006, 2008, 2009), this thesis, which is inscribed in a qualitative-interpretative approach of a critical analysis perspective , lies on the speech of social responsibility and the way like that is employed in seeking for legitimacy and prestige within the neopentecostal brazilian religious field, more specifically of the Universal Church of the Kingdom of God. The general goal of this research is t reflect upon the speech on social responsibility and the rethoric of selfpromotion of the Universal Church through the role of social actors in the making of his her identities, materialized in the newspaper Folha Universal. In order to achieve that, we have conjugated, in this research, social and discursive analysis. On the linguistic-discursive approach, the research is based on the Critical Analysis of Discourse (ACD), specially in Fairclough (2001, 2003, 2006), a proposal that provides theoretical-methodological tools to investigate the language beyond the linguistic structures , that is, the discourse, social practices in which it occurs and more ample structures. Theoretical assumptions were also used of Sistemico-Functional Linguistics(LSF), matching with categories of the Transitivity System of Halliday (1994, 2004), of the forms of representation of social actors in the socioeconomic perspective by Van Leeuwen (1997, 2008) and of the Appraisal system by Martin and White (2005). As we develop the argumentation on thesobre social role of religion in this thesis, we make use of the authors such as Freston (1994), Oro (1997, 2003), Campos (1996, 1999), Mariano (1999), Meneses (2008), among several ones. We have also used a series of concepts and categories coming from the field of communication and marketing on the business social responsability and social marketing . In this area, we take as references the contributions of Bueno (2003), Fossá and Sartoretto (2003) and Zenone (2006). The corpus of the work is framed by news taken at the newspaper Folha Universal, in which are given the social responsibility actions of the church . The timeframe used was on the editions of 2010 thru 2012. Results found at he analysis of the News lead to semantic features of Assessment of Affection, Judgment and Appreciation, many times followed by Gradation, and the Attribution, one of the subsystems of the Attachment, are evidence of positive assessments for the Universal Church and its agents and make up rethorical elements which provide structure for the discourse of the Universal Church at the newspaper Folha Universal consisted of its image (style) of social responsibility . Results show that the most frequente social actors of the discourse are, on one hand, the Universal Church itself and its volunteers, famous (actors, actresses, presenters), politicians and authorities, on the other hand, the population which was helped by the Church social projects . The first group seems to be Always activated, however the second one, most of the time rather passive. These are also represented by assimilation in most of the occurrences, however the other ones by individualization and nomination entitled by honorification, except for the volunteers that are represented either as an individual, or as a group

Stpahylococcus aureus biofilms on central venous haemodialysis catheters

As infecções devido a biofilmes bacterianos são comuns em pacientes sob tratamento em hemodiálise. Neste estudo, 16 pacientes (7 homens, 9 mulheres, de 22 a 81 anos, média 50 anos de idade), com um total de 25 cateteres de hemodiálise (3 de triplo-lúmen e 22 de duplo-lúmen) de poliuretano inseridos em veia subclávia foram estudados. Os cateteres permaneceram no local de 3 a 91 dias (média de 47 dias). Os cateteres foram removidos devido ao: mau funcionamento (44%), suspeita de infecção relacionada ao cateter (20%), viabilidade de um acesso permanente (16%), remoção acidental (12%), sinais e sintomas de infecção no local da inserção do cateter (4%) e contaminação exógena (4%). Culturas positivas de ponta foram observadas em sete cateteres (28%), concomitantemente com três culturas positivas de sangue. Das culturas de sangue foram identificados Staphylococcus aureus (12%) e de uma das conexões foi isolado S. aureus. Biofilmes foram observados sobre todas as pontas de cateteres. Os S. aureus isolados do sangue e cateter (ponta e conexão) eram resistentes a pencilina e sensíveis a azitromicina, ciprofloxacina, clindamicina, cloranfenicol, gentamicina, oxacilina, rifampicina, sulfametoxazole, tetraciclina e vancomicina. As cepas de S. aureus isoladas de sangue, ponta de cateter e conexão foram consideradas idênticas devido à coincidência do perfil de sensibilidade. E similaridade genética, avaliada por meio de ribotipagem.

A Produção do Flagelo : a re-produção do espaço social da seca na cidade de Mossoró (1877-1903-1915)

The great droughts re- produced spaces in the city of Mossoró / RN in the end of the nineteenth century to the beginning of the twentieth century. Its dimension exceeds the climatic effects becoming social locus when advances over the political and economic sectors, social and cultural of the North / Northeast Brazilian societies during that period. This way, analyzing the re-production of social space in episodes of Mossoró‟s droughts is our toil. So try to reveal each segment, route and aspect of production of space in its size and interface between the perceived, conceived and lived, and subjects related to it - refugees, population and authorities - during the droughts of 1877, 1903 and 1915 within Mossoró city. Therefore, issues such as the constitution and representation of the city and social space in the terrifying experience of the drought of 1877, the production of fixed objects and flows of the urban web through of migrant labor, attempts to control, discipline and spatial planning and ways to resistance to these charges in daily sphere are key issues addressed in this work. For this we use diverse sources as minutes of the city council, reports from provincial presidents, media, memory books and others that sustain us in building our narrative and problematic. This way, the spatial production of Mossoró‟s droughts reveals itself in the field of relations and political-economic transformations and sociocultural, inextricably, that shapes and mobilizes your own social space