Geochemistry of phosphatic crusts from the shelf off Peru

Authigenic phosphorite crusts from the shelf off Peru (9°40°S to 13°30°S) consist of a facies with phosphatic coated grains covered by younger phosphatic laminite. The crusts are composed of carbonate fluorapatite, which probably formed via an amorphous precursor close to the sediment water interface as indicated by low F/P2O5 ratios, Sr and Ca isotopes, as well as rare earth element patterns agreeing with seawater-dominated fluids. Small negative Ce anomalies and U enrichment in the laminite suggest suboxic conditions close to the sediment-water interface during its formation. Increased contents of chalcophilic elements and abundant sulfide minerals in the facies with phosphatic coated grains as well as in the laminite denote sulfate reduction and, consequently, point to episodical development of anoxic conditions during phosphogenesis. The Peruvian phosphorites formed episodically over an extended period of time lasting from Middle Miocene to Pleistocene. Individual phosphatic coated grains show a succession of phosphatic layers with varying contents of organic matter and sulfide-rich phosphatic layers. Coated grains supposedly formed as a result of episodic suspension caused by high turbulence and shifting redox conditions. Episodic anoxia in the pore water induced pyritization in the outermost carbonate fluorapatite layer. Phosphatic coated grains were later transported to the place of crust formation, where subsequent laminite formation was favored under lower energy conditions. A similar succession of phosphatic layers with varying contents of organic matter and sulfide-rich layers in the laminite suggests a formation mechanism analogous to that of individual coated grains.

U/Th systematics of authigenic carbonates and d18O records from Hydrate Ridge, off the coast of Oregon, USA

Uranium (U) concentrations and activity ratios (d234U) of authigenic carbonates are sensitive recorders of different fluid compositions at submarine seeps of hydrocarbon-rich fluids ("cold seeps") at Hydrate Ridge, off the coast of Oregon, USA. The low U concentrations (mean: 1.3 ± 0.4 µg/g) and high 234U values (165-317 per mil) of gas hydrate carbonates reflect the influence of sedimentary pore water indicating that these carbonates were formed under reducing conditions below or at the seafloor. Their 230Th/234U ages span a time interval from 0.8 to 6.4 ka and cluster around 1.2 and 4.7 ka. In contrast, chemoherm carbonates precipitate from marine bottom water marked by relatively high U concentrations (mean: 5.2 ± 0.8 µg/g) and a mean d234U ratio of 166 ± 3 per mil. Their U isotopes reflect the d234U ratios of the bottom water being enriched in 234U relative to normal seawater. Simple mass balance calculations based on U concentrations and their corresponding d234U ratios reveal a contribution of about 11% of sedimentary pore water to the bottom water. From the U pore water flux and the reconstructed U pore water concentration a mean flow rate of about 147 ± 68 cm/a can be estimated. 230Th/234U ages of chemoherm carbonates range from 7.3 to 267.6 ka. 230Th/234U ages of two chemoherms (Alvin and SE-Knoll chemoherm) correspond to time intervals of low sealevel stands in marine isotope stages (MIS) 2, 4, 5, 6, 7 and 8. This observation indicates that fluid flow at cold seep sites sensitively reflects pressure changes of the hydraulic head in the sediments. The d18OPDB ratios of the chemoherm carbonates support the hypothesis of precipitation during glacial times. Deviations of the chemoherm d18O values from the marine d18O record can be interpreted as to reflect temporally and spatially varying bottom water and/or vent fluid temperatures during carbonate precipitation between 2.6 and 8.6°C.

Vertical flux reconstruction for sediment cores off Chile

Biogenic opal and organic carbon vertical rain rates in sediment cores reveal a strong cyclicity in the productivity of the upwelling system off presently arid northern Chile during the last 100,000 years. Changes in productivity are found to be in phase with the precessional cycle (~20,000 years) and with inputs of iron from the continent. During austral summer insolation maxima, increased precipitation and river runoff in the region appear to have brought high inputs of iron, mainly from the Andes, to the coastal ocean enhancing primary productivity there. We interpret our results as providing evidence for iron control of past productivity in this upwelling system and for a tight link between productivity and orbital forcing at midlatitudes.

The Canyon System off Fimbulisen

In der vorliegenden Arbeit werden Daten einer systematischen Vermessung in der Lazarev Sea nahe des Fimbul-Ice-Shelfs (Fimbulisen) genutzt, die während der Expedition ANT XIX-2 mit dem Fächersonarsystem Hydrosweep DS-2 und dem Sedimentecholot Parasound erhoben wurden. Nach kurzer Darstellung der Hintergründe dieser durchgeführten Untersuchungen in dem Messgebiet wird allgemein auf wesentliche Aspekte der Hydroakustik hinsichtlich der Anwendung von Echolotsystemen eingegangen. Schwerpunktmäßig soll dabei der parametrischen Effekt, das Messprinzip parametrischer Sedimentecholote, behandelt werden. Nach anschließender Anführung zweier praktischer Anwendungen hydroakustischer Messverfahren anhand des Hydrosweep DS-2 und des Parasound-Systems wird eingehend deren Positionierung auf FS 'Polarstern' dargestellt, da sich bei der Aufbereitung der Messungen zeigte, dass sich das größte Problem der Daten beider Systeme in der minderwertigen Qualität der Navigationsdaten abzeichnete. Aus den bereinigten Tiefendaten der Fächersonarmessung wird ein digitales Geländemodell (DGM) mit einer Rasterweite von 100 m generiert. Dieses Modell liegt für die weitere Bearbeitung digital und in Form einer bathymetrischen Karte im Maßstab 1:250,000 vor, bei der die Topographie des Canyon-Systems nahe dem Fimbulisen durch Isolinien mit einer Aquidistanz von 50 m dargestellt wird. Die als Ergebnis der prozessierten Parasound-Daten erhaltenen Seismogramme, die gefiltert im digitalen Bildformat mit bekannter Start- und Endposition für einen definierten Tiefenbereich vorliegen, können zusammen mit dem DGM in einem dreidimensionalen Modell dargestellt werden. Dieses in digitaler Form vorliegende Modell kann durch den Nutzer interaktiv durchschritten und die darin enthaltenen Messergebnisse in ihrer Gesamtheit sowie in Detailansichten aus verschiedenen Perspektiven betrachtet werden, was das gegenseitige Verständnis und Einschätzung der Ergebnisse aus den beiden Messverfahren fördert. Diese gemeinsame Darstellungsweise eines digitalen Geländemodells in Kombination mit den Seismogramm-Bildern des Sedimentecholotes Parasound bietet sich auch hinsichtlich einer geologischen Klassifizierung der verschiedenen Echotypen und einer anschließenden Interpretation der Sedimentationsvorgänge in einem flächenhaft vermessenen Gebiet an.

Sediment metabolism in samples off Northwest Africa

Sediments off northwest Africa were assayed for activities of the respiratory electron transport system (ETS) and for primary amino nitrogen. ETS activities were used to compute respiratory oxygen consuption, carbon oxidation, and nitrate reduction rates. Activities were correlated with depth of the water column, and their longshore distribution resembled that of euphotic zone phytoplankton productivity. Protein concentrations were closely correlated with ETS activities. Carbon biomass was calculated from protein and compared with other computed values. The carbon oxidation rate accounted for 13 % of the region's primary production.