Peter Stadler: Pestalozzi. Geschichtliche Biographie. Band 2: Von der Umwälzung zur Restauration. Zürich: Verlag Neue Zürcher Zeitung 1993 [Rezension]

Rezension von: Peter Stadler: Pestalozzi. Geschichtliche Biographie. Band 2: Von der Umwälzung zur Restauration. Zürich: Verlag Neue Zürcher Zeitung 1993, 679 S.

Symmetry reduction due to gallium substitution in the garnet Li6.43(2)Ga0.52(3)La2.67(4)Zr2O12

Single-crystal structure refinements on lithium lanthanum zirconate (LLZO; Li7La3Zr2O12) substituted with gallium were successfully carried out in the cubic symmetry space group I [Formula: see text]3d. Gallium was found on two lithium sites as well as on the lanthanum position. Due to the structural distortion of the resulting Li6.43(2)Ga0.52(3)La2.67(4)Zr2O12 (Ga-LLZO) single crystals, a reduction of the LLZO cubic garnet symmetry from Ia[Formula: see text] d to I [Formula: see text]3d was necessary, which could hardly be analysed from X-ray powder diffraction data.

Gerhard Tulodziecki: Medienerziehung in Schule und Unterricht. Bad Heilbrunn: Klinkhardt 2. Aufl. 1992 [...] [Sammelrezension]

Sammelrezension von: 1. Gerhard Tulodziecki: Medienerziehung in Schule und Unterricht. Bad Heilbrunn: Klinkhardt 2. Aufl. 1992, 205 S. 2. Wolfgang Schill/Gerhard Tulodziecki/Wolf-Rüdiger Wagner (Hrsg.): Medienpädagogisches Handeln in der Schule. Opladen: Leske + Budrich 1992. 327 S.

Gerard Kahn: Janusz Korczak und die jüdische Erziehung. Janusz Korczaks Pädagogik auf dem Hintergrund seiner jüdischen Herkunft. Deutscher Studien Verlag 2. Aufl. 1993 [Rezension]

Rezension von: Gerard Kahn: Janusz Korczak und die jüdische Erziehung. Janusz Korczaks Pädagogik auf dem Hintergrund seiner jüdischen Herkunft. Deutscher Studien Verlag 2. Aufl. 1993, 164 S.

EMMA 2--a MAGE-compliant system for the collaborative analysis and integration of microarray data

Background: Understanding transcriptional regulation by genome-wide microarray studies can contribute to unravel complex relationships between genes. Attempts to standardize the annotation of microarray data include the Minimum Information About a Microarray Experiment (MIAME) recommendations, the MAGE-ML format for data interchange, and the use of controlled vocabularies or ontologies. The existing software systems for microarray data analysis implement the mentioned standards only partially and are often hard to use and extend. Integration of genomic annotation data and other sources of external knowledge using open standards is therefore a key requirement for future integrated analysis systems. Results: The EMMA 2 software has been designed to resolve shortcomings with respect to full MAGE-ML and ontology support and makes use of modern data integration techniques. We present a software system that features comprehensive data analysis functions for spotted arrays, and for the most common synthesized oligo arrays such as Agilent, Affymetrix and NimbleGen. The system is based on the full MAGE object model. Analysis functionality is based on R and Bioconductor packages and can make use of a compute cluster for distributed services. Conclusion: Our model-driven approach for automatically implementing a full MAGE object model provides high flexibility and compatibility. Data integration via SOAP-based web-services is advantageous in a distributed client-server environment as the collaborative analysis of microarray data is gaining more and more relevance in international research consortia. The adequacy of the EMMA 2 software design and implementation has been proven by its application in many distributed functional genomics projects. Its scalability makes the current architecture suited for extensions towards future transcriptomics methods based on high-throughput sequencing approaches which have much higher computational requirements than microarrays.

(SP,SP)-(–)-(E)-1,2-Bis(methyl­phenyl­phosphino­yl)ethene

The title compound, C(16)H(18)O(2)P(2), possesses two stereogenic P atoms and shows a distorted s-cis conformation of each O=P-C=C moiety. This has been suggested on the basis of the stereochemical result of 1,3-dipolar cyclo-additions with nitro-nes and is now confirmed by the present crystal structure analysis. There are two crystallographically independent molecules in the asymmetric unit.

Durability of Ag-TiO(2) Photocatalysts Assessed for the Degradation of Dichloroacetic Acid

The stability of Ag-TiO(2) photocatalysts was examined for the photocatalytic degradation of dichloroacetic acid (DCA) as a function of the recycling times. The photocatalytic activity was investigated by measuring the rate of H(+) ions released during the photodegradation of DCA and confirmed by measuring the total organic carbon removal. The photodegradation reactions were studied at pH 3 and pH 10 for a series of Ag-TiO(2) photocatalysts as different with Ag loadings. All the Ag-TiO(2) and bare TiO(2) photocatalysts showed a decrease in photocatalytic activity on recycling for the DCA photodegradation reaction. The decrease in activity can be attributed to poisoning of active sites by Cl(-) anions formed during the photocatalytic DCA degradation. The photocatalytic activity was, however, easily recovered by a simple washing technique. The reversibility of the poisoning is taken as evidence to support the idea that the recycling of Ag-P25 TiO(2) photocatalysts does not have a permanent negative effect on their photocatalytic performance for the degradation of DCA. The choice of the preparation procedure for the Ag-TiO2 photocatalysts is shown to be of significant importance for the observed changes in the photocatalytic activity of the Ag-TiO2 particles. Copyright (C) 2008 Victor M. Menendez-Flores et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

[3 + 2]-Cycloadditions of nitrile ylides after photoactivion of vinyl azides under flow conditions

The photodenitrogenation of vinyl azides to 2H-azirines by using a photoflow reactor is reported and compared with thermal formation of 2H-azirines. Photochemically, the ring of the 2H-azirines was opened to yield the nitrile ylides, which underwent a [3 + 2]-cycloaddition with 1,3-dipolarophiles. When diisopropyl azodicarboxylate serves as the dipolarophile, 1,3,4-triazoles become directly accessible starting from the corresponding vinyl azide. © 2013 Cludius-Brandt et al.

Martin Rothland (Hrsg.): Belastung und Beanspruchung im Lehrerberuf. Modelle, Befunde, Interventionen 2. überarbeitete Auflage. Wiesbaden: Springer VS 2013 (286 S.) [Rezension]

Rezension von: Martin Rothland (Hrsg.): Belastung und Beanspruchung im Lehrerberuf. Modelle, Befunde, Interventionen 2. überarbeitete Auflage. Wiesbaden: Springer VS 2013 (286 S.; ISBN 978-3-5311-8246-9)

Variabilidade espacial da resistência mecânica do solo à penetração sobre a produtividade do milho 2ª safra.

2016

Valores críticos de resistência à penetração em diferentes conteúdos de água do solo na sucessão soja/milho 2ª safra.

2016