Symmetry reduction due to gallium substitution in the garnet Li6.43(2)Ga0.52(3)La2.67(4)Zr2O12
| Data(s) |
2016
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|---|---|
| Resumo |
Single-crystal structure refinements on lithium lanthanum zirconate (LLZO; Li7La3Zr2O12) substituted with gallium were successfully carried out in the cubic symmetry space group I [Formula: see text]3d. Gallium was found on two lithium sites as well as on the lanthanum position. Due to the structural distortion of the resulting Li6.43(2)Ga0.52(3)La2.67(4)Zr2O12 (Ga-LLZO) single crystals, a reduction of the LLZO cubic garnet symmetry from Ia[Formula: see text] d to I [Formula: see text]3d was necessary, which could hardly be analysed from X-ray powder diffraction data. |
| Identificador | |
| Idioma(s) |
eng |
| Publicador |
Chester : International Union of Crystallography |
| Relação |
http://dx.doi.org/10.1107/S2056989016001924 ISSN:2056-9890 |
| Direitos |
CC-BY 2.0 https://creativecommons.org/licenses/by/2.0/ frei zugänglich |
| Fonte |
Acta crystallographica. Section e, crystallographic communications 72 (2016) Pt. 3 |
| Palavras-Chave | #crystal structure #garnet #lithium lanthanum zirconate (LLZO) #symmetry reduction #ddc:500 |
| Tipo |
status-type:publishedVersion doc-type:article doc-type:Text |
