582 resultados para Clinopyroxene


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Spinel harzburgites from ODP Leg 209 (Sites 1272A, 1274A) drilled at the Mid-Atlantic ridge between 14°N and 16°N are highly serpentinized (50-100%), but still preserve relics of primary phases (olivine >= orthopyroxene >> clinopyroxene). We determined whole-rock B and Li isotope compositions in order to constrain the effect of serpentinization on d11B and d7Li. Our data indicate that during serpentinization Li is leached from the rock, while B is added. The samples from ODP Leg 209 show the heaviest d11B (+29.6 to +40.52 per mil) and lightest d7Li (-28.46 to +7.17 per mil) found so far in oceanic mantle. High 87Sr/86Sr ratios (0.708536 to 0.709130) indicate moderate water/rock ratios (3 to 273, on the average 39), in line with the high degree of serpentinization observed. Applying the known fractionation factors for 11B/10B and 7Li/6Li between seawater and silicates, serpentinized peridotite in equilibrium with seawater at conditions corresponding to those of the studied drill holes (pH: 8.2; temperature: 200 °C) should have d11B of +21.52 per mil and d7Li of +9.7 per mil. As the data from ODP Leg 209 are clearly not in line with this, we modelled a process of seawater-rock interaction where d11B and d7Li of seawater evolve during penetration into the oceanic plate. Assuming chemical equilibrium between fluid and a rock with d11B and d7Li of ODP Leg 209 samples, we obtain d11B and d7Li values of +50 to +60 per mil, -2 to +12 per mil, respectively, for the coexisting fluid. In the oceanic domain, no hydrothermal fluids with such high d11B have yet been found, but are predicted by theoretical calculations. Combining the calculated water/rock ratios with the d7Li and d11B evolution in the fluid, shows that modification of d7Li during serpentinization requires higher water/rock ratios than modification of d11B. Extremely heavy d11B in serpentinized oceanic mantle can potentially be transported into subduction zones, as the B budget of the oceanic plate is dominated by serpentinites. Extremely light d7Li is unlikely to survive as the Li budget is dominated by the oceanic crust, even at small fractions.

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Concentrations of dark-colored, highly vesicular, quench-textured mesostasis occur commonly in volcanic rocks drilled in the Lau Basin during Leg 135. These segregations occur as veins, patches, and vesicle linings in rocks with 49%-54% SiO2. The segregations are depleted in Mg, Ca, Al, Sc, Ni, and Cr and enriched in Ti, Ba, Y, and Zr compared to the groundmass with which they occur. Many of the segregations are unusually enriched in copper. The elemental variations show that the segregations are residual liquids produced by 12%-55% crystallization of plagioclase and clinopyroxene, with minor olivine, opaques, or orthopyroxene from the groundmass melt. The liquids forming the segregations are mobilized and emplaced in earlier formed vesicles during the rapid crystallization of the groundmass. The dominant process in this mobilization and emplacement is volatile exsolution from crystallizing melts constrained by a rigid crystalline framework. This exsolution produces significant overpressures within the late-stage melts; the overpressure drives the residual melts through the walls of the older vesicles, along planes of weakness, and into voids. This mechanism is consistent with the occurrence of bimodal vesicle populations in many of the host lavas.

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Rocks of the lower sheeted dike complex of Hole 504B sampled during Leg 140 were analyzed for major and trace element compositions to investigate the effects of igneous processes and hydrothermal alteration on the compositions of the rocks. The rocks are relatively uniform in composition and similar to the shallower dikes. They are moderately evolved mid-ocean-ridge basalts (MORB) with relatively high MgO (7.9-10 wt%) and Mg# (0.60-0.70), and have unusually low incompatible element contents (TiO2 = 0.42-1.1 wt%, Zr = 23-62 ppm). Discrete compositional intervals in the hole reflect varying degrees of differentiation, and olivine and plagioclase accumulation in the rocks, and may be related to injection of packets of dikes having similar compositions. Systematic depletions of total REE, Zr, Y, TiO2, and P2O5 in centimeter-size patches are most likely attributed to exclusion of highly differentiated, late-stage interstitial liquids from small portions of the rocks. The rocks exhibit increased H2O+ reflecting hydrothermal alteration. Replacement of primary plagioclase by albite and oligoclase led to local gains of Na2O, losses of CaO, and slightly positive Eu anomalies. Some mobility of P2O5 led to minor increases and decreases in P2O5 contents, and some local mobility of Ti may have occurred during alteration of titanomagnetite to titanite. Higher temperatures of alteration in the lower sheeted dikes led to breakdown of pyroxene and sulfide minerals and losses of Zn, Cu, and S to hydrothermal fluids. Later addition of anhydrite to the rocks in microfractures and replacing plagioclase caused local increases in sulfur contents. The lower sheeted dikes are a major source of metals to hydrothermal fluids for the formation of metal sulfide deposits on and within the seafloor.

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Ocean Drilling Program Hole 990A penetrated 131 m of subaerially emplaced Paleocene flood basalts on the Southeast Greenland margin with a recovery of 74%. Shipboard P-wave velocity (Vp), density, and magnetic susceptibility were measured with 2- to 15-cm intervals on the core. Individual flow units were divided into four zones based on the observed petrophysical characteristics. From the top, these are Zone I (<7 m thick with a Vp of ~2.5 km/s), Zone II (3-5 m thick with a strongly increasing Vp from 2.5 to 5.5 km/s), Zone III (up to 20 m thick with a Vp of ~5.5-6.0 km/s), and Zone IV (<2 m thick with a strongly decreasing Vp from 6.0 to 2.5 km/s). Eighteen samples were selected from three of the fourteen penetrated basalt units for geochemical, petrological, and petrophysical studies focusing on the altered, low-velocity upper lava Zones I and II. Zone I is strongly altered to >50% clay minerals (smectite) and iron hydroxides, and the petrophysical properties are primarily determined by the clay properties. Zone II is intermediately altered with 5%-20% clay minerals, where the petrophysical properties are a function of both the degree of alteration and porosity variations. Shipboard and shore-based measurements of the same samples show that storage permanently lowers the elastic moduli of basalt from Zones I to III. This is related to the presence of even small quantities of swelling clays. The data show that alteration processes are important in determining the overall seismic properties of flood basalt constructions. The degree and depth of alteration is dependent on the primary lava flow emplacement structures and environment. Thus, the interplay of primary emplacement and secondary alteration structures determine the elastic properties of basalt piles. Rock property theories for sand-clay systems are further used to model the physical property variations in these altered crystalline rocks.

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During the last 8 m.y. the Papuan Peninsula region of Papua New Guinea has been affected by extension which opened the Woodlark Basin. The present-day spreading tip is located at the foot of the Moresby Seamount, a crustal block whose northern flank is an active low-angle normal fault related to this extension. During Ocean Drilling Program Leg 180 (7 June-11 August 1998), 11 sites (1108-1118) were drilled along a north-south-trending transect across the Woodlark Basin just ahead of the spreading tip. Four of these sites (1118, 1109, 1114, and 1117) reached the crystalline basement, which is composed of diabase and gabbro. Sites 1118 and 1109, located on the Woodlark Rise, belong to the hanging wall block, and Sites 1114 and 1117, located on the crest of the Moresby Seamount, belong to the footwall block and the fault zone itself. Most of the basalt, diabase, and gabbro that were recovered show a well-preserved magmatic texture. The diabase, which is the most abundant rock type, has a coarse-grained ophitic texture composed of poikilitic clinopyroxene including radiating, locally skeletal plagioclase laths with interstitial iron oxide grains. Secondary mineralogy consists of chlorite, zeolite, calcite, albite, and quartz. The gabbro shows a medium-grained granular texture. The magmatic mineralogy consists of euhedral laths of plagioclase and anhedral interstitial clinopyroxene. Secondary mineralogy consists of a magnesio to actinolitic hornblende, chlorite, clinozoisite, zeolite, quartz, and calcite. The retrograde metamorphic evolution of both gabbro and diabase occurred under low amphibolite to subgreenschist facies conditions associated mainly with brittle deformation and the development of a local low-temperature shear zone. This shows no evidence for high thermal gradient in the crust during the continental rifting.

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In northeastern Siberia, Russia, a 1.2 m sediment core was retrieved and radiocarbon dated from a small and shallow lake located at the western side of the lower Lena River (N 69°24', E 123°50', 81 m a.s.l.). The objective of this paper is to reconstruct the palaeoenvironmental variability and to infer major palaeoclimate trends that have occurred since ~ 13.3 cal. kyrs BP. We analysed the diatom assemblages, sedimentology (grain size, total organic carbon (TOC), total nitrogen (TN)), and the elemental and mineralogical composition using X-ray fluorescence (XRF) and X-ray diffractometry (XRD) of the sediment core. Our results show parallel changes in the diatom species composition and sediment characteristics. Enhanced minerogenic sediment input and the occurrence of pyrite is indicative of a cold period between ~ 12.7-11.6 cal. kyrs BP. The diatom data enable a qualitative inference about the local ecological conditions to be made, and reveal an oligotrophic lake system with alkaline and cold conditions during the earliest Holocene. Moderately warmer climates are inferred for the period from ~ 9.1 to 5.7 cal. kyrs BP. The major shift in the diatom assemblage, from dominance of small benthic fragilarioid taxa to a more complex diatom flora with an influx of several achnanthoid and naviculoid diatom species, occurred after a transitional period of about 1400 years (7.1 to 5.7 cal. kyrs BP) at ~ 5.7 cal. kyrs BP, indicating a circumneutral and warmer hydrological regime during the Holocene thermal maximum (HTM). Diatom valve concentrations declined starting ~ 2.8 cal. kyrs BP, but have been rising again since less than or equalt to 600 cal. years BP. This has occurred in parallel to the increased presence of acidophilous diatom taxa (e.g. Eunotia spp.) and decreased presence of small benthic fragilarioid species in the most recent sediments, which is interpreted as the result of neoglacial cooling and subsequent recent climate warming. Our findings are compared to other lake-inferred climate reconstructions along the Lena River. We conclude that the timing and spatial variability of the HTM in the lower Lena River area reveal a temporal delay from north to south.

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Focussing on heavy-mineral associations in the Laptev-Sea continental margin area and the eastern Arctic Ocean, 129 surface sediment samples, two short and four long gravity cores have been studied. By means of the accessory components, heavy-mineral associations of surface sediment samples from the Laptev-See continental slope allowed the distinction into two different mineralogical provinces, each influenced by fluvial input of the Siberian river Systems. Transport pathways via sea ice from the shallow shelf areas into the Arctic Ocean up to the final ablation areas of the Fram Strait can be reconstructed by heavy-mineral data of surface sediments from the central Arctic Ocean. The shallow shelf of the Laptev Sea seems to be the most important source area for terrigenous material, as indicated by the abundant occurence of amphiboles and clinopyroxenes. Underneath the mixing Zone of the two dominating surface circulation Systems, the Beaufort- Gyre and Transpolar-Drift system, the imprint of the Amerasian shelf regions up to the Fram Strait is detectable because of a characteristical heavy-mineral association dominated by detrital carbonate and opaque minerals. Based On heavy-mineral characteristics of the potential circum-Arctic source areas, sea-ice drift, origin and distribution of ice-rafted material can be reconstructed during the past climatic cycles. Different factors controlling the transport of terrigenous material into the Arctic Ocean. The entrainment of particulate matter is triggered by the sea level, which flooded during highs and lows different regions resulting in the incorporation of sediment from different source areas into the sea ice. Additionally, the fluvial input even at low stands of sea level is responsible for the delivery of material of distinct sources for entrainment into the sea ice. Glacials and interglacials of climate cycles of the last 780 000 years left a characteristical signal in the central Arctic Ocean sediments caused by the ice- rafted material from different sources in the circum-Arctic regions and its change through time. Changes in the heavy-mineral association from an amphibole-dominated into a garnet-epidote-assemblage can be related to climate-related changes in source areas and directions of geostrophic winds, the dominating drive of the sea-ice drift. During Marine Isotope Stage (MIS) 6, the central Arctic Ocean is marked by an heavy-mineral signal, which occurs in recent sediments of the eastern Kara Sea. Its characteristics are high amounts of epidote, garnet and apatite. On the other hand, during the Same time interval a continuous record of Laptev Sea sediments is documented with high contents of amphiboles on the Lomonosov Ridge near the Laptev Sea continental slope. A nearly similar Pattern was detected in MIS 5 and 4. Small-scale glaciations in the Putorana-mountains and the Anabar-shield may have caused changes in the drainage area of the rivers and therefore a change in fluvial input. During MIS 3, the heavy-mineral association of central Arctic sediments show similar patterns than the Holocene mineral assemblage which consists of amphiboles, ortho- and clinopyroxenes with a Laptev Sea source. These minerals are indicating a stable Transpolar-Drift system similar to recent conditions. An extended influence of the Beaufort Gyre is only recognized, when sediment material from the Amerasian shelf areas reached the core location PS2757-718 during Termination Ib. Based On heavy-mineral data from Laptev-Sea continental slope Core PS2458-4 the paleo-sea-ice drift in the Laptev Sea during 14.000 years was reconstructed. During Holocene sea-level rise, the bathymetrically deeper parts of the Western shelf were flooded first. At the beginning of the Atlantic stage, nearly the entire shelf was marine influenced by fully marine conditions and the recent surface circulation was established.

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Mineralogical (microprobe) and geochemical (X-ray fluorescence, neutron activation analyses) data are given for 18 samples of volcanic rocks from the Guatemala Trench area (Deep Sea Drilling Project Leg 67). Typical fresh oceanic tholeiites occur in the trench itself (Hole 500) and in its immediate vicinity on the Cocos Plate (Site 495). Several samples (often reworked) of "spilitic" oceanic tholeiites are also described from the Trench: their mineralogy (greenschist facies association - actinolite + plagioclase + chlorite) and geochemistry (alteration, sometimes linked to manganese and zinc mineralization) are shown to result from high-temperature (300°-475°C) hydrothermal sea water-basalt interactions. The samples studied are depleted in light rare-earth elements (LREE), with the exception of the slightly LREE-enriched basalts from Hole 500. The occurrence of such different oceanic tholeiites in the same area is problematic. Volcanic rocks from the Guatemala continental slope (Hole 494A) are described as greenschist facies metabasites (actinolite + epidote + chlorite + plagioclase + calcite + quartz), mineralogically different from the spilites exposed on the Costa Rica coastal range (Nicoya Peninsula). Their primary magmatic affinity is uncertain: clinopyroxene and plagioclase compositions, together with titanium and other hygromagmaphile element contents, support an "active margin" affinity. The LREE-depleted patterns encountered in the present case, however, are not frequently found in orogenic samples but are typical of many oceanic tholeiites.

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Seven sites were drilled during Leg 67 along a transect across the Middle America Trench off Guatemala: four (Sites 494, 496, 497, and 498) on continental slope, two (Sites 499 and 500) on Trench floor, and one (Site 495) on the Cocos Plate. We studied the mineralogy of sediments from Sites 494, 495, 496, 499, and 500. Our objective was to investigate the origin and source of separate minerals and mineral assemblages, giving special attention to the influence of the alteration of basalts on the sediment mineralogy, which we expected to be particularly important in layers just above oceanic basement.

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Dissertação (mestrado)—Universidade de Brasília, Instituto de Geociências, Pós-Graduação em Geologia, 2015.

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Calbuco Volcano, in Southern Chile, has eruptive products of predominantly andesitic hornblende-bearing lava. A purpose of this work is to understand magmatic processes and how Calbuco magma chemistry is related to the explosive volcanic character. Calbuco lava has a mineral assemblage of plagioclase, hornblende, orthopyroxene, clinopyroxene, olivine, and magnetite and entrained gabbroic xenoliths with the same mineral assemblage. The presence of hornblende is evidence for dissolved water in the magma. Detailed petrographic/textural analysis has been done using petrographic microscopy and back-scattered electron imaging (BSE); geochemical analysis by electron microprobe (EPMA). Major findings include 1) that hornblende and hornblende-bearing gabbroic cumulates crystallize from Calbuco magma, 2) that plagioclase grains are compositionally zoned, recording evidence of temperature, chemical, and water content fluctuations in the magma, and 3) that hornblende is unstable under upper magma chamber conditions at Calbuco, and is breaking down into plagioclase, olivine, orthopyroxene, clinopyroxene, and magnetite in the magma.