609 resultados para hidrocarbonetos policíclicos aromáticos
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High fuel consumption and its inadequate control in fuel stations caused the pollution of soil and aquifers. These consequences created more concern with the increased exploration of aquifers to supply the groundwater demand. The objective of this study was to evaluate the eficiency and efectiveness of the of pump and treat technique of the water applied to the Coastal Aquifer in the cleaning up of the plumes produced by the leaking of fuel in the gas station Auto Posto Baía do Sol Ltda. The gas station is located in São Sebastião, in the north coast of São Paulo State. In the case of Auto Posto Baía do Sol Ltda., the technique of pump and treat was eficient and the plume produced by the leakage was completely removed. However, the efectiveness of this technique was low due to the long time required for the complete operation.
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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Pós-graduação em Ciência dos Materiais - FEIS
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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The contamination of the physical environment occurs as a result of the lack of planning and inadequate management of hazardous products. Due to the difficulty of the characterization and study of soil and groundwater, the contamination has been long neglected. The characterization of these areas by research techniques through direct methods such as physical and chemical analysis, are widely used in the diagnosis and monitoring. However, despite presenting quantitative results, this method is not representative in spatial terms. The purpose of this work is to bring geophysical complementation with the diagnosis, bringing the spatial element for the detection of the contamination plume. In the study area, there was a railway accident in 1999 in which three wagons fell and spilled 240,000 L of diesel onto the soil. The main objective is to assess the presence of contaminants in the residual phase and dissolved in the subsurface, using the technique of Electrical Tomography (ETR), understand the effects of natural attenuation process in the degradation of hydrocarbons and changes in electrical properties in soil and groundwater. The results allowed the definition of three distinct patterns of resistivity region with presence of dissolved phase, set in a historical chemical analyzes: low values (> 60Ω.m) associated with the presence of hydrocarbons in an advanced stage of degradation, intermediate values (260Ω.me 511Ω .m) indicative of coexistence of residual hydrocarbons and dissolved phase, and high values (> 1000Ω.m), which reveal the prevalence of residual phase with incipient degradation, possibly in high toxicity concentrations for effective action of biodegradation processes. The diagnostic of areas with potential accumulation of residual phase can subsidize the planning of remediation techniques and promote the complete decontamination of the area
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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The constant petrol fuel leak in gas stations has caused concern in many countries around the world. Those fuels have toxic organic compounds in their composition, like Polycyclic Aromatic Hydrocarbons (PAH), which are harmful to the human health. In this work the efficiency of the protection layer with a High Density Polyethylene (HDPE) membrane of 2.5 mm thickness was evaluated. The study was based in the diffusive process in the intact membrane by a permeameter developed to evaluate the diffusive process. The membrane was putted in the middle of the system to separate two sides: a local soil impregnated with diesel oil (in one side) and pure water (in the other side). The chromatography technique was conducted to evaluate the contamination in the pure water. The analyses were made monthly in a total period of 6 months of research. The results tests show that the membrane was less effective to antracene and naphthalene compounds. Despite that, the results showed that the HDPE membrane is a good alternative to prevent contamination of water and soil by the compounds under study up to one year, based on the performance in the time of study.
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)