A Concise Approach to a Gelsemine Core Structure using an Oxygen to Carbon Bridge Swapping Strategy

A tricyclic core structure related to gelsemine was synthesized from an oxabicyclo[3.2.1]octanone by a three-step bridge swapping strategy involving elimination of the bridging ether oxygen and intramolecular Michael addition of a tethered cyanoacetamide unit.

Research on Ultimate Loading Carrying Capacities in Concrete Bridge Deck Slabs with Consideration of Compressive Membrane Action

In the investigation of real loading capacities in concrete bridge deck slabs,the study of this type of structure was carried out with consideration of compressive membrane action.A series of experimental test of steel-concrete bridge structures was developed with the analysis of influences from the varying of structural parameters on loading capacities,including reinforcement percentages,supporting beam sizes and concrete compressive strength.Through the study of the experimental results,it was found that the real structural loading capacities are larger than those predicted by current design methods.Therefore,based on the previous research,a prediction method for loading capacities of concrete bridge deck slabs was established with consideration of CMA,which was built based on the plastic ultimate analysis.In this method,the lateral restraint stiffness subjected by concrete bridge deck slabs was provided.The proposed theoretical model is capable of predicting the loading capacities of this type of structure accurately with comparison of results from several bridge deck experimental tests.

Sustainable bridge construction through innovative advances

Sustainability is now recognised as a key issue that must be addressed in the design, construction and lifelong maintenance of civil engineering structures. This paper briefly discusses the generic aspects of sustainability, but the main focus is its application to bridges. Motorway bridges built in the 1960s and 1970s had design lives of 120 years; many, however, were showing signs of deterioration after only 20–40 years. This led to much (ongoing) debate on the issue of initial versus full life-cycle costing. In order to address the highly complex issue of the sustainability of bridges, this paper considers the following specific areas that impinge on this important subject: the impact on sustainability of different forms of bridge construction and maintenance/repair/replacement strategies; the utilisation of innovative in situ testing equipment for assessing the long-term durability of concrete; the development of innovative structural designs for bridges that inherently have greatly extended lives at minimal, if any, additional cost.